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DOC. NO. PDRP0456-8110-CA-106-0002 REV.

O1
HDO DOC. NO. A4-2100866-106-BEP-Vol I-004
UNIT SIZING CALCULATIONS
PARADIP REFINERY PROJECT CRS UNIT
FOR
INDIAN OIL CORPORATION LIMITED
CONSULTANT: -
FOSTER WHEELER (INDIA)
SUBMITTED
BY

DORR-OLIVER HOUSE,
CHAKALA, ANDHERI (EAST), MUMBAI 400099
INDIA
TEL. NO. :-022 28359400
FAX NO. :- 022 28365659

O1 10.05.2010 ISSUED FOR APPROVAL AS RK JNP


PREPARED CHECKED APPROVED
REV. DATE REVISIONS
BY BY BY
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INDIAN OIL CORPORATION LIMITED 2 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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UNIT SIZE CALCULATION


LEGENDS

EL : Epoxy Lined
TD : Total Depth
SWD : Side Water Depth
FB : Free Board
MOC : Material of Construction
HRT : Hydraulic Retention Time
DVD : Dead Volume Depth .
OWS : Oily Water Sewer .
CRWS : Contaminated Rain Water Sewer .

UNIT SIZE CALCULATION


CRS PLANT UNIT 106
INDIAN OIL CORPORATION LIMITED 3 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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CONDENSATE RECOVERY SYSTEM FEED WATER ANALYSIS


CRS Feed Water Characteristic
Sr. No. Description Unit Normal Design
as Such as Such as CaCO3
Physical Parameter
o
1 Temperature C 40 40 -
2 Total Dissolved Solids g/l 5000 5000 -
3 pH - 7.5 - 9.5 7.5 - 9.5 -
4 Oil mg/l <1 <1 -
o
5 KMnO4 Value @ 100 C mg/l Nil Nil -
Cations
6 Na + K as CaCO3 g/l 100.00 1000 2173.91
9 Ammonia g/l 500.00 1000 2941.18
7 Ca Hardness as CaCO3 g/l < 40 400 1000.00
8 Mg Hardness as CaCO3 g/l < 24 240 1000.00
10 Iron as Fe g/l 30.00 200 357.14
11 Copper g/l 10.00 100 154.93
11 Nickel g/l 30.00 200 0.00
Total Cation g/l - - 7627.16
Anions
12 Total alkalinity (as CaCO3) g/l 0.00 - 20.0000
13 Chlorides as Cl g/l 100.00 1000.00 2445.011
14 Sulphates as SO4 g/l 100.00 1000.00 1041.667
Total Anion g/l - - 3506.68
Others
15 Total Silica as SiO2 g/l 120.60 603.00 500.00
16 Carbon dioxide g/l < 200 1000.00 1136.36
Ionic Load
17 MB Cation Load mg/l - - 7.627
18 MB Anion Load based on Total Anion mg/l - - 5.143
19 MB Anion Load based on SiO2 mg/l - 0.603 -

INDIAN OIL CORPORATION LIMITED 4 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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OIL COALESCER

Total flow to be treated = 1100 m3/hr

Total oil in the inlet = 20 ppm (for Design)

Dissolved oil in the inlet = 2 ppm (for Design)

Total oil in the inlet = 2 ppm ( Normal)

Dissolved oil in the inlet = 0.5 ppm (Normal)

pH = 7.5 9.5

Temperature = < 50 deg. C

Number of working units = 8 nos.

Number of standby units = 3 nos.

Total number of units = 11 nos.

Flow per unit = 1100 / 8


= 137.5 m3/hr (1)

Resin Grade = Coalescer grade

Resin size = 0.3 mm to 1.5 mm

Process conditions = Continuous

Operating pH range = 0 12

Velocity of condensate in oil = 11 m / hr (2)

Minimum Bed depth = 250 mm


Bed depth recommended = 400 mm

Area of oil coalesce unit required = Flow per unit (1)


___________
Velocity (2)

= 137.5 / 11
= 12.5 m2 (3)
Minimum diameter calculated D = 12.5 x 4/

= 3989 mm

Diameter provided = 4000 mm (4)


