ANSWER OF QUESTION

1. Equation reaction of tollens reagent with glucose:

CH 2OH CH 2OH

H O H H OH

OH
H
H + 2 Ag(NH3)2 +
OH
H
H COO
-
+ 2 Ag+ + 4 NH3 + H2O
HO OH (pereaksi Tollens) HO (cermin perak)
H OH H OH

(glukosa)

2. Equation reaction of benedict reagent with lactose:

3. Molecule formula of sucrose

CH 2OH CH 2OH
HOCH2 O H
H O H CH2OH O H H O H
H HO
OH
H
H O H HO + HCl OH H + H
H CH 2OH
HO CH 2OH HO OH
HO H
H OH HO H H OH

(sukrosa) (glukosa) (fruktosa)

Sucrose when reacted with tollens reagents can not be formed a silver mirror
because the sucrose structure binds to the hemiacetal group and is not mutarotated,
and if reacted with benedict, sucrose is not produced by a red brick precipitate
because the sucrose structure has no aldehyde and ketone free groups.
4. Glucose and fructose produce the same osazon because the monosaccharides
have the same H and OH groups in 3, 4 and 5 carbon atoms.
5. Hydrolysis of sucrose by acid then reacted with excess phenylhydrazine will
produce one compound alone because of the influence of invertase enzymes
that cause the change of rotation direction of the polarization plane to the right
and to the left called the inverse that produces only one compound that is
inverse sugar.
6. The meaning of the phrase "five acetyl groups can be incorporated into glucose
and fructose molecules" ie glucose and fructose can form double bonds and
four acetyl groups that can be bonded.
7. The meaning of "only eight acetyl groups that can be incorporated into the
sucrose molecule has only two binding rings of four acetyl groups meaning
only three methyl groups can enter the molecule of sucrose.
8. Sugar present in solution after hydrolysis of sucrose is glucose and fructose.
The both can reduce benedict reagents because they are reducing sugars having
aldehyde or ketone free groups.