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WATER RESOURCES RESEARCH, VOL. 47, W00H03, doi:10.

1029/2010WR010066, 2011

Rethinking hyporheic flow and transient storage to advance


understanding of streamcatchment connections
Kenneth E. Bencala,1 Michael N. Gooseff,2 and Briant A. Kimball3
Received 30 September 2010; revised 12 January 2011; accepted 29 January 2011; published 26 March 2011.
[1] Although surface water and groundwater are increasingly referred to as one resource,
there remain environmental and ecosystem needs to study the 10 m to 1 km reach scale
as one hydrologic system. Streams gain and lose water over a range of spatial and temporal
scales. Large spatial scales (kilometers) have traditionally been recognized and studied as
riveraquifer connections. Over the last 25 years hyporheic exchange flows (110 m) have
been studied extensively. Often a transient storage model has been used to quantify the
physical solute transport setting in which biogeochemical processes occur. At the longer
10 m to 1 km scale of stream reaches it is now clear that streams which gain water overall can
coincidentally lose water to the subsurface. At this scale, the amounts of water transferred
are not necessarily significant but the exchanges can, however, influence solute transport.
The interpretation of seemingly straightforward questions about water, contaminant, and
nutrient fluxes into and along a stream can be confounded by flow losses which are too small
to be apparent in stream gauging and along flow paths too long to be detected in tracer
experiments. We suggest basic hydrologic approaches, e.g., measurement of flow along
the channel, surface and subsurface solute sampling, and routine measurements of the
water table that, in our opinion, can be used to extend simple exchange concepts from
the hyporheic exchange scale to a scale of streamcatchment connection.
Citation: Bencala, K. E., M. N. Gooseff, and B. A. Kimball (2011), Rethinking hyporheic flow and transient storage to advance
understanding of streamcatchment connections, Water Resour. Res., 47, W00H03, doi:10.1029/2010WR010066.

1. Introduction may be useful in interpreting solute transport influenced by


streamcatchment connections.
1.1. The Stream Is Not a Pipe
[2] Generally, surface water and subsurface water systems 1.2. Hyporheic Flows: A StreamCatchment Continuum
are understood to be connected in a manner in which a stream
[4] Hyporheic exchange flow is stream water exchanging in
receives water and solutes from the subsurface; the water
the shallow subsurface. With these flows an apparent loss of
and solute continue to be transported without return to the water from the streams returns as a gain downstream (or,
subsurface (Figure 1a). However, the stream is not a pipe. In
conversely, an apparent gain of water in the stream is the return
some hydrologic systems there can be continuing exchange
of an upstream loss). The volumes of water involved in the
between the stream and the connecting subsurface systems
exchanges are typically insignificant as a fraction of the stream
(Figure 1b). The volume of water in this continuing exchange
flow. The significance of hyporheic exchange is in the move-
is not necessarily significant; rather, it is the exchange that
ment of solutes from the stream into the subsurface (Figure 2).
can further have influence on solute transport and aquatic
(See current, extensive reviews of hyporheic processes and
ecosystems.
significance from the viewpoints of hydrogeomorphology,
[3] The purpose of this article is to present a set of chal-
ecology, and nutrient dynamics in Poole [2010], Boulton
lenges in working to understand the connections of streams
et al. [2010], and Mulholland and Webster [2010], respec-
to their catchment at scales longer (in time and space) than tively. In the subsurface, solutes from the stream may be in
hyporheic exchange and shorter than that of regional river
an environment of different pH and dissolved oxygen and
aquifer interactions. To build the context, we introduce
in which contact with solid (abiotic or biotic) surfaces is
an understanding of hyporheic exchange and the now com-
enhanced. The stream water, temporarily in the subsurface,
mon transient storage interpretation of solute transport. We
may undergo reactions altering the biogeochemical signature
close with our opinions on basic hydrologic approaches that
of that water as it goes back into the stream. With hyporheic
flow the stream and the catchment ecosystem can be viewed
and studied as a continuum in which each is a boundary con-
1
U.S. Geological Survey, Menlo Park, California, USA. dition of the other rather than separate components of a system.
2
Department of Civil and Environmental Engineering, Pennsylvania
State University, University Park, Pennsylvania, USA.
3
Utah Water Science Center, U.S. Geological Survey, West Valley 1.3. Transient Storage: Simple Conceptual View
City, Utah, USA. of Hyporheic Flows
[5] The transient storage model (TSM) is a simple con-
Copyright 2011 by the American Geophysical Union. ceptual model of the streamcatchment continuum that builds
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Figure 1. (a) The streams function in its catchment is viewed simply as that of a pipe. (b) A contrasting
view of the streams function places the stream as an integral part of the catchment system [from Bencala,
1993].

