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Comparison of Three Methods of Relative

Permeability Measurement
Jeffrey T. Hawkins: Production Research and Development, Conoco Inc.,
Ponca City, Oklahoma

Abstract: Relative permeability curve shapes of granular Old, Unpreserved Core


carbonate cores from a Middle East reservoir were compa- Often the only core that is available for analysis is old
rable regardless of the conditions and methods of measure-
ment. However, variations among the tests in flow rate, vis- core that was not properly preserved. Because of the ex-
cosity ratio, and pore volumes of water injected did affect pense or time involved, it may not be possible to obtain
residual oil saturation. Thus, this research confirms the im- a fresh, carefully preserved core. In such cases, an old,
portance of reservoir condition relative permeability mea- unpreserved core could be used as a substitute. Unfor-
surements because of the significant impact of test conditions tunately, because of loss of light ends or deposition and
on residual oil saturation. The three types of measurements oxidation of heavy ends, the wettability of the core may
were ambient condition unsteady-state, ambient condition be altered (Richardson et al., 1955; Treiber et al., 1972).
steady-state, and reservoir condition unsteady-state. This Thus, this core would be unsuitable for native-state
study provided a unique opportunity to compare relative measurement, and would have to be measured restored-
permeabilities from these different methods on the same core. state.
All data were from first cycle waterfloods on restored-state
core. The rock/fluid interaction was oil-wetting in character.
Although the residual oil saturation varied, the shapes of the Core With Altered Wettability
relative permeability curves from the three methods were
similar. In addition, a new equation was developed for nor- Research by Sharma and Wunderlich (1 987) and Yan
malizing relative permeability curves, which accounts for the and co-workers (1 988) has shown that most drilling fluid
different residual oil saturations of the various samples. components alter rocWfluid wettability, even those that
have traditionally been regarded as bland components.
INTRODUCTION They have found this to be true both for oil-based and
To assist in production simulation studies, i.e., history water-based mud. Some people have used lease crude as
matching and performance forecasting, relative perme- a drilling fluid to try to avoid wettability alteration. Safe-
abilities were measured on core from a Middle East res- ty concerns aside, however, even crude oil as a drilling
ervoir. No freshly cut core was available for this study. fluid would probably be exposed to air, possibly altering
Thus, it was necessary to restore older, unpreserved core the oils wetting characteristics. Even with a bland drilling
to its original native-wettability (Cuiec, 1975, 1977; mud, hysteresis in relative permeability measurements
Wendel et al., 1985; Gant and Anderson, 1986). This was often makes native-state analysis inappropriate.
accomplished by cleaning the core to a water-wet state,
saturating the sample with a synthetic brine, flushing the Core on the Wrong Flooding Cycle
sample with dead reservoir crude, and aging the sample
Because of hysteresis in relative permeability mea-
at reservoir temperature for 1,000 hr.
surements it may be desirable to conduct restored-state
In many cases, restored-state analysis is the only way
analysis even on fresh core. Numerous studies in the lit-
to get representative data. There are three major reasons
erature have identified the phenomenon of relative per-
why it is often necessary to measure relative permeabil-
meability hysteresis (Josendal et al., 1952; Levine, 1954),
ities on restored-state rather than native-state core.
and Pate1 and co-workers (1985) have shown evidence
1. The available core was not properly preserved. that it exists in the reservoir. Hysteresis in relative perme-
2. The cores wettability was altered due to interaction abilities can take two forms, flooding phase dependence
with drilling fluids. and cycle dependence. Flooding phase dependence means
3. The core is on the wrong flood cycle (due to water- that results are different when relative permeabilities are
flooding or flushing during coring) and the results are measured during an oil flood than when measured during
affected by hysteresis. a waterflood. Cycle dependence means that results are
different when initially relative permeabilities are mea-
sured on a waterflood cycle, then the sample is oilflooded
Originally presented as paper SCA-8804 at the 1988 SCA Confer- back to irreducible water saturation (S,,,J, and then rel-
ence. ative permeabilities are measured again on a second cycle

September-October, 1989 The Log Analyst 363

I
Hawkins

Table 1: Rock and fluid properties. I uu

Porosity 20-2690
Permeability 9-26 md
Irreducible water saturation 5- 10%
Rock type Granular limestone
Fluid gravity 32 API
Reservoir temperature 230F
Reservoir pressure 3,000 psia
Gadoil ratio 400 scf/stb

