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RANK BOOSTER TEST SERIES

12th and 13th STUDENTS


FULL TEST - 1 [PAPER - 2]
TARGET IIT - JEE - 2016
Date : 19-04-2016 Duration :3 Hours Max. Marks : 240

_________________________________________________________________________________________
INSTRUCTIONS
In each part of the paper, Section-A contains 8 questions & Section - B contains 12 questions. Total number of
pages are 24. Please ensure that the Questions paper you have received contains ALL THE QUESTIONS in each
section and PAGES.
SECTION - A
Q.1 to Q.8 are Integer answer type questions (whose answer is 1 digits [0 to 9]) & carry 4 marks each. No Negative
Marking.

SECTION - B
Q.1 to Q.8 are Multiple choice Questions has four choices (A), (B), (C), (D) out of which one or more than one is/are
correct & carry 4 marks each. 2 mark will be deducted for each wrong answer.

Q.9 to Q.12 are based upon a Paragraph. Each Question has four choices (A), (B), (C), (D) out of which one or more than
one is/are correct & carry 4 marks each. 2 mark will be deducted for each wrong answer.

NOTE : GENERAL INSTRUCTION FOR FILLING THE OMR ARE GIVEN BELOW.
1. Use only blue/black pen (avoid gel pen) for darkening the bubble.

2. Indicate the correct answer for each question by filling appropriate bubble in your OMR answer sheet.

3. The Answer sheet will be checked through computer hence, the answer of the question must be marked by shading the
circles against the question by blue/black pen.

4. While filling the bubbles please be careful about SECTIONS [i.e. Section-A (include Integer type), Section - B [Multiple type]
& Section-C (Comprehension type)].

394,50 - Rajeev Gandhi Nagar Kota, Ph. No. : 93141-87482, 0744-2209671


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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 2

PART - I [MATHEMATICS]
SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s
"k. kkRed
i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions.
(The answer of each of the questions is 1 digits)
i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS
Ai zR; sd i z'u dkmkj dsoy
d ksesnhft
1 va ; sA
1. The total number of integral solution for x, y,
z such that xyz = 24, is 'n' then number of 1. x, y, z t
cfd xyz = 24 gks( dsfy , i w . kkZ
a
d h; gy ksadh
even divisiors of n is equals to - dq
yla
[ ; k'n' gSr c n dsl e foHkkt dksadhl a [ ; kgksxh%
&

2. If 3n is a factor of the determinant


1 1 1
1 1 1 n
C1 n 3
C1 n6
C1
n n3 n 6
2. ; fn l kj f.kd dk, d xq
. ku[ k.M
C1 C1 C1 , n
C2 n 3
C2 n6
C2
then the maxi mum
n n3 n6
C2 C2 C2
3n gSr c n dk vf/kdr e eku gksxk%
&
value of n is

1 2 1 23 3
3. Sum infinite terms of the series 3. Js.kh cot 1 4 cot 2 4

1 2 3 1 2 3
cot 1 4 cot 2 4
3
co t 1 3 2 ...........dsvuU
r i nka
sdk
4
3
cot 1 32 .... ...........is m find [m]
4 ; ksx m gSr c [m] Kkr dhft , A
(where [ * ] denotes greatest integer (t gk [ * ] egke i w
. kkZ
a
d Qy u dksn' kkZ
r k gS
)
function)

4. For any x, y R, xy > 0 then the minimum 2x x3y 4y2


4. fdl h x, y R dsfy, xy > 0 gSr c 3

y 3 9x4
2x x3y 4y2
value of 3 is
y 3 9x4 dkU; w
ur e eku gksxk%
&

(SPACE FOR ROUGH WORK)

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Just when the caterpillar thought the world was ending, he turned into a butterfly.
Page # 3 RANK BOOSTER PROGRAM [FULL TEST - 1]

5. In a ABC, the median to the side BC is of 5. , d f=kHkq


t ABC esa
,Hkq
t k BC dh ekf/; dk dh y EckbZ
1 1
length
11 6 3
and it divides A into
11 6 3
gSr Fkk; g A dks30 o 45 dks.kea
sckVr h
angles of 30 and 45 find length of BC gSr c BC dhy EckbZKkr dhft , A

x 1 y 2 z 3 x 1 y 2 z 3
6. Let L1 : be a line and 6. ekuk L1 : , d j s[kkgSr FkkP
3 1 3 3 1 3
P : 4x + 3y + 5z = 50 be a plane. L2 is the : 4x + 3y + 5z = 50 , d l er y gS Al er y P esa, d
line in the plane P and parallel to L1. If j s[kk L2 gSt ksL1 dsl ekUr j gS
A ; fn j s[kkL1 o L2 dks
equation of the plane containing both the
lines L1 and L2 and perpendicular to plane P
j [ kusoky kr Fkkl er y P dsyEcor l er y dhl ehdj .k
is ax + by + 5z + d = 0 then find the value of ax + by + 5z + d = 0 gSr c (a + b + d) dkeku
(a + b + d). Kkr dhft , A

1
7. Let f (x) be an odd function and 7. ekuk f (x) , d fo"ke Qy u gSr Fkk x f (x ) dx = k
1 1 0
3
x f (x ) dx = k and x f ( x ) dx = k3. 1
3
0 0
r Fkk x f ( x ) dx = k3 gS
A
1 0
3
If (x k) f ( x ) dx =64 then find the value 1
3

of k.
1 ; fn (x k) f ( x ) dx =64 gSr c k dk eku Kkr
1
dhft , A
8. The direction ratios of two lines L1 and L2
are < 4, 1, 3 > and < 2, 1, 2 >
8. nksj s[kkvksaL1 o L2 dsfnd~
&vuq i kr e' k%< 4, 1, 3
respectively. A vector V is perpendicular
> r Fkk< 2, 1, 2 > gS A, d l fn' k V , nksuksaj s[kkvksa

to L1 and L2 both such that V = 15 . If
L1 o L2 dsy Ecor bl i z d kj gSfd V = 15 gS A; fn

V = x1i x 2j x 3k , then find the value of V = x1i x 2j x 3k gS , r c | x1 x2 x3 | dk
| x1 x2 x3 |.
eku Kkr dhft , A

(SPACE FOR ROUGH WORK)

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 4

SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE] [ cgqoS
d fYi d
i z'u i zd kj ]
Q.1 to Q.8 has four choices (A), (B), (C), (D) out i z-1 l si z-8 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
of which ONE OR MORE THAN ONE is correct
; k, d l svf/kd^^ l ghgS
A
1. If y = f(x) be the equation of a parabola
which is touched by the line y = x at the 1. ; fn y = f(x) , d i j oy ; dhl ehdj .kgSt ksj s[kky =
point where x = 1. Then x dksx = 1 i j Li ' kZdj r kgS
Ar c
(A) f'(0) = f'(1) (B) f'(0) = f'(1) (A) f'(0) = f'(1) (B) f'(0) = f'(1)
(C) f(0) + f'(0) + f''(0) = 1 (C) f(0) + f'(0) + f''(0) = 1
(D) 2f(0) = 1 f'(0) (D) 2f(0) = 1 f'(0)