upon the fundamental 1D model of solute advection and solute, delaying downstream transport for time scales longer
dispersion by providing a transient storage zone connected to than advection and dispersion (see Figure 3).
the channel. This transient storage zone is conceptually a [6] The TSM has several variations in representing solute
wellmixed reservoir of finite size that temporarily holds exchange between the main channel and the transient storage

Figure 2. Idealized representation of hyporheic exchange in (a) plan view (lateral exchange) and (b) ver-
tical cross section (vertical exchange) (reprinted from Hester and Gooseff [2010] with permission from
Environmental Science and Technology. Copyright 2010 American Chemical Society).
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Figure 3. Conceptual diagram representing conservative solute transport in the OTIS transient storage
model (redrawn from Runkel [1998]). Conservative solutes are transported in the main channel via
advection and dispersion, and they exchange with a finite transient storage zone. Lateral inflows and out-
flows of water can be simulated to influence mass of solute represented in the stream finite difference control
volume. Transient storage of solutes occurs as a function of hyporheic exchange and exchange with surface
transient storage zones (eddies, backwaters, etc.).

locations, though the most common is a singlerate mass ical processes that move mass and energy between the main
transfer approach, as is implemented in the onedimensional channel and surface versus subsurface storage zones are
transport with inflow and storage (OTIS) model [Runkel, likely to be very different. Further, the heterogeneity within a
1998]: single storage zone type (e.g., all pool margins) may be great
  enough that the residence times and biogeochemical efficacy
@C Q @C 1 @ @C of each zone is substantially different. The TSM, as typically
 AD CS  C qL CL  C
@t A @x A @x @x implemented, applies reachrepresentative characteristics to
1 these processes without discrimination. Thus, in character-
izing the representative storage zone influence on storage,
the singlestorage zone TSM lumps many zone types and
dCS A exchange processes. In addition to these challenges, the
 C  CS ; 2
dt AS most commonly used TSM (as implemented in OTIS) uses a
finite difference solution scheme so that all mass that leaves
where C is the main channel conservative solute concentra- the channel to move into transient storage must return in the
tion (M L3), CS is the storage zone conservative solute same part of the channel. Hence, there is no solute transfer
concentration (M L3), A is the crosssectional area of stream or communication from upstream to downstream along
(L2), AS is the crosssectional area of storage zone (L2), a is subsurface flow paths, as they are not explicitly represented
the storage zone exchange coefficient (T 1), qL is the lateral in the solute transport model.
inflow rate (L3 T 1 L1 of stream length), CL is the lateral [8] Alternative to the TSM, several mathematical models
inflow concentration of conservative solute (M L3), D is the have been produced with similar conceptual models, but
dispersion coefficient (L2 T 1), x is the distance downstream different mathematical exchange characterizations. Several
(L), t is time (T), and Q is streamflow rate (L3 T 1). of these have focused on exchange that is not of the single
rate mass transfertype characterized in the TSM by an
1.4. Limitations of the Transient Storage Concept exponential storage residence time distribution. For example,
[7] The simple conceptual basis of the TSM is both its Wrman et al. [2002] developed a transient storage model
greatest strength and its greatest weakness. The transient with lognormal residence time distribution, and Haggerty
storage zones in the conceptual and numerical models are et al. [2002] and Gooseff et al. [2003] have applied models
lumped representations of a diverse array of realworld with power law residence time distributions in their storage
locations of temporary solute storage, such as eddies behind zones. A twostorage zone version of the TSM with differ-
boulders, channel margins, pool margins, and hyporheic ing storage zone parameters has been evaluated theoretically
exchange. Whereas this is a great advantage from the per- [Choi et al., 2000] and implemented practically [Harvey
spective of simplifying the representation of the real world, et al., 2005; Marion et al., 2008; Briggs et al., 2009, 2010]
not all storage zones have the same spatial and temporal to separate surface transient storage from subsurface transient
scales nor provide the same biogeochemical function. Surface storage. Whereas all of these approaches yield excellent
storage zones (e.g., eddies) host very different conditions than simulated fits to observed stream tracer data, each of these
subsurface storage zones (hyporheic flow paths). Some conceptual and numerical models has different interpretations
storage zones may be nested within others; for example, of the influence of transient storage on solute transport. For
water may have to pass through a surface transient storage example, mean storage residence times would be calculated
zone to enter a subsurface transient storage zone. The phys- differently, and therefore, implications for storage zone bio-

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nection of streams to their catchment at larger 10 m to 1 km


scales.

