66 fagre me (: amerm).18 Gatk 1995 3. Chemistry of the following name reactions: aldol condensation, Claysen condensation, Dieck-mann reaction, Perkin reaction, Reimer-Tiemann reaction, Cannizzaro reaction. 4, Polymeric Systems ical chemistry of polymers; End group analysis, Sedimentation, Light Scattering and Viscosity of polymers. (8) Polythylene, Polystyrene, polyvinyl chloride, Ziegler Natta Catalysis, Nylon, Terylene. (0) Inorgenic Polymeric Systems; Phosphonitric halide compounds; Sili- cones; Borazines, (a) Phy Friedel.—Craft reaction, Reformatsky reaction, pinacol-pinacilone wagner Mecrwein and Beckmann rearrangements and their mechanisms uses of | the following reagents in organic synthesis: O5 O4, HTO4. NBS, dibocrane, Naliquid ammonia. NaBEE!, LiAIN4 5. Photochemical reactions of organic and inorganic compounds types. of reactions and examples. and avnthetic uses-—Methods used in structure determina- tion: Principles and applications of w—Visible. TR, TH, NMH and mass spectra for structure determination of simple organic and inorganic molecules. 6, Molecular structural determination; Principles and Applications to simple organic and inorganic Molecules. (8 Rofational spectra of diatomic molecules (Infrared and Raman) isotopic substitution and rotational constants. (i) Vibrational spectra of diatomic, linear symmetric, linear asymmetric and bent tri-atomic molecules (Infrared and Raman). (Gf Specificity of the functional groups (Infrared and Raman). (io) Electronic Speetra singlet and triplet states, conjugated double bonds, a Bunssaturated carbonyl compounds, (v) Nuclear, Magnetic Reasonance; chemical shiét, spin-spin coupling, (vi) Electron Spin Reasonance, Study of inorganic complexes and free radicals, 09-CIVIL ENGINEERING a PAPER I (A) Theory and Design of Structures: (@) Theory of structures: Energy theorems—Castrigliano theorems T and IT, unit load method and method of consistent deformation applied fo heams and piniointed plane frames, Slope deflection. moment distribution and Kai method of analysis applied to indeterminate beams and rigid frames.fagre az (amanem),15 Gré1995 “7 it i ib in i itevia for maximum sheer force and bending moment Moving come traveraed by a system of moving loads, Thlghoe lines for simply supported plane pinjointed girders. Arches: Three hinged, two hinged and fixed archesrib shortening and temperature effects-Infiuence lines Matrix methods of analysis: Force method and displacement method. (®) Stractural steel: Factors of safety and load factors. Design of tension and compression members, beams of built up section, riveted and welded plate girders, gentry girders, stanchions with battens and lacings, Slab aud gusseted’ baces. Design of highway and railway bridges—Through the deck type plate girder, Warren girder and Prattruss. (¢) Reinforced concrete. Limit, state method design—Reoommendations cf IS codes—Design of one-way and two-way slabs, staircase slabs, simple and continuous beams of reetanglar, T and L sections. Compression members under direct load with or without eccentriei footings, isolated and combined. Retaining walls, cantilever and counterfort types—Methods and systema of prestressing, Anchorages, Analysis and design of sections for flecuer, loss of prestress. (B) Fluid Mechanics: Fluid properties avd their role in fluid motion, fluid statics including for- ees acting on plane and curved surfaces. Kinematics and Dynamics of Fluid Flow: Velocity and accelerations, stream Jines, equation of continuity, irrotational and rotational flows, velocity potential and stream function, flow-nets and methods of drawing flow net, sources and sinks, flow separation and stagnation, Enler’s equation of motion, energy and momentum equations and their applications to pipe flow, free aud forced vortices, plane and curved stationary ane moving vanes, cluice gates, weirs, orifice meters and venturimeters Dimensional Analysis and Similirade: Buckinghham's Pi theorem, simi larities, mode laws, undistorted and distorted models, movable bed models, model calibration, cate . ib Laminar Flow: Laminar flow between parallel stationary and movi ates, flow through tube, Reynolds’ experiments, lubrication principles ema son Boundary Layers: Laminar and turbulent boundary layer Jaminar sub-layer, smooth and ro' ona fiat plate, ugh boundaries, drag and lift. a68 fear tat _(mavarem),18 storg,1998 lent Flow Through Pipes:, characteristics of turbulent flow, velocity distribution and variation of fiction Tact, hydroutio grade Hine and folal energy line, siphons, expansions and contractions in pipes, pipe network, water hammer. Channel