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1 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
PART TEST I
PAPER-2
ANSWERS KEY

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS


1. D 24. B 47. B
ALL INDIA TEST SERIES

2. A 25. C 48. A

3. B 26. C 49. A
4. A, D 27. B, C, D 50. A, B, D
5. C 28. A, C 51. A, B
6. A, C 29. A 52. B, C

7. B, C, D 30. A, D 53. D

8. B, D 31. B, C, D 54. B, D
9. B 32. A 55. A

10. B 33. D 56. A


11. 5 34. 5 57. 2

12. 9 35. 7 58. 7


13. 8 36. 8 59. 1
14. 4 37. 4 60. 4

15. 6 38. 2 61. 3


16. 5 39. 4 62. 7
17. 2 40. 3 63. 0

18. 6 41. 3 64. 9


19. 7 42. 7 65. 1
20. 3 43. 3 66. 7

21. 00006.25 44. 205.02 67. 00000.12


22. 00006.40 45. 28.88 68. 00000.21
23. 00018.75 46. 8.34 69. 00000.15

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AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 2

Physics PART I

SECTION A
2H
1. D 2g(2R)
g

2. Moment of inertia of combined system about y-axis


2
R
4m 2 2
2 mR mR mR2 2mR2
4 4 2
Conservation of angular momentum along y-axis
R
mv0 2mR2
2
v0

4R

1 1
3. fk on the block B = mg i k
2 2
i k
Pfk mg
(v 0k)
2 2
mgv 0

2
dQ 2
mgv0 2mgv 0
dt 2

4. For equilibrium T + dT

2 2


0

Rg cos d Rg sin d
0 d
dN

=1
At the position of maximum tension in the rope
Rdgcos (Rdgsin )
= 45
At any , Rdg
dT Rdgcos Rdgsin

Tmax 4


0

dT Rg (cos sin )d
0

1 1
Tmax Rg sin cos 04 Rg
2

2
1 Rg

2 1
5. Acceleration of particle P and Q along the incline is same.
Acceleration of particle P perpendicular to the incline plane is 10 cos 60 = 5 m/s2
So, v P 5(2) = 0
v P = 10 m/s

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3 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

6. R = u = constant
dR d
R 0
dt dt
d dR

dt R dt
In time dt radius decreases by dR
2RdR = uddt
dR ud

dt 2R
d ud

dt R 2R
u2 d

2 R 3
Iu2 d

2R 3
Iu2 d
F
2R 4

7. For pure rolling motion, static friction would act in the forward direction on the sphere. Work done
by static friction is change in the kinetic energy of the sphere. Work done by static friction on the
complete sphere + Plank system is zero.

8. F applied by external agent = Weight + thrust force = xg + v2


v 2
Energy lost in the complete lift = W F K.E. U =
2

9. For perfectly in elastic collision both blocks have same velocity after collision.

4 2

1
10. e 3 3
2 3
SECTION C
1 R
11. 2g R mg R
2 2
2
m 5 kg
2 1


12.

W 2rxdxP
0
= rP2
105
= (0.3)(3 102) 102 = 9 J

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AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 4

13. v v02 2gy O x



y
and v sin = v0 (as given in question)
bead
v0
sin
v 20 2gy v
y
v0
tan =
2gy
dy v0

dx 2gy
(3gv0 x)2/3
y
2g
a+b+c=8
L D C
14. Time to cross, t =
v cos u
uL
ut = d L tan
v cos u
uL L B
v v
dcos L sin
uL
vmin 4 m/s B
d2 L2
d A

15. If they meet a height h after time T of the projection of the second.
1 1
Then, h = u(T) g(T)2 v(T t) g(T t)2 (i)
2 2
5t 2 3t
T
10t 2
dT
For minimum T, 0
dt
50t2 20t 6 = 0
6
t = 0.6 =
g

16. For car + trailer system


Pmax = (3mg sin + 3kmv 2)v
For car only
Pmax = (mg sin + 4kmv2)2v
(3mg sin + 3kmv2)v = (mg sin + 4kmv2)2v
gsin
k
5v 2
For down the incline kmv 2t = mg sin
v2t = 5v2

