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K = [NH3]2
[N2] [H2]3
K = [ICl]2
[Cl2]
K = [NO] [O2]1/2
[NO2]
Determine Concentrations.
PCl5 (g) PCl3 (g) + Cl2 (g)
After 0.0500 -x 0.150 +x 0.250 + x
Substitute 0.0228 .177 .277
Therefore Kp = 1.8
11.If 5.0 moles of O2 and 4.0 moles of NO were entered into an empty 1.0
liter flask, calculate the equilibrium constant if the amount of NO 2 found at
equilibrium was 1.5 moles.
2 NO (g) + O2 (g) 2 NO2 (g)
Initial 4.0 M 5.0 M 0
Change -2x -x +2x
After 4.0 2x 5.0 - x 2x
Using 1.5 = 2x and therefore x = 0.75 M
After 4.0 1.5 5.0 0.75 1.5
Substitute 2.5 4.25 1.5
K= (1.5) 2
= 0.085
(2.5)2(4.25)
12.Two moles of NH3 were entered in a 1.0 liter container at 650C. At
equilibrium only 71% of the original NH3 was found. Determine the
equilibrium constant of the following reaction.
2 NH3 (g) N2 (g) + 3 H2 (g)
Initial 2.0 M 0 0
Change -2x +x +3x
After 2.0 2x +x +3x
Using 2.0 2x = 2.0(71%) so x = 0.29
After 2.0 2(.29) 0.29 +3(0.29)
Substitute 1.42 0.29 0.87
K= (0.29)(0.87)3 = 0.095
(1.42)2
13.If the equilibrium constant for the following reaction is 0.10, determine
the final concentration of ICl, if 4.0 moles of I2 and Cl2 were entered
initially into an empty 1.0 liter flask.
I2 (g) + Cl2 (g) 2 ICl (g)
Initial 4.0 M 4.0 M 0
Change -x -x +2x
After 4.0 x 4.0 - x 2x
Plug into equilibrium expression and solve for x.
0.10 = [2x]2 so x = 0.546
[4.0 x] 2
Determine Concentrations.
After 4.0 0.546 4.0 - 0.546 2(0.546)
Substitute 3.5 3.5 1.1