Flow:, uniform, non-uniform flows, specific energy and spe- cio Sen, critical depth, resistance equations and variation of "roughness cocficient, Rapidly varied flow, flow in contractions, flow at sudden drop, dydraalic jump and its applications, surges and waves, Gradually varied Flow, diterential equation of gradually varied flow, classification of surface profiles, controt section, step metood of integration of varied flow equation (C) Soil Mechanios and Foundation Engineering: Soil composition, influence of clay minerals on engineering behaviour, Effective stress principle, change in effective stress due to water flow condition, statio water table and steady How conditions permeability and compressibility of soils, Strongth behaviour, strength determination through direct and triaxial tests, total and effective stress strength parameters, total and effective stress paths. Methods of site exploration, planning a subsurface exploration programme, sampling procedures and sampling disturbance, penetration tests and plate load tests und data interpertation Foundatioa types and selection, footings, rafts, piles, floating foundations, effect of footing shape, dimensions, depth of embedment, load inclination ard id water on bearing capacity,” settlement components, computation. for iate and conrolidation settlements, limits on total and differential sot. tlement, correctica for rigidity. q 2 Inde x? foundations, philosophy of deep foundations, piles, estimation of a ba aren P. capacity, Hrd and dynamic approaches, pile Toad teste, Seperation into sitin friction and point beating, under-reamed piles, well for? dations for bridges and aspects of design, * cee . Higawoggng sams, Earth pressure, states of plastic equilibrium, Culmann’ edi determination of lateral thrust determination of anchor forcd and depth of Penetration, reinforced earth retaining walls, concept, materials and applications. Machine foundations, modes of vibratio quency, criteria for design, effect of vibrati () Computer Programming: aime eee of computers, components of computers, history and development; nm, determination of natural fre. ion on soils, vibration isolation, Fortran/Basio programming, constants, variables statements library functions, control statements, tinovadiz ‘pressions, arithmatic tional GO-TO state.fag ae (auPTen),15 qth 1995 68 7 CONTINUE, ments, computed GO-TO statements, IF and DO statements, CONTINUE, CALL, RETURN STOP, END statements, I/O statements, FORMATS, field specifications. eae . ae ri a Subseripted variables, arrays, DIMENSION statement, function an subroutine sub programmes, application to simple probieme with flow charts in civil engineering. Paver 1 Note—eandidate shall answer questions from any two parts, Part—A. Building Construction: Physical and mechanical properties of construction materials, factors influencing selection, brick and clay products, limes and cements, polymorie materials and special uses, damp-proofing materials. Brickwork for walls, types, caving walls, design of brick masonary walls S. cole, factors of safety, serviceability and strength requirements of walls, floors, roots, ceiling, finishing of buildings, plastoring, Pointing, painting. Funetional planning of building, orientation of buildings, clements of Sre-proof construction, repairs to damaged and cracked buildings, use of ferre- cement, fibre-reinforeed and polymer concrete in construction, techniques and materials for low cost housing. Building estimates and specificati and CPM methods. Part—B. , construction scheduling PERT ‘Transportation Engineering: Roads, Trafio engineering and trafic surveys, interseoti i signi, Teabe si 1g ‘ys, intersections, road signs, Claesifcation of roads, plannings and geometric design Design of exible and rigid pavements, on pavement layers and design methodologies Part—C. Indian Road Congress guidelines Water Resources and Irrigation Engineoring Hydrology: Hydrologic cycle, preci itation, evalorati depression storage, infiltration, hydrograph, unit hydeograph fe transpiration, lysis, flood estimation. equency ana”ry at mse (saTeTem),15 ford, 1995 ae 5 teapot pee Ground water flow: Specific yield, storage co-efficient, o0-officien meability, confined aad unomfined "aquifers. radial flow into a well under confined and unconfined conditions, tubewells, pumping and recuperati tests, ground water potential. i G ‘ingle and Water resources planning: Ground and surfact water resourees, single anc multipurpose projects, storage capacity of rsservoirs, reservoirs losses, resorvoir sedimentation, flood routing through reservoirs, economics of water resources