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5 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

17. At the starting (with respect to COM frame) At the instant of maximum elongation (with
respect to the COM frame)
v0 v

2 2

v0 v0 2
v

2 2 2 2
v0
2 2
Conservation of angular momentum with respect to centre of mass (COM) frame
v
2m 0 2mv
2 22
v
v 0
4 2
From conservation of energy with respect to centre of mass frame
1 v2 v2 1 v2
2 m 0 0 2 m 0 = Uspring
2 8 8 2 32
2
1 1 7mv 0
Uspring mv 02 = 2 Joule
4 32 32

18. considering torque of real and pseudo force in the frame of P,


R R
mg m 2R
2 2
R g R
mg m R mgR C O
2 R 2
2
R
R2 3 mg
IP m m R2 mR
2
N
2 4 2
2mgR 2g 2 P fs
6 rad/s
3mR 2 3R

dv
19. sg at t = 1 sec
dt
s 0.4
At t = 3 sec velocities of plank and block are equal.
2 k g(2) v at t = 3 sec = 8
k 0.3
s+k=4+3=7

A
20. Since , the upper block will move faster than the
4 2 f
middle block and hence force of friction on upper block is
B f
towards left
f
f mg
4
g
aA leftward
4

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AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 6

m 3
f m g mg
2 2 4
aB g (leftward)
3
a A /B g (rightward)
4
3L
For sliding down the block B, A has to move a distance
8
relative to block B.
3L 1 3
gt 2
8 24
L
t 3 sec.
g
SECTION D

21. mg T = ma1 f=T 2T


2mg 2T = 2ma2
So, a1 = a2
a1 a2
Relative acceleration of bead with respect to end = 3a
1
displacement of block x = at 2 = 6.25 m
2 3 mg 2mg

22. A = 0 f N
Mg N N
N cos
2
2
For disc, N sin = f + f cos
Nsin Mgsin cos N
f f
1 cos 2(1 cos ) Mg W

R
M = L and L A f
f
tan
2
1
f gR cos
2
1 2 4
8 10
2 10 5
32
6.40 N
5

dv
23. v k(L x) , where k is a constant.
dx v0 v
v 0 /2 L x (L x)

v0

vdv k (L x)dx
0

3
v02 KL2
4
3 v 02 3
So initial retardation = KL = 25 18.75 m/s2
4 L 4

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7 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

Chemistry PART II

SECTION A

2NH4 OH H2SO 4 NH4 2 SO 4 2H2 O


24. Initial 1 m mol 0.4 m mol 0
0.2m mol 0 0.4 m mol
2 0.4 0.2
NH4 , NH4 OH
14 14
0.8 / 14
pOH pK b log
0.2 / 14
= 4.76 + log4 = 4.76 + 0.6
= 5.36
pH = 14 - 5.36 = 8.64

Ea1 Ea 2
25.
T1 T2
200 100

T1 298
T1 = 596 K = 323oC
o
180 C
26. 2BF3 6NaH B2H6 6NaF

27. P F bond length is less than P Cl bond length


P F 159.6 pm P Cl 200.5 pm.
28. (i) Li has stronger reducing character than Na in aqueous solution.
(ii) Li2CO3 is thermally less stable than Na2CO3.

6
29. Pyrosilicates have general formula Si2 O7 .

30. (i) Formula of borax is Na2[B4O5(OH)4].8H2O.

(ii) Aqueous solution of borax is weakly alkaline.


31. K P PNH3 PH2S
Addition of NH4HS(s) at equilibrium does not change the concentration of NH3(g).

K sp Ag2CO3 4 10 12
32. Ag 2 105 M
2
CO
3
102

K AgCl 1.8 10 10
33. Cl sp
Ag 2 105
= 9 10-6 M.