2. If A and B are invertible square matrices of


the same order, then which of the following 2. ; fn A o B l eku dksfV dhO
;q
Re.kh; oxZeS
fVDl gSr c
is correct? fuEu ea
sl sdkS
ul sfodYi l ghgS
\
(A) adj(AB) = (adjB) (adjA) (A) adj(AB) = (adjB) (adjA)
(B)( adjA)' = (adjA')
(B)( adjA)' = (adjA')
(C) |adjA| = |A|n1, where n is the order of
matrix A t gk n eS
(C) |adjA| = |A|n1, fVDl A dhdksfV gS A
(D) adj(adjB) = |B|n2, where n is the order (D) adj(adjB) = |B| , t gkn eS
n2
fVDl B dhdksfV
of matrix B
gS
A
3. If be non real complex cube root of unity,
4
3. ; fn bdkbZdk vokLr fod l fEeJ ?kuew
y gSr c
p
4

then the value of


p 1
7 may equal to
p 1
p

2
q 7 dk eku gksl dr k gS
%
&
q1

q1
2
q

1 i 3 1 i 3 1 i 3 1 i 3
(A) (B) 2 (A) 2
(B) 2
2

1 i 3 1 i 3 1 i 3 1 i 3
(C) (D) 2 (C) 2
(D) 2
2

(SPACE FOR ROUGH WORK)

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Just when the caterpillar thought the world was ending, he turned into a butterfly.
Page # 5 RANK BOOSTER PROGRAM [FULL TEST - 1]

4. The expression m
4n 1
m1 2k 2k
m
4. O
;a
td
m1
sin
k 1 m
i cos


m
4n 1
m1 2k 2k

m1
sin
k 1 m i cos m
(A) dk okLr fod Hkkx 1 dscj kcj gS
A
(A) has real part equal to 1 (B) i w
. kZ
r %okLr fod gS
A
(B) purely real
(C) i w
. kZ
r %dkYi fud gS
A
(C) purely imaginary
(D) has imaginary part equal to 2 (D) dkdkYi fud Hkkx 2 dscj kcj gS
A

5. If a function satisfies the relation 5. ; fn , d Qy u] l EcU/k f(x) f''(x) f(x) f'(x) =


f(x) f''(x) f(x) f'(x) = (f'(x))2 x R and (f'(x))2 x R r Fkkf(0) = f'(0) = 1 dksl a rq
"V
f(0) = f'(0) = 1, then identify which of the dj r kgSr c fuEu dFkuksaesal sdkS
ul k
l sl ghgS
\
following statement(s) is (are) correct ?
(A) l ehdj .k f(x) = ex nksgy j [ kr hgS
A
(A) Equation f(x) = ex has two solutions
(B) Equation f(x) = ex has exactly one solution (B) l ehdj .kf(x) = ex , d gy j [ kr hgS
A

1 f(x) 1 1 f(x) 1
(C) lim f(x) (D) lim 1 (C) lim f(x) (D) lim 1
x e x0 x x e x0 x

6. Let x, y be real variable satisfying the 6. ekuk x, y okLr fod pj gSt ksx2 + y2 + 8x 10y
x + y + 8x 10y 40 = 0. Let a = max
2 2
40 = 0 dksl arq"V dj r sgS
Aekuka = max
( (x 2)2 (y 3)2 ) and ( (x 2)2 (y 3)2 ) r Fkk

b = min ( (x 2)2 (y 3)2 ) , then : b = min ( (x 2)2 (y 3)2 ) gSr c%


&
(A) a + b = 18 (B) a + b = 4 2
(A) a + b = 18 (B) a + b = 4 2
(C) a b = 4 2 (D) ab = 73
(C) a b = 4 2 (D) ab = 73

(SPACE FOR ROUGH WORK)

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 6

7. Let f (x) = cot x tan x 2 tan 2x 4 tan 7. ekuk f (x) = cot x tan x 2 tan 2x 4 tan
n n
4x 8 cot 8x, x , n I and 4x 8 cot 8x, x , n I r Fkk
8 8
g (x) = x3 + 6x 1.
g (x) = x3 + 6x 1 gS
A , d vU; Qy u h (x) gSt ks
One more function h (x) is defined as
n n
h:R , n I R , h (x) = f (x) + g (x) h:R , n I R , h (x) = f (x) + g (x)
8 8
then identify the correct statement(s). } kj ki fj Hkkf"kr gSr c l ghdFkuksadhi gpku dhft , A

(A) h ' ' = (A) h ' ' =
24 4 24 4
(B) h (x) is odd function (B) h (x) fo"ke Qy u gS A
(C) h (x) is increasing in the domain.
(C) h (x) i z kUr esao/kZ
eku gS A
(D) If the equation h (x) = has a solution
in (0, 3) then number of integral values (D) ; fn l ehdj .kh (x) = va r j ky (0, 3) esa, d gy
of is 7. j [ kr hgSr c dsi w. kkZ
a
d h; ekuksadhl a[ ; k7 gSA

8. Let a1, a2, a3 R0 and a1 + a2 cos 2x + a3 8. ekuk lHkh x R ds fy;s a1, a2, a3 R0 rFkk
sin2x = 0 for all x R, then a1 + a2 cos 2x + a3 sin2x = 0 gS] rks

(A) Vec tors a a1i a 2j a 3k and (A) l fn 'k a a1i a 2j a 3k r F kk

b 4 i 2 j k are perpendicular to each b 4 i 2 j k ,d nwljs ds yEcor~ gSA
other.

(B) Vec tors a a1i a 2j a 3k and
(B) l fn 'k a a1i a 2j a 3k r F kk

b i j 2 k are parallel to each other.. b i j 2 k ,d nwljs ds lekUrj gSA

(C) If vector a a1i a 2j a 3k is of length (C) ;fn lfn'k a a1i a 2j a 3k dh yEckbZ 6
gS] rks fer ;qXeksa esa ls ,d
6 , then one of the ordered triplet
(a1, a2, a3) = (1, 1, 2).
(a1, a2, a3) = (1, 1, 2) gSA
(D) If 2a 1 + 3a 2 + 6a 3 = 26, then (D) ;fn 2a 1 + 3a 2 + 6a 3 = 26 gS ] rks
a1i a 2 j a 3k equals 2 6 . a1i a 2 j a 3k dk eku 2 6 gSA

(SPACE FOR ROUGH WORK)

Corporate Head Office : Motion Education Pvt. Ltd., 394 - Rajeev Gandhi Nagar, Kota-5 (Raj.)