projects. Water requirement for crops: consumptive use of water, quality of irriga- tion water, duty and delta, irrigation methods and their efficiencies. Canals: Distribution system for canal irrigation, canal eapacity, canal losses, alignment of main and distributary canals, most efficient section, lined channels, their design, regime theory, critical shear stress, bed load local and suspended load transport, cost analysis of lined and unlined canals, drainage behind lining. Water logging: causes and control, drainage system design, salinity. Canal structures: Design of regulation, cross-drainage and communication works, cross regulators, head regulators, canal falls, aqueducts metering flumes and canal outlets, Diversion head works: Principles of impermeable foundations, iment exclusion. design of weirs on perceable and Khosla’s theory, energy dissipation, stilling basins, storago works: Types of dams, design principles of rigid gravity and earth dams, stability analysis, foundation treatment, joints and. galleries, control of seepage, construction methods and machinery. Spillways: {ypes, crest gates, energy dissipation. River training: objectives of river training methods of river training, Part—D. Environmental Engineering: Water Fesoutroes, ground and surface water, demand of water, impurities of water and bacteriological analysis, supply%Estimation of water ground water’ hydraulics, predicting and their significance, physical, chemical water bone diseases, standards for potable water, Intake of water: Pumping and gravity schemes, Water treatment: Principles of coagulation, flocculation and sedi i i » floc ita fion, slow, rapid, pressure, biffow and multi-media filters, chlorination ne ing, removal of taste, odour and salinity. a eeegeeeeaaaee Water storage and distribution: Storage and balanci i location and capacity. a’ fereegeecas types,comm), 15 qa, 1995 n Distribution eystem: layout, hydrauties of pipelines, pipe fittings, valves {ncluding check and pressure reducing valves, meters, analysis of distribution of optimal design based intenance of disribution systems using Hardy Cross methods general prineip! on cost headloss ratio criterion, lenlx detection, systems, pumping stations and their operations. Sewerage system. domestic and industrial wastes, storm sewage separate and combined system, flow through severs, design of sewers, sewer appurtenan- es, manholes, inlets, junctions, syphon. Sewage characterisation: BOD, COD, solids, dissolved oxygen, nitrogen and TOC. Standards of disposal in “normal water courze and on land, Sewage treatment: working, principles, units, chambers, sedimentation fank, trickling filters, oxidation ponds, activated sludge process, septic. tank, disposal of shidge, recycling of waste water. Solid waste: collection and disposal Environmental pollution: ecological -halance, water pollution control acts, radio active wastes and disposal environmental impact assessment for thermal power plants, mines. n: site and orientation of buildings, ventilation and damp proof houses drainage, conservancy and waterbone system of waste disposal, sanitary appliances, latrines and nrinals, rural sanitation. 10.COMMERC AND ACCOUNTANCY a PAPERT ‘Accounting and Finance Part I: Accounting, Anditing and Taxation. __ Accounting as a financial information system—Impact of behavioral sciences—Methor's of accounting of changing price levels with particualr refe- Fence to current Purchasing Power (CPP) acoonnting Advanced problems of companies accounts —Amaleamatiin absorption and reconstruction of companes-- Accounting of holding companies—Valuation of shares and goodwill, Control: lership functions—Property control legal and management, Importact provisions of the Tneome Tax Act. 1961—Definition Charge of Income Tax—Lxemptions Denreciation and investment _allowance-Staplo Problems of computation of income nndor the varions heads and determinate: Of assessable ircome—Income Tax anthoritios Nature and functions of Cost Acconntins—Cost classification —Techni of segregating semivarinhle costs into fixed and vnriahle component jek ‘ot. ing FIFO and weighted average mothods or ealeulating equivalent’ donee te Pfoductin “Reconciliation of cost and financial acoounts Marginal Ceetag' Zost volume profit zelationship: Algchraic formula and graphical ray resenta tion—Shut-down point—Techniques ef cost control and est reduction” Budge. tary control flesible Budgets-Standard costinus and variance analy dee oe sibility aeconnting Ba: Snheeaaie ses of charging overhears and their i : : ses sing rarls and rent fallacy — Costing fur pricing decisions. inherent fallacy