SECTION C
2rn
34.
n

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AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 8

2 3.14 0.529 10 10 n 2

n
1.67 10 9 2 3.14 0.529 10 10 n
n 5

35. 2Cr OH3 IO3 4OH 2CrO 42 I 5H2 O


x = 2, y = 1, z = 4
x y z 2 1 4 7

36. A g 3B g
4C g
ax a 3x 4x
ax 4x a 5x
[A] = a x = 5x x = 4x
[B] = a 3x = 5x 3x = 2x
[C] = 4x
4

Kc
C
3
A B
4
4x
3
4x 2x
=8

37. CO 2 g C s

2CO g

2x 2x
2 x 2x 3
x=1
PCO2 2 1 1 atm, PCO 2x 2 1 2 atm
2 2
PCO 2
Kp 4
PCO2 1

n 1
t1/ 2 1 P
38. 2 n1=1
t1/2 2 P1
n 1
10 200
n=2
5 100
n1
2=2

39. Boron Nitride, Boric acid, Beryllium hydride, Graphite.


-8
40. (i) 10 M HCl
(ii) 0.01 M solution of NH4Cl
(iii) 0.01 M solutin of B(OH)3

200 1
41. CH3 COOH C1 0.5
400
200 0.1
HCOOH C2 0.05
400

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9 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

H K a1 C1 K a2 C2

10 6

0.5 10 5 0.05
-3
= 10
pH = - log 10-3 = 3

42. The following molecules/ion are planar


CO32 ,NO3 , XeF4 ,I3 ,COCl2 ,SO3 ,I2 Cl6 (solid)

43. Al OH3 NaOH NaAlO2 2H2O


Soluble
Zn OH 2 2NaOH Na2 ZnO2 2H2 O
Soluble
Sn OH2 2NaOH
Na2 SnO 2 2H2 O
Soluble
SECTION D

44. For shortest wavelength n2


1 1 1
4 RH 2 2
min 3
1 4
RH
min 9
9 1
min nm
4 RH
= 205.02 nm
45.

S 2Cl4 g
2SCl2 g
Initial 4 0
At equilibrium 0.2 7.6
0.2 7.6
S 2Cl4 SCl2
10 10
2

Kc
SCl2
S2Cl4
7.6 7.6

10 10
0.2
10
= 28.88

1
46. pOH at th equivalence point = 14 9.3 = 4.7
4
1
At th equivalence point
4

pOH pK b log
Salt
Base
0.25x
4.7 pK b log
0.75x

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AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 10

1
4.7 pK b log
3
pK b 4.7 log3
3
At th equivalence point
4

pOH pK b log
Salt
Base
0.75x
pOH 4.7 log3 log
0.25x
pOH 4.7 log3 log3
pOH 4.7 2 log3
pOH 4.7 2 0.48
pOH 5.66
pH = 14 5.66 = 8.34

Mathematics PART III

SECTION A

1 1
47. Put x in I2 and x 1 in I3
1 t t
2
10
x2 x 1 1
We get 3 1 2 dx
20 x 3x 1
x 1 x 2
x3 3x 1 du
Let u then 2
x x 1 u

x 2 dy 2xydx x 3 y 2 ydx xdy


48.
x4 x4
y
d 2
x xyd xy
y

x2
2
y xy
ln 2 c
x 2

3lnk 2
49. k3
1
1
k3 1
3 P 3 , 3lnk
So, f(k) = k + 3lnk 1 k
1
f f e 0
e
(1, 2)

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11 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

2 4x
4y 5 5
3 3 3 1 4x 15
50. y 2
4 2
4y 5 4 4 4y 5 27 9
,
4 4
3
y for 4x 15 0
4
27/4
1 12 9 15 27
f x dx 2 4 4 x=
4
x=
4
15/4

51.
x 1 4 y 1 x dy
2 2

4 x 1 3 y 1 y dx
2 2

2 2
Let y 1 = v(x 1)
6v 2 2 x2 1 dv

4 3v x dx
4 3v x
6v 2 2 dv x 2 1 dx
2
2 y 2 1 1 y2 1
1

tan 3 2
ln 6 2 2 ln x2 1 c = 0

3 x 1 4 x 1

52. (A) 2C1(2 2 1)5


(B) (2 2 1)5 1
(C) (2 2 1)4 1
(D) (2 2 1)2 = 9

53. Let g(x) = f(x) x2 1


g(1) = g(2) = 0
So; g(C1) = 0 for at least one C1 (1, 2)
Similarly g(C2) = 0 for at least one C2 (2, 3)
Using LMVT on x (C1, C2)
g C2 g C1
g(C) = 0
C2 C1
f(C3) = 2