2. StreamCatchment Connections
[10] In discussing streamcatchment connections, we refer
to a loosely specified portion of the continuum of surface
water to groundwater interactions. These connections have
one or more of the following characteristics.
[11] 1. Flows are dispersed in the sense that an individual,
welldelineated flow is insignificant.
[12] 2. There may be exchange between the surface and
subsurface occurring in both directions.
[13] 3. The primary importance of the connection is on
the flux of solutes, while over the longitudinal distance of the
stream the dispersed exchanges may or may not change the
Figure 4. Conceptual, schematic profile of stream channel stream discharge.
exchange with an underlying nested subsurface flow net- [14] 4. The exchanges occur over larger (10 m to 1 km)
work. The dashed box represents the region influenced by spatial scales than typically associated with hyporheic flows
an individual reachscale tracer test. Thick arrows represent (110 m).
flow paths in the stream channel and in the underlying sub- [15] These interactions of surface water and groundwater
strate. The thick dashed arrow (tail end of flow path C) repre- are, again loosely, distinguished from the dominantly uni-
sents a subsurface flow path with residence time longer than directional flows at the 110 km scale of discharge of an
the duration of tracer concentration measurement. Flow paths alluvial aquifer feeding a river network or, conversely, a
A, B, and C (tail end) are unlabeled with tracer and dilute the mountain range drainage system recharging a semiarid area.
measurable tracer concentrations in the channel. These flow [16] The distinction from the spatial scale of hyporheic
paths are considered gross hydrologic gain in the context of flow is significant in that at the hyporheic scale flow (carrying
the tracer test. Flow paths C (head end), D, and E remove solutes along) leaving the stream returns to the stream over a
tracer mass during the tracer test and reduce the amount of distance on the order of 10 m. At the larger spatial scale, water
tracer mass recovered. These flow paths are considered gross leaving the stream has flowed back into the catchment sub-
hydrologic loss in the context of the tracer test. Flow paths surface, seemingly a loss from the stream. If this water returns
labeled F return tracer to the stream in measurable concentra- to the stream far down valley seemingly as now yet again a
tions after a temporary period of storage relative to channel gain to the stream, it likely will have mixed extensively with
flow. These flow paths are considered transient storage dur- other waters en route. At the scale of hyporheic flow, the
ing the tracer test and do not influence the stream water bal- exchange of solutes between the surface and the subsurface is
ance [from Payn et al., 2009]. commonly referred to as transient storage; at larger scales
this terminology is not descriptive of the longterm storage
geochemical cycling would be interpreted differently as well that may occur. In this longterm storage, water and solute
[Gooseff et al., 2003]. that leave the channel may return over time and space scales
[9] Stream solute transport studies (and therefore subse- longer than can be quantified in the typical tracer study.
quent TSM modeling and/or mass balance analyses) are [17] We believe it is reasonable to assert that stream eco-
inherently limited by practical issues. To characterize return systems with hyporheic exchange are now routinely under-
flows (i.e., hyporheic flows), the detection limit of the solute stood and studied as a fully integrated ecosystem with surface
tracer is perhaps the most important restriction. Small fluxes and subsurface zones. Also at the larger riveraquifer scale,
of highly concentrated hyporheic water returning to the water is viewed as a single hydrologic resource [e.g., see
stream channel after much of the stream tracer has passed may Winter et al., 1998]. For the intermediate scale of stream
not provide enough signal to be observed when concentration catchment connections we are proposing that studies need to
detection limits are high. Furthermore, without additional be designed to recognize a complex hydrologic system with
information (such as the discharge at the upstream and fundamentally disparate scales of surface and subsurface
downstream ends of a reach of interest [see Payn et al., 2009], transport processes [e.g., Woessner, 2000]. This hydrologic
the stream tracer approach is generally insensitive to system is distinct both from an integrated ecosystem in which
streamflow losses. When tracerlabeled water leaves the detailed coupled processes can be identified and from a
channel (as illustrated in Figure 4), it does not change the single resource in which the readily defined components of
concentration of the remaining water in the channel. Dilution the system are linked. Streamcatchment connections at the
of the tracer by lateral inflowing water is, however, readily intermediate 10 m to 1 km spatial scale have influences on
observed. The result of both gains and losses occurring along public policy issues such as environmental flow management
a stream reach may confound both the estimates of lateral for aquatic ecosystem health and land use management, such
inflows and therefore the quantification of streamcatchment as restoration of streams affected by mine drainage. A time
connections. The transient storage concept and the associated frame in which these connections influence the system is
implicit interpretation of tracer transport have been highly most clearly the time of transport of water and solute along
useful in developing an understanding of hyporheic pro- the stream. The spatially cumulative influence of hyporheic
cesses. The limitations of the concept and its interpretation, exchange flows acts in this time frame. The connections are
however, call for caution as we seek to understand the con- also evident in a steady, or static, time frame of a study to