Just when the caterpillar thought the world was ending, he turned into a butterfly.
Page # 7 RANK BOOSTER PROGRAM [FULL TEST - 1]

[COMPREHENSION TYPE] [ Ja
[ ky kc) &cks/ku i zd kj ]
Q.9 to Q.12 are based upon a paragraph. Each
i z-9 l si z-12 r d] , d vuq
PNsn i j vk/kkfj r gS
A i zR;sd i 'zu esapkj
questions has four choice (A), (B), (C), (D) out of
fodYi (A), (B), (C), (D) ft uesal s, d ; k, d l sv f/kd l ghgS
A
which ONE OR MORE THAN ONE is correct

Paragraph for Question Nos. 9 to 10


v uq
PNsn i z'u l a
[ ; k 9 l s10

Let a hyperbola whose centre is at origin. A ekuk , d vfr i j oy ; ft l dk dsUnzew


y fcUnqi j gS
A, d
line x + y = 2 touches this hyperbola at j s[kk x + y = 2 bl vfr i j oy ; dksP(1, 1) i j Li ' kZ
P(1, 1) and intersects the asymptotes at A dj r h gSr Fkk vuUr Li f' kZ
; ksadksA o B i j bl i zd kj
and B such that AB = 6 2 units. i zfr PNsn dj r hgSAB = 6 2 bdkbZ
A

9. Equation of asymptotes are 9. vuUr Li f' kZ


; ksa dhl ehdj .kgS
%
&
(A) 5xy + 2x2 + 2y2 = 0 (B) 3x2+4y2+6xy=0 (A) 5xy + 2x2 + 2y2 = 0 (B) 3x2+4y2+6xy=0
(C) 2x2 + 2y2 5xy = 0 (D) None of these (C) 2x2 + 2y2 5xy = 0 (D) bues
al sdksbZugh

10. Angle subtended by AB at centre of the


10. vfr i j oy ; dsdsUnzi j AB } kj kcuk; kx; kdks.kgS
A
hyperbola is

4 2
4 2 (A) sin1 (B) sin1
(A) sin1 (B) sin1 5 5
5 5

3
3 (C) sin1 (D) bues
al sdksbZugh
(C) sin1 (D) None of these 5
5

(SPACE FOR ROUGH WORK)

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 8

Paragraph for Question Nos. 11 to 12 v uq


PNsn i z'u l a
[ ; k 11 l s12
Let f : [1, ) [a, ) defined by 2
ekuk f : [1, ) [a, ) gSt ks f(x) = 22x 4x
} kj k
2x 2
4x
f(x) = 2 and g : , [c, d] defined i fj Hkkf"kr gSr Fkkg : 2 , [c, d] gSt ks
2

cos x 3 cos x 3
by g(x) = are two invertible functions g(x) = } kj ki fj Hkkf"kr gS
( nksO
;q
Re.kh; Qy u
cos x 2 cos x 2

11. Which of the following can be co-domains of


gS
A
h : R A s.t. h(x) = 4ax2 + 2cx + d 11. fuEu ea
sl sdkS
ul k h : R A dk l g&i zkUr gSt cfd
(A) [0, ) (B) [1, ) h(x) = 4ax2 + 2cx + d gks
(A) [0, ) (B) [1, )
1 1
(C) , (D) , 1 1
4 4 (C) , (D) ,
4 4

12. Domain of (fof1) (x) and (f1of) (x) are 12. (fof1) (x) r Fkk(f1of) (x) dk i zkUr gksxk%
&
(A) [1, ] and (1, ) (A) [1, ] r Fkk(1, )

1 1
(B) , & [1, ) (B) , r Fkk[1, )
4 4

1
1 (C) [1, ) r Fkk 4 ,
(C) [1, ) & 4 ,

1 1
(D) 4 , r Fkk 4 ,
1 1
(D) 4 , and 4 ,

(SPACE FOR ROUGH WORK)

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Just when the caterpillar thought the world was ending, he turned into a butterfly.
Page # 9 RANK BOOSTER PROGRAM [FULL TEST - 1]

PART - II [PHYSICS]
SECTION - A SECTION - A
[INTEGER ANSWER TYPE] [ fo' y s
"k. kkRed i z'u i zd kj ]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS
Ai zR; sd i z'u dkmkj dsoy
(The answer of each of the questions is 1 digits)
d ksesnhft
1 va ; sA
1. For the situation shown in the figure, find
the speed of cylinder at the instant shown in 1. fp=k ea snh xbZfLFkfr dsfy , ] fp=k esan' kkZ
, x, {k.k i j
figure.
2 7 cm / s
fl y s.Mj dhxfr gksxh&
A B 2 7 cm / s
30 7 cm / s A B
30 7 cm / s
2. A stone targeted at point P which is in the
same horizontal plane through the point of
projections, falls x1 distance before the point
2. , d i RFkj dksfcUnqP i j l k/kkx; k t ksi z{ksi.kfcUnq} kj k
P when angle of projection is 15. It goes x2 l eku {kSfr t r y esagS
] ; g i RFkj fcUnqP l sx1 nw j hi gy s
distance beyond when the angle of projection ghfxj t kr kgSt c i z{ksi.kdks.k15 gS A; g i RFkj fcUnqP
is 45. The proper angle of projection is 30 l sx2 nw
j hvkxsfxj r kgS
] t c i z{ksi.kdks.k45 gksrkgS AfcUnq
to hit the point P. If the velocity of projection P i j Vdj kusdsfy , i z {ksi.kdks.k30 gS A; fn i z{ksi.kosx
remains same, find the value of
3 1x 1
. 3 1x 1
x2 l eku j gr k gS
] r ks x2
dk eku Kkr dj ksA
3. If X-axis is taken as reference line and
Y-axis in vertically upward direction. The 3. ; fn X-v{kdksl a nHkZ j s[kk r FkkY-v{kdks/okZ /kj i j
potential energy of a parabolic plate y2 = kx dhfn' kkesay srsgSr ksfp=kesan' kkZ, vuq
l kj i `"B O ; eku
of surface mass density as shown in the
?kuRo dh, d i j oy ; Iy sV y2 = kx dhLFkS fr t t kZ
ga2k
figure is . Find the value of n. ga2k
y n gS
] r ksn dkeku Kkr dj ksA
n
y
y2 = kx
(a,b)
y2 = kx
(a,b)

x
x

(SPACE FOR ROUGH WORK)

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 10

20x 20x
4. A standing wave y = A sin 3 cos 4. , d LFkk; hr j a
x y = A sin 3 cos (1000t)

