1 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
PART TEST I
PAPER-1
ANSWERS KEY

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

1. A, B 19. A, C 37. A, B, C, D
ALL INDIA TEST SERIES

2. B, C 20. A, C 38. A, B, C, D

3. A, C 21. A, B, C, D 39. B, C

4. B, C 22. A, B, C, D 40. A, C

5. A, C, D 23. B, C 41. A, C

6. B, C 24. A, B 42. A, B, C

7. A, C 25. A, C, D 43. A, B, D

8. C 26. B 44. C

9. B 27. A 45. D

10. D 28. D 46. A

11. B 29. B 47. B

12. A 30. A 48. C

13. C 31. D 49. C

14. 4 32. 5 50. 4

15. 9 33. 4 51. 0

16. 4 34. 5 52. 9

17. 8 35. 4 53. 1

18. 8 36. 2 54. 5

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AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 2

Physics PART I

SECTION A

1. 20 T1 = 2a (for 2 kg block) .(i)

T2 10 = 1a (for 1 kg block) .(ii)
2
1 1 1 1 a
T1 T2 (2) (2) (for the shaft + disc system)
2 2 2 2 1/ 2
So, T1 T2 = 2a .(iii)
After solving these three equation
2
a = 2 m/s

3R2 R
2. vCM R2 (from pure rolling)
4 2
1 1 2
mgh mv 2cm mR 2 2 (from conservation of energy)
2 25
10gh
v CM
13

3. From free body diagram of sand particle

tan = S = h/R
1 h
work required = R2hg .
3 4 h
The system is in unstable equilibrium.

4. For small angle of inclinations, ball rolls without slipping. So there is no work done by friction. At
some critical angle C, the ball starts slipping. For > C, energy would be lost due to work done
by kinetic friction. But again for ( = /2), friction would be zero.

5. As going up, speed of the particle is decreasing and hence the time taken in crossing the
windows will be t1 < t2 < t3 (If W 1 = W 2 = W 3)
Simultaneously V t
V1 < V2 < V3
For unequal windows t1 = t2 = t3 may be if W 3 < W 2 < W1

dU A B
6. F 3 2
dr r 3r
3A
For equilibrium F = 0, r =
B
B2 A B r
(for r0 )
6A 2r02 3r0 3

7. P 2(i j) 2( 2i 2j)
= 6i 2j kg-m/s

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 3 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

1
So, P makes angle tan1 with positive x-axis which is also the direction of normal force
3
1
exerted on the ball. So the plane surface makes an angle tan1 with positive x-axis.
2 3

h
8. Center of mass of a triangular uniform plate from its base is 1m
3

2 7 7 5 2
9. Iaxis = MR2 MR2 MR2 9 9 kg-m
5 5 5 7

U 3
10. MhCM (2) 2 m
g 3

11. For elevator acceleration 1.5 m/s2, tension in cord 2 and cord 3 is zero
So, T1 150 = (15) (1.5)
Tension in cord 1, T1 = 172.5 N

12. For elevator acceleration 1 m/s2, tension in cord 2 and cord 3 decreases.
So, 165 + T 2 (7.5 T) 150 = (15) (1)
T = 5 N
Tension in cord 2, T2 = 2.5 N

13. For elevator acceleration 2 m/s2, tension in cord 2 and cord 3 is zero.
So, T1 150 = (15) (2)
Tension in cord 1, T1 = 180 N
So, displacement of block = 15 cm downward.

SECTION C
2Rdg
/2
14.
0


2 (1 2 )Rg cos d 2(1 2 )R g

d d

2( 1 2 )R g 1Rdg
a 4 O R
2R

15. At vmax
2 km
Av max F (where k is a proportionalty constant)
v max
m
m2/3 v max
2

v max
1/9
vmax m

1
16. 1.25 = (10)t 2
2
t = 0.5 sec
Distance of the cylinder from the truck = 8 0.5 = 4 m

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AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 4

d v2
17. 2T sin dN Rd ( is linear mass density of belt)
2 R
2
Td dN = v d O


2 2 2
T
so total normal = dNcos T cos d v 2 cos d
d


2 2 2
N = 8 newton dN T

18. F 2mA (v 0 v)2 (v 0 v)2

= 2(1026 )(1025 )(1) (5 2)2 (5 2)2

= 0.2 40 = 8 N

Chemistry PART II

SECTION A
19. Vn
40
PPCl3 PCl2 2 0.8 atm
100
0.8 0.8
KP 1.6 atm
0.40
KP 1.6
KC n
0.037
RT 0.0821 520
Increase in pressure increases the number of moles PCl5(g).