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identify the location and quantity of nutrient or contaminant have been in upland catchments that can be considered
load from the catchment. Alternatively, on an annual time gaining reaches, resulting in tracer dilution profiles that are
scale, the summation of apparent catchment solute inputs to straightforward and provide the data needed to calculate
the stream may be different than the stream solute exports spatially detailed estimates of stream discharge and stream-
from the catchment, the differences being caused by losses flow gain. And yet, in some catchments, a seemingly normal
and then apparent gains in the streamcatchment connections. tracer dilution profile has resulted in a substantial overesti-
[18] Streamcatchment connections are the locations where mate of stream discharge at the end of the study reach. For
the stream water column is in hydraulic contact with adjacent example, in Red Butte Creek, a research catchment near Salt
water tables. These connections may drive exchanges of Lake City, Utah, a dilution profile for a bromide tracer is
water between the aquifer and the channel, where potential illustrated in Figure 5. This bromide profile resembles many
for exchange is a function of the spatiotemporal head distri- that come from upland catchments, with clear gaining seg-
bution and flux is a function of both head gradients and ments indicated by dilution of the tracer. Using the mass
hydraulic conductivity. That these are dynamic in both time injection rate and injectate concentration, a tracer dilution
and space is a general statement that most hydrologists can discharge was calculated (see equations in the work by
agree upon. However, the true temporal and spatial hetero- Kimball et al. [2002]) and is illustrated along with the bro-
geneity of connections between streams and aquifers is rarely mide concentration. Stream discharge increased at the tribu-
quantified well and incorporated into conceptual and tary inflows but also along parts of the reach where no visible
numerical models. As such, our understanding of exchange inflows were observed, suggesting dispersed inflow of water
dynamics between streams and aquifers remains incomplete. along the study reach from the subsurface. Areavelocity
[19] Streamflow gains generally are easier to identify than discharge measurements also were obtained in the stream the
losses of stream water. Some are obvious to the naked eye, day of the synoptic sampling. Although not all of these were
such as streamside seeps and springs. Stream tracer experi- rated as good measurements because of the difficulties of
ments will also generally identify locations of lateral inflows measuring discharge in mountain streams by this method
between tracer sampling sites as tracer concentrations at [Jarrett, 1992], taken together they clearly indicate a lower
downstream locations are diluted (however, amounts of lat- stream discharge for most of the study reach. If both the tracer
eral inflows can be difficult to determine if streamflow losses dilution discharge and the areavelocity discharge represent
have occurred upstream of the gain; see more detail about this sound data, then the simplest explanation for the discrepancy
in section 3.1). Inflows to channels may be hyporheic return would be that this stream gains substantial quantities of water
flows (a mix of stream water and groundwater) or they may be (Figure 4, flow paths A and B) but subsequently loses much
contributions of pure groundwater from the larger aquifer. of that water to flow paths on scales longer than hyporheic
Streamflow losses are more difficult to identify because they flows (Figure 4, flow paths C, D, and E).
are not visible and they do not influence stream tracer con- [22] Faced with this dilemma in Red Butte Creek, various
centrations. Losses of water from streams to aquifers have means were used to estimate an accurate discharge profile.
one of two fates: they either mix with groundwater and For example, using areavelocity measurements that were
reenter the channel at a downstream location or they follow rated good (five of the measurements at different locations
deeper, more distal flow paths that mesh into a larger valley along the stream), the bromide tracer data were used to esti-
bottom aquifer. From the scales of grains to watersheds, the mate discharge by dilution both upstream and downstream
geologic structure of the stream and catchment is a primary from each of these points, generating a whole series of pos-
control on the fate of streamflow gains and losses. Whereas sible discharge profiles (Figure 6). Each of these results in a
we can generally identify short (spatially and temporally) much smaller discharge than the tracer dilution discharge, but
exchanges or flow paths, our ability to observe and document it is not clear which should be selected.
temporally and spatially long exchange flow paths is poor. [23] This one example in Red Butte Creek illustrates the
We often rely on models because direct observations of tracer need for (1) recognizing the utility of measuring stream dis-
signatures, etc., do not provide the resolution necessary to charge not only at the catchment outlet but also along the
support evidence of streamgroundwater exchanges in long stream reach and (2) increasing appreciation that tracer and
temporal or spatial contexts. physical measurements of discharge may be measuring dif-
[20] In section 3 we set out three basic challenges to ferent aspects of flow. A number of flow measurements by
understanding the flow and solute transport pathways that complementary methods, spread out along the stream, may
may be significant in connection of streams and their catch- be needed to fully understand the dynamics of exchange
ment at scales longer than that of hyporheic exchanges. between the stream and its catchment. Differences between
While describing these challenges, we offer suggestions of tracer and physical measurements of discharge have been
basic hydrologic approaches to address these challenges previously noted [e.g., Zellweger et al., 1989] and ascribed to
with field measurements. the observation that tracer methods will measure some por-
tion of flow within the subsurface in addition to the flow
3. Basic Hydrological Measurements Needed strictly in the surface channel.
for Understanding at the Scale of StreamCatchment
Connections 3.2. Challenge 2: Estimating the Distribution
of StreamCatchment Exchange Flux
3.1. Challenge 1: Measurement of InChannel Flow
[24] The issues of discharge measurement in a given stream
[21] During the past 2 decades, many massloading studies reach having subsurface flow translate into challenges for
have been done in streams affected by acid mine drainage calculating an accurate catchment mass loading of solutes to
[Kimball et al., 2004, 2007]. The majority of these streams the stream. In extending studies to multiple, successive

