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Density Specific heat Heat of pyrolysis where and identify the elevation and azimuth
g , kg/m3 cg , J/kg K hpyr , MJ/kg angles associated to the generic line of sight, re-
960 1632 1.1 spectively.
The radiative intensity at wall coming from a
generic line of sight can be computed integrating
the RTE along the whole radiation path length. The
RTE expresses the balance of the radiative inten-
2.2 Thermal radiation sity I along a generic direction s including con-
Thermal radiation has to be separately modeled tributions due to absorption/emission and eventu-
in order to compute the radiative wall heat flux ally in/out-scattering. Under the assumption of
needed by the GSI balance equations. The basic gray/non-scattering medium it reduces to the form:
hypotheses adopted here are those of gray/diffuse
dI
wall and gray/non-scattering medium. The gray as- = j e I = Ib I (8)
ds
sumption is quite accurate for the wall, because of
its continuous behavior over the spectrum, while where j e and identify the emission and absorp-
it allows to significantly reduce the computational tion coefficients associated to the generic point into
time, by means of a global treatment of spectral the gas mixture, respectively.
features, when it is introduced for the medium. The RTE formal solution is given by:
The high roughness level expected for the reced- Z w
ing surface, on the other hand, is well in agree- Iw = I0 exp 0
ds +
ment with the diffuse wall hypothesis, since reflec- 0
Z w w (9)
tion from rough surfaces approximates the diffuse
Z
e 00 0
reflection regime [18]. The non-scattering nature + j exp ds ds
0 s0
of soot [19] and the absence of other solid parti-
cles suspended in the gas phase, finally, agrees and expresses that the intensity at wall coming
with a non-scattering behavior of the medium. It from a certain line of sight is due to the contribu-
is also assumed that radiation does not affect the tions from the point at the opposite side surface 0
flowfield significantly [20], because of the relative and from each point crossed within the medium.
Each contribution decays by absorption through the
medium itself, until the calculation point at wall w is
reached.
In order to find out a solution of the RTE, a
boundary condition in terms of radiative intensity at
the opposite side surface and a suitable model for
the mixture absorption coefficient are needed.
The radiative intensity at the opposite side sur-
face, under the assumption of gray/diffuse wall, has
the form:
0 T04 + 0 q0,rad
I0 = (10)
which is composed by the radiative intensity emit-
ted by the wall, according to a certain emissivity
0 , and reflected by it, in a way proportional to the
wall reflectivity 0 . Since such a boundary condi-
Figure 1: Planck-mean absorption coefficients for
tion depends on the radiative intensity reflected by
water vapor, carbon dioxide and carbon monoxide.
the wall and, accordingly, on the incoming radiative
wall heat flux, an iterative procedure is required.
The mixture absorption coefficient is derived by A specific radiative code based on the described
means of a global model, typically used for high- model has been developed using the DTM. First,
temperature combustion mixtures under vibrational the equations of the problem have been written in
equilibrium conditions: a finite form by using a discretization of both the
Nrad solid angle, for each calculation point, and the path
length, for each ray spread out. Then, the equa-
X
=p Xj p,j (11)
j=1
tions have been integrated by means of a summa-
tion over the path length of each ray, in order to
which states that the absorption of radiative energy evaluate the relevant radiative intensity, and over
is proportional to the the number of molecules per the solid angle corresponding to each calculation
unit volume, represented by the pressure p, and to point, in order to compute the associated radiative
the weighted sum of the absorption coefficients rel- wall heat flux. The field and wall local parame-
evant to the participating species j = 1, ..., Nrad , ters needed by the code have been calculated from
which are essentially water vapor, carbon dioxide the CFD simulations, with which the DTM computa-
and carbon monoxide [19, 21]. Their molar frac- tions have been coupled. A suitable ray-tracing pro-
tion Xj are used as weights, while their absorption cedure has also been implemented into the code.
coefficients p,j , known as Planck-mean absorp- The code has been validated against exact solu-
tion coefficients, are averaged over the whole spec- tions given in [4] for an infinitely long square cav-
trum. The behavior with temperature of these co- ity of edge L, with cold/black walls, in a medium
efficients has been described up to 2500 K by [22], with constant absorption coefficient , for differ-
and up to 2800 K by [23], fitting the curves reported ent values of the optical thickness = L. For
in [19, 21]. More recently, in [24], an updated the validation, 1024 rays with a spatial integration
model for the Planck-mean absorption coefficients step of 104 L have been used. Figure 2 shows
up to 5000 K has been presented. This model, the very good agreement between the exact and
summarized in Fig. 1, has been selected for the the present DTM solutions, in terms of radiative
present work. heat flux, non-dimensionalized with the black-body
Table 3: ORPHEE firing test average results [27].
[17] Ramohalli, K. and Yi, J., Hybrids Revisited, [27] Carmicino, C. and Russo Sorge, A., Ex-
No. 90-1962, 26th AIAA/ASME/SAE/ASEE perimental Investigation into the Effect of
Joint Propulsion Conference, Orlando, FL, Solid-Fuel Additives on Hybrid Rocket Per-
July 16-18, 1990. formance, Journal of Propulsion and Power ,
Vol. 31, No. 2, 2015, pp. 699713.
[18] Hsu, S. T., Engineering Heat Transfer , Van
Nostrand Company, 1963. [28] Lyon, R. and Jassens, M., Polymer Flamma-
bility, FAA DOT/FAA/AR-05/14, 2005.
[19] Modest, M. F., Radiative Heat Transfer , Aca-
demic Press, 2013.
[20] Liu, J. and Tiwari, S. N., Radiative Heat
Transfer Effects in Chemically Reacting Noz-
zle Flows, Journal of Thermophysics and