INDIAN OIL CORPORATION LIMITED 5 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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C/S area of each Coalescer unit = / 4 x 42

= 12.571 m2 (5)

Volume of resin required = C/S area of each coalescer x Depth of resin

= 12.571 m2 x 0.4 m

= 5.028 m3 (6)

Vessel height below the bottom


Strainer = 500 mm
= 0.5 m (7)

Height between resin


Top strainer = 500 mm
= 0.5 m (8)

Chimney height = 500 mm


= 0.5 m (9)

Space provided for collecting free


Oil = 1000 mm
= 1m (10)

Total ht. of vessel calculated = (7) + (8) + (9) + (10) + 0.4 m

= 0.5 + 0.5 + 0.5 + 1.0 + 0.4


= 2.9 m

Ht. of vessel provided = 3.0 m

INDIAN OIL CORPORATION LIMITED 6 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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CARTRIDGE FILTER

Design flow (total) = 1100 m3/hr (1)

No. of Cartridge Filters working = 2 nos. (2)

No. of Cartridge Filters standby = 1 no. (3)

Total No. of Cartridge Filters = 3 nos. (4)

Flow per filter = Design flow (1)


__________________
No. of Cartridge Filter working (2)

= 1100 / 2

= 550 m3/hr (5)

Micron rating of Cartridge Filter = 5 micron

Type of Cartridge = PP wound

MOC of Cartridge filter = SS 316


MOC of Cartridges = Polypropylene (PP)

Flow through each 10 Cartridge = 1.0 m3/hr


Flow through each 40 cartridge = 4.0 m3/hr

No. of cartridges of 40 long per filter= 550 / 4.0

= 137.5

138 Nos.

Size of cartridge filter = as per manufacturer model

INDIAN OIL CORPORATION LIMITED 7 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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ACTIVATED CARBON FILTER

Total flow to be treated = 1100 m3/hr (1)

Total No. of ACF provided = 09 nos. (6W + 3 S)

Flow rate per ACF = 1100/6


= 183.33 m3/hr (2)

Inlet oil = 5 ppm

Desired outlet oil = BDL

Total suspended solids = Nil

Service velocity = 15 m3/hr/m2


= 15 m/hr (3)

Minimum C/S area based on service


Velocity = (2) / (3)

= 183.33 m3/hr
___________
15 m/h

= 12.22 m2 (4)

Minimum retention time required = 10 min

Minimum carbon volume required = (2) x 10/60


(for each unit)

= 183.33 x 10/60

= 30.56 m3 (5)

Maximum specific flow rate = 6 m3/hr/m3

Minimum volume of carbon required = 183.33/6


For each unit = 30.56 m3 (6)

Maximum bed depth of carbon = 2.5 m (7)

Minimum C/S area based on Max. Bed depth = (6) / (7)

= 30.56 m3
_______
2.5 m

= 12.222 m2 (8)
INDIAN OIL CORPORATION LIMITED 8 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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Minimum cross section area required = Maximum of (4) & (8)


= 12.222 m2 (9)

Minimum diameter of vessel required = 12.222 x 4/

= 3.945 mm

Diameter of vessel provided = 4.0 mm (10)

C/S area of vessel provided = / 4 x 42

= 12.56 m2 (11)

Actual service velocity = Flow per unit (1)


_______________
C/S area provided (11)

= 183.33 / 12.56

= 14.6 m/hr (12)

Minimum carbon bed depth = 2.2 m

Carbon depth calculated = (6) / (11)

= 130.56 / 12.56

= 2.433 m (13)

Carbon bed depth provided = 2.433 mm (14)

Volume of activated carbon


Provided for each ACF = 30.56 m3 (15)
Actual specific flow rate = 6.0 m3/hr/m3

Supporting media layer depth (Silex) = 50 mm (fine 2 6 mm)


= 0.05 m (a)

Supporting media layer depth (Silex) = 50 mm (coarse 14 mm)


= 0.05 m (b)

Total supporting media depth = 100 mm


= 0.1 m
Supporting Media volume = C/S area x 0.1 m

= (11) x 0.1

INDIAN OIL CORPORATION LIMITED 9 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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= 12.56 x 0.1
= 1.256 m3 (16)

Total bed height provided = (14) + (a) + (b)

= 2.433 + 0.05 + 0.05


= 2.533 m (19)

Free board provided = 75% of bed ht.