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Figure 5. Variation of bromide concentration and estimated tracer dilution discharge with distance along
the study reach, Red Butte Creek, Utah. Independent areavelocity discharge measurements are indicated
that show the difference between the estimated tracer dilution discharge and instream discharge. The
two sections of stream that are discussed in the text with Figure 7 are shaded and are labeled A and B here.

stream reaches, judgments are needed to interpret the influ- where the concentration increases from less than 80 mg/L to
ence on mass load of inflows individually too small to be almost 160 mg/L. Dilution of sulfate concentration also is
measured and of subsurface flow paths longer than the scale indicated where Parleys Fork enters the stream. The zone of
of hyporheic exchange observed in the standard tracer greatest increase from 1902 to 2953 m included only a few
experiment. The longitudinal profile of sulfate concentrations visible inflows, suggesting that the increases in sulfate had to
along Red Butte Creek (Figure 7) indicates areas of the stream result from dispersed subsurface inflow of water with higher

Figure 6. Variation of discharge estimates with distance along the study reach. The tracer dilution dis-
charge is repeated for comparison to estimated discharge profiles. Each of the profiles starts with an
areavelocity measurement at the indicated distance along the study reach, and then the amount of dilution
of the bromide tracer upstream and downstream from that point was used to indicate changes.
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Figure 7. Variation of sulfate concentration and load with distance along the study reach, Red Butte
Creek, Utah. Note the break in concentration scale in showing the range of inflow sulfate concentrations.
Loads include cumulative instream load and cumulative inflow loads (see Kimball et al. [2002] for
equations). Two discharge profiles were used to calculate these loads, the tracer dilution discharge and the
lowest discharge profile from the lowest estimated profile using the areavelocity discharge at 4600 m as a
basis (see Figure 5). The two sections that are discussed in the text are shaded and are labeled A and B.

