Sol 9

1
AITS-FT-II-(Paper-2) PCM(Sol)-JEE(Advanced)/15
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ANSWERS, HINTS & SOLUTIONS

FULL TESTII
(PAPER-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1. B C B
ALL INDIA TEST SERIES
2. B A C
3. A D D
4. B A B
5. A C D
6. C D D
7. D C C
A, B A, B, C, D C, D
8.
A, B, C A, B, C B, C
9.
A, B B, D A, B, D
10.
A, B, D C, D A, C
11.
12. A B B
13. A B D
14. A B B
15. A C A
16. B D C
(A) (q), (A) (s), (B) (r), (A) (p, q, s)
(B) (p, q, s, t), (C) (q), (D) (p) (B) (t) (C) (s)
1.
(C) (p, q, s, t), (D) (q)
(D) (r, s)
(A) (r), (B) (r), (A r), (B s ), (A) (p) (B) (q)
2. (C) (p), (D) (p) (C p, ), (D q) (C) (p)
(D) (t)
1. 3 2 3
2. 2 5 4
3. 7 2 2
4. 2 6 7
5. 5 2 8
6. 4 4 5
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2
Physics PART I
SECTION A
1. Momenta and charged are equal and opposite, so sense of the motions are opposite.
Mv
R= their radii are equal.
qB
2. We can not assume total mass to be concentrated at centre of mass for calculation of all the thing e.g.
for calculation of moment of inertia, calculation of torque of centrifugal force on a rod about hinge as
shown.
(i) (ii)
6. Kx = (m + M) a + ma cos
Block: a + a cos = g sin
...(ii)
From (i) & (ii)
Kx mgsin cos
a K1x K 2
M msin2
Max. compression
2mgsin cos
= Block + Wedge
K
7. Net magnetic moment of loop formed is zero, hence torque due to magnetic field is zero.
11. K = K D + KP A
1 1 1 v
= mv 20 1 m(2V0 )2 C
2 2 2
11 O
= mV02
4
3
SECTION C
3. Let A, B, and C be C.M. of larger
section , smaller section and total rod
L L
CC ' , AC '
12 6
1
2 2
L L L 2
OC = =
2 6 12
65
L
12
Moment of inertia about O
7
I ML2 Maximum torque of about O
8
3Mg
max = (OC)
2
65 g
max = max
I 7 L
sin 900
4. = 2
sin 300 900
300
5. kx0 = ma0
L ML2 3 g
6. = /I = Mg
2 3 2L
Mg N
acm = L/2 = 3g/4 =
M
Mg
N=
4
4
Chemistry PART II
SECTION A
1. Diazomethane being a base will pick up the hydrogen which is most acidic. The H of the OH group
ortho to NO2 group is most acidic
OH OH

H O O
NO2 OH NO2 OH
CH 2 N N

CH 3 N N
2. Choice (B) is incorrect as all the gases above their respective Boyles temperature show throughout
+ve deviation.
4. All reducing sugars are mutarotating. Although IV is an -hydroxy ketone and hence reducing but it
cant mutarorate as it is not a carbohydrate/cant form ring. In II the glycosidic bond is in between two
anomeric carbons and hence ring opening cant occur. Thus non-reducing as well as non-
mutarotating.
5. Mg 3 N 2 6H 2O
3Mg(OH) 2 2NH3
(A)
2NH 3 3CuO
3Cu N 2 3H 2O
(C)
NaNO2 Zn NaOH Na2 ZnO2 NH3 H2O