Free board provided = 0.75 x 2.533


= 1.9 m (20)

Height on straight (HOS) calculated = (19) + (20)


= 2.533 + 1.9
= 4.433 m (21)

Height on straight provided = 4.5 m (22)

Backwash source = Treated condensate water

Backwash velocity = 12 m / hr

Back wash flow required = C/S area(11) x 12


= 12.56 x 12
= 150.72 m3/hr (23)

Back washing time = 10 minutes

Quantity of back wash waste


For each unit = 150.72 x 10 / 60
= 25.12 m3 (24)

Rinse flow rate = same as service flow rate


= 183.33m3/hr

Rinse time = 5 minutes

Quantity of rinse waste = 183.33 x 5/60


= 15.278 m3 (25)
Total waste per unit due to
Back washing & rinsing
of ACF = (24) + (25)
= 25.12 + 15.278

= 40.4 m3 (26)

Total waste from 6 ACFs = 40.4 x 6


= 242.4 m3

INDIAN OIL CORPORATION LIMITED 10 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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CONDENSATE POLISHING UNIT MIXED BED EXCHANGER


SIMULTANEOUS REGENERATION

Total no. of streams = 4 Nos. (2 working + 1 regeneration


Standby + 1 Normal standby)

Flow rate per stream = 550 m3/hr (1)

Regeneration mode = Simultaneous

Regenerant temperature = 40 deg. C

Exhaustion/operation time = 42 hrs (2)


Per cycle

Net output per cycle = 23100 m3 (3)

Waste water per cycle = 142.50 m3 (4)


(Refer regeneration
Calculation sheet)
Gross output per cycle = (3) + (4)
= 23100 + 142.59
= 23242.59 m3

Gross flow rate per Exchanger = 553.4 m3/hr (5)

Considering Cation Bed

Ionic Load on cation bed as CaCO3 = 7.63 mg/l


= 7.639 g/m3 (6)

Work done per cycle Gross O/P per x


Ionic
As CaCO3 = cycle m3 load
(g/ m3)
__________________________
1000
= 23242.59 x 7.63
_______________
1000

= 177.27 kgs (7)

Regeneration level (100%) = 60 kg/m3 of resin (8)

Exchange capacity = 39 kg of ionic load/m3 (9)


of resin
Correction factor due to ionic ratio = 1.0

Derating factor = 0.7


INDIAN OIL CORPORATION LIMITED 11 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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Total Correction factor = 0.7 (10)

Design exchange capacity = (9) x (10)


= 39 x 0.7
= 27.3 kg / m3 (11)

Work done per cycle = 177.27 kg (from 7)

Effective resin volume = (7) kg


Based on work done ____
(11) kg/m3

= 177.27 m3
_______
27.3

= 6.493 m3 (12)

Maximum specific Bed volume (BV) = 46 m3/hr (13)

Effective resin volume based on


specific bed volume = (5)
____
(13)

= 12.03 m3 (14)

Effective resin volume considered = Maximum of (12) & (14)

= 12.03 m3 .. (15)

Maximum surface flow rate = 60 m3/hr/m2 (16)

Minimum C/s area based on


Maximum surface flow = (5)
_____
(16)

= 9.223 m3/hr (17)

Maximum bed depth = 1000 mm


= 1.0 m (18)

Minimum C/s area based on max = effective resin volume (15)


Bed depth _____________________
Max bed depth (18)
INDIAN OIL CORPORATION LIMITED 12 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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= 12.03
_______
1.0

= 12.03 m2 .. (19)

Considering Anion Bed

Anionic Load on Anion Bed = 5.14 mg/l


= 5.14 g/m3 (20)

Work done per cycle Gross O/P per x 5.14 g/m3


As CaCO3 = cycle m3

__________________________
1000

= 23242.59 x 5.14
_______________
1000

= 119.54 kgs (21)

Regeneration level = 60 kg/m3 (22)

Anionic Exchange capacity = 26.5 kg/m3 (23)


Correction factor = 1.0 (a)