sulfate concentration than the stream concentration. To cal- because the sulfate concentration increases in that first seg-
culate load from this sulfate concentration profile requires ment, a small increase in load is indicated. This could imply
the choice of just one of the possible discharge profiles the inflow of an amount of sulfaterich water too small to be
(Figure 6). Two possible versions of sulfate mass load are observed by tracer dilution. Larger increases in sulfate load
indicated in Figure 7, representing the maximum and mini- over the next two segments result from higher sulfate con-
mum discharge profiles in Figure 6. The first uses the tracer centration and water inflow indicated by tracer dilution.
dilution discharge and the second uses the minimum Using the change in mass load of sulfate and the change in
adjusteddischarge profile based on the areavelocity mea- discharge, it is possible to calculate an effective inflow con-
surement at 4600 m. Comparing the cumulative instream centration, which is the concentration that would be necessary
loads (Figure 7, solid squares and triangles), the tracer dilu- to cause the measured change in load for a given stream
tion discharge results in almost 5 times greater load for tracer segment [Kimball et al., 2002]. The calculated inflow con-
dilution load than the adjusteddischarge load (Figure 7). By centrations for the second and third segments, using either of
summing the load from each of the sampled inflows (see the instream loading curves, compare very well with the
Kimball et al. [2002] for equations), a cumulative inflow load range of the sampled inflows downstream at the left bank
is calculated. Comparing the cumulative instream and inflow springs. Thus, despite the great difference between cumu-
loads using the tracer dilution discharge (Figure 7, solid and lative instream and inflow loads through these segments, the
open squares), the cumulative instream load is almost calculated increases result from plausible sources given the
5 times greater than the inflow load at the end of the study range of sulfate concentration among the sampled inflows.
reach. For the adjusteddischarge loads (Figure 7, solid and [26] In contrast to this, looking at two segments down-
open triangles), the instream load is over 3 times the inflow stream from Parleys Fork, from 4133 to 4804 m (shaded
load. The difference between cumulative instream and area B), the discharge increases in both segments but the
inflow loads has often been considered unsampled load in sulfate concentration remains constant in the stream. Calcu-
mass loading studies [Kimball et al., 2006]. However, some lating the effective sulfate concentration as above results in a
of this difference also could be a result of water returning value of approximately 139 mg/L for both segments, which is
to the stream from the catchment after traveling along flow very similar to the instream concentration of 142 mg/L along
paths on the scale of 10 m to 1 km. This circumstance could this reach. This could be a condition indicating that the
result in water and solute load being double counted. A increase in discharge represents inflow of water that has
closer examination of two sections of the discharge and traveled a flow path on the scale of more than 10 m and then
sulfateloading profiles (Figures 5 and 7) can illustrate these reentered the stream (similar to flow path C illustrated in
possibilities. Figure 4). The loading would be double counted. On this
[25] Focusing on three stream segments from 2183 to same scale, if part of the solute mass in a stream segment were
2369 m (shaded area A in Figures 5 and 7), we see no dilution lost to a longer flow path so that it was not accounted for at the
of bromide in the first segment and then two slight decreases end of the study reach, it may be a lost or overcounted
in bromide concentration in the next two segments. However, source (similar to flow path D illustrated in Figure 4). This is
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and connection to the channel change throughout this storm