20.
1s 1s

r r

1s

4 r 2 2

o
0.53 A
r

21. All the reactions are disproportionation reactions.

22. CaC2 2H2O Ca OH2 C2H2

CaC2 N2 Ca NCN C
Be2 C 4H2 O 2Be OH 2 CH4
Cyanamide ion [N = C = N]2- is isoelectronic with CO2.

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 5 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

NO g NO2 g
N2 O3 g
23. 3P 5P 0
3P x 5P x 2y x

2NO2 g N2 O4 g
5P x 2y y
PN2 O4 PN2 O4
KP2 2
, 8 2
P NO2
0.5
PN2O4 2 atm
y 2 atm
Ptotal PNO PNO2 PN2O3 PN2O4
5.5 3P x 0.5 x 2
3P = 3, P = 1
5P x 2y = 0.5
5 1 x 2 2 = 0.5, x = 0.5 atm.
PN2 O3
K P1
PNO PNO2
0.5
0.4 atm
2.5 0.5
PNO 2.5 atm PNO2 0.5 atm PN2O3 0.5 atm,PN2O4 2atm

24. B F bond in BF3 is smaller due to P P back bonding.

B3N3H6 9H2O 3NH3 3H3BO3 3H2
In T I3 oxidation state of T is +1.

25. NH4 OH HCl

NH4 Cl H2 O
600.1 6 400.1 4 0
2 0 4
The resulting solution is a basic buffer.
NH4
pOH pK b log
NH4OH
4
pOH 4.74 log 5.04
2
pH 14 5.04 8.96

26. Decomposition of HI on surface of gold is a zero order reaction.

st 2.303 a
27. For a 1 order reaction k log .
t ax

nd 1 1 1
28. For 2 order reaction k .
t a x a

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AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 6

Solution for the Q. No. 29 to 31.

F
F F

Br

F F

Hybridisation sp3 d2
Shape square pyramidal
Lone pair in central atom = 1

Cl

ICl2 I

Cl
Hybridisation sp3 d
Shape Linear
Lone pair in the central atom = 3

XeOF2 Xe O

F
Hybridisation sp3 d
Shape T-shaped
Lone pair in the central atom = 2

SECTION C
1
32. 2LiNO3 Li2O 2NO2 O2
2
1 mol of LiNO3 will produce NO2 = 1
2Mg NO3 2
2MgO 4NO2 O2
1 mol of Mg NO3 2 will produce NO2 = 2
2Ca NO3 2

2CaO 4NO2 O2
1 mol of Ca NO3 2 will produce NO2 = 2

2NaNO3 2NaNO2 O2
Total number of moles of NO2 produced = 5
Z
33. V 2.188 10 6 m / sec.
n
2.188 106 1
n 4
5.47 105
According to de-Broglie, total number of waves made by an electron in one complete revolution
=n=4

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 7 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

34. The following species are paramagnetic.

N2 , O2 , B 2 , H2 , He 2

35. CH3 COOH NaOH CH3 COONa H2 O

60.10.6 x0.1 0
0.6 0.x 0.x
The resulting solution is a buffer solution.
CH3 COO 0.x
pH pK a log 0.3 log
0.6 0.x
CH3COOH
0.x
0.x log2 log
pH pK a log 0.6 0.x
0.6 0.x
0.x
0.x 2
5.04 4.74 log 0.6 0.x
0.6 0.x x =4

36.

A g
B g C g
10 1 10 10

100 83
D 50, d 41.5
2 2
Dd

d n 1
50 41.5
0.2
41.5 2 1
Number of moles of C at equilibrium 10 10 0.2 2

Mathematics PART III

SECTION A
37. Shown in the figure y-axis

y = {x}
x-axis
0 3 4

3
x x
2 2

1 1
x x
38. (A) x x
2 1
4 x 2 1
x

4 x 1/ x 2 1

1
x
1 x 1
So, 2

8 1 8
4 x 1
x

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AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 8

x x2 1
1

0

4 x 4 x2 1 8

1
So: f x 2x x sin2x injective but not onto
2
(B) f(x) = x3 cos x + x2 (3 sin x + 2 cos x) + 4x(sin x + 2)
Many one onto

1 n1 r 4 3 2
39. Tn f where f(x) = x + x + x + 2, f(x) is an increasing function for x > 0.
n r 0 n
1 1 n 1
Tn f 0 f ..... f
n n
n
1
167
x
4
Tn x3 x2 2 dx
0
60
1 n r 1 1 r 167
Sn f > f ..... f n = 60
n r 1 n n n

n
sin t cos t
40. (A) Let dt An
0
t
2
1 sin t cos t dt
An sin t cos t dt .....
0

2

1 1 1 1
> 1 ..... sin t cos t dt
2 3
n 0

2 2 1 1 1
> 1 .....
2 3 n
3 sin x 8 3 sin x
(C)
2
3 sin x 8 3 sin x
3 1 4
(D) 1 tan x 3 and
x
3 tan x 4 3
So;
x