Ammonium salts containing anions which are oxidizing in nature, on heating liberates N2(g) instead of
NH3.
9. At constant pressure, the addition of inert gas shifts the equilibrium towards larger no. of moles.
14. Since, it liberates a gas on reaction with dilute H2SO4, it cannot be a sulphate salt, it would be a
carbonate salt. Malachite ore of copper, CuCO3. Cu(OH)2 is green in colour.
2
15. Cu NH3 4 2KCN Cu CN 2 2K 4NH3
Blue colour Yellow ppt
decomposes
2Cu CN 2 2CuCN CN 2
White ppt
3
CuCN 3KCN Cu CN 4 3K
Colourless
Cu1 has a d10 configuration, so it is tetrahedral in shape with sp3 hybridization.
16. Gravimetric estimation of Cu2+ would be possible only when the given procedure gives an insoluble
compound on treatment with a given reagent.
5
Cu SCN 2 2K
Cu2 2KSCN
Black ppt
decomposes
2Cu SCN2 2CuSCN SCN2
White ppt
With other reagents, either there is no reaction or even if it reacts, then the product is a soluble
compound.
SECTION C
1. Only two optically active isomers are possible.
CH3 CH3
H Br Br H
H Br Br H
Br H H Br
CH3 CH3
rCnH2n 2 1 MH2 O
2.
rH2 O 2 MCnH2n2
MCnH2n2 = 4 18 = 72
12 n + 1 (2n + 2) = 72
14n + 2 = 72
n=5
3. Let formula of hydrated dibasic acid be H2 A .x H2 O
Equivalent of dibasic acid = Equivalent of NaOH
2.505 2 35
1
M 1000
2.505 2 1000
M 143.14
35 1

H2 A.xH2 O H2 A xH2 O
Mole of H2 O formed x mole of hydrated dibasic acid

(1.01 0.72) 1.01
x
18 143.14
x 2.28
degree of hydration is 2.
OH OH
COOH Br Br
4. + 3Br2(aq) + CO2+3HBr
(Molar mass = 138) Br
276
Moles of salicylic acid 2
138
Moles of Br2 required = 3 2 = 6.
5. Let basicity of acid be n.
Equivalent of acid = Equivalent of KOH
6
1 n 0.768

146 56
0.768 146
n 2
56
6. Three in the ring and fourth on the CH2 group as shown
1 2
4
CH2 3
7
Mathematics PART III

SECTION A
1. Let x bullet are fired at A

E1 the target is at A, E2 the target at B
E the target is hit
27 1 E
P E1 , P E2 , P = probability that target is hit when x bullet are fired at A
28 28 E1
x
1
= 1
3
47 x
E 1
P 1
E2 3
x 47 x
A A 27 1 1 1
P E P E1 P P E2 P = 1 1
E1 E2
28 3 28 3

27 x 1 x 47
= 1 3 3
28 28
d 27 x 1 x 47

dx
P E
28
3 ln3
28
3 ln3
d2 27 1
dx2
P E 28 ln3 2 3 x 28 ln32 3x 47 0
d
For maximum P(E)
dx
P E 0 27 3x = 3x 47 x = 25
x x 1 ..... x r 1
2. For 0 r n, the polynomial x Cr is of degree r
r!
x x x
Q(x) = C0 + C1 + .. + Cn is polynomial of degree n
Q(k) = 2k for k = 0, 1, 2, .., n
P(x) = Q(x) x then
P(n + 1) = Q(n + 1) = 2n + 1 1
3. If a polynomial a0xn + a1xn 1 + .. + an is such a polynomial,

We can assume a0 = 1, let r1, r2, .., rn are its roots
r12 r22 ..... rn2 a12 2a2 , r12r22 ..... rn2 an2
a12 2a2 2/n
AM GM an
n
a1, a2 = 1, we must have a2 = 1, and n 3
Polynomials are
(x 1), (x + 1), (x2 + x 1), (x2 x 1), (x3 + x2 x 1), (x3 x2 x + 1)
f n 1 8 22 65 209 732
4. For n = 1, 2, 3, 4, 5, 6, = 3, , , , ,
f n 3 8 22 65 209
8 f n 1 8
The minimum of these is , for n > 6, 3
3 f n 3
5. Let 1 + sin x = y
8
1 3y 3y
I dy again let t2
y 1 y 1 y
t2 t 3
I = 8 dt 3 ln 2 tan1 t c
t 2

3 t 1 2
t 3
1/3 1/3
6. Let a 108 10 , b 108 10
a b = x, a3 b3 = 20, ab = 2
3 3 3 3
x = (a b) = a b 3ab(a b) = 20 6x
3
x + 6x 20 = 0
x = 2 is only one real solution
7. c1c2 = 1000 320 = 680

