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1. Introduction
*
Corresponding
author. The inherent con-ditions standing these challenge that
E-mail address: alaanooh@hotmail.com (A.Z. of these wells cause the extreme pressures should be extremely
rheological parameters of and temperatures. considered.
Noah).X H
P fluids to differ The narrow Additionally, HPHT
enormously. Challenges boundary between wells frequently
Peer review under responsibility of Egyptian of HPHT wells include the pore pressure have high ECD
Petroleum Research Institute. the high cost essential for and fracture leading to down
the equipment and the gradient is also hole problems such
materials that are able to significant as mud losses into
1 Research Institute. under the CC http://creativecommons.org/lic
1 Production and BY-NC-ND enses/by-nc-nd/4.0/).X
http://dx.doi.org/10.1016/j.ejpe.2016.0 This is an open
hosting by Elsevier license (
3.002 access article
B.V.
4.2 ml
Wetting agent
and the mixture is thermally aged in hot rolling with oil base mud Mud weight of this sample 1.7 ml
over for 16 h at 350 LF. After 16 h the mixture is out and the 12 PPg: Viscofire
rheological parameters are measured again using the HPHT 8g
viscometer at 120 LF (at 500 psi) and the HPHT fluid loss at 350 LF Oil=water ratio 88=12: Lime
(at 500 psi). This nanocomposite with oil base mud was used for 3g
drilling in HPHT wells. Barite
2.3. Characterization 255 g
Filter loss reducer
2.2.4. Preparation of PSBR/CaCO3 nanocomposites 2.5 g
2.3.1. X-ray diffraction (XRD) Fresh water
(33 ml water + 15 g CaCl2)
The preparation of PSBR/CaCO3 nanocomposites, 0.5 g of PSBR The crystal structure of the
was dissolved in 10 ml of toluene to obtain a 5% solu-tion after one filler powders was determined
hour of stirring. The polymer nanocomposite solution was prepared using a Philips X-ray
by adding modified nano-CaCO3 pow-der into PSBR solution and diffractometer (PW 1930
the mixture was stirred for 16 h and then sonicated for 30 min, and generator, PW 1820 resolution of 4 cm1 and 32
the mixture is thermally goniometer), equipped with Cu scans. The samples were
Ka radiation (45 kV, 40 mA, prepared by pressing 100 mg of
with k = 0.15418 nm). The KBr and 2 mg of powder to
aged in
scans of the analy-sis were run give a thin disk. A reference
hot
in 2h range of 580L with step spectrum of a pure KBr disk is
rolling with oil base mud over
size of 0.02 and step time of 1 used.
for 16 h at
s.
350 LF.
After 2.3.3. Scanning electron
16 h the mixture is out and the microscopy (SEM)
rheological 2.3.2. Fourier transmission
infrared spectroscopy (FT-IR) The morphology of the
parameters are measured another time using the HPHT vis-cometer nanomaterials was detected
at 120 LF and the HPHT fluid loss at 350 LF and 500 psi. This FT-IR spectra of nano-CaCO3 using a scanning electron
nanocomposite with oil base mud was used for drilling in HPHT microscopy (SEM) (High
and ZnO-NPs were achieved
wells. Resolution Quanta FEG 250-
using a Thermo Scientific
Nicolet 380 Spectrometer, SEM, Czech Republic) to
2.2.5. Preparation of oil base mud sample at Egyptian Mud USA, in the spectral range investigate the fil-ler dispersion
Engineering Company (EMEC) between 4000 cm1 and 600 cm1 and the compatibility between
polymer and fil-ler. The
with a
2.2.5.1. Composition of oil base mud sample. This method involves surfaces of the samples were
in mixing of the raw materials in different percent-ages; after this, Table 1 Composition of oil base examined without coated gold
the freshwater is added to mixture drop by drop through stirrer in mud. and at low vacuum.
