P2

Lembar Perhitungan
Reaksi
CH3COOH + C2H5OH C2H5COOC2H5 + H2O
A B C D
o
1. Variabel 1(Suhu 50 C)

1,05 62,8 0,98 1000

CAO =
60/ 250

CAO = 4,31 mol/L

0,813 179,426 0,95 1000

CBO =
46 / 250

CBO = 12,05 mol/L

(0,42)(50,25)
CA= 5

CA = 0,084VNaOH 0,25

t (menit) Volume titran (ml) CA (mol/L) XA0

0 46 3,61 0,187
10 40,6 3,16 0,289
20 35 2,69 0,395
30 28 2,10 0,528
40 23 1,68 0,622

CA=CAO(1-XA)= 4,31(1-XA)
CB=CB0-CA0XA=12,05-4,31XA
CC=CAOXA=4,31XA
CD=CAOXA=4,31XA
C B0 12,05
= = =2,798
4,31

1
 P2

dengan

Pada Saat Kesetimbangan

K=
Konstanta kesetimbangan (Kc)
(0,622)2
K= =(10,622)(2,7980,622)=0,586

Diketahui data Gf standar (Perry, 2008)

Gf 298 CH3COOH = - 389900 J/mol
Gf 298 C2H5OH = - 174780 J/mol
Gf 298 CH3COOC2H5 = - 328000 J/mol
Gf 298 H2O = - 241814 J/mol
maka :
G 298 = (Gf 298 CH3COOC2H5 + Gf 298 H2O) - ( Gf 298
CH3COOH + Gf 298 C2H5OH )
= (-328000 - 241814) - (-389900- 174780)
= -5134J/mol
Hf reaksi = Hf produk - Hf reaktan
Diketahui data Hf standar(Perry, 2008) :
Hf 298 CH3COOH = - 484500J/mol
Hf 298 C2H5OH = - 277690J/mol
Hf 298 CH3COOC2H5 = - 480000J/mol
Hf 298 H2O = - 285830J/mol
maka :
H 298 = (Hf 298 CH3COOC2H5 + Hf 298 H2O) - ( Hf 298
CH3COOH + Hf 298 C2H5OH )
= (- 484500- 277690) - (- 480000- 285830J/mol= -3640 J/mol (eksotermis)
Dari persamaan vant Hoff (Levenspiel, 1999) :

2
 P2

G 298 = - RT ln K
-5134 J/mol = - (8,314 J/mol K).(298 K).ln
K298
ln K298 = 2,072
K298 = 7,94
harga K pada suhu 50oC (323 K ) yang sesuai dengan variabel tetap percobaan dapat
dihitung :

ln (K2/K1) =-
3640 1 1
ln (K323/K298) = [ ]
8,314 323 298
ln (K323/K298) = -0,1137
K323/0,651 = 0,89
K323 = 7,066

Mencari Nilai XA
2
= 10[(1 )( )- ]

2
= 14,31[(1 )(2,798 )- 7,066]

= 14,31[0,85842 3,798 + 2,798]


= 1[3,6992 16,369 + 12,059]


= 13,699[2 4,425 + 3,26]

1

3,699 0 (24,424+3,26)
= k

Rumus ABC
(2 4,424 + 3,26) =
2 4
2
4,424 4,4242 413,26
2
4,424 2,556
2

Sehingga didapat X1 = 3,489 dan X2 = 0.934

Maka (2 4,424 + 3,26) = (XA 3,489)(XA 0.934)

0.270 0 ( = +
3,489)( 0.934) 3,489 0,934

( 0.934)+( 3,489)
= + = ( 3,489)( 0.934)
3,489 0.934

3
 P2

A + B = 0 x -0,934

-0.934A - 3,489B = 1 x 1

B = -0.391

A = 0.390

Sehingga persamaan menjadi

0,390 0,391
0,27[0 ((XA3,489) 0 ]=k1.t
(XA0,934)