2 2
c 1p = c1c 2 320 600 , PQ = r1 c1p = 1000 600 = 400
8. S = + = 1
2
z2n 1
3 z 1 1
P = = z 2 2
sec 2
z 1 1
z 1 z 2 4 2n 1
z
1
9. f6 fm x f4 x
1 x
fm x 1 1
f6 fm x
fm x 1 x
x 1
Let f m(x) = k fm x f6 x m = 6
x
1
Assign, f n(f4(x)) = f 3(x) =
x
1 1 1 t 1
fn let 1 x = t x = t hence, n = 5
1 x x
x x x
10. Given equation can be written as xf t dt t f t dt f t dt sin x cos x x 1 differentiating
0 0 0
x
x f x f t dt x f x f x cos x sin x 1 again differentiating
0
f(x) = f(x) sin x cos x which is linear differential equation of 1st order whose solution gives
x x
ye = e cos x + c
x = 0, y = 0 c = 1
x
f(x) = e cos x
11. Let f(1) = t

1
Put x = 1 in f x f f x 1 .. (1)
x
We get
1
tf(t + 1) = 1 t 0 and f(t + 1) =
t
1 1
Put x = t + 1 in equation (1), we get f t f 1
t t 1
9
1 1 1 5
1 t
t t 1 2
1 5 1
But for t , t > 1 f(1) < f(1 + t) = 1 a contradiction
2 t
12. Let M (line be r ai bj ck then acute angle between L and M is

a c cos 2b sin a c 3
cos
2 2 a2 b2 c 2

, a + c = 0, b = 0, c = a
6
M i k
13.
M meets the given plane in P1, 2 3, 0, 2 3 line L meets the plane in

P 2cos 2 3, 2 2 sin , 2 cos 2 3
2
Thus (PP1) = 8
P describes a circle of radius 2 2
14. In radians we can say

x x x
sin x sin sin or sin 2
180 180 180
180 360
x or x
180 180
p m
On comparing with and
q n
We have, m = 360, n = 180, p = 180, q = 180
m + n + p + q = 900
15. lim
A C x 2 2
Bx
2 for existence of limit A = C
2
x B
x A C
x
BC B
Hence, (using A = C2)
A C
B
L 2
A C
If C = A then limit does not exist hence C A
B
4
C
16. g(x) = 2f(10 2x) g(L = 2) = 2f(6) = 0
SECTION B
x/2
1. (A) x 2 5x 6 x 2 5x 4 A
x/2
x2 5x 6 x 2 5x 4 B
10
x4 x x
Now, A + B = 2 4 2 2 4 , AB 2 2
AB=0A=B
Since power of A and B are same
x = 0, x2 5x 4 0 x = 0, 4, 1
2
x2 x 2 x2 x 2
(B) Equation can be written as 2 a 3 2 a 4 0
x x 1 x x 1
x2 x 2 7
t 2 as t 1,
x x 1 3
7
Equation reduces to t2 (a 3)t + (a 4) = 0 at least one root of equation lies in 1,
3
t = a 4, 1
7 7 19
One root lies in 1, 1 a 4 a 5,
3 3 3
2 2
2 x x
(C) 1 x 1 ..... 1 3 ..... P0 P1x ..... Pr x r ..... .. (1)
2 2
x
Replace x by
2
2 2 2
x x x x n
1 1 2 ..... 1 n P0 P1 ..... Pr x .....
2 2 2 2