10
waterflood. The second cycle waterflood results are often
different than the first cycle waterflood results.
Because of relative permeability hysteresis, only data
from a first cycle waterflood accurately represent the res-
ervoir waterflood. Obtaining core that has not already
been through the first cycle waterflood is difficult. The
reservoir may be under active water drive or waterflood,
or if a water-based mud is used in drilling, the core will
have been flushed with water during coring. In either case,
the core when it reaches the laboratory will already have
gone through a first cycle waterflood, thus native-state 0 .05 .1 . I 5 .2 .25 .3 .35 .4
analysis would be on the wrong cycle. POROSITY
During coring, the core is usually flushed by mud fil- Figure 1: Air permeability versus porosity.
trate. Normally, when fresh-state core plugs are taken
at the laboratory they are then flushed with brine to re-
move mud filtrate (continuing the first cycle waterflood).
The core plugs are then flushed back to S,, with oil, and are contradictory, with some studies showing significant
the relative permeability measurements are then made differences (Amaefule and Handy, 1982) between the two
on a second cycle! So, no matter to what lengths we have methods while other studies show agreement (Johnson et
gone to preserve native-wettability, the measurements al., 1959) between the two methods.
are made on the wrong cycle and are affected by hysteresis. In light of the historical controversy concerning mea-
Our experience shows that these hysteresis effects are more surement methods, relative permeabilities for this study
significant than minor alterations in wettability, espe- were measured three different ways on restored-state
cially for the non-wetting phase. The wettability resto- core. The three different methods were 1) unsteady-state
ration process, on the other hand, simulates the initial oil at ambient conditions, 2) steady-state at ambient con-
migration into the reservoir, and subsequent relative ditions, and 3) unsteady-state at reservoir conditions. In
permeabilities are measured on a first cycle waterflood. the figures used in this paper these three methods are
Cycle dependent relative permeabilities are why we abbreviated AC USS, AC SS, and RC USS. Because each
recommend restored-state analysis, even for fresh core. test was run on a separate sample, we have a comparison
We recommend using a bland, low fluid loss mud for of the methods on geologically similar plugs, rather than
coring, because the absence of wettability altering com- the same plugs.
pounds will leave the core easier to clean. We also care-
fully preserve the core, again, because the core will be
easier to clean if it is not exposed to oxygen or allowed ROCK AND FLUID PROPERTIES
to dry out. The relative permeability measurements were made on
Much work has been published in the literature con- core plugs from a granular limestone from an oil field in
cerning the effect of temperature on relative permeability the Middle East. Table 1 summarizes the pertinent rock
(Honarpour et al., 1986). However, the published data and fluid properties.
are contradictory. For example, some studies indicate a A crossplot of helium porosity versus air permeability
strong temperature effect (Edmonson, 1965), while other for the core plugs is shown in Figure 1. In general the
studies indicate no temperature effect (Miller and Ramey, core plugs possessed similar properties. Procedures for
1985). Likewise, there have been some studies published restoration to native wettability and for the three different
comparing the steady-state and unsteady-state methods measurement methods are described in the following sec-
of relative permeability measurement. Again, these data tions.
364 The Log Analyst September-October, 1989
Relative Permeability Measurement Methods

