100%(1)100% нашли этот документ полезным (1 голос)
303 просмотров31 страница
India is the fifth largest producer of steel in the world with a crude steel production of 50. Million tonnes per annum. Steel making involves removal of impurities as their respective oxides (except sulphur which is reduced) the oxides are eliminated either as gas (e.g. Carbon as carbon monoxide) or as liquid oxide product of suitable chemical character known as slag. Steel can be produced efficiently only if refining is adequate i.e. Right quality slag is made and clean
India is the fifth largest producer of steel in the world with a crude steel production of 50. Million tonnes per annum. Steel making involves removal of impurities as their respective oxides (except sulphur which is reduced) the oxides are eliminated either as gas (e.g. Carbon as carbon monoxide) or as liquid oxide product of suitable chemical character known as slag. Steel can be produced efficiently only if refining is adequate i.e. Right quality slag is made and clean
Авторское право:
Attribution Non-Commercial (BY-NC)
Доступные форматы
Скачайте в формате PDF, TXT или читайте онлайн в Scribd
India is the fifth largest producer of steel in the world with a crude steel production of 50. Million tonnes per annum. Steel making involves removal of impurities as their respective oxides (except sulphur which is reduced) the oxides are eliminated either as gas (e.g. Carbon as carbon monoxide) or as liquid oxide product of suitable chemical character known as slag. Steel can be produced efficiently only if refining is adequate i.e. Right quality slag is made and clean
Авторское право:
Attribution Non-Commercial (BY-NC)
Доступные форматы
Скачайте в формате PDF, TXT или читайте онлайн в Scribd
The iron and steel industry enjoys a high priority in the
development plans of most countries , primarily because of the significant role of steel in their industrial development and economic growth. India's ranking in terms of per capita consumption of steel is at the 15th position internationally at 39 Kg. From a crude steel output of 6.5 million tonnes since 1965 – 66, India is now the fifth largest producer of steel in the world with a crude steel production of 50.85 million tonnes per annum superseded only by China, Japan, USA and Russia. The growth from 2005 to 2006 had been a phenomenal 11.4%. The role played by steel in the economic development of a country can be visualized from the fact that even countries who do not possess any raw materials have gone ahead with bold plans of steel development based on imported raw materials. MODERN STEELMAKING - BASICS
Steel making involves removal of impurities as their
respective oxides (except sulphur which is reduced). The oxides are eliminated either as gas (e.g. Carbon as carbon monoxide) or as liquid oxide product of suitable chemical character known as slag. Steel can be produced efficiently only if refining is adequate i.e. Right quality slag is made and clean slag and metal separation is brought about. Except sulphur, all the rest (carbon, silicon, manganese, phosphorus) are removed through oxidation processes and are favoured under oxidizing conditions of steel making. The present requirement of sulphur in steel is more stringent as continuous casting is invariably adopted to convert liquid steel into billets/blooms with a sulphur level of around 0.02% to avoid transverse cracking. It is universally accepted that very low sulphur contents can only be produced through modern and efficient external de-sulphurisation techniques for hot metal from blast furnaces. Calcium carbide and magnesium bearing reagents injected with a carrier gas are found to lower down sulphur to extremely low levels. MODERN STEELMAKING - HISTORY
Modern steel making is supposed to have begun
with the advent of the Bessemer process of steelmaking in the 1860s in the UK. This was followed by open hearth processes, but its productivity could not exceed beyond 35 tons/hour as against that of 500 tons/hour from LD, OBM or Hybrid processes. The demands of increased productivity coupled with lower capital cost led to steelmaking in basic lined furnaces, making basic slag, using oxygen as the refining media to be generally known as basic oxygen furnace (BOF) or LD steel making. Oxygen steel making is now universally adopted for steel production since 1950s to maintain efficiency and economy, processes being faster, economical and easily controllable. MODERN STEELMAKING – BOF/LD STEEL MAKING In an LD refining is complete in about 20 - 25 minutes of oxygen blowing and a tap to tap time of 40 to 60 minutes is needed. The oxidizing conditions in LD are not conducive to desulphurisation. External desulphurisation