(1000t) is set up in a taut string where x , d r uhgq bZj Ll hesaLFkkfi r gksrhgSt gkx r Fkky ehVj
and y are in metre. The distance between A
two successive points oscillating with the esagS
Avk; ke l snksy u dj usokysnksekxr fcUnq
v ksads
2
A e/; nw
j h(x) cm gksl dr hgS A x dkeku Kkr dj ksA
amplitude can be equal to (x) cm. Find
2
value of x.
5. /ofu r j axksdh, d Vsu , d pkS M+
si kbZ
i l sxq t j r hgSr Fkk, d
5. A train of sound waves is propagated along [ kq
y sfl j sl si j kofr Z
r gksrhgS A; fn r j a
xka
sdkvk; ke 0.002
a wide pipe and it is reflected from an open
cm gS , vkofk 1000 Hz r Fkk r j a xnS /; Z40 cm gS , r ks
end. If the amplitude of the waves is 0.002
cm, the frequency 1000 Hz and the wave- i kbZ
i dsvUnj [ kq y sfl j sl s10 cm dhnw j hi j , d fcUnq
length 40 cm, the amplitude of vibration at a i j dEi Uu dkvk; ke (0.0x) cm gksxkA x dkeku Kkr
point 10 cm from open end inside the pipe dj ksA
will be (0.0x) cm. Find value of x.
6. O ; eku m = 4 kg dkCy kW d O ; eku M = 8kg dh, d
6. A block of mass m = 4 kg is attached to a
spring of constant, k = 32 Nm 1 by a rope
f?kj uhi j y Vdhgq bZj Ll hds} kj k, d fLi azx l st q
M+ kgq
vk
that hangs over a pulley of mass M = 8kg. If gSAft l dkfLi azx fu; r ka
d k = 32 Nm 1 gS A; fn fudk;
the system starts from rest with the spring vr kU; fLi a
zx dsl kFkfLFkj voLFkkl si zkj EHkgksrkgSr ksCykW
d
unstretched, The speed of the block after it dhxfr 1 m r d fxj usdsckn x.4 ms1 gS Ax Kkr dj ksA
falls 1 m is x.4 ms1 . Find x. Treat the f?kj uhdksfMLd dhr j g ekur sgS A
pulley as a disc.
k
k

M M

m
m
7. A ball is thrown vertically upward from the
roof of a building with a certain velocity . It 7. , d ckWy dks, d fcfYMax dhNr l s, d fuf' pr osx dsl kFk
reaches at the ground in 9 s. When it is i j dhvksj Qsa d k t kr k gS
A; g 9 l S
d .M esat ehu i j
thrown downward from the roof with the same i gq
pr hgSAt c bl sNr l suhpsdhr j Q ml hosx l sQsa dk
initial speed, it takes 4 s to come at ground . t kr kgSr ks; g 4 l S
d .Mesat ehu i j i gq
p t kr hgS
A; fn
How much time (in second) will it take to
reach at ground if it just released from the bl sNr l suhpsdhvksj dsoy NksM+fn; kt k; sr ks; g t ehu
rest from the roof ? i j i gq
pusesafdr uk l e; (l S d .Mesa) ysxh?
(SPACE FOR ROUGH WORK)

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8. A small block is kept on a rough inclined plane 8. , d NksVsC y kW


d dksdks.ki j >q d s, d [ kqj nj sr y i j j [ kk
of inclination .
The inclined plane is just sufficiently rough x; k gS A >q d k gq
v k r y ?k"kZ
. k xq
. kka
d dsl kFk dsoy br uk
with friction coefficient that the block would i ; kZ Ir [ kq
j nj kgSfd Cy kW
d dksFkksM+ kl k/kDdknsusi j ; g
fall and slide down with a uniform speed as
fxj sr Fkk , d l eku osx l suhpsfQl y sA vc Cy kW d dks
the result of even the slightest jerk.
Now, the block is pushed horizontally with i zkj fEHkd osx v0 = 2 m/s dsl kFk {kS fr t r %/kDdk fn; k
an initial speed v0 = 2 m/s. The block slides t kr kgS AC y kW
d fdl hosx l s<ky i j fQl y r kgSt ksi fj ek.k
down the slope with a velocity that changes
in both magnitude and direction. Find the fi- r Fkkfn' kknksuksaesai Fkd gSACykW d dkva fr e osx Kkr dj ksA
nal speed of the block.

v0
A
v0
A

SECTION - B
SECTION - B
[ cgqoS
d fYi d i z'u i zd kj ]
[MULTIPLE OBJECTIVE TYPE]
Q.1 to Q.8 has four choices (A), (B), (C), (D) out i z-1 l si z-8 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
of which ONE OR MORE THAN ONE is correct ; k, d l svf/kd^^ l ghgS
A

1. The driver of a car moving on road ABC 1. , d dkj dk pky d l M+


d ABC i j xfr dsnkS
j ku , d
appl i es uni form break throughout i ts
l eku czsd y xkr k gS
A dkj dh xfr fuEur e fcUnqA i j
motion. The speed of car is 27 m/s at the
bottom A and 13 m/s at the top point C. The 27 m/s r FkkmPpr e fcU
nqC i j 13 m/s gS
AfcUnqC dh
distance of C from point A along ABC is 80 m. A l sABC dsvuq
fn' knw
j h80 m gS
AA fcUnqi j dkj dk
The acceleration of car is 4.5 m/s2 at point A
Roj .k4.5 m/s2 r FkkfcUnqC i j or kf=kT; k130 m gS
A
and radius of curvature at point C is 130 m.
Path portion DBE is straight line. i FkDBE l h/khj s[kkgS
A
(take 8 = 2.83, 13.94 = 3.7) ( 8 = 2.83, 13.94 = 3.7 fy ft , )

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 12

C C

E E
B B

D D
A A
Mark the correct options.
(A) The radius of curvature at point A is 257.6 l ghfodYi pqfu, %
m
(B) The magnitude of tangential accelera- (A) fcU
nqA i j o dhf=kT; k257.6 m gS A
tion is 3.5 m/s2 at point A. (B) fcU
nqA i j Li ' kZ
T; k; hRoj .k dki fj ek.k 3.5 m/s2
(C) The magnitude of acceleration at point B gSA
is 3.5 m/s2 (C) fcU
nqB i j Roj .kdki fj ek.k3.5 m/s2 gS A
(D) The magnitude of acceleration of point C
(D) fcUnqC i j Roj .kdki fj ek.k3.7 m/s2 gS A
is 3.7 m/s2

