Sample Paper-2

Chemistry

Class XII

1. Write the product obtained when benzyl phenyl ether is heated with HI.
2. Why gelatin is added to ice-cream.
3. Out of Br- and I- which is a better nucleophile.
4. Why are fluorine and oxygen compound called oxygen fluorids.
5. Acidic hydrolysis of sucrose called inversion reaction ?
6. Give IVPAC name of-
Br
CH3

H3C-CH-CH2CH3
7. Give reaction involved in leaching carried out in case out in case of copper pyrite.

8. Iodoform has antiseptic properties, explain.

9. Give reasons-
a. Tertiary amines do not undergo acylation.
b. Aniline readily reacts with bromine to give 2,4,6, - tribromoanmiline
10. X-ray diffraction studies show that copper crystallizes in an fcc unit cell with cell edge length of
3.608x 10-8 cm. In a separate experiment Cu is determined to 10Vc a P of 8.92 g/cm3, calculate
atomic mass of Cu.
11. Refractive index of a solid is observed to have same value along all directions. Comment on the
nature of this solid.
12. Refractive index of a solid is observed to have same value along all directive comment on the
nature of this solid.
13. The following curves is obtained when molar conductivity m is plotted. Square root
concentration for two electrolyte A & B.
a. What can you say about nature of 2 electrolytes
b. How do you account for the inverse in molar conductivity m for the electrolytes A & B
dilution

A

B

OR
(Ba (OH)2 = 457.6 -1 cm2 mol-1
(Ba Cl2) = 240.6 -1 cm2 mol-1
(NH4Cl) = 129.8 -1 cm2 mol-1
Find m (NH40H)
The half life period of a Ist order reactor is bomin. What percentage will be left after.
14. Complete following reaction

I2 +HNO3

Zn +HNO3 (dil)

15. Write the mechanism of hydration of ethene to form ethanol.

16. The value fG for formation of Cr2O3 is -540K J mol-1 and that of Al2O3 is -827 KJ mol-1, Is the
reduction of Cr2O3 possible with Al.
17. The sum of Ist and 2nd initialization enthalpies 3rd and 4th ionization enthalpies of Nickel and
platinum are
IE1 +IE2(MJ mol-1) IE3 +IE4(MJ mol-1)
Ni 2.49 8.80
Pt 2.26 6.70

Based on the above information answer the following-

Which is the most common oxidation state for Ni and Pt ? Why ?
18. Give the structure A,B,C in following reactions-

C6H5NO2 Fe/HCl A NaNO2/HCl B H2O/H+C

273K
NH3 NaOBr NaNO2/HCl
CH3COOH A B C
D

19. A galvanic cell consists of metallic Zn plate immersed in 1 MZn (NO3)2 and plate of Pb in 0.02 M
Pb(NO3)2. Calculate the e.m.f. of the cell. Given E0Zn2+/Zn = -0.76V, E0Pb2+/Pb = -0.13V
20. Write reaction use for synthesis of
a. Teryline
b. PHBV
c. Nylon -6, 6
21.
a. What are reducing sugars.
b. Mention the type of linkages responsible for the formation of the following.
i. Primary structure of proteins.
ii. Cross-linking of Polypeptide Chains.
iii. helix formation
iv. -sheet structure
22. Complete the following chemical equations-

Cr2O72- + Sn 2+ + H+

MnO4- + Fe2+ + H+

MnO4- + S2O3 2- + H2O

Indicate the steps in preparation of K2Cr2O7 from chromite Ore

23. Give explanation for following

a. Ortho-nitrophenol is more acidic than ortho-methoxy phenol.
b. Alcohols are easily protonated in comparison to phenols.
c. The relative ease of dehydration of alcohols is 30 > 20 > 10
24. An antifreeze solution is prepared from 222.6 g of ethylene glycol (C2H6O2) and 200g of water
calculate the molarity of the solution.
25.
a. Name the anionic detergent
b. Name two narcotics which are used as analgesic
c. Name a substance which can be used as analgesic and antipyretic

26.
a. What are zeolites. Give example.
b. Give one example of each-
i. Homogeneous catalyst
ii. Heterogeneous catalyst
iii. Auto catalyst
iv. Poison catalyst
27. A metal ion Mn+ having d4 valence electronic configuration combines. With three didintate
ligands to form a complex compound (assuming 0 > P)
a. Draw the diagram showing d-orbital splitting during the complex formation.
b. Write the electronic configuration of the valance electrons of the metal Mn+ ion in terms
of t2g and eg.
c. What type of hybridization will Mn+ ion have

28. A translucent waxy solid (A) on heating in an inert atmosphere is converted to its allotropic form
(B) Allotrope (A) on reaction with very dilute aqueous KOH liberates a highly poisonous gas (C)
having rotten fish smell. With excess of chlorine is forms (D) which hydrolysis to compound (E).
Identify compound A to E and give reactions.
Or
An element A exist as a yellow solid in standard state. It has an allotrope (B). A form a volatile
hydride (C) which is foul smelling gas and is extensively used in qualitative analysis of salts.
When treated with oxygen (C) forms an oxide O which is a colourless, pungent smelling gas.
This gas when passed through acidified KMnO4 solution, decolourises it O gets oxidized to
another oxide E in the presence of a heterogeneous catalyst. Identify A,B,C,D,E and also give
the chemical equation.
29. A compound X( C2H4O) on oxidization gives Y(C2H4O2) X under gaes haloform reaction. On
treatment with HCN. X forms a product Z. Which on hydrolysis gives 2- Hydroxy propanoic acid
a. Write down structure of X & Y.
b. Name the product when X reacts with dil NaOH
c. Write down the equations for the reaction involved.
Or
An organic compound X undergoes acid hydrolysis to form two compound Y and Z. Y
reacts Na2CO3 to form A. A is heated with soda lime to form B(CH4) Y on reduction with
LiAIH4 form Z . identify X,Y,Z,A and B and write the reactions involved
30. Consider the reaction A P. The change in concentration of A with time is show in the
following plot.
a. Predict the order of the reaction
b. Derive the expression for the time required for 99.99% competition of the reaction
Or
a. List the factors on which rate of a chemical reaction depends.
b. The half life for decay of radioactive C14 is 5730 years. An archeological artifact containing
wood has only 80% of the C14 activity as found in living trees. Calculate the age of artifact.