Derating factor = 0.9 (b)

Total Correction factor = (a) x (b)


= 1.0 x 0.9
= 0.9 (24)

Design exchange capacity = Exchange x Total


Capacity Correction factor
(23) x (24)
= 26.5 x 0.9
= 23.85 kg / m3 (25)

Effective resin volume = (21)


Based on work done ____
(25)

= 119.54
_______
INDIAN OIL CORPORATION LIMITED 13 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

23.85

= 5.012 m3 (26)

Maximum surface flow (bed volume = 46 m3/hr/m3

Effective resin volume = (5)


Based on work done ____
(46)

= 553.4
_______
46

= 12.03 m3 (27)
Silica load on Anion Bed
As CaCO3 = 0.6 mg/l (28)

Regeneration level = (22)


60 kg/m3 Refer Resin Mfr. data

Silica Exchange capacity = 2.1 kg/m3 (29)


Correction factor = 1.0 (a)

Derating factor = 0.9 (b)

Total Correction factor = (a) x (b)


= 1.0 x 0.9
= 0.9 (c)

Design exchange capacity = (29) x (c)


= 21 x 0.9
= 1.89 kg / m3 (30)

Work done per cycle = Gross O/P per x Ionic load


Due to silica load cycle m3
______________________________
1000

= 23242.59 m3 x 0.69 m3
_______________
1000

= 14.02 kgs (31)

INDIAN OIL CORPORATION LIMITED 14 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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Effective resin volume = Work done (31)


Based on work done _________________________
Design exchange capacity (30)

= 14.02
_______
1.89

= 7.415 m3

Total Effective resin volume based on


Anionic load + silica load = (26) + (31)

= 5.012 + 7.415

= 12.427 m3 (32)

Effective resin volume to be considered = Maximum of (27) & (32)


= Maximum of 12.03 m3& 12.427 m3

= 12.427 m3 .. (33)

Maximum surface flow rate = 60 m3/hr/m2 (34)

Minimum C/s area based on


surface flow = (5)
_____
(34)

= 553.4 m3/hr
______
60 m3/hr/m2

= 9.223 m2 (35)

Maximum bed depth = 1000 mm


= 1.0 m

INDIAN OIL CORPORATION LIMITED 15 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

Minimum C/s area based on max = (33)


Bed depth ____
(1.0)

= 12.42
_______
1.0

= 12.42 m2 .. (36)

Based on Cation & Anion calculations

Minimum C/s area to be considered = Maximum of (19) & (36)

= 12.427 m2 (37)
_______
2.5 m

Minimum unit diameter calculated = 12.427 x 4/

= 3.977 m

Unit Diameter provided = 4.0 m (38)

Considering rubber lining of thickness = 4.5 mm

C/S area of Mixed Bed provided = (4000 9)2 x /4


_________
1000

= 12.515 m2 (39)

Resin bed depth with effective resin volume = (15)


____
(39)

= 0.961 m (40)

Minimum resin depth criteria for


Cation bed = 0.5 m

Resin bed depth of 0.961 m ( 0.5 m) is OK

Anion Bed
INDIAN OIL CORPORATION LIMITED 16 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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Resin bed depth with effective


Resin volume = (33)
_____
(39)

= 0.993 M (41)

Minimum resin bed depth

Criteria for anion bed = 0.5 m

Resin bed depth of 0.993 m (> 0.5 m ) is OK

Total bed depth provided


Considering cation & Anion = (40) + (41)
= 0.961 + 0.993
= 1.954 m (42)

Considering free board of 100%

Free board required = 1.954 m (43)

Total height of Bed required = (42) + (43)

= 1.954 + 1.954
= 3.908 m

Total height of bed provided = 4.0 m (44)

Considering Cation Bed

Stoichiometric required as CaCO3 = Work done as CaCO3

= 177.27 kg

Regeneration level = 60 kg/m3

Resin volume = 12.03 m3

Therefore HCl required as 100% = 60 x 12.03


= 721.77 kg (45)

conversion factor = 1.37

HCl required as CaCO3 = 988.825 (46)

regeneration efficiency = 177.27


INDIAN OIL CORPORATION LIMITED 17 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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______ x 100
988.825