2. Two identical blocks each of mass m are con- 2. nks, d l eku C


ykW
d ft udsO
; eku m gS
A, d gYdhdekuh
nected by a light spring of constant k = 100 ft l dkfLi zax fu; r ka
d k = 100 N/m gSl st q M+
hgSAi zkj EHk
N/m. Initially, spring is compressed upto 0.2
m and then released. Which of the following esafLi a
zx dks0.2 m r d nck; k l fEiM+
hr t kr kgSr FkkfQj
statements is/are correct ? NksM+kt kr kgS AfuEu esal sdkS
ul kdFku l R; gS?
A B
A B
m m
m m
(A) The work done by the spring on the block
(A) t c fLi a zx vr kU; y EckbZi j vkr hgS
] r c fLi a
zx } kj k
A when the spring comes in natural length is
Cy kW
d A i j fd; k x; k dk; Z1 J gS A
1J
(B) t c fLi a zx vr kU; y EckbZi j vkr hgS
] r c fLi a
zx } kj k
(B) The work done by the spring on the block
B when the spring comes in natural length is
Cy kW
d B i j fd; kx; k dk; Z1 J gS A
(C) fLi a
zx } kj kfudk; (C y kW
d A+C y kW
d B) i j fd; kx; k
1J
(c) The work done by the spring on the dk; Z2 J gS A
system (block A + block B) is 2 J (D) fLi azx } kj kfudk; (Cy kW
d A+C y kW
d B) i j fd; kx; k
(d) The work done by the spring on the dk; Z2 J gS A
system (block A + block B) is 2 J
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3. Two springs with negligible masses and force 3. nksux.; O ; eku r Fkkcy fu; r ka d K1 = 200 Nm1 r Fkk
constants K 1 = 200 Nm1 and K 2 = 160
K2 = 160 Nm1 dhfLi a zx } kj k, d m = 10 kg O ; eku
Nm1 are attached to the block of mass m =
10 kg as shown in the figure. Initially the dk Cy kWd l sfp=kkuql kj t qM+hgS A i zkj EHk esaCy kW
d fLFkj gS]
block is at rest, at the equilibrium position in l kE; koLFkkdhfLFkfr esafLi a
zx ukr ksr uko esaukghl EihM+ u
which both springs are neither stretched nor esagSAl e; t = 0 i j , d r hl j kvkos'k50 Ns dkCy kW d
compresse d. At ti me t = 0, a sharp dksfn; kt kr kgS A
impulse of 50 Ns is given to the block.

K1 K2
K1 K2
m
m

friction less
friction less
(A) Period of oscillations for the mass m is
s.
(A) Period of oscillations for the mass m is s. 3
3
(B) Maximum velocity of the mass m during (B) Maximum velocity of the mass m during
its oscillation is 5 ms1 its oscillation is 5 ms1
(C) Data are i nsufi ci ent to determi ne (C) Data are i nsufi ci ent to determi ne
maximum velocity. maximum velocity.
(D) Amplitude of Oscillation is 0.42 m. (D) Amplitude of Oscillation is 0.42 m.
4. A small sphere of radius R is held against the
inner surface of larger sphere of radius 6 R 4. , d NksVsxksy sdksft l dhf=kT; kR gSdks, d vU; cM+ sxksy s
(as shown in the figure). The masses of large dsvUnj ft l dhf=kT; k6 R gS(fp=kkuq l kj ), dhvkar fj d
and s mal l s pheres are 4M and M
l r g i j nck dj j [ kk x; k gS S
A cM+ sar Fkk NksVsxksy sads
respectively. This arrangement is placed on
a horizontal table. There is no friction O ; eku e' k%4M r Fkk M gS A; g O ; oLFkk , d {kS fr t
between any surfaces of contact. The small Vscy i j dhxbZgS Al Ei dZl r gksadse/; fdl hi zd kj dk
sp he re i s now re l e as ed . Fi nd the
coordinates of the centre of the large sphere, ?k"kZ
. kughagS
A vc NksVsxksy sdksNksM+ kt kr kgS S
At c NksVk
when the smal ler sphere reaches the xksy kBhd foi j hr Nksj i j i gq
p t kr kgS Ar c cM+ sxksy sds
opposite extreme postion.
dsUdsfunsZ ' kka
d Kkr dhft , A
(A) (L + 2R, 0) y
y
(A) (L + 2R, 0)
(B) (L + R, 0) 6R (B) (L + R, 0) 6R
(C) (L 2R, 0) R x R x
O (L, 0) (C) (L 2R, 0) O (L, 0)
(D) (L R, 0) 4M (D) (L R, 0) 4M

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 14

5. In the figure shown, the lines of action and 5. fp=kkuq l kj cy ksadhj s[kkvksar FkkHkq t kvksadhf; kj s[kkewy
moment arms of two forces about the fcUnqO i j gS A ; g ekfu, dh; scy fdl hn`<+oLr qi j
origin O. Imagining these forces to be
acting on a rigid body pivoted at O, all
vkj ksfi r gS] t ksfd O i j fdydhr gS Al Hkhl fn' kfp=kkuq
l kj
vectors shown being in the plane of the , d ghr y esagS ] i fj .kkehvk?kw
. kZgksxkA
figure, the resultant torque will be

1 2
1 2
r1 r2
r1 r2 F1 F2
F1 F2 O
O
(A) (F2r2 sin F1r1 sin1) out of plane of the (A) (F2r2 sin F1r1 sin1) i `"B l er y l sckgj dh
page vksj
(B) (F1r1 sin F2r2 sin2) into plane of the (B) (F1r1 sin F2r2 sin2) i `"B l er y l sva
nj dh
page vksj
(c) (F2r2 sin F1r1 sin1) into plane of the
(C) (F2r2 sin F1r1 sin1) i `"B l er y l sva
nj dh
page
(d) None of these vksj
(D) bues
al sdksbZughA
6. A string of mass 0.2 kg/m and length l = 0.6
m is fixed at both ends and stretched such
6. , d 0.2 kg/m O ; eku r Fkkl = 0.6 m y EckbZdhj Ll h
that it has a tension of 80 N. The string dsnksuksafl j ksadksbl i zd kj r kfur fd; kx; k gSfd bl es
vibrates in 3 segments with maximum a
r uko 80 N gS Aj Ll h3 HkkxksesadEi Uu dj r hgS
Aft l dk
amp l i tude of 0. 5 cm . The maxi mum
transverse velocity amplitude is vf/kdr e vk; ke 0.5 cm gS A r d dEi Uu dj r h gS
A
(A) 1.57 m/s (B) 6.28 m/s vf/kdr e vuq i zLFkosx gS&
(C) 3.14 m/s (D) 9.42 m/s (A) 1.57 m/s (B) 6.28 m/s
(C) 3.14 m/s (D) 9.42 m/s
7. A wave equation which gives the displace-
7. ,d rja
x l ehdj .kt ksy-fn' kkesafoLFkki u fuEu nsrhgS
;
ment along the y-direction is given by ;
y = 104 sin (60 t + 2 x)
y = 104 sin (60 t + 2 x)
t gkx r Fkky ehVj esagS A t l e; l S
d .MesagSA; g r j a
x
where x and y are in metre and t is time in
second. This represents a wave dksi znf' kZ
r dj r kgS&
(A) travelling with a velocity of 30 m/s in the (A) 30 m/s dsos x dsl kFk_ .kkRed x fn' kkesafopj .k
negative x direction dj j ghgS A
(B) of wavelength m (B) ft l dhr j a xnS
/; Z m
(C) of frequency 30/ Hz (C) ft l dhvkofk30/ Hz
(D) of amplitude 104 m (D) ft l dhvk; ke 104 m

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Page # 15 RANK BOOSTER PROGRAM [FULL TEST - 1]

