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17-11-2013 10 10 MINUTES
Q.No.1. Encircle the correct answer.
(i). Ketones are always reduced to
(a) Prim. alcohol (b) Sec. Alcohol (c) Ter. alcohol (d) All alcohols
(ii). Aldol product on heating undergoes
(a) decomposition (b) dehydration (c) rearrangement (d) Oxidation
(iii). Acetone is prepared by the hydrolysis of
(a) ethyne (b) propyne (c) ethane (d) propane
(iv). Cannizzaros reaction is not given by
(a) Formaldehyde (b) Acetaldehyde
(c) Benzaldehyde (d) Tri methyl acetaldehyde
(v). Acetone reacts with HCN to form cyanohydrin. It is an example of
(a) electrophilic addition (b) electrophilic substitution
(c) nucleophilic addition (d) nucleophilic substitution

Which of the following is not alicylic?

(a) Cylo hexane (b) Cyclobutane (c) Toluene (d) Cyclopentene
Number of acidic hydrogen present in 1-Butyne is:
(a) 1 (b) 2 (c) 3 (d) 4
(v) Chemically Baeyers reagent is:
(a) 1% alkaline KMnO4 (b) 1% acidic KMnO4
(c) 2% alkaline KMnO4 (d) 2% acidic KMnO4
Polymerization of acetylene forms:
(a) propane (b) butane (c) benzene (d) naphthalene
Vicinal dihalides on treatement with Zn dust give:
(a) alkenes (b) alkynes (c) alkanes (d) all of these

Q.No.2. Write short answers of the following questions. (10 x 2 = 20)

(i). What is formaline? Give its two uses.
XI (F.Sc.) 30 50 MINUTES
(ii). Which are those weak oxidizing agents which can oxidize aldehydes but not ketones?
(iii). Give equations for reaction of phenylhydrazien with the following:
(a) Ethanal (b) Propanone

(iv)Why alkenes are more reactive than alkanes?

(v) What are terminal alkynes and how these behave acidic in nature?

(vi) How neoprene is obtained from alkynes?

Q.3 a) Explain free radical mechanism for reaction of chlorine with methane in the
presence of sunlight?
(b) Distinguish between: (4)
(i) Butanone and 3-pentanone
(ii) Acetaldehyde and benzaldehyde