= 17.927%

Un-utilized Hcl as CaCO3 = 988.825 177.27

= 811.555 (47)

Considering Anion Resin

Stoichiometric required as CaCO3 = Work done as CaCO3

= 119.54 kg

Regeneration level = 60 kg/m3

Resin volume = 12.427 m3

NaOH required as 100% = 60 x 12.427


= 745.65 kg (48)

Conversion factor = 1.25

NaOH required as CaCO3 = 745.62 x 1.25


= 932.03 kg (49)

regeneration efficiency = 119.54


______ x 100
932,03

= 12.826%

Un-utilized NaOH as CaCO3 = 932.03 119.54

= 812.49 kg (50)
From (47) & (50)

Chemical required for neutralization = self neutralized

Chemical required for neutralization = 812.49 811.555

= 0.935 kg (HCl) as CaCO3

= 0.935 / 1.37

= 0.68 kg (HCl) as 100%.

INDIAN OIL CORPORATION LIMITED 18 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
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SUMMARY OF CRS MIXED BED (MB) EXCHANGER


(i) Diameter of MB Exchanger : 4.0 metre
(ii) Height on Straight (HOS) of MB : 4.0 metre
(iii) Material of Construction of MB : CS with 4.5 mm thick Rubber
Lining
(iv)Total Cation Resin Volume for MB : 12.03 m3
(v) Total Anion Resin Volume for MB : 12.427 m3
(vi)Hydrochloric Acid Required
for Regeneration (as 100%) : 721.77 kg per MB per
Regeneration
(vii)Sodium Hydroxide (NaOH) Required
for Regeneration (as 100%) : 745.65 kg per SBA per
Regeneration

INDIAN OIL CORPORATION LIMITED 19 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

CRS Regeneration

Mixed Bed Regeneration = Simultaneous regeneration


Using HCl & NaOH

Size of Mixed Bed Exchanger = 4.0 m dia x 4.0 m HOS

C/S area of MB including


Rubberlining of thickness of 4.5 mm = {(4000 9)/1000}2 x /4

= 12.515 m2 (1)

In Mixed Bed, regeneration is carried out simultaneously by acid from bottom (counter current) and
Alkali from top (co flow). With this, compaction of Bed is maintained without any requirement of down
flow and up flow arrangement of water for bed compaction.

Quantity of Acid (100%) required per regeneration

= 721.77 kg (2)

Quantity of Alkali (100%) required per regeneration

= 745.65 kg (3)

Acid injection concentration = 4% w/v


= 40 kg/m3 (4)

Caustic injection concentration = 4% w/v


= 40 kg/m3 (5)

Step 1

Middle Collector Flush; Source: Feed

Basis of flow for Middle Collector Flush


= 9 m3/hr per unit C/S area of
Mixed Bed
= 9 m3/hr/m2

Middle collector flush flow rate = 9 x C/s area of MB (1)

= 9 x 12.515
= 112.635 m3/hr (6)

Duration of Middle Collector Flush = 5 minutes

= 5
INDIAN OIL CORPORATION LIMITED 20 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

____ = 0.08333 hrs (7)


60
Middle Collector Flush water = (6) x (7)

= 112.635 x 0.08333
= 9.39 m3 (8)

Step 2: Backwash

Basis of flow rate and water generated is as Step 1 , but duration of back wash is twice of that of Middle
Collector Flush, i.e. 10 min

Backwash waste generated = 9.39 x 2


= 18.78 m3 (9)

Step 3: Acid Pre-injection

Source: MB water
Flow Counter current

&

Alkali Pre-injection

Source: MB water
Flow Cocurrent

Acid pre-injection flow rate = 5


___ x Acid injection flow rate
6

5
___ x X m3/hr
6

Where X = Acid injection flow rate (10)

Duration of Acid pre-injection = Duration of Alkali pre-injection

= 2 min
= 2/60
= 0.0333 hr (11)

Acid pre-injection waste = (10) x (11)

Z1 = 5
__ x X x 0.0333 (12)
6

Alkali pre-injection flow rate = 5


INDIAN OIL CORPORATION LIMITED 21 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

