Gardobond G 4040

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Gardobond G 4040
Version: 5.0 Revision Date 10.10.2013 Print Date 29.07.2014
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : Gardobond G 4040
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Phosphating solution for metal surfaces.
stance/Mixture
Recommended restrictions : None known.
on use
1.3 Details of the supplier of the safety data sheet

Company : Chemetall Ltd
Denbigh Road
Bletchley Milton Keynes MK1 1PB
Telephone : 01908 649333
Telefax : 01908 373939
Contact person product safety

Telephone : +49(0)6971652292
E-mail address : msds.de@chemetall.com
1.4 Emergency telephone number

Emergency telephone : 01908 649333
number
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Corrosive to metals, Category 1 H290: May be corrosive to metals.
Skin corrosion, Category 1B H314: Causes severe skin burns and eye damage.
Skin sensitisation, Category 1 H317: May cause an allergic skin reaction.
Carcinogenicity, Category 1A H350i: May cause cancer by inhalation.
Reproductive toxicity, Category 1B H360D: May damage the unborn child.
Specific target organ toxicity - repeated H373: May cause damage to organs through pro-
exposure, Category 2 longed or repeated exposure if inhaled.
Chronic aquatic toxicity, Category 3 H412: Harmful to aquatic life with long lasting ef-
fects.
Classification (67/548/EEC, 1999/45/EC)
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SAFETY DATA SHEET
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Carcinogenic Category 1 R49: May cause cancer by inhalation.

Toxic to Reproduction Category 2 R61: May cause harm to the unborn child.
Corrosive R34: Causes burns.
Harmful R48/20: Harmful: danger of serious damage to
health by prolonged exposure through inhalation.
Sensitising R43: May cause sensitisation by skin contact.
Dangerous for the environment R52/53: Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environ-
ment.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :
Signal word : Danger
Hazard statements : H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H350i May cause cancer by inhalation.
H360D May damage the unborn child.
H373 May cause damage to organs through pro-
longed or repeated exposure if inhaled.
H412 Harmful to aquatic life with long lasting ef-
fects.
Precautionary statements : Prevention:

P201 Obtain special instructions before use.
P260 Do not breathe vapours, aerosols.
P262 Do not get in eyes, on skin, or on clothing.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take
off immediately all contaminated clothing.
Rinse skin with water/ shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with wa-
ter for several minutes. Remove contact
lenses, if present and easy to do. Continue
rinsing.
P308 IF exposed or concerned:
P310 Immediately call a POISON CENTER or
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SAFETY DATA SHEET
Gardobond G 4040
doctor/ physician.
Hazardous components which must be listed on the label:

13138-45-9 Nickel(II) nitrate
Additional Labelling:
Restricted to professional users.
Labelling according to EC Directives (1999/45/EC)

Hazard pictograms :
Toxic
R-phrase(s) : R49 May cause cancer by inhalation.

R61 May cause harm to the unborn child.
R48/20 Also harmful: danger of serious damage to
health by prolonged exposure through in-
halation.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
S-phrase(s) : S53 Avoid exposure - obtain special instruc-

tions before use.
S23 Do not breathe vapours, aerosols.
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immedi-
ately with plenty of water and seek medical
advice.
S36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S45 In case of accident or if you feel unwell,
seek medical advice immediately (show
the label where possible).
S60 This material and its container must be
disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to
special instructions/ Safety data sheets.
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Hazardous components which must be listed on the label:

18718-07-5 Manganese bis(dihydrogen phosphate)
13138-45-9 Nickel(II) nitrate
Special labelling of certain : Restricted to professional users.

mixtures
2.3 Other hazards

Classification "corrosive" due to the extreme pH value.
SECTION 3: Composition/information on ingredients

3.1 Substances
not applicable
3.2 Mixtures
Chemical nature : Aqueous solution of inorganic salts.
Hazardous components
Chemical Name CAS-No. Classification Classification Concentration
EC-No. (67/548/EEC) (REGULATION [%]
Registration num- (EC) No
ber 1272/2008)
Manganese 18718-07-5 Xn; R48/20 Eye Irrit. 2; >= 25 - < 50
bis(dihydrogen phos- 242-520-2 H319
phate) 01-2119968560- Xi; R36
32-0000 STOT RE 2;
01-2119968560- R52/53 H373
32-0001
01-2119968560- Aquatic Chronic
32-0002 3; H412
01-2119968560-
32-0003
Orthophosphoric acid 7664-38-2 C; R34 Met. Corr. 1; >= 5 - < 10