8. A small particle traveling with a velocity v 8. , d NksVk d.k v osx l sxeu dj r sgq , ] l eku nzO ; eku o
collides elastically with a spherical body of
f=kT; k r dhxksfy ; oLr q(i zkj EHkesafoj ke i j ) l si zR; kLFk
equal mass and radius r initially kept at rest.
The center of this spherical body is located : i l sVdj kr kgS Abl xksy h; oLr qdkdsUnzd.kdhxfr
a distance (<r) away from the direction of dhfn' kkl snw j h(<r) i j LFkkfi r gS A VDdj dsckn&
motion of the particle. After collision :
(A) d.k: dr kgSr Fkkxks y h;
(A) particle stops and
spherical body move v oLr qd.k dhfn' kk esaxeu v
r
r
in the direction of dj r hgS A
particle (B) d.k o xks y h; oLr qnksuks, d nw l j sdsy Ecor ~xeu
(B) both particle and spherical body move dj r sgSA
perpendicular to each other
v
v (C) VDdj dsckn d.k dk osx gS
A
(C) Velocity of particle after collision is r
r
(D) Velocity of the spherical body after v 2
(D) VDdj dsckn xksy h; oLr qdk osx r 2 gS
A
v 2 r
collision is r 2
r [ Ja
[ ky kc) &cks/ku i zd kj ]
[COMPREHENSION TYPE] i z-9 l si z-12 r d] , d vuq
PNsn i j vk/kkfj r gS
A i zR;sd i 'zu esapkj
Q.9 to Q.12 are based upon a paragraph. Each fodYi (A), (B), (C), (D) ft uesal s, d ; k, d l sv f/kd l ghgS
A
questions has four choice (A), (B), (C), (D) out of
which ONE OR MORE THAN ONE is correct v uq
PNsn i z'u l a
[ ; k 9 l s10
Paragraph for Question Nos. 9 to 10 nzO
; eku m dh, d oLr qpkbZh l sfoj ke l sfxj usdsckn]
After falling from rest through a height h a body of nzO; eku M(M>m) mBukvkj EHkgksrkgS; g , d f?kj uhesa
mass m begins to raise a body of mass M(M>m) la; ksft r gS
A
connected to it through a pulley.

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 16

9. Determine the time it will take for the body 9. nzO


; eku M dhoLr qdsl e; cr kb, ; g okLr fod fLFkfr esa
of mass M to return to its original position. oki l vkr hgS
A
m 2h 2m h m 2h 2m h
(A) (B) (A) (B)
Mm g Mm g Mm g Mm g
2m 2h 2m 2h 2m 2h 2m 2h
(C) (D) (C) (D)
Mm g Mm g Mm g Mm g
10. Find the fraction of kinetic energy lost when 10. t c nzO
; eku M dhoLr qxfr esat dZgksrhgSt c xfr t
the body of mass M is jerked into motion.
t kZgkfu dkHkkx Kkr dhft , &
M M
(A) (B) M M
Mm Mm (A) (B)
m Mm Mm
(C) (D) None of these m
Mm (C) (D) buea
sl sdksbZugha
Mm
Paragraph for Question Nos. 11 to 12
In the given figure F = 10 N, R = 1 m, mass of the v uq
PNsn i z'u l a
[ ; k 11 l s12
body is 2 kg and moment of inertia of the body fn; sx; sfp=kesaF = 10 N, R = 1 m, oLr qdknzO ; eku 2 kg o
about an axis passing through O and perpendicular
to plane of body is 4 kg-m2. O is the centre of mass oLr qdkt M+ Ro vk?kw. kZO l sxq
t j usoky ho oLr qdsr y dsy Ecor ~
of the body. dsi fj r %4 kg-m gS
2
A O oLr qdknzO ; eku dsUnzgS
A

11. If the ground is smooth, what is total


kinetic energy of the body after 2 seconds? 11. ; fn /kj kr y fpduk gS
] r ks2 l S
d .M ckn oLr qdh dq
y
(A) 100 J (B) 75 J xfr t t kZD; kgksxh\
(C) 50 J (D) 25 J
(A) 100 J (B) 75 J
12. If ground is sufficiently rough to ensure rolling, (C) 50 J (D) 25 J
what is kinetic energy of the body now in 12. ; fn /kj kr y i j y q
<+
d usdsfy, i ; kZ
Ir [ kq
j nj kgS
] vc fn; s
the given time interval? x; sl e; kUr j ky esavc oLr qdhxfr t t kZD; k gksxh\
(A) 18.75 J (B) 25.67 J (A) 18.75 J (B) 25.67 J
(C) 16.67 J (D) None of these (C) 16.67 J (D) bues
al sdksbZugha
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Page # 17 RANK BOOSTER PROGRAM [FULL TEST - 1]

PART - III [CHEMISTRY]


SECTION - A SECTION - A
[ fo' y s
"k. kkRed
i z'u i zd kj ]
[INTEGER ANSWER TYPE]
Q.1 to Q.8 are INTEGER ANSWER TYPE Questions. i z-1 l si z-8 r d fo' y s"k.kkRed i z'u gS
Ai zR; sd i z'u dkmkj dsoy
(The answer of each of the questions is 1 digits) d ksesnhft
1 va ; sA
1. 39 gram of anhydrous Na2O2 is treated with 1. 39 gram fut Z
y h; Na2O2 dks1 yhVj Ba
Msr uq
H2SO4 dsl kFk
1 lit of cold dilute H2SO4. The volume strength
of H2O2 solution formed is 3.36. What is the mi pkfj r dj r sgS
AfufeZ
r H2O2 foy; u dhvk; r u l keF; Z3.36
one-tenth value of percentage yield of H2O2. gS
AH2O2 dhi zfr ' kr yfC
/kdk1/10 eku D; kgS
\

2. How many compounds have more necleophilic 2. fdr us; kS


fxd by sDVkW
uLusghi zfr LFkki u vfHkf; kdhvksj
nature of benzene ring than C6H6 towards C6H6 dhvi s
{kkcsUt hu oy ; dhvf/kd ukfHkdLusghi zd fr
electrophilic substitution reaction ?
j [ kr sgS\
OH CH3 NO2
N O OH CH3 NO2
N O

Cl COCl SO3H
Cl COCl SO3H

O
O
O C CH3
O C CH3

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 18

3. How many of the following is d3s hybridised. 3. fuEu esal sfdr usd3s l a
d fj r gS
A
CrO2Cl2 KMnO4 CrO2Cl2 KMnO4
K2CrO4 K2CrO4
PbCrO4 K2MnO4 PbCrO4 K2MnO4
K2Cr2O7 K2Cr2O7

4. Find the no. of molecules which will not exhibit 4. v.kq


v ksadhl a
[ ; kcr kb, t kssp feJ.kughan' kkZ
r sgS
&
sp mixing. NO N2 B2 C2
NO N2 B2 C2 O2 O22+ O22 N22+
O2 O22+ O22 N22+ N2+
N2+