of molten iron in transfer ladles is the answer. Major steel plants around the world have adopted this process to achieve a sulphur level below 0.001%. Use of multi hole lances (4 to 7 hole lances) in larger converters has cut down blowing time, improved the yield and increased lining life. However, 90% of phosphorus in the metal is removed in LD to 0.025%. Lining life of 1000 heats are now common. Lining life of tarred dolomite lining in LD at TATA steel has achieved the international norm of 1200 heats with consequent cost advantages amounting to almost Rs.175-200/Ton of liquid steel. Methods have been devised for continuous monitoring of carbon and temperature during the blow and make mid- course corrections to attain correct turn- down conditions. Heat times need to be further improved. Compared to 30 to 40 minutes obtained in large converters in other countries, the heat time in India is around one hour. By intensifying blowing rates, improving operating practices and cutting down delays, it should be possible to reduce heat time to 40 to 50 minutes. This is significant as even a one minute saving means an increase in production by 2%. From less than 3 million tonnes in 1957, there has been a spectacular rise in world LD capacity to more than 50% of the total world production of 1244 million tons. The changing pattern of steel making and the increasing share of LD steel are illustrated in FIG 1. CHANGING PATTERN OF STEELMAKING MODERN STEEL MAKING – OBM/HYBRID STEEL MAKING Modifications to the basic LD process (generally known as BOF) came in the form of OBM process where oxygen with fluxes are blown through the bottom of the vessel. Further modification led to hybrid blowing where top and bottom blowing simultaneously with oxygen has been successfully used and has the potential of being the favoured process for future steel making. The OBM process (oxygen bottom maxhutte) developed in Germany in 1967 claim inherent advantages of a quieter blow and better mixing that could be gained by blowing pure oxygen through converter bottom along with an endothermic shielding of the oxygen stream with propane/ natural gas to protect converter bottom refractories. The proven advantages of the OBM process over other oxygen steel making process are : Installation cost advantage - of OBM over BOF is between 5% to 8% for a new facility. - Lower vessel size (0.6 cum/ton of steel as against 0.8 cum/ton of steel in case of BOF). - Low structural cost (no high bay furnace aisle, no complex elevated bin system). Improved yield and lower material usage: - 1.5% to 2% higher yield due to less FeO in slag. - Better Recovery of ferro alloys due to lower oxygen level in bath. - 5% - 10% lower oxygen requirement due to intimate and thorough mixing of oxygen in bath. Product quality: - Phosphorus and sulphur removal very effective. Production rate: - Use of oxygen blowing rate 25% higher then BOF of same capacity shortens tap to tap time with consequent increase in production rate by 10% compared to BOF. - Higher metallic yields contribute to increased productivity. MODERN STEELMAKING – ELECTRIC ARC FURNACE (EAF) STEELMAKING Steelmaking through EAF became a commercial practice at the beginning of the last century. In EAF oxidizing and reducing conditions can be maintained at will during refining and a variety of steels can be manufactured with very low sulphur and phosphorus. In view of the availability of power and that too at competitive rates with respect to other fuels like oil, oxygen, bigger EAF have come to use. From a share of 8% in 1950, EAF share in total global steel production is now more than 30%. This share is likely to go up in view of the increasing cost of fuel vis-a-vis power. New EAFs are coming up for production of even mild steels with: Design Modification - Rapid melting technology - Water cooled panels - Eccentric shell with bottom tapping - Emission / noise control Process Modification - Coupling with ladle refining furnace (LRF, VOD, AOD, etc.) - Process automation - Foamy slag practice Charge Modification - Use of hot metal - Use of DRI (sponge iron) Capacities have increased to compete with other steel making processes to obtain desired economy of production. Use of ultra high power (UHP) in place of regular power supply results in saving of melting time (30%) and of refining time (10%). Very often UHP furnaces are used for melting coupled with LRF for final refining. Net total transformer rating in coupled condition is much lower. Roof inserted water- cooled lance for injecting oxygen in large EAF bring in economy in manufacture. Use of hot metal from blast furnace along with sponge iron result in reduced power consumption for overall