___ x Alkali injection flow rate


6

5
___ x Y m3/hr (13)
6

Where Y = Alkali injection flow rate

Alkali pre-injection waste = 5


__ x Y x 0.0333 (14)
6

Step 4: Acid injection

Source: MB water
Flow Counter current

&

Alkali injection

Source: MB water
Flow Cocurrent

Quantity of Acid (100%) required per


Regeneration = 721.77 kg

Acid injection concentration = 4% w/v


= 40 kg/m3
Volume of 4% solution = 721.77 kg
_____
40 kg/m3
= 18.044 m3 (15)

Quantity of Alkali (100%) required per


Regeneration = 745.65 kg

Alkali injection concentration = 4% w/v


= 40 kg/m3

Volume of 4% solution = 745.65 kg


_____
40 kg/m3
= 18.64125 m3 (16)

Duration of Acid pre-injection = Duration of Alkali injection

= 15 min (17)
INDIAN OIL CORPORATION LIMITED 22 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

Acid injection flow rate = 18.044 m3


_______
15/60 hr

= 18.044 x 60/15

X = 72.176 m3/hr (18)

Alkali injection flow rate = 18.64125 m3


_______
15/60 hr

= 18.64125 x 60/15

Y = 74.565 m3/hr (19)

From (10) & (18)

Acid pre-injection flow rate = 5


__ x X
6

= 5
__ x 72.176
6

= 60.14667 m3/hr (20)

From (12)

Acid pre-injection waste = 5


__ x 72.176 x 0.0333
6

= 2.0 m3 (21)

From (13) & (19)

Alkali pre-injection flow rate= 5


__ x Y
6

= 5
__ x 74.565
6

= 62.1375 m3/hr (22)

From (14)
INDIAN OIL CORPORATION LIMITED 23 UNIT SIZING CALCULATIONS FOR TANKS
PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

Alkali pre-injection waste = 5


__ x 74.565 x 0.0333
6

= 2.07 m3 (23)
Step 5: Acid Rinse

Source: MB water
Flow Counter current

&

Alkali Rinse

Source: MB water
Flow Cocurrent

From unit size calculation

Effective resin volume = 12.03 m3 (24)

Basis of Acid Rinse waste

= Alkali Rinse Waste

= 4 x effective resin volume


= 4 x 12.03 m3
= 48.12 m3 (25)

Acid Rinse flow rate = Acid pre-injection flow rate (20)

= 60.14667 m3/hr

Alkali Rinse flow rate = Alkali pre-injection flow rate (22)

= 62.1375 m3/hr

Duration of Acid rinse= Acid rinse waste (25)


_____________
Acid rinse flow rate (m3/hr)

= 48.12
_____
60.14667

= 48 min (26)

INDIAN OIL CORPORATION LIMITED 24 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

Duration of Alkali rinse = Alkali rinse waste (25)


_____________
Alkali rinse flow rate (m3/hr)

= 48.12
_____
62.1375

= 46.5 min (27)

Duration of Acid rinse= Duration of Alkali rinse


= Maximum of (26) & (27)
= 48 min (28)

Step 6: Drain Down

Duration of Drain Down = 5 min

Step 7: Air mixing

Basis of air mixing = 2 Nm3/hr per unit C/S area of mixed bed
= 2 Nm3/hr/m2

Air required = 2 Nm3/min/m2 x C/S area of Mixed Bed (1)

= 2 x 12.515
= 25.03 Nm3/min
= 25.03 x 60 Nm3/hr
= 1501.8 Nm3/hr (29)

Duration of air mixing = 10 minutes

Step 8: Force Settle

Source: Feed water


Flow Coflow

Duration of force settle = 3 minutes


Flow rate during force settle = Service flow rate
= 550 m3/hr

INDIAN OIL CORPORATION LIMITED 25 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

Waste due to force settle = 550 x 3/60


= 27.5 (30)

Step 9: Filling

Source: Feed
Flow Coflow

Flow rate during filling = Service flow rate


= 550 m3/hr

Duration of filling = 2 min

Waste due to filling = 550 x 2/60


= 18.33 m3 (31)

Step 10:

