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Abstract
Carbon dioxide removal section in ammonia plant is highly
energy intensive. Many developments have been made to
make it more energy efficient and environmental friendly.
a-MDEA process for CO2 removal is one of the best
available process to meet the specific plant conditions of
high CO2 purity, minimum H2 loss, no corrosion, low
energy requirement and low capital investment. At IFFCO
Kalol MEA CO2 removal process was revamped to direct
solution swap of a-MDEA process. Revamping of CO2
removal section was part of uprating the plant capacity for
higher production. a-MDEA process have increased the
CO2 absorption capacity and reduced the energy
requirement with no capital cost.
1.0 Introduction
Carbon dioxide is an undesirable constituent in the synthesis gas because it poisons the
ammonia synthesis catalysts. CO2 content in the synthesis gas therefore must be reduced
to 5 to 10 PPM by volume. CO2 absorption is carried out by selective absorption after the
low temperature shift conversion. The CO2 removal processes are based on chemical and
physical absorption of CO2 in a solvent. There are number of processes available to
remove CO2 from the synthesis gas. Based on the process used, the gas absorption can be
classified as Physical or Chemical absorption process.
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Physical absorption processes generally use an organic solvent which absorbs CO2 as a
function of its partial pressure. Due to high CO2 loadings, which are attainable, low
circulation rates and less utility costs are involved for these types of processes. The most
commonly used physical absorption process is Selexol process where solvent used is a
homologue of diethylether of polythelene-glycols.
The chemical absorption process can be classified in three main categories ;the hot
potassium carbonate process, the alkanolamines process and other chemical absorption
process. Commercially available Hot potassium carbonate processes are Befield process,
Glycine Vetrocoke process and Cataract process. In Alkanolamines processes solution has
an amine component. Mostly used solutions were monoethanolamine (MEA),
diethanolamine(DEA) etc. Present day most preferred solution in alkanolamines processes
is activated Methyl Diethanol Amine (a-MDEA).
Activated MDEA process for CO2 removal is a physical/chemical absorption process. It
behaves as a physical absorption process at higher partial pressure of CO2 and as a
chemical absorption process at low CO2 partial process. The bulk of the solution can be
regenerated by simple flashing, leading to very low energy consumption.
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3. Purity of CO2 in case of activated MDEA process is 99.8 % while in case of other
processes, it is about 98. 5 %. The hydrogen content in CO2 in case of activated MDEA
is less. The hydrogen content in CO2 makes explosion mixture in urea plant and higher
hydrogen increases the ammonia losses. Higher hydrogen also has an influence on
corrosion in urea process because it contributes to hydrogen penetration and consequent
destruction of oxide film.
4. Utilisation of all the existing equipments i.e. not making any changes in the system.
5. Lower energy requirement.
6. Lower MDEA make up requirement.
7. MDEA (Methyl diethanol amine) is environment friendly and biodegradable chemical.
8. MEA solution is a corrosive solution, while MDEA is non-corrosive. Hence MDEA
system does not require any corrosion inhibitor.
9. Additional refrigeration system was required for Selexol process.
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3.2.1 Low energy requirement:
With MEA system energy consumption was 36000 Kcal/kgmol of CO2 removed. With
a-MDEA, it was possible to reduce the energy consumption to 26000 Kcal/kgmole of
CO2 removed as against the design consumption figure of 32000 Kcal/kgmol of CO2
removed. The energy requirement and operating parameters of both the processes are
summarised in table-2. The 3.5 kg/cm2g steam requirement in steam reboiler remains
at 10 to 15 t/h against earlier steam consumption of 20 to 25 t/h even though CO2
removal requirement is 27% higher. 40% MDEA solution along with 6.5% piprazine is
circulated in close loop in the system. CO2 loading in rich MDEA solution remains 35
to 45 Nm3/t of solution. While CO2 loading in lean solution remains about 5 Nm3/t of
solution. After change over, iron in the circulating solution is remaining below 5 ppm.
CO2 slip in the product stream is remaining below 250 ppm (v/v).
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Also this increased higher reflux ratio, higher concentration of MDEA in reflux and higher
hydrogen concentration in product CO2. Hydrogen concentration reached as high as 1.2 to
1.4% (V/V) from 0.8 % V/V. Higher dosing of anti foamer agent did not reduce the
foaming tendency. Antifoamer consumption remained very high. Mechanical filters
provided at absorber liquid outlet, carbon filter inlet and carbon filter outlet was cleaned
and found that lot of antifoamer is being removed in the filters. Activated carbon bed was
isolated, foaming tendency reduced. With time the system has become stable, system is
working extremely well.
5.0 Conclusion
Activated MDEA process is most suitable in the plants which are using MEA CO2
removal process. IFFCO Kalol is satisfied with the operating performance, operating
reliability and low maintenance of a- MDEA system. a-MDEA system was the excellent
choice for revamping the CO2 removal section. Operation of the system is excellent and
smooth even at uprated plant load with least energy requirement.