1 1
0,27[0,3900 ((XA3,489) + (XA0,934) ]=k1

(XA3,489)(0,934)
0,1053ln(XA0,934)(3,489)= k1.t=y=mx

t(x) X Y xy x2
0 0,187 0,01772 0 0
10 0,289 0,02988 0,2988 100
20 0,395 0,0452 0,904 400
30 0,528 0,0704 2,112 900
40 0,622 0,0947 3,788 1600
=100 2,021 0,2579 7,1028 3000

k1 = m = 1,944x10-3 mol/menit

K= k2=k1/K = 1,944x10-3/7,066 = 2,752x10-4 mol/menit

2. Variabel 2(Suhu Reaksi 60)

1,05 62,8 0,98 1000

CAO =
60/ 250

CAO = 4,31 mol/L

0,813 179,426 0,95 1000

CBO = 242,2
46 /

CBO = 12,05 mol/L

4
 P2

(0,42)(50,25)
CA= 5

CA = 0,084VNaOH 0,25

t (menit) Volume titran (ml) CA (mol/L) XA0

0 46 3,614 0,18695163
10 39,5 3,068 0,30978628
20 30 2,27 0,48931384
30 21 1,514 0,65939258
40 14,3 0,9512 0,78600675
CA=CAO(1-XA)= 4,31(1-XA)
CB=CB0-CA0XA=12,05-4,31XA
CC=CAOXA=4,31XA
CD=CAOXA=4,31XA
C B0 12,05
= = =2,798
4,31

dengan

Pada Saat Kesetimbangan

K=
K saat t=40 maka konstanta kesetimbangan
= 0,7862/(1-0,786)(2,798-0,786)
= 1,4348
Diketahui data Gf standar (Perry, 2008)
Gf 298 CH3COOH = - 389900 J/mol

5
 P2

Gf 298 C2H5OH = - 174780 J/mol

Gf 298 CH3COOC2H5 = - 328000 J/mol
Gf 298 H2O = - 241814 J/mol
maka :
G 298 = (Gf 298 CH3COOC2H5 + Gf 298 H2O) - ( Gf 298
CH3COOH + Gf 298 C2H5OH )
= (-328000 - 241814) - (-389900- 174780)
= -5134J/mol
Hf reaksi = Hf produk - Hf reaktan
Diketahui data Hf standar(Perry, 2008) :
Hf 298 CH3COOH = - 484500J/mol
Hf 298 C2H5OH = - 277690J/mol
Hf 298 CH3COOC2H5 = - 480000J/mol
Hf 298 H2O = - 285830J/mol
maka :
H 298 = (Hf 298 CH3COOC2H5 + Hf 298 H2O) - ( Hf 298
CH3COOH + Hf 298 C2H5OH )
= (- 484500- 277690) - (- 480000- 285830J/mol= -3640 J/mol (eksotermis)
Dari persamaan vant Hoff (Levenspiel, 1999) :
G 298 = - RT ln K
-5134 J/mol = - (8,314 J/mol K).(298 K).ln
K298
ln K298 = 2,072
K298 = 7,94
harga K pada suhu 60oC (333 K ) yang sesuai dengan variabel tetap percobaan dapat
dihitung :

ln (K2/K1) =- ln
3640 1 1
(K323/K298) = [ 298]
8,314 333
ln (K323/K298) = -0,1544
K323/0,651 = 0,856

K323 = 6,80

Mencari Nilai XA
2
= 10[(1 )( )- ]

2
= 14,31[(1 )(2,798 )- ]
6,8

= 14,31[0,8522 3,798 + 2,798]

6
 P2

= 1[3,672 16,369 + 12,059]


= 13,67[2 4,46 + 3,285]

1

3,67 0 (24,46+3,285)
= k

Rumus ABC
(2 4,46 + 3,285) =
2 4
2
4,46 4,462 413,285
2
4,46 2,598
2

Sehingga didapat X1 = 3,529 dan X2 = 0.931

Maka (2 4,46 + 3,285) = (XA 3,529)(XA 0.931)

0.2724 0 ( = +
3,529)( 0.931) 3,529 0,931

( 0.931)+( 3,529)
= + = ( 3,529)( 0.931)
3,529 0.931

A + B = 0 x -0,931

-0.931A - 3,529B = 1 x 1

B = -0.384

A = 0.382

Sehingga persamaan menjadi

0,382 0,384
0,2724[0 ((XA3,529) 0 ]=k1.t
(XA0,931)

1 1
0,2724[0,3820 ((XA3,529) + (XA0,931) ]=k1

(XA3,529)(0,931)
0,1040ln[(XA0,931)(3,529)= k1.t=y=mx

t(x) XA Y xY x2
0 0,18695 0,01765 0 0
10 0,30979 0,03252 0,3252 100
20 0,48931 0,06202 1,2404 400
30 0,65939 0,1066 3,198 900
40 0,78601 0,16719 6,6876 1600
100 1,6452 0,38598 11,4512 3000

7
 P2

k1 = m = 3,73x10-3
K=k1/k2 k2=k1/K =3,73x10-3 /6,8
K2= 5,487x10-4