Final Source: Feed


Rinse Flow Coflow

Flow rate during final rinse = Service flow rate


= 550 m3/hr

Duration of final rinse = 10 min

Waste due to final rinse = 550 x 10/60 = 91.67 m3 (32)

INDIAN OIL CORPORATION LIMITED 26 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

Summary : Table (D) CRS MIXED BED (MB) EXCHANGER

Flow Time Volume Water


Sr. No. Operation Basis
m3/hr minutes m3 source
1. Middle Collector Flush 9 m3/hr/m2 112.635 5 9.39 Feed

2. Backwash 9 m3/hr/m2 112.635 10 18.78 Feed


5/6 injection MB
3. Acid pre-injection 60.14667 2 2.0
flow water
5/6 injection MB
4. Alkali pre-injection 62.1375 2 2.07
flow water
MB
5. Acid injection 72.176 15 18.044
water
MB
6. Alkali injection 74.565 15 18.64125
water
4 x effective MB
7. Acid Rinse 60.14667 48 48.12
resin volume water
4 x effective MB
8. Alkali Rinse 62.1375 48 48.12
resin volume water
9. Drain down 5

10. Air mixing 2 Nm3/hr/m2 1501.8 10 - -

11. Force Settle Service flow 550 3 27.5 Feed

12. Filling Service flow 550 2 18.33 Feed

13. Final Rinse Service flow 550 10 91.67 Feed

Total Time for Regeneration = 110 Minutes

Feed Water required = 165.67 m3

MB / CRS Water = 136.9953 m3

Total Waste Water for Regeneration = 302.6653 m3

INDIAN OIL CORPORATION LIMITED 27 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

UNIT SIZING CALCULATION FOR CRS UNIT- DOSING/STORAGE TANKS

1. ACID MEASURING TANK FOR MB (106-TK-003 A/B)


No of Tanks = 2
Feed requirement per regeneration = 9.63 m3/hr.
{Basis: Feed requirement is the actual dosing rate per MB. The details given in the Chemical
Consumption, Doc no. PDRP0456-8110-PD-106-0003}
Pumpable capacity of tank required
as per chemical consumption = 2.3 m3 .
{Basis: As per the Chemical Consumption Doc no. PDRP0456-8110-PD-106-0003}
Storage Time available
at feed flow = (2.3/9.63).
= ~ 15 Min.
Side Water Depth provided = 1.6 m .
Area Required = ( 2.3/1.6 )
= 1.43 m2 .
Diameter of Tank Required = 1.35 m.
Diameter of Tank Provided = 1.4 m.
Size of Tank provided = 1.4 m x 1.6 m SWD
+0.298 m FB +0.294 m DVD .

2. ALKALI MEASURING TANK FOR MB (106-TK-004A/B)


No of Tanks = 2
Feed requirement per regeneration = 14.92 m3/hr.
{Basis: Feed requirement is the actual dosing rate per MB. The details given in the Chemical
Consumption, Doc no. PDRP0456-8110-PD-106-0003}
Pumpable capacity of tank required
as per chemical consumption = 3.42 m3 .
{Basis: As per the Chemical Consumption Doc no. PDRP0456-8110-PD-106-0003}

Storage Time available


at feed flow = (3.42/14.92).
= ~ 15 Min.
Side Water Depth provided = 1.8 m

INDIAN OIL CORPORATION LIMITED 28 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1
[Type text]

Area Required = (3.42/1.8)


= 1.89 m2
Diameter of Tank Required = 1.55 m
Diameter of Tank Provided = 1.6 m .
Size of Tank provided = 1.6 m x 1.8 SWD
+0.298 m FB +0.294 m DVD .

3. RESIN TRANSFER VESSEL(106-V-006)


No of Tanks = 1
{Basis: Resin requirement will be depend upon the no. of vessels in which resin used & the resin
life, for vessel design Effective Volume 40.85 m3 is considered}
Diameter of Tank Provided = 3.4 m
Height of Tank provided = 4.5 m.

INDIAN OIL CORPORATION LIMITED 29 UNIT SIZING CALCULATIONS FOR TANKS


PARADIP REFINERY PROJECT CRS UNIT DOC NO PDRP0456-8110-CA-106-0002 REV O1

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