5. Find out number of substrates those cannot 5. mu vfHkdkj dksdhl a


[ ; kKkr fdft , t ksdsfut kj ksvfHkf; k
undergo cannizzaro's reaction. ughnsrsgSA

O O O O

H C H, Ph C H, H C H, Ph C H,

O O O O

H3C C H, C H , H3C C H, C H ,

O O O O O O
, , , ,
H C C H Cl3C C H H C C H Cl3C C H

O O O O O O O O
Ph C C Ph , Ph C C H , Ph C C Ph , Ph C C H,

O CH O CH

O O

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6. The orbit and orbital angular momentum of 6. , d by sDVkW


u dk d{kh; r Fkk d{kdh; dks.kh; l a
osx
3h 3 h
an electron are and 3h 3 h
2 2 respectively.. e' k% r Fkk gS
Ami dks'kft l esafn; kx; ke
2 2
Find multiplication of no. of Radial & no. of
Angular nodes for the subshell in which the mi fLFkr gksrkgS
] dsf=kT; uksMr Fkkdks.kh; uksM+
ksdhl a
[;k
given e is present.
dkxq
. kuQy Kkr dj ksA
7. , Ydksgyksdhl a
[ ; kcr kb, ] t ks/kukRed vk; ksMkQ
sWkW
eZi j h{k.k
7. Find out the number of alcohols that can
give positive iodoform test.
nsl dr sgSA
OH
OH
(i) (ii)
(i) (ii)
OH
OH
OH
OH
OH
OH |
| (iii) CH CH3 (iv)
(iii) CH CH3 (iv)

8. eksy j nzO
; eku 96 g/mol dh , d /kkr q'M' y ksjhu l s
8. A metal 'M' of molar mass 96 g/mol reacts
with Fluorine to form a salt represented as f; k d j , d MFx i z
d kj dky o.kcukr hA'x' Kkr dj us
MFx. In order to determine 'x', 41.20 gms of
dsfy , 41.20 gms y o.kdks100 gm H2O esa?kksy us
slat is dissolved in 100 gm of H2O & boiling
pt. of the soln. was determined to be 374.38K. i j foy ; u dkDoFkuka
d 374.38K i zkIr gq
v kA
[Kb(H2O) = 0.512 K kg/mol. Tb(H2O) = 373] [Kb(H2O) = 0.512 K kg/mol. Tb(H2O) = 373] 'x'
Find 'x'. (Assume No. dissociation of salt).
Kkr dj ksA(ekuky o.kdkfo; kst u ughagksrk)
SECTION - B SECTION - B
[MULTIPLE OBJECTIVE TYPE] [ cgqoS
d fYi d i z'u i zd kj ]
Q.1 to Q.8 has four choices (A), (B), (C), (D) out i z-1 l si z-8 esapkj fodYi (A), (B), (C), (D) gS
] ft uessal s^^, d
of which ONE OR MORE THAN ONE is correct ; k, d l svf/kd^^ l ghgS
A

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1. For a strong electrolyte MCl2 in water at 25C 1. 25C i j t y es a, d i zcy oS


|qr vi ?kV~
; MCl2 dsfy ,
the following data is given. fuEu MkVkfn; kx; kgS A
conc. (mol/lit) 0.16 1 l kUnzrk(mol/lit) 0.16 1

M 1cm2mol1 282 240

M 1cm2mol1 282 240


M
2
(Maq 1
) 110 cm mol ; 2 1
M N 90 )
2
aq
M

(M2aq ) 1101cm2mol1; M Naq
2
90 )

(A) of MCl2 at 25C = 310 1cm2mol1
M (A) M of MCl2 at 25C = 310 1cm2mol1
(B) M of MCl2 at 25C = 212 1cm2mol1 (B) M of MCl2 at 25C = 212 1cm2mol1
(C) M of NCl2 at 25C = 290 1cm2mol1 (C) M of NCl2 at 25C = 290 1cm2mol1

(D) M of NCl2 at 25C = 202 1cm2mol1 (D) M of NCl2 at 25C = 202 1cm2mol1

2. Identify the correct statement 2. l ghdFku i gpkfu, A


(A) Frenkel defect appears in AgI, Zns and
AgBr (A) AgI, Zns r FkkAgBr es asa
d y nks"ki k; kt kr kgS
A
(B) Zinc Blende structure is obtained when (B) t c Zn v) Zpr q
+2
"dQy dh; Hkkxksadks?ksjr sgSr ks
Zn+2 occupies half tetrahedral sites ft a
d Cy sUMl aj puki zkIr gksrhgS
A
(C) Ferrimagnetism is in the allignment of
magnetic moments (C) y ks
g pqEcdRo pq Ecdh; vk?kw . kksZdsxBca
/ku esagksrkgS
A

but not in . fdUr q esaugha

(D) In antifluorite structure cations are (D) , U


VhyksjkbMl j pukesa
a /kuk; u CCP esaO; ofLFkr gksrs
arranged in CCP while Anions occupy all the gSt cfd _ .kk; u l Hkhpr q
"Qy dh; fj Dr ksadks?ksjr sgS
A
tetra hedral void.
NaOH
NaOH 3. PhCH=O+CH3CHO kW
l mRikn
3. PhCH=O+CH3CHO Cross product Select
the correct statement about the product.
mRikn dsl a nHkZesal ghdFku pq
fu, &
(A) product give 1,4 addition with Gilman's (A) mRi kn fxyeku vfHkdeZ d dsl kFk1,4 ; ksxt nsrkgS
A
reagent. (B) mRi kn RMgX dsl kFk1,2 ; ksxt nsrkgS A
(B) Product gives 1,2 addition with RMgX
(C) mR
i kn C H(COOC2H5)2 dsl kFk1,4 ; ksxt nsrkgS
A
(C) Product give 1,4 addition with CH(COOC2H5)2 (D) mRi kn T; kfefr ; l eko; or kn' kkZ
r kgS
A
(D) Product shows geometrical isomerism.

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Page # 21 RANK BOOSTER PROGRAM [FULL TEST - 1]

4. When H2S is passed through Hg22 , we get: 4. t c H2S dksHg22 l sxq


t kj r sgS
] r kskIr gksrkgS
\
(A) HgS (B) HgS + Hg2S (A) HgS (B) HgS + Hg2S
(C) HgS + Hg (D) Hg2S (C) HgS + Hg (D) Hg2S

5.
5.

