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17-11-2013 10 10 MINUTES
Q.No.1. Encircle the correct answer.
(i). Ketones are always reduced to
(a) Prim. alcohol (b) Sec. Alcohol (c) Ter. alcohol (d) All alcohols
(ii). Aldol product on heating undergoes
(a) decomposition (b) dehydration (c) rearrangement (d) Oxidation
(iii). Acetone is prepared by the hydrolysis of
(a) ethyne (b) propyne (c) ethane (d) propane
(iv). Cannizzaros reaction is not given by
(a) Formaldehyde (b) Acetaldehyde
(c) Benzaldehyde (d) Tri methyl acetaldehyde
(v). Acetone reacts with HCN to form cyanohydrin. It is an example of
(a) electrophilic addition (b) electrophilic substitution
(c) nucleophilic addition (d) nucleophilic substitution
Q.3 a) Explain free radical mechanism for reaction of chlorine with methane in the
presence of sunlight?
(b) Distinguish between: (4)
(i) Butanone and 3-pentanone
(ii) Acetaldehyde and benzaldehyde