3
1 y y
41.
2

cosec 2 x2 y 2 d x 2 y 2 2 d
x x

4
1 2 y / x
cot x 2 y 2
2
4

c 0

7/8
42. I f f x dx ..... (1)
1/8
7/8 7/8
I f f 1 x dx f 1 f x dx ..... (2)
1/8 1/8
3
So, 2I
4

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 9 AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18

2 2
2 sin2x x sec 2 x tan x cos x cos x
43. e
x sec x tan x
x tan x
2
dx = e
2
x sec 2
x tan
x

2
2 cos2 x
= e x sec x tan x c
2

44.-46. (I) f(x) = ||x 6| |x 8|| |x2 4| + 3x |x 7|3 is continuous x R and not differentiable at
x = 2, 2, 6, 7 & 8
(II) f(x) = (x2 9)|x2 + 11x + 24| + sin|x 7| + cos|x 4| + (x 1)3/5 sin(x 1) is continuous
x R and not differentiable at x = 8 & 7
3 /5 3
x 1 2 : x 1

1

(III) f x x cos 1 4x 3 3x : 1 x 1 is discontinuous at x = 1 & 1 not differentiable
2

5/3
x 1 : 1 x 2

1
at x = 1, & 1
2
(IV) f(x) = {sin x}{cos x} + (sin3{x})([x]), x [1, 2]

Let g x sin x x sin2 x


cont. at x I

g(I+) = g(I) so differentiable at x = I and for {sin x}{cos x}

3
Doubtful points for non differentiability are x = 0, , ,
2 2

{sin x}{cos x} is discontinuous at x = 0, , 2
2

So not differentiable at x = 2n, 2n +
2

47.-49. (I)
3 1 3 3
x 1 x 3
4
4 x2 4 x2
(II) u sin ln cos ln
1 x 1 x

4 x2
0
1 x
4 x2
ln
1 x

So; 2 u 2
1 1
(III) Let |x + 5| = t; g(t) 0,
2 4

gt
t 2
t 2 t 2
(IV) cos1 x
< ln(cos1 x) ln < 2

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AITS-PT-I (Paper-1)-PCM (Sol)-JEE(Advanced)/18 10

SECTION C
3 2 2
50. Let cot A = a then a + a |a + x| + |a x + 1| = 1
3 2 2 2 2 3
|a + a x| + |a x + 1| = (a x + 1) (a x + a )
|| + || =
So, 0 and 0
Now take cases: a 1 and 1 < a 0 & 0 < a 1
1 1
Finally we get, a ( , 5] ,
5 6

51. 0 f(x) 2
and g(3) 2 5, 4 4, 2 5
4 4
Also g x dx f x dx f 4 f 0 2, 2 2 5
0 0
Case-I: Let g(x) > 0 and g(x) > 0 S K
4
4
Clearly g x dx Area MDKS = 4
0 O M D
Which is a contradiction x=3 x=4
Thus, there is no such C
Similarly case-II: Let g(x) < 0 and g(x) < 0

x 13 3x
52. f f 1 7 9 15
2 2 0 2 3 5 6 8 9
2 2 2 2
f(x) = f(8 x)
f(x) = f(8 x)
1 15
f f 0
2 2
f(2) = f(6) = 0
f(3) = f(5) = 0
9 7
f f 0
2
2
d
f x f x
f(0) = f(8); h x
dx
Clearly: h(x) has minimum 18 zeroes
53. y = 0 x = 2 Y
Let P be the point of inflection
So; P (2, 2b a 16)
Equation of tangent line passing through inflection
P
Point: y = (b 12)x a + 8 .....(1)
Let Q (2 + h, 3h 1)
Locus of Q: 3x y = 7 ..... (2)
X
From equation (1) and (2), we get ! x=2
So; a = 15 and b = 15

k 4
2k 3 k 2 k 1 1 1
n
n 5 x 4 dx x 5
54. lim
n
k 1 3n5 n2 n 5k 0
3 3 5 0 15
5
n

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