event. Likely, there is a coincident downvalley change in
water table gradients that is not expressed here. At the
scale of a 23 km2 mountain catchment, Jencso et al. [2009]
have documented the temporal dynamics of hillslope
riparianstream hydraulic connections (i.e., when the hill-
slope is contributing water to the riparianstream system) as
a function of lateral contributing area. They found that larger
lateral contributing areas had a more consistent aquifer
stream connection.
[30] We propose that a stream is a dynamic expression of
local groundwater conditions, where exchanges of water
between the catchment and the channel are consistently
changing in response to heterogeneous temporal and spatial
water table dynamics. These dynamic changes to boundary
conditions of the channel occur at several spatial and tem-
poral scales. Whereas we can generally acknowledge that
Figure 8. Water level elevations along a lateral transect of streambeds are made of porous media, our development of
wells in watershed 1, H. J. Andrews Experimental Forest, understanding hydraulic process is largely confined to the
Oregon, United States, during a 3 day storm event. Note the boundaries of the channel. To improve our understanding
dynamic temporal pattern of gradients among the three wells of how streams are dynamically connected to catchments,
in comparison to the stream. we must at least (1) develop our conceptual and numerical
models of streams in their catchment settings and (2) develop
and apply improved techniques to detect the water table
significant because, in terms of loading profiles, that loss dynamics at space and time scales that influence stream
would have the same effect on a loading profile as would the catchment hydrologic connections.
removal of load through biogeochemical processes, com- [31] One severe limitation in our approach to characteriz-
plicating the interpretation of mass transfer processes. These ing streamcatchment connections is that we have relied
two possibilities point to the need for an understanding of heavily upon observations of solute transport in the stream
basic hydrology to quantify solute loading at this scale. alone. The transport of solute downstream is affected by a
[27] Sampling of stream and subsurface chemistry has been host of processes that we ultimately attempt to interpret from
widely used in identifying the temporal variation in the flow solute breakthrough curves observed downstream, including
components of runoff at the catchment scale to streams. Here advection, dispersion, and exchange between fast and slow
we are suggesting that sampling in the subsurface along 10 m water (and also reaction in the case of nonconservative tra-
to 1 km reaches of stream can be combined with spatially cers). Whereas our physical and mathematical understanding
discrete stream discharge measurements to enhance our inter- of advection and dispersion is quite mature, our conceptual
pretation of the significance of local flow losses in a stream and numerical models of exchange continue to evolve in an
that is gaining water overall, as in this discussion. effort to better fit a simulation of transport to an observed
solute breakthrough curve. The solution to this challenge is
not extensive collection of solute concentrations from the
3.3. Challenge 3: Observing the Distribution of Where subsurface, as demonstrated by Harvey and Bencala [1993]
and When the Stream Is Connected to the Catchment
and Wondzell [2006]. However, emerging new techniques,
[28] Perhaps the most significant challenge to character- such as using electrical resistivity during stream tracer
izing streamcatchment connections arising from the use of experiments to image solute distribution in the subsurface
stream solute transport approaches is the simplicity of the in two and three dimensions [Ward et al., 2010a], are
conceptual model that oversimplifies a finite zone with which developing with promise of advancing our conceptual and
streams directly interact. The connections between streams numerical models of solute transport [e.g., Ward et al.,
and catchments are extensive in both space and time, with 2010b] and streamcatchment connections.
exchanges occurring along a continuum of flow path lengths,
transport times, and flow capacities. Hence, assessing stream 4. Opinion Summary
catchment connections from the stream perspective alone will
always be of limited utility. [32] The 10 m to 1 km scale of streamcatchment con-
[29] Several different types of streamcatchment connec- nections we have discussed is inherently messy. The
tions exist and occur over different temporal and spatial physical process characteristics are heterogeneous through-
scales. Each likely has a different influence on stream water out the catchment. This will make detailed process modeling
conditions. One example is a temporally dynamic connection unreliable; while treating the catchment as a box and the
between the stream and adjacent riparian aquifers. Figure 8 stream as a pipe will not account for the transitions and
presents a 10 day time series of stream and water table ele- transformations we know occur. We propose here that
vations from three wells adjacent to the stream, each 23 m through the previous 25 years of detailed study of smaller
apart, arranged normal to the stream. During a 3 day storm spatial scale hyporheic exchange flow we now have consid-
event, the water table elevations and local gradients shift erable understanding of the degree to which streams are
substantially, particularly in relation to the far riparian well. continuously connected to their catchment. Flow and solute
These data suggest that flow direction in the riparian aquifer exchange with a stream and the connectivity of a stream to its

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W00H03 BENCALA ET AL.: OPINION W00H03

catchment are seemingly straightforward characteristics of a pling, 19971998, in Integrated Investigations of Environmental Effects
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done over the catchment scale are no doubt time and labor River Watershed, Jefferson County, Montana, edited by D. A. Nimick,
S. E. Church, and S. E. Finger, U.S. Geol. Surv. Prof. Pap., 1652,
intensive to collect. However, such approaches, as we suggest Chap. D6, 191262.
(measurement of flow along the channel, surface and sub- Kimball, B. A., D. K. Nordstrom, R. L. Runkel, K. R. Vincent, and P. L.
surface solute sampling, and routine measurements of the Verplanck (2006) Questa baseline and premining groundwater quality
water table) are needed to establish and quantify the extent to investigation. 23. Quantification of mass loading from mined and
unmined areas along the Red River, New Mexico, U.S. Geol. Surv.
which streamcatchment connections are determining solute Sci. Invest. Rep., 20065004, 36 pp.
transport and transformation. Kimball, B. A., K. WaltonDay, and R. L. Runkel (2007), Quantification of
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