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Gate 2012 Solution : CH : CHEMICAL ENGINEERING
Solution:
x1 2 x2 3 x3 2
x2 x3 1
2 x2 2 x3 0
1 2 3 1 2 3 2
[A] 0 1 1 [A] 0 1 1 1
0 2 2 0 2 2 0
Rank of [A]:
1 2 3 1 2 3
[A] 0 1 1
R3 2 R2
0 1 1 Rank of [A] = 2
0 2 2 0 0 0
1 2 3 2 1 2 3 2
Rank of [A] 0 1 1
1 R3 2 R2
0 11 1
0 2 2 0 0 0
0 2
1 2 3 2 1 2 3 2
[A] 0 1 1 1
R3 2 R 2
0 1 1 1
0 2 2 0 0 0 0 2
Rank of [A] 3
d2y
Solution: (d ) is correct 4y 0
dx 2
Form of Auxiliary equation m 2 4 0
m=2
The roots of the auxiliary equation are equal and opposite
y = a cosh 2x + b sinh 2x
t
Solution: (b) is answer f (t ) e
x x 2 x3
ex 1 ......... (Taylor series expansion)
1! 2! 3!
t
t t2 t3
e 1 2 3 .........
2 6
for t (given in question)
t
t
e
1 (Higher term can be ignored)
So P1V1r P2 V2r
r
P1 V2 P1
0.5 (given in question)
P2 V1 P2
1
V2
(2) r
V1
TC
T
1
Solid /Liquid
Solid
2
Liquid/vapor
Triple-point line
Solution: (a ) is answer
Left solid line Saturated liquid line
From TC
Right solid line Saturated vapor line
If we go for constant entropy position (i) to position (ii) for saturated liquid line, liquid
will be compressed and state of water will be sub cooled liquid.
Solution: (a ) is answer For steady state and neglect any heat loss from the heat
exchanger to the surrounding (given in question)
Qcold stream Q hot stream
Q
S
T
Th in Tc , in (given in question)
Scold stream Shot stream
Solution: (a ) is answer
Reading
Solution: (c) is answer Blasius solution for float plate for laminar boundary layer
Vs
thickness; 5
4
1
So, ( x) 2
Solution:
NP
100 1000
2
Da nP
Re =
P
NP (Power Number)
P n3 D5a
For Reynolds number > 104
P const
N P constant given
N1 N 2
dq dT
Solution: (d ) is answer K
dA dx
Conductive resistance in solid
BIOT Number
Convective resistance in fluid
dT
dq BIOT number < 1 (given)
Resistance
d T Resistance There is two condition either upper term is less or denominator
term is high
In this condition if conductive resistance in solid is less temperature change will be less;
you can say temperature profile is uniform.
If convective resistance in fluid is high so T will also be high and temperature drop in
fluid is significant.
hA
T T t
Solution: (c) is answer e CP V
To T
Unsteady state equation for conduction
Final temperature is same
T T
constant
To T
h A1 h A2
t1 t2
CP V1 CP V2
e e
h A1 t1 h A 2 t2
C P V1 C P V2
t2 A1 V2 r12 r23 4 3
. . A = 4 r 2 ; V = r
t1 A 2 V1 r22 r13 3
t2 r2
t1 r1
t2
Radius of sphere is doubled 2
t1
K
h V 0.8 D 0.2 s 0.8 K
Constant average velocity
h D 0.2
b a
c
d
e
y
xP x
x
CA
1
1 n kt (1 n)
C A CAo
1 1
C1 n C(1 n ) kt (1 n)
no A
CA
For half life C A o and t t 1
2 2
1 1 2n 1 1 1
1 n
k t 1 (1 n) t1 n 1
C1Ao n C Po 2 2 k (n 1) C Ao
2
Solution: (a ) is answer
Catalytic reforming is used to convert paraffins and naphthenes to aromatics which have
high octane rating.
Solution: (a ) is answer
For figure gain and phase curve decreasing continuously with frequency.
dt (t ) e . dt dt
d da
t et dt ab dx a b dx dx (b dx) dx
t
0 0
t
t e (1) e dt t e et |0 = (0 0) (0 1) = 1
t t t
0 0 t0
7z i
Solution: (b) is answer z ( z
2
1)
dz where | z | < 2
|z| = 2
i
Solution: (a ) is answer
t=0 P=0
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t = tf P Ps
Mass balance N f Ni N
N f U f N i Vi ( N) H s
where, U f C V (T f TR ) R TR TR Refrigeration temperature
U i C V (Ti TR ) R TR
H s C P (T TR )
N f [CV (T f TR ) RTR ] N i [C V (Ti TR ) RTR ] (N f N i ) C P (T TR )
[N f C V T f N i C V Ti ] [N i TR (C V R) N f TR (C V R)]
(N f N i ) C P Ts (N f N i ) C P TR
[N f C V T f N i C V Ti ] [N i TR C P N f TR C P ] (N f N i ) C P Ts (N f N i ) C P TR
[N f C V T f N i C V Ti ] (N f N i ) C P TR (N f N i ) C P Ts (N f N i ) C P TR
N f C V T f N i C V Ti (N f N i ) C P Ts