231-633-2 H290
01-2119485924-24
Nota B Skin Corr. 1B;
H314
Manganese nitrate 10377-66-9 O; R 8 Ox. Sol. 2; >= 2.5 - < 3

233-828-8 H272
Xn; R22-R48/20
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SAFETY DATA SHEET
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Acute Tox. 4;
C; R34 H302
R52/53 Skin Corr. 1C;

H314
Eye Dam. 1;
H318
STOT RE 2;
H373
Aquatic Chronic
3; H412
Nickel(II) nitrate 13138-45-9 O; R 8 Ox. Sol. 2; >= 0.5 - < 1

236-068-5 H272
01-2119492333-38 Carc.Cat.1; R49
Carc. 1A; H350i
Repr.Cat.2; R61
Muta. 2; H341
Mut.Cat.3; R68
Repr. 1B;
T; R48/23 H360D
Xn; R20/22 STOT RE 1;

H372
Xi; R38-R41
Acute Tox. 4;
R42/43 H332
N; R50-R53 Acute Tox. 4;

H302
Nota E Skin Irrit. 2;

H315
Eye Dam. 1;
H318
Resp. Sens. 1;
H334
Skin Sens. 1;
H317
Aquatic Acute
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SAFETY DATA SHEET
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1; H400
Aquatic Chronic
1; H410
M-Factor:1
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
For the full text of the Notas mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Take off contaminated clothing and shoes immediately.
First-aid crew: Ensure self-protection.
Move out of dangerous area.
If inhaled : Move to fresh air.

If symptoms persist, call a physician.
In case of skin contact : Wash off immediately with plenty of water for at least 15 min-
utes.
Call a physician immediately.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
If swallowed : Rinse mouth with water.

Immediately give large quantities of water to drink.
Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Risks : If swallowed, severe burns in the oral cavity and throat as well
as danger of perforation of the digestive tract and stomach.
May cause an allergic skin reaction.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
For specialist advice physicians should contact the Poisons
Information Service.
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SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Unsuitable extinguishing : High volume water jet

media
5.2 Special hazards arising from the substance or mixture
Specific hazards during fire- : Hazardous decomposition products formed under fire condi-
fighting tions.
nitrogen oxides (NOx)
Oxides of phosphorus
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters
Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear personal protective equipment.
Refer to protective measures listed in sections 7 and 8.
6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.
6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Ensure adequate ventilation.
Soak up with liquid binder (sand, kieselguhr, acid binder, uni-
versal binder).
Sweep up and shovel into suitable containers for disposal.
6.4 Reference to other sections

See chapter 8 and 13
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SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms.
Have eye wash bottle or eye rinse ready at the work place.
Avoid contact with skin and eyes.
Do not breathe vapours, aerosols.
Advice on protection against : Normal measures for preventive fire protection.

fire and explosion
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Store in a place accessible by authorized persons only.
areas and containers Store at room temperature in the original container.
Keep container tightly closed in a dry and well-ventilated
place.
Further information on stor- : Avoid contact with metals.

age conditions Protect from frost.
Storage temperature : 7 - 40 C
7.3 Specific end uses

Specific use(s) : Phosphating solution for metal surfaces.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Control pa-
Components CAS-No. Value Update Basis
rameters
Manganese 18718-07- TWA 0.5 mg/m3 2006-09-01 GB EH40
bis(dihydroge 5 Manganese
n phosphate)
Further informa- : 2: Where no specific short-term exposure limit is listed, a figure three times the long-term expo-
tion sure should be used
Manganese
18718-07- OELV - 0.05 mg/m3
5 8 hrs Manganese
(TWA) Respirable
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Further informa- : SCOEL/SUM/127 - Adopted by the European Commission, June 2011

tion
Manganese
18718-07- OELV - 0.2 mg/m3
5 8 hrs Manganese
(TWA) Inhalable
Further informa- : SCOEL/SUM/127 - Adopted by the European Commission, June 2011

tion
Manganese
Orthophos- 7664-38-2 TWA 1 mg/m3 2000-06-16 2000/39/EC
phoric acid
Further informa- : Indicative

tion
7664-38-2 STEL 2 mg/m3 2000-06-16 2000/39/EC
Further informa- : Indicative

tion
7664-38-2 TWA 1 mg/m3 2005-04-06 GB EH40
7664-38-2 STEL 2 mg/m3 2005-04-06 GB EH40
Manganese 10377-66- TWA 0.5 mg/m3 As 2006-09-01 GB EH40