economy. Heat time is not affected in an EAF when sponge iron used has a metalization of more than 92%. Hot metal and sponge iron in EAF route is 30-40% cheaper then hot metal and BOF combination for equivalent production capacity. The clear advantages of the EAF are: - Yield nearly 91% - Furnace availability 96% - Favourable cost pattern of electrical energy - Wide range of furnace capacity - Flexibility in terms of irregular production MODERN STEEL MAKING – INDUCTION FURNACE STEEL MAKING For steel making, medium and high frequency induction furnaces are universally adopted. It is essentially a process of melting and hardly any refining take place, a process wherein what goes in must come out. Thin layer of dry slag (works as insulating cover) does not take part in refining. Limited holding capacity and inability to control the composition of the melt except through careful selection of scrap appear as the chief draw backs of the induction furnace from metallurgical and commercial viewpoints. In spite of inherent inadequacies as a melting unit for making quality steel, growth in mild steel capacity through induction furnace melting in India has been a phenomenal 26% in 2005 – 06 over 2004 – 05 as against 7% through EAF melting. During 2006-07 Mini Steel plants contributed 25.20 million tonnes out of a total of 50.85 million tons produced in India. EAF's share was 9.8 million tons. The rest 15.40 million tons being from induction furnace. A record number of 787 induction furnace unit were in existence in 2005-06, secondary refining being absent in most cases. Except the Indian subcontinent, nowhere in the world basic quality steelmaking employ the induction furnace route. This stems from the fact that lot of small time steel players have adopted this route involving low capital cost and lower manufacturing cost. Under the existing conditions, manufacture of steel through DRI route employing induction furnace as the only melting unit can not achieve the norms set by the relevant BIS standards. MODERN STEELMAKING – QUALITY AND COST Quality means attaining desired specification with respect to: Chemical composition Cleanliness Gas content Cost is substantially affected by energy consumption and cost of raw materials e.g. Use hot metal in EAF has a distinct cost advantage. Whole efficiency of a steelmaking shop can be broadly assessed in terms of Production Rate Yield Quality of Production Refractory Consumption LOOKING AHEAD -GROWTH PROSPECTS– IRON AND STEEL INDUSTRY IN INDIA While contributing almost 6% of the GNP, crude steel production has grown at a CAGR (cumulative annual growth rate) of 10.5% while capacity has shown a 7.5% growth over a period of 5 years between 2001-02 to 2005-06. Given the pace and scale of infrastructure/ construction activities, prospects of future growth in the steel industries is directly linked with the growth in its downstream industries i.e. Re-rolling. The most notable aspect is of course the entry of global steel majors POSCO, Mittal Steel and others to set up steel plants in the country, which are expected to alter the dynamics of the Indian Iron and Steel Industry upon commencement. India has attained the status of the fifth largest crude steel producer in the world in 2007 and this status will be positively affected once these expansion projects become operational. The National Steel Policy has laid down the long– term vision of growth for the Indian steel Industry and domestic steel entrepreneurs are pursuing an expansion plan that is ambitious by all standards. The Vision: 110 million tonnes of steel production by 2019 - 20. SUGGESTED BIBLIOGRAPHY Making, Shaping and Treating of Steel, an ASTM Publication. An Introduction to Modern Steel Making by Dr. R. H. Tupkary and V. R. Tupkary. International Symposium on “Fifty Years of Metallurgy” at BHU in December, 1973. Paper presented by Dr. M. N. Dastur on “Iron and Steel Industry in India”. The ASEA-SKF Steel Refining Process by M. Tiberg, T. Buhre, H. Herlitz of SKF Helefors Steel works IFJ, April 1966. Electric Furnace Round- Up The Magazine of Steel Producing, June 1966. Manufacture of Iron and Steel, Vol.I and II by G. R. Bashforth, An Asia Publication. M. N. Jha et. Al., Tata Search , 1994, P.15. Sanjay Kumar et. Al., Tata Search, 1994, P.35. Iron Making and Steel Making by A. Chatterjee, 1996, 23(4), P. 293.
Oxy-Acetylene Welding and Cutting: Electric, Forge and Thermit Welding together with related methods and materials used in metal working and the oxygen process for removal of carbon
Oxy-Acetylene Welding and Cutting
Electric, Forge and Thermit Welding together with related methods and materials used in metal working and the oxygen process for removal of carbon