uess Paper of Chemistry 1st Year Important Long Questions

What is boiling point? What is the effect of external pressure on boiling point? Why the temperature of a
liquid remains constant at boiling point although heat is continuously supplied? OR Give graphical
explanation for elevation of boiling point of a solution
An ideal gas is enclosed in a container having volume 500 cm3 at S.T.P. Its mass comes out to be 0.72
g. What is the molar mass of this gas? OR What is mole fraction in solutions? Compare molar and molar
solutions. OR What is molar heat of combustion? How it is measured by bomb calorimeter? OR 250 cm3
of the sample of hydrogen effuses four times as rapidly as 250 cm3 of an unknown gas. Calculate the
molar mass of an unknown gas. OR Calculate the pH of a buffer solution in which 0.11 molar CH3COONa
and 0.09 molar acetic acid solutions are present Ka for CH3COOH is 1.85 x 10-5.
Define orbital. Discuss shape of its two types. OR Explain the molecular orbital structures of following
molecules on the basis of the MOT: (i) N2 (Nitrogen) (ii) 02 (Oxygen). OR Define atomic orbital
hybridization with reference to Sp3, Sp2 and Sp modes of hybridizations for pH3, C2H and C2H. OR
Describe the bonding in 01 according to molecular orbital theory and explain its paramagnetic property.
State first law of thermodynamics. Prove that AE = q
Explain demonstration of Grahams law.
Degcribe Daltons law of partial pressure. Write its three applications. OR Explain Daltons law of partial
pressure and give its applications in breathing process.
Describe Millikans Oil Drop Method for the measurement of charge on electron.
Describe the construction and the working of standard hydrogen electrode. OR What is standard
hydrogen electrode (SHE)? How it is used to measure the electrode potential of zinc?
Give three statements of Raoults law and also mention how Raoults law helps in determining the ideality
of a solution. OR Explain Raoults law when both components in the solution. OR State and explain
Raoults law in three forms.
How does the Arrhenius equation help us to calculate the energy of activation of a reaction?
What are ionic solids? Give their properties in detail. OR What are molecular solids? Write their
properties. OR What are molecular solids? Give examples and explain their properties.
Calculate the number of grams of At2S3 which can be prepared by the reaction of 20g of At and 30g of
sulphur. How much the notAimiting reactant is in excess?
What is crystallization? Explain all steps of crystallization.
A mixture of two liquids, hydrazine, N2H and N20 are used in rockets. They produce N2 and water
vapours. How many grams of N2 gas will be formed by reacting 100g of N2H and 200g of N20.
Define electron affinity. Name the factors affecting it. How does it vary in the periodic table?
Where is plasma found? Write few applications of plasma.
Define enthalpy of reaction. How is it measured by glass calorimeter? OR Define enthalpy of
neutralization. Also discuss glass calorimeter in detail.
Describe Linds method for the liquefaction of gases.
Describe the electrolysis of molten sodium chloride and a concentrated solution of sodium chloride.
Define electrode potential. Describe the construction of voltaic cell and reaction occurring in the cell. OR
Explain the term: (i) half life period (ii) order of reaction. OR Write the electrochemical reactions involved
therein. OR N2 (g) , and H2 (g) combine to give NH3 (g). The value of Kc in this reaction is 6.0 x 10-2.
Calculate the value of Kp for this reaction. OR How rate of reaction depends upon the following factors (i)
Nature of reactants (ii) Surface area.
What are liquid crystals? Give three uses in daily life.
What is hybridization? Discuss sp2 hybridization with example. OR Explain structure of CH on the basis
of hybridization theory.
What is electrochemical series? Give its applications.
What are buffer solution? Why do we need them in daily life.
What are azeotropic mixtures? Explain them with the help of graphs.
Write a detailed note on activation energy. Explain with graphs.
Define and explain Hesss law and give its applications. OR Define and explain Hesss law of constant
heat summation with examples.
Write down the steps to calculate empirical formula.
What is stoichiometry? Give its assumptions. Mention two important laws, which help to perform the
stoichiometric calculations.
Describe the freezing point depression method for the determination of molecular mass of an organic
compound. OR How depression in freezing point is measured uy Beckmanns apparatus?
What is mass spectrometer? How is it used to determine the relative atomic masses of isotopes?
Write down the main postulates of VSEPR theory and discuss the structure of NH3 with reference of this
theory. OR Discuss with two suitable examples VSEPR theory of covalent bond.
State the construction and functioning of glass calorimeter.
Outline the important industrial applications of electrolysis. OR Describe the electrolysis of molten NaCt
and aqueous solution of NaCt.
What are enzymes? Give examples in which they act as catalyst. Mention the characteristics of enzymes.
Write four characteristics of a catalyst.
How volume and pressure were corrected by Vander Waals?
What is H-Bonding? Discuss H-Bonding in biological compounds.
Write down the properties of cathode rays. OR What are cathode rays? How these rays are produced?
OR How are positive rays produced in discharge tube? Give properties of these rays.
Explain paramagnetic behaviour of 02 on the basis of MOT and prove MOT is superior to other theories.
Define vapour pressure and give a method for its measurement.
What is an ideal gas? Real gases deviate more from ideal behavior at low temperature and under high
pressure. Explain. OR What is the general gas equation? Derive it in various forms?
Write a note on fuel cells.
Define the following germs: (i) Transition temperature (ii) Allotropy (iii) Isomorphism (iv) Polymorphism