nitrate 9 Mn
Further informa- : 2: Where no specific short-term exposure limit is listed, a figure three times the long-term expo-
tion sure should be used
As Mn
Nickel(II) 13138-45- TWA 0.1 mg/m3 2007-08-01 GB EH40
nitrate 9 Nickel
Further informa- : 53+54: Substances that can cause occupational asthma (also known as asthmagens and
tion respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an im-
munological, irritant or other mechanism. Once the airways have become hyper-responsive,
further exposure to the substance, sometimes even to tiny quantities, may cause respiratory
symptoms. These symptoms can range in severity from a runny nose to asthma. Not all work-
ers who are exposed to a sensitiser will become hyper-responsive and it is impossible to iden-
tify in advance those who are likely to become hyper-responsive. 54 Substances that can
cause occupational asthma should be distinguished from substances which may trigger the
symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not
include the disease themselves. The latter substances are not classified asthmagens or respira-
tory sensitisers.
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Wherever it is reasonably practicable, exposure to substances that can cause occupational

asthma should be prevented. Where this is not possible, the primary aim is to apply adequate
standards of control to prevent workers from becoming hyper-responsive. For substances that
can cause occupational asthma, COSHH requires that exposure be reduced as low as is rea-
sonably practicable. Activities giving rise to short-term peak concentrations should receive
particular attention when risk management is being considered. Health surveillance is appropri-
ate for all employees exposed or liable to be exposed to a substance which may cause occupa-
tional asthma and there should be appropriate consultation with an occupational health profes-
sional over the degree of risk and level of surveillance.
Can be absorbed through skin. The assigned substances are those for which there are con-
cerns that dermal absorption will lead to systemic toxicity.
Capable of causing occupational asthma. The identified substances are those which: - are
assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause
sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication
'Asthmagen? Critical assessments of the evidence for agents implicated in occupational
asthma' as updated from time to time, or any other substance which the risk assessment has
shown to be a potential cause of occupational asthma.
Capable of causing cancer and/or heritable genetic damage. The identified substances include
those which: - are assigned the risk phrases 'R45: May cause cancer'; 'R46: may cause herita-
ble genetic damage'; 'R49: May cause cancer by inhalation' or - a substance or process listed
in Schedule 1 of COSHH.
Where no specific short-term exposure limit is listed, a figure three times the long-term expo-
sure should be used
Carcinogenic applies for nickel oxides and sulphides.
The 'Sen' notation in the list of WELs has been assigned only to those substances which may
cause occupational asthma.
Sensitizing applies for nickel sulphate.
Nickel
Further informa- : 53+54: Substances that can cause occupational asthma (also known as asthmagens and
tion respiratory sensitisers) can induce a state of specific airway hyper-responsiveness via an im-
munological, irritant or other mechanism. Once the airways have become hyper-responsive,
further exposure to the substance, sometimes even to tiny quantities, may cause respiratory
symptoms. These symptoms can range in severity from a runny nose to asthma. Not all work-
ers who are exposed to a sensitiser will become hyper-responsive and it is impossible to iden-
tify in advance those who are likely to become hyper-responsive. 54 Substances that can
cause occupational asthma should be distinguished from substances which may trigger the
symptoms of asthma in people with pre-existing airway hyper-responsiveness, but which do not
include the disease themselves. The latter substances are not classified asthmagens or respira-
tory sensitisers.
Wherever it is reasonably practicable, exposure to substances that can cause occupational
asthma should be prevented. Where this is not possible, the primary aim is to apply adequate
standards of control to prevent workers from becoming hyper-responsive. For substances that
can cause occupational asthma, COSHH requires that exposure be reduced as low as is rea-
sonably practicable. Activities giving rise to short-term peak concentrations should receive
particular attention when risk management is being considered. Health surveillance is appropri-
ate for all employees exposed or liable to be exposed to a substance which may cause occupa-
tional asthma and there should be appropriate consultation with an occupational health profes-
sional over the degree of risk and level of surveillance.
Capable of causing occupational asthma. The identified substances are those which: - are
assigned the risk phrase 'R42: May cause sensitisation by inhalation'; or 'R42/43: May cause
sensitisation by inhalation and skin contact' or - are listed in section C of HSE publication
'Asthmagen? Critical assessments of the evidence for agents implicated in occupational
asthma' as updated from time to time, or any other substance which the risk assessment has
shown to be a potential cause of occupational asthma.
Capable of causing cancer and/or heritable genetic damage. The identified substances include
those which: - are assigned the risk phrases 'R45: May cause cancer'; 'R46: may cause herita-
ble genetic damage'; 'R49: May cause cancer by inhalation' or - a substance or process listed
in Schedule 1 of COSHH.
Carcinogenic applies for nickel oxides and sulphides.
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SAFETY DATA SHEET
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The 'Sen' notation in the list of WELs has been assigned only to those substances which may
cause occupational asthma.
Sensitizing applies for nickel sulphate.
DNEL/DMEL
Orthophosphoric acid : End Use: DNEL, Workers, Industrial use
Exposure routes: Inhalation
Potential health effects: Long-term local effects
Exposure time: 8 h
Value: 2.92 mg/m3
Manganese nitrate : End Use: DNEL, Workers