54. Let x 3
f 3 0
3 1.732050807.....
p
As the decimal part increases then in the expression , q becomes very large
q
2
So, 0
2q q q sin2 q 5
3 2

Hence, lim f x 0
x 3
Thus, f(x) is continuous at each irrational

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AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 12

55.-56. 7
193 1 cos y cos y 7
2 3

x 7 ; x0
So; g x
x 7 ; x0
So; g(x)min = 7
So; f(x) = x + cos x

3 /2
55. A 32 x x cos x dx 1
y = f (x)
/2
3 y = f(x)
3 /2
= 3 2 sin x /2 2 2
= 6(1 1) = 12 3
2 2

56. 2x = x2 intersect at 3 points


SECTION C

x : 0 x 1

57. g x 1 : 1 x 2
x 3 : x 2

58. Q(x) is an increasing function


e6 e6
2
So, Q x dx x dx
e3 e3
6
Q(e ) 7

1 x n 1 xn x 1
59. 1
1 xn 1 xn
N n xn
x x 1 N xn x 1
So, ln 1
x n
ln 1
n0 1 xn n0
1 x n

n
1 1 1 n x n 1
So, x 1 ..... x
1 x
2
1 x3 1 x2k n0 1 xn
1 1 1
x 1 2
3
..... 2k 1
1 x 1 x 1 x
2
So, limit =
e

60. For least area = 0


4
256

So; Amin = 2 12 x 2 4 dx
0
3

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13 AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18

2 sin 2
61. tan2 t 0,
2 2
tan sin 2
2 2
sin
So; tan2 t 2 2
0,
tan sin max 2

Since; in 0, : tan 2 > 2 and the same is subtracted from Nr and Dr both
2
So; maximum value occurs at O+
2 1
Therefore tan t ; t ,
3 6 2

62. So; 2x + 7 = k
7 k 7k 7k y = kx : k > 0
x ,
2 2 2
7 k 2
7 k 7k
Also 7 6 k
4 2 2
k 7 24 , 7 24 (Rejected) 1 6

So: k 7 24,
Similarly: consider case-II if k < 0 then k , 7 24

Second Method
Clearly: m1 < k < k2 m2
For slope of ON
m1
(x2 7x + 6) = kx M
Must have equal roots
For slope of OM
x2 7x + 6 = kx N
Must have equal roots
O

63. g(f(x)) = x
So; g(f(x))f(x) = 1
f x
g f x 3
f x
1 43
So; g 3 and g 3 3
23 5 23

1 1/3
64. f (x) = [x] + {x}
9/2 9/2
1/3 17 3
So, x dx x dx = 10/3
2 2
2 2

x
t8 1
65. Let f x 8 2
dt 3x 2
0 t t 1
f(0) = 2, f(1) = negative
So; f(x) has one root in [0, 1]

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AITS-PT-I (Paper-2)-PCM (Sol)-JEE(Advanced)/18 14

66. f is an odd function


So; f(7) = 7, f(5) = 5, f(2) = 3
x , f(x) 7 5 2 02 5 7
x , f(x)

SECTION D
3
67. Let 1 x = t
1 3 1 3 1
1 t
2 2
3I1 1 t dt and 3I2 1 dt
0 0
1 3
= 3 1 2 1 t 1 t 1 dt (Using integration by parts)
2 2

3I2 3 1 2 3I 3 1 2 3I
2 1

I1 3 1 3 1 3 1
So, 0.2 1 0.2 1.2
I2 2 2 2 2 2 2

68. Roots of the f(x) = 0 are (1, 0) and 1 1


then f(f(x)) = 0 (where f(x) = t)
f(t) = 0 t = , 1
So; total number of distinct real solutions = 2 + 1 = 3
1

69. f(x) = (x 1)5(x + 2)6(195x2 + 153x + 30)


f(x) = 0 if x = 1, 2, x1, x2
Clearly: there are 3 inflexion points

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