Equating the coefficient of xr
22 Pr 1 Pr 2
Pr putting x0 in (1), we get P0 = 1
2r 1
1 1
P1 2 1 2 ..... 4
2 2
(D) x + y + z = n, x 1, y 1, z 1 number of solution is Pn n 1Cn3
n 1 n n 1
Cn 3 Cn 2 Cn1 n 1n 2 n n 1 n n 1
n n 1 n 2 1
Cn 2 Cn 1 Cn n n 1 n n 1 n 1n 2
8
n 1
Cn 1 n 2
Cn n 3
Cn1 n n 1 n 2 n 3 n 2
n 1
1 n n 1 n
1
On applying C3 C3 C2, C1 C1 C2 and C1 C1 + C3 = 0 2n 1 = 1
2
0 2 n 1 1
|| = 1
6
2. (A) z = (2 cos 30 cos 18 + i2 sin 30 cos 18)
= 26 cos6 18 (cos 180 + i sin 180) = 26 cos6 18
2 dy
(B) f(x) + f (x) = 1 y 2 1 y = tan (c x)
dx

We must have c a = 2n 1 and c b = 2n 1 for some n I
2 2
ba
min 1

(C) Let cos1 x = then tan tan 1
4 2 4 2
2 sec = 1
11
1
sec no solution
2

(D) 7 = 4 = 3 tan 4 = tan 3
7
t3 21t2 + 35t 7 = 0, t = tan2
2 3
Above equation has the roots tan2 , tan2 , tan2 and sum of roots = 21
7 7 7
1
Replacing t =
r
7r3 35r + 21r 1 = 0 has three roots
2 3
cot 2 , cot 2 , cot 2 and sum of roots = 5
7 7 7
SECTION C
f x dx
1. Let g x x 2 x 13 .. (1)
A B C D E
= x x 2 x 1 x 12 x 13 dx

B D E
= A ln x Cln 1 x
x 1 x 2 x 12
Since g(x) is a rational function hence A = C = 0
B D E
g x 2 2
3
dx .. (2)
x x 1 x 1

Comparing (1) and (2), we get f(x) = (B + D)x 3 + (3B + D + E)x2 + 3Bx + B
f(x) is quadratic
B + D = 0, f(0) = 1 gives B = 1 D = 1
f(x) = (2 + E)x2 + 3x + 1
f(0) = 3
1 0 1
2. 0 1 1 R1 R1 R 3 , R 2 R 2 R 3 on solving [x] + [y] + [z] + 1, taking maximum value, we
x y z 1
get 4
36 3 8
3. tan1 tan1 tan1
77 4 15 2
cot cot and hence A

cot 1
cot
and tan tan 1 A + B = 2
4. A = f(1) = 19
B = g(9) = 2 ln 3
C= 3
1

3 x 2 2x 2
dx ln9 ln27 ln3
2
2 x 3x 6x 11
12
t2
d
D= g x dx 6g 9 12 ln 3
dt 1
A(B + C) D = 7 ln 3 k = 7
2 O
5. r1 r2 r1 r2 sin
n
A3
2 2
r1 r2 r1 r2 cos
n n r2
2 2
The given equality reduces to tan 1
n n
2 8 A1 r1 A2
m n m z , least n = 8
n 4 1 4m
6. Using reflection property of ellipse equation of reflected

ray SP is B P
4x + 3y = 12 .. (1)
Solving equation (1) with ellipse, we get
75 32 S S
A ,
17 17
A
Equation of reflected ray BS is
16x + 63 + 48 = 0 .. (2)
Equation of incident ray PB is
y=4 .. (3)
Equation of bisector of (2) and (3) with negative slope gives normal to circle at 3 which is
4x + 32y 53 = 0
75
Point B is , 4 , using parametric equation of line ordinate of centre is 5
4

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ANSWERS, HINTS & SOLUTIONS

NaNO2 Zn NaOH Na2 ZnO2 NH3 H2O

Blue colour Yellow ppt

1. Only two optically active isomers are possible.

Mole of H2 O formed x mole of hydrated dibasic acid

Mathematics PART III

1. Let x bullet are fired at A

3. If a polynomial a0xn + a1xn 1 + .. + an is such a polynomial,

7. c1c2 = 1000 320 = 680

11. Let f(1) = t

12. Let M (line be r ai bj ck then acute angle between L and M is

14. In radians we can say

16. g(x) = 2f(10 2x) g(L = 2) = 2f(6) = 0

cot cot and hence A

6. Using reflection property of ellipse equation of reflected

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