Potential health effects: Long-term systemic effects
Value: 0.2 mg/m3
Nickel(II) nitrate : End Use: DNEL, Workers

Potential health effects: Long-term systemic effects
Value: 0.05 mg/m3
End Use: DNEL, Workers

Potential health effects: Long-term local effects
Value: 0.05 mg/m3
8.2 Exposure controls

Engineering measures
Ensure adequate ventilation, especially in confined areas.
Personal protective equipment

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
Recommended Filter type:
NO-P3
Hand protection : Neoprene

Protective gloves complying with EN 374.
The exact break through time can be obtained from the pro-
tective glove producer and this has to be observed.
Protective gloves have to be replaced at the first sign of dete-
rioration.
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SAFETY DATA SHEET
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Eye protection : Tightly fitting safety goggles

Eye protection (EN 166)
Skin and body protection : Chemical resistant protective clothing according to DIN EN
13034 (Type 6)
Hygiene measures : Take off contaminated clothing and shoes immediately.

Avoid contact with skin and eyes.
Keep away from food, drink and animal feedingstuffs.
Wash hands before breaks and immediately after handling the
product.
Protective measures : Handle in accordance with good industrial hygiene and safety
practice.
Facilities storing or utilizing this material should be equipped
with an eyewash facility and safety shower.
Environmental exposure controls

General advice : Do not flush into surface water or sanitary sewer system.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : liquid
Colour : green
Odour : perceptible
Flash point : not applicable
Autoignition temperature : not auto-flammable
pH : <2
at
20 C
(undiluted)
Solidification tempera- : < 7 C

ture/range
Boiling point/boiling range : no data available
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SAFETY DATA SHEET
Gardobond G 4040
Vapour pressure : no data available
Density : 1.29 - 1.33 g/cm3

at 20 C
Method: DIN 51757
Water solubility : completely miscible
Flow time : ca.15 sec.

at 23 C
4 mm
Method: ISO 2431
9.2 Other information

Corrosion : Corrosive to metals
Explosivity : Gives off hydrogen by reaction with metals.
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Gives off hydrogen by reaction with metals.
10.4 Conditions to avoid

Conditions to avoid : To avoid thermal decomposition, do not overheat.
10.5 Incompatible materials

Materials to avoid : Reducing agents
Incompatible with bases.
10.6 Hazardous decomposition products

Risk of decomposition. : No decomposition if stored and applied as directed.
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SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg
Method: Calculation method
Acute oral toxicity

Manganese bis(dihydrogen : LD50: > 2,000 mg/kg
phosphate) Species: rat
Method: OECD Test Guideline 420
Orthophosphoric acid : LD50: 2,600 mg/kg

Species: rat
Nickel(II) nitrate : Acute toxicity estimate: 500 mg/kg

Method: Converted acute toxicity point estimate
Skin corrosion/irritation
Skin irritation : Causes severe burns.
Serious eye damage/eye irritation

Eye irritation : Causes serious eye damage.
Eye irritation
Manganese bis(dihydrogen : Species: rabbit
phosphate) Result: Severe eye irritation
Causes serious eye irritation.
Respiratory or skin sensitisation

Sensitisation : May cause an allergic skin reaction.
Carcinogenicity
Remarks : May cause cancer by inhalation.
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Reproductive toxicity
Remarks : May damage the unborn child.
Target Organ Systemic Toxicant - Repeated exposure