CH 3O OCH3 O
CH 3O OCH3 O
C OCH3
(i) H3O
(A) C OCH3
(i) H3O
C OCH3 (ii) (A)
C OCH3 (ii)
O
Zn,Hg,HCl 1 O
Zn,Hg,HCl

Cl 2, (monochlorination)
(C) (B) Cl 2, (eks
uksDyksjhuhdj .k)
hv (C) (B)
hv
A, B, C are respectively
A, B, C e' k%gS
&
O O
O O
Cl
C OH Cl
(A) , , C OH
(A) , ,

O O
Cl Cl
(B) , , (B) , ,

O O O Cl O O O O Cl O
C OH C OH C OH C OH C OH C OH
(C) , (C) ,

(D) None of these (D) bues


al sdksbZugha

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 22

6. Which of the following is not correct? 6. fuEu esal sdkS


ul k xy r gS \
(A) XeO3 has four and four -bonds. (A) XeO3 pkj r Fkk pkj - ca /k j [ kr k gS
A
(B) The hybridization of Xe in XeF4 is sp3d2 (B) Xe dk l a d j .k XeF4 esasp3d2 gS A
(C) Among noble gases, the occurrence of
argon is highest in air. (C) mR d`"V xSl ksaesal svkW xZu dkmRl t Z u ok; qesamPpr e
(D) Liquid helium is used as cryogenic liquid. gksrkgS
A
(D) nzo ghfy ; e i fj ' khr u r j y ds: i esai z;qDr gksrkgSA

7. Select the correct statement(s). 7. l ghdFku pq


fu; s
O O
|| ||
(A) HOOC CH 2 NH C CH NH 2 is a (A) HOOC CH 2 NH C CH NH 2
| |
CH 3 CH 3
dipeptide of Glycine & Alanine, whose Xy kbfl u o , y sukbu esaMkbi sIVkbM gSft l dk l a
f{kIr
abbreviated name is GLY-ALA
uke GLY-ALA gS A
OH
OH
(B) s hows K e to-e nol
(B)

O
O
tautomerism.
(C) Phenol & benzoic acid can be distinguished dhVksbZukW
y py ko; or kn' kkZ
r kgS
A
by NaHCO3. (C) NaHCO3 ds} kj k fQukW y r Fkk csUt ksbd vEy dks
O foHkDr dj r sgS
A
O
O O O
O
(D ) and c an be
(D) vk; ks
MksQkeZi fj {k.kds} kj k o
O
distinguished by iodoform test. O
dksfoHkDr dj r sgS
A

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8. p Cu2O + q MnO4 + r H2O s MnO2 + t Cu 8. p Cu2O + q MnO4 + r H2O s MnO2 + t Cu


(OH)2 + u OH (OH)2 + u OH
where p, q, r, s, t and u are stoichiometric t gkap, q, r, s, t r Fkku l a
rq
fy r j kl k; fud vfHkf; kesa
coeff. of resspective reaction species in la
xr vfHkf; kLi h'kht dsj l l ehdj .kfer h; xq
. kka
d gS
%
&
Balanced Chemical equation
(A) r dkeku = 1
(A) Value of r = 1
(B) Value of u = 2 (B) u dkeku = 2
(C) Value of p = 3 (C) p dkeku = 3
(D) Value of q = 2 (D) q dkeku = 2

[COMPREHENSION TYPE] [ Ja
[ ky kc) &cks/ku i zd kj ]
Q.9 to Q.12 are based upon a paragraph. Each
questions has four choice (A), (B), (C), (D) out of i z-9 l si z-12 r d] , d vuq
PNsn i j vk/kkfj r gS
A i zR;sd i 'zu esapkj
which ONE OR MORE THAN ONE is correct fodYi (A), (B), (C), (D) ft uesal s, d ; k, d l sv f/kd l ghgS A
Paragraph for Question Nos. 9 to 10 v uq
PNsn i z'u l a
[ ; k 9 l s10
1 gram of CH4 diffuses in 20 sec under certain 1 gram of CH4 fuf' pr voLFkkvks aesa20 sec esafol fj r
conditions. Under the same conditions 20 gksrkgS Al eku voLFkkvksa esa 20 g gkbMksd kcZ u(A) 40
g of a hydrocarbon (A) diffused in 40 sec.10 sec. es afol fj r gksrkgS
A 'A' ds10 mg uew usdksbl dh
mg. of sample of 'A' requires 8.40 ml of H2 vl ar Ir kdhek=kkeq Dr dj usdsfy , P = 760 mm r Fkk
gas at P = 760 mm & T = 0C to remove it's
T = 0C i j 8.40 ml H2 xS l dhvko' ; dr kgS A
degree of unsaturation.
9. The number of bonds present in hydrocarbon
'A'. 9. gkbMksd kcZ
u 'A' esami fLFkr ca
/kksadhl a
[ ; kgS
A
(A) 2 (B) 1 (A) 2 (B) 1
(C) 3 (D) 4 (C) 3 (D) 4

10. No. of O2 molecules required for complete 10. 1 eks


y 'A' dsl a
iw
. kZngu dsfy , vko' ; d O2 v.kq
v ksadh
combustion of 1 mole of 'A'. la
[ ; kgS
A
(A) 4 (B) 8 (A) 4 (B) 8
(C) 7 (D) 6 (C) 7 (D) 6

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RANK BOOSTER PROGRAM [FULL TEST - 1] Page # 24

Paragraph for Question Nos. 11 to 12 v uq PNsn i z'u l a[ ; k 11 l s12


For a typical nucleophilic aromatic substitu- , d U; q
fDy ; ksfQfy d , sjksesfVd i zfr LFkki u vfHkf; kgksrh
tion reaction to take place. gSa
1. Nucleophilic atom should be of oxygen,
1. U;qfDy ; ksfQfy d i j ek.kqvkW Dl ht u] ukbVkst u ; k
nitrogen or sulphur
2. Leaving groups should be halide.
l YQj gksl dr kgS a
3. There should be strong electron with- 2. i z
fr d"khZl eq g gsy kbMgksl dr kgS a
drawing at ortho and para position to 3. i z
fr d"khZl ew g vkFkkZs; ki sjkfLFkfr l si zcy by sDVkW
uks
leaving group. dksf[ kpr kgS A
Cl NH2
Cl NH2 Cl NH2
Cl NH2
Cl NH2 Cl NH2
NH2
+ Cl
NH2 R.D.S.
+ Cl
R.D.S.
C C C C
C C C C O CH3 O CH3 O CH3 O CH3
O CH3 O CH3 O CH3 O CH3

11. r st hl sgksusoky hU;q


fDy ; ksfQfy d , sjksesfVd i zfr LFkki u
11. Fastest nucleophilic aromatic substitution
reaction take place in. vfHkf; kfuEu esagksrhgS a

F Cl Br I F Cl Br I

(A) (B) (C) (D) (A) (B) (C) (D)

NO2 NO2 NO2 NO2 NO2 NO2 NO2 NO2

12. Find out correct product of following reac- 12. fuEu vfHkf; kesal ghmRikn dksi gpkfu; sA
tion.
NO2
NO2
CH3 O ?
CH3 O High temp.
?
High temp. F
F Cl
Cl
NO2 NO2
NO2 NO2
(SPACE FOR ROUGH WORK)
(A) (B)
(A) (B) OCH3 F
OCH3 F Cl OCH3
Cl OCH3
NO2 NH 2
NO2 NH 2

(C) (D)
(C) (D) OCH3 F
OCH3 F OCH3 OCH3
OCH3 OCH3

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