barrel for 1 h ( Table 1). Then they are put in thermo cup using
different temperatures. The next step is to measure the mud rheology Diesel 2.3.4. Transmission electron
by HPHT viscometer. Controlling mud weight depends on the microscopy (TEM)
238 ml
percentage of diesel and barite.X Emulsifier
The structure and surface morphology of the prepared ZnO-NPs and of emulsion stability is The XRD patterns of ZnO
its nanocomposites were studied using JEOL JEM-1230 generally smooth, shiny and nanoparticles and PSB/ZnO
transmission electron microscope (TEM) with accel-eration voltage does not adhere to the stirring nanocomposites are displayed
of about 80 kV. The nanocomposite samples were prepared by spindle of a mixer. By con- in Fig. 1. The XRD profile
adding a small drop of the dispersion of polymer bio- trast, a mud with a low degree ZnO-NPs showed characteristic
nanocomposites onto a Lacey carbon film-coated copper grid and of emulsion stability is dull, peaks corresponding to the
allowed to dry initially in air then by applying high vacuum grainy and shows a marked planes (100) at 2h = 30.74L,
tendency adhere to the spindle. (002) at 2h = 34.5L, (101) at 2h
The oil wetness or oil wetting = 36.8L, (102) at 2h = 47.7L,
tendency of an invert emulsion (110) at 2h = 56.2L, (103) at 2h
3. Results and discussion mud is defined here as the = 61.7L and (112) at 2h =
ability of the mud to 67.6L. This XRD pattern shows
In this paper, the authors offer a solution to one of the most incorporate foreign materials that the preparation of ZnO-
significant challenges of the drilling fluids in HPHT (high pres-sure into the external, or oil phase. NPs leads to wurtzite phase and
high temperature) wells circulation as ( Table 2); carrying the drill A mud with high emulsion all the diffraction peaks agree
cuttings back to the surface for continuous polymers has been stability is phase. A mud with with the reported JCPDS data.
widely used as drilling additives because of their unique structure high emulsion sta-bility is oil This was confirmed by TEM
that makes them able to plug pores, and stand the high temperature wet, by definition, but may not observation, in which ZnO-NPs
and pressure conditions. Conversely, the properties of the mud can necessarily be oil wetting. appear as spherical particles
be further enhanced by using nano-materials that can enable the with size around 6 nm as shown
drilling fluid to function better under extreme conditions. X in ( Fig. 2). Furthermore, the
3.1. Structure of ZnO XRD patterns ofX
Electrical stability (ES) of an oil base mud is considered a measure nanoparticles
of its emulsion stability. In the laboratory, a mud with a high degree
Please cite this article in high temperature wells by using polymer nanocomposites
press as: A.Z. Noah et al., based on ZnO & CaCO3 nanoparticles, Egypt. J. Petrol.
Enhancement of yield
point at high pressure X
(2016), http://dx.doi.org/10.1016/j.ejpe.2016.03.002
4 A.Z. Noah et al.
Table 2 Influence of polymer nanocomposites based on modified nano-CaCO 3 and ZnO-NPs on oil base mud.
Composition
Before hot rolling
After hot rolling
Before hot rolling/after point
point
pressure 500 psi)
29 0.5 ZnO-NPs
600
Blank (PSBR) 6
88
600 10
31
60
200 26
22
28 600
16
83
600 6
29
58 9
25
21
11/6
15
1220/1850
15/12
with 0.5 PSBR
1200/850
after 300
16 h 57
300 100
38 22
3
8 300
54
300 100
36 22
3
8
after 16 h
200
43
200 6
0.5 modified
29 10
600
77 200
27 40
23
200 6
600
28 9
71
25
21
10/7
1200/1550
nano-CaCO3 100
300 34
38
100 3
22 8
100
300 33
36
100 3
22 8
3
6 12
13
3
12
b
a
[20] J.K. Yong, H.K. Kyoung, S.L. Chang, B.S. Kwang, J. Ceram.X
[16] A.M. Youssef, H. Abou-Yousef, S.M. El-Sayed, S. Kamel, Int.X
Please cite this article in press as: A.Z. Noah et al., Enhancement of yield point at high
pressure high temperature wells by using polymer nanocomposites based on ZnO &
CaCO3 nanoparticles, Egypt. J. Petrol. (2016),
http://dx.doi.org/10.1016/j.ejpe.2016.03.002 X