Orthophosphoric acid : Species: rat
Application Route: Oral
NOAEL: <= 500 mg/kg bw/d
Toxicology Assessment
Acute effects : If swallowed, severe burns in the oral cavity and throat as well
as danger of perforation of the digestive tract and stomach.
Repeated dose toxicity : May cause damage to organs through prolonged or repeated
exposure if inhaled.
SECTION 12: Ecological information
12.1 Toxicity
Ecotoxicology studies for the product are not available.
Toxicity to fish
Manganese bis(dihydrogen : LC50: 8.71 mg/l
phosphate) Species: Fish
NOEC: 0.17 mg/l

Species: Fish
Toxicity to daphnia and other aquatic invertebrates

Orthophosphoric acid : EC50: > 100 mg/l
Exposure time: 48 h
Species: Daphnia magna (Water flea)
Toxicity to algae
Orthophosphoric acid : EC50: > 100 mg/l
Exposure time: 72 h
Species: Desmodesmus subspicatus (green algae)
NOEC: 100 mg/l

Exposure time: 72 h
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Species: Desmodesmus subspicatus (green algae)

12.2 Persistence and degradability
Biodegradability : no data available
12.3 Bioaccumulative potential
Bioaccumulation : Bioaccumulation is unlikely.
12.4 Mobility in soil
Mobility : no data available
12.5 Results of PBT and vPvB assessment

This mixture does not contain substances considered to be persistent, bioaccumulating and toxic
(PBT)., This mixture does not contain substances considered to be very persistent and very bioac-
cumulating (vPvB).
12.6 Other adverse effects
Additional ecological informa- : water endangering
tion
: Harmful to aquatic life with long lasting effects.
Do not flush into surface water or sanitary sewer system.
Even leakage of small amounts in the subsoil can contaminate
drinking water.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : Dispose of as hazardous waste in compliance with local and
national regulations.
Contaminated packaging : Dispose of as hazardous waste in compliance with local and

national regulations.
Waste Code : Waste codes should be assigned by the user, preferably in

discussion with the waste disposal authorities.
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SECTION 14: Transport information
ADR
UN number : 3264
UN proper shipping name : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Ortho-
phosphoric acid
Transport hazard class(es) : 8
Packing group : II
Classification Code : C1
Hazard Identification Number : 80
Limited Quantity (LQ) Inner : 1.00 L
Packaging
Maximum quantity : 30.00 KG
Labels : 8
Tunnel restriction code : (E)
Environmentally hazardous : no
IATA
UN number : 3264
Description of the goods : Corrosive liquid, acidic, inorganic, n.o.s. Orthophosphoric
acid
Class : 8
Packing group : II
Labels : 8
IATA_C
Packing instruction (cargo : 855
aircraft)
Packing instruction (LQ) : Y840
Maximum quantity : 30.00 L
IATA_P
Packing instruction (passen- : 851
ger aircraft)
Packing instruction (LQ) : Y840
Maximum quantity : 1.00 L
IMDG
UN number : 3264
Description of the goods : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Ortho-
phosphoric acid
Class : 8
Packing group : II
Labels : 8
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EmS Number 1 : F-A

EmS Number 2 : S-B
Marine pollutant : no
RID
UN number : 3264
Description of the goods : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Ortho-
phosphoric acid
Transport hazard class(es) : 8
Packing group : II
Classification Code : C1
Hazard Identification Number : 80
Labels : 8
Limited Quantity (LQ) Inner : 1.00 L
Packaging
Maximum quantity : 30.00 KG
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REACH - Candidate List of : This product does not contain substances of very high con-
Substances of Very High cern (Regulation (EC) No 1907/2006 (REACH), Article 57).
Concern for Authorisation
(Article 59).
Water contaminating class : WGK 2 water endangering

(Germany) VWVWS A4
Other regulations : The product is classified and labelled in accordance with EC

directives or respective national laws.
Regional or national implementations of GHS may not imple-
ment all hazard classes and categories.
15.2 Chemical Safety Assessment

For a mixture it is not mandatory to include an exposure scenario in the material safety data sheet.
The necessary safety - related information is stated in the first 16 sections.
SECTION 16: Other information

Full text of R-phrases referred to under sections 2 and 3
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SAFETY DATA SHEET
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R8 Contact with combustible material may cause fire.

R20/22 Harmful by inhalation and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R42/43 May cause sensitisation by inhalation and skin contact.
R43 May cause sensitisation by skin contact.
R48/20 Harmful: danger of serious damage to health by prolonged exposure
through inhalation.
R48/23 Toxic: danger of serious damage to health by prolonged exposure
through inhalation.
R49 May cause cancer by inhalation.
R50 Very toxic to aquatic organisms.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R53 May cause long-term adverse effects in the aquatic environment.
R61 May cause harm to the unborn child.
R68 Possible risk of irreversible effects.
Full text of H-Statements referred to under sections 2 and 3.