PV f PVi
Nf Ni V f Vi
RT f RTi
P f Pi
P f C V Pi C V C P Ts
T f Ti
P f Pi P f Pi C V Pf Pi P f Pi C V
T f Ti Ts C P Tf Ti Ts C P
Pf
Tf
Pi P f Pi C V
T T C
i s P
for P Pi 0 Pf Ps
Ps
Tf r Ts
0 (Ps 0) 1
Ti Ts r
Solution: (a ) is answer
x1 x2
given
S R[ x1 ln x1 x2 ln x2 ]
G H T S for constant T
G
For G minimum 0
x1
G 5 x1 (1 x1 ) RT[ x1 ln x1 (1 x1 ) ln(1 x1 )]
G
5 10 x1 RT ( x1 ln x1 ) RT [(1 x1 ) ln(1 x1 )]
x1 x1 x1
5 10 x1 RT [1 ln x1 1 ln(1 x1 )]
G
For minimum 0
x1
0 5 10 x1 RT [1 ln x1 1 ln(1 x1 )]
Put x1 0.5 R.H.S. = L.H.S. = 0
P 150 U (1 ) 2
Solution: (a ) is answer
L D 2P 3
R1
R2
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A 2 4 R 22 4(2 R 1 ) 2 16 R 12
A1 4 R12 A1F12 A 2 F21
F11 F12 1 F21 F22 1 F11 0 F12 1
A1 4 R 2
1
F21 F12 . 1 1
A2 16 R 12 4
1 3
F22 1 F21 1
4 4
Solution: (a ) is answer
By heat balance
(m C P T) Hot stream (m C P T)Cold stream
2 2.1 (90 40) = 1 4.2 (T 10)
T = 60 C
LMTD = 30 C
Q U in A T ( m C P T) Hot
1m
U in 6 5m 30 2 2.1 (90 40)
100cm
U in 7.427
25%
R
2%
xe xc= 0.1
= 0.005
Moisture
Given A
R 5 kg H O/m 2 .h
c 2
x1 0.25 0.005
xc 0.1 0.005 from graph
x2 0.02 0.005
Ls L x x
t ( x1 xc ) s c ln c
A Rc A R c x2
50 50 0.0950 0.0950
(0.2450 0.0950) ln
5 5 0.0150
= 1.5 + 1.753 = 3.253
F
xF
B
xB
1 1 26
2 9 12(2 kc _
3 b1
a1 a2 a3 a0
b1
a1
For stability b1 0
9 26 12(2 kc )
b1 0
9
9 26
2 kc kc 17.5
12
1
Kc
Solution: (c) is answer
C( s )
P s 1
R( s ) 1 1
1 Kc
P s 1 m s 1
Closed loop system the overall transfer function
Given P 8, m 1
K c ( s 1) K c ( s 1) K c ( s 1)
K c (8s 1) ( s 1 K c 8s 2 9 s 1 8 2 9
1 K s 1 K s 1
c c
with compensation s 2 s 1
2 2
8 9
2 2
1 Kc 1 Kc
Condition for critically damped response 1
9 8
2 2
1 Kc 1 Kc
2
9 8
2(1 K ) 1 K
c c
K c 1.531
A A i (1 i ) n
Solution: (b) is answer , i %, n
P P (1 i ) n 1
P Present worth, A Annual worth
Given: P 2 106 Rs. i = 0.15 n = 3 year
2 106 .15 (1.15)3
By formula A 875953.9 Rs.
(1.15)3 1
Net energy savings = 20 GJ/year
Assume cost of energy = x
For break even condition
20 x = A 20x = 875953.9 x = 43800
mass of C mass of C
Solution: (b) is answer Given: y = 2x where y x
mass of A mass of B
y2 y1
X2 x1
yN+1
y1
x0
xN
1 1
Previous question Data : xo xN xN 1 0
4 400
Put in Kremsers equation
FB
FFB
1 Reactor Separator FC
FA
Solution: (a ) is answer
FRG
4 (given)
FPG
FPG 2 from question no. (50)
FRG 4 2 8 mol/sec.
Material balance at point (i)
FR FFB 5 2 3
FB FFB YRB FRG YRB
FRG 8 8
FB 5 mol/sec.
given
FFB 2 mol/ sec.
Solution: (d ) is answer
V = 0 (stationary)
y Fluid
x b
DV
Navier stokes equations s P 2 V sg
Dt
s DV
0; for steady state
Dt
P 0; No pressure gradient in x direction
sg = 0; horizontal flow
0 0 2 V 0
d 2 Vx
2 V 0 0
dy 2
d Vx
C1 Vx C1 y C 2
dy
Boundary condition y=0 Vx V
y=b Vx 0
Vx C1 y C 2
1st B.C. V C1 (0) C 2
V C2
2nd B.C. 0 C1 b C 2
Solution: (a ) is answer
y
Vx V 1
b
d Vx V
dy b
d Vx
y x (Shear stress: force per unit area in x direction)
dy
V V
b b
1
Solution: (c) is answer For mixed flow reactors (1 k i ) N
1 XA
Given k = 0.28 (From last question)
V 2
N=3 V = 2 liter i 2 min
Vo 1
1
(1 0.28 2) 2
1 XA
1
(1.560)3
1 XA
1 X A 2.634 X A .7366 means 73.66%
Solution: Setbacks
dP
50 10q
dq
dP
Profit is maximized when 0
dq
0 = 50 10 q q=5
(a ) is answer
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Solution: In option (d) This countrys expenditure on educational reforms is very loss
can not use very with less.
Solution: (a ) is answer
3 4
1 2 K,L,M,N
D,E G,H,I
B
C G F K J P O V
AD
x1 x2 x3 ....
Assertion R: Average =
n
x x2 x3 ....
Double each entry = 2 1 2 mean
n
R is correct
( x1 xavg ) 2 ( x2 xavg ) 2 ......
Assertion S: Standard deviation =
n
Doubling each other
[(2 x x1 2 x xavg ) 2 (2 x2 2 xavg ) 2 ......]
n
(2) standard deviation
2
S is correct
= 4 standard deviation