H272 May intensify fire; oxidiser.
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if in-
haled.
H341 Suspected of causing genetic defects.
H350i May cause cancer by inhalation.
H360D May damage the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure if
inhaled.
H373 May cause damage to organs through prolonged or repeated exposure
if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of Notas referred to under section 3
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- EN
SAFETY DATA SHEET
Gardobond G 4040
Nota B Some substances (acids, bases, etc.) are placed on the market in
aqueous solutions at various concentrations and, therefore, these solu-
tions require different labelling since the hazards vary at different con-
centrations. In Annex I entries with Note B have a general designation
of the following type: nitric acid ....%. In this case the manufacturer or
any other person who markets such a substance in aqueous solution
must state the percentage concentration of the solution on the label.
Example: nitric acid 45 %. Unless otherwise stated, it is assumed that
the percentage concentration is calculated on a weight/weight basis.
The use of additional data (e.g. specific gravity, degrees Baum) or
descriptive phrases (e.g. fuming or glacial) is permissible.
Nota E Substances with specific effects on human health (see Chapter 4 of
Annex VI) that are classified as carcinogenic, mutagenic and/or toxic for
reproduction in categories 1 or 2 are ascribed Note E if they are also
classified as very toxic (T+), toxic (T) or harmful (Xn). For these sub-
stances, the risk phrases R 20, R 21, R 22, R 23, R 24, R 25, R 26, R
27, R 28, R 39, R68 (harmful), R 48 and R 65 and all combinations of
these risk phrases shall be preceded by the word "Also". Examples: R
45-23 "May cause cancer. Also toxic by inhalation". R 46-27/28 "May
cause heritable genetic damage. Also very toxic in contact with skin and
if swallowed".
Further information
This data sheet contains changes from the previous version in section(s): 3
This data sheet contains changes from the previous version in section(s): 14
The information provided is based on our current knowledge and experience and apply to the product
as delivered. Regarding the product properties, these are not guaranteed. The delivery of this safety
datasheet does not free the recipient of the product from his own responsibility to follow the relevant
rules and regulations concerning this product.
20 / 20
- EN

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

Contact person product safety

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Carcinogenic Category 1 R49: May cause cancer by inhalation.

2.2 Label elements

Signal word : Danger

Hazard statements : H290 May be corrosive to metals.

Precautionary statements : Prevention:

Hazardous components which must be listed on the label:

Labelling according to EC Directives (1999/45/EC)

R-phrase(s) : R49 May cause cancer by inhalation.

S-phrase(s) : S53 Avoid exposure - obtain special instruc-

Hazardous components which must be listed on the label:

Special labelling of certain : Restricted to professional users.

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Orthophosphoric acid 7664-38-2 C; R34 Met. Corr. 1; >= 5 - < 10

Manganese nitrate 10377-66-9 O; R 8 Ox. Sol. 2; >= 2.5 - < 3

R52/53 Skin Corr. 1C;

Nickel(II) nitrate 13138-45-9 O; R 8 Ox. Sol. 2; >= 0.5 - < 1

Xn; R20/22 STOT RE 1;

N; R50-R53 Acute Tox. 4;

Nota E Skin Irrit. 2;

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : Move to fresh air.

If swallowed : Rinse mouth with water.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing : High volume water jet

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on protection against : Normal measures for preventive fire protection.

Further information on stor- : Avoid contact with metals.

7.3 Specific end uses

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Further informa- : SCOEL/SUM/127 - Adopted by the European Commission, June 2011

Further informa- : SCOEL/SUM/127 - Adopted by the European Commission, June 2011

Further informa- : Indicative

Further informa- : Indicative

7664-38-2 STEL 2 mg/m3 2005-04-06 GB EH40

Manganese 10377-66- TWA 0.5 mg/m3 As 2006-09-01 GB EH40

Wherever it is reasonably practicable, exposure to substances that can cause occupational

Manganese nitrate : End Use: DNEL, Workers

Nickel(II) nitrate : End Use: DNEL, Workers

End Use: DNEL, Workers

8.2 Exposure controls

Personal protective equipment

Hand protection : Neoprene

Eye protection : Tightly fitting safety goggles