PROCEDURES ability measurements were made at the Tulsa, Oklahoma


Restoration of Native Wettability facility of Core Laboratories, Inc. After restoration, each
sample was loaded into a hydrostatic core holder and
Core plugs nominally 1.5 inches in diameter by 3.5 flushed down to S,,, with a 20 centipoise refined mineral
inches in length were cut from preserved core. To restore oil. The sample was then flushed with Isopar-L, which
native wettability, the plugs were first cleaned by cycles has a viscosity at room temperature of 1.5 centipoise.
of carbon dioxide saturated methanol, followed by carbon The Isopar-L was then miscibly displaced by a mixture
dioxide saturated toluene. Subsequent USBM wettability of Isopar-L and iododecane. The iododecane is used to
tests (Donaldson, 1981) confirmed that the core was clean attenuate X-rays during the flow tests so that saturations
and water-wet. After the plugs were cleaned, they were can be calculated. Using the Isopar-Lliododecane mix-
placed in a Hassler-type core holder, confined at approx- ture KO@ S,, was measured.
imate reservoir overburden pressure, evacuated, and then Each sample was then loaded into an aluminum Hass-
saturated with a synthetic, filtered formation brine. The ler-type core holder, between two Berea Sandstone mixing
cores were then flushed with filtered (0.22 micron) and headers, which had previously been flushed to S,, with
degassed crude oil from the reservoir. Care was taken in the Isopar-Lhododecane mixture. A mixture of oil and
obtaining the crude oil sample to ensure that nothing was synthetic formation brine was then flowed through the
added to the crude (demulsifiers, etc.), and that the crude core at various ratios (water flow rate increasing, oil flow
oil's exposure to air was minimized. rate decreasing) until finally only water was flowing through
Approximately 10 pore volumes of crude oil were the core. Flow was continued at each ratio until equilib-
flushed through the sample, driving the core plug to S,. rium was attained as determined by a constant pressure
The plugs were then submerged in crude oil in a pressure drop and X-ray scan profile. X-ray attenuation scans were
vessel with a 100 psig cap of methane. The vessel was made at each equilibrium point so that saturations could
then placed in an oven at the reservoir temperature of ultimately be determined. Effective permeabilities were
230F and allowed to age in the crude oil for 1,000 hr. calculated from Darcy's law, using the flow rates, fluid
While some researchers have shown that wettability equi- viscosities, plug dimensions, and the measured pressure
librium can sometimes be established in a shorter period drops. Corresponding fluid saturations were determined
(Cuiec et al., 1979), based on other research (Hjelmeland from the X-ray measurements.
and Larrondo, 1986) we have determined 1,000 hr of
restoration to be sufficient. After restoration, relative Unsteady-State Reservoir Condition
permeabilities were measured by three different methods. Measurements
After restoration, a sample was loaded into a hydro-
Unsteady-State Ambient Condition Measurement static core holder with a 3,400 psi overburden. With a
The unsteady-state ambient condition relative per- back pressure of 300 psi, degassed crude oil was injected
meability measurements were made at Conoco's Pro- into the sample. The system temperature was then raised
duction R&D facility in Ponca City, Oklahoma. After to 230"F, and three pore volumes of recombined reservoir
restoration, the plugs were placed in a Hassler-type core fluid were injected to displace the dead crude. The sample
holder with 2,500 psi confining pressure. Additional water was allowed to equilibrate overnight, then an additional
was displaced from the plugs by flushing them with ap- two pore volumes of reservoir fluid were injected and KO
proximately 10 pore volumes of Blandol@,a refined min- @ S,, was measured.
eral oil with a viscosity of 25 centipoise. This was done Synthetic reservoir brine was injected until a 99.9%
so that low values of S,,, comparable to field values, could water-cut was observed. Water relative permeability at
be established. The Blandola was then miscibly displaced residual oil saturation (Krw@ S0J was then measured.
with 0.8 centipoise decane. Oil permeability at irreducible During the test, water production, gas production, oil
water saturation (KO@ SwI)was then measured with dec- production, and pressure drop were monitored and un-
ane. steady-state relative permeabilities were calculated using
The plugs were then waterflooded at a constant injec- the technique of Johnson and co-workers (1959).
tion rate of 10 ml/min. During the flood, the pressure
drop across the core and the volume of decane produced RESULTS
were automatically measured. The data, consistingof water Table 2 summarizes the relative permeability results
injected, pressure drop, and decane produced, were then from the three methods.
analyzed using a modification of the technique of Johnson
and co-workers (1959). Relative Permeabilities at Low Water
Saturations
Steady-State Ambient Condition Measurement In unsteady-state relative permeability measurements
The steady-state ambient condition relative perme- no data are available between S,, and the breakthrough

September-October, 1989 The Log Analyst 365


Hawkins

Table 2: Summary of waterflood relative permeabilities. 1


~~

Oil dis-
placed .9
S,,, K,,@S,,, S,,, (YO
Sample no. (Yo PV) (md) (Yo PV) K,,, @ S,,, OOIP)
.8
Ambient condition unsteady-state >-
1 6.3 8.3 2.5 1.16 91.3 c-
A .7
2 -
4.9 6.0
- 11.2 0.80 87.5 m
6
Averages 5.6 1.2 6.9 0.98 92.4
Ambient condition steady-state I .6
w
3 6.8 9.1 19.4 0.43 19.2 W
4 7.2 7.1 21.6 0.46 16.7 a .5
5 6.9
- 6.3
- -
14.3 0.49 84.6 W
L .4
Averages 7.0 7.1 18.4 0.46 80.2 I-
Reservoir condition unsteady-state 4
w .3
6 10.0 8.3 24.9 0.37 12.3 E
7 9.0 8.5 21.0 0.48 76.9
8 10.0 9.6 24.2 0.53 73.1 .2
9 8.0 c
4.8
_ -
29.2 0.52
- 68.3
Averages 9.3 7.8 24.8 0.48 12.7 .I
n
W

Table 3: Average water saturations for first datum point.


0 .I .2 .3 .4 .5 .6 .7 .8 .9 1
~ WATER SATURATION
Average water
saturation for first Figure 2: Ambient condition unsteady-state relative perme-
Method datum point abilities with basis of K,, @ S ,,,,.
Ambient condition unsteady-state 57%
Ambient condition steady-state 29O/o 1
Reservoir condition unsteady-state 40%
.9
saturation. Likewise, in steady-state relative permeability
measurements no data are available between S,, and the .8
average saturation established for the first injection ratio c
of water and oil. Table 3 contains the average saturation 4 .7
m
at the first measurement point available for each of the
three methods. I .6
The relative permeability curves for each of the meth- [y:
W
ods are drawn in over the entire saturation range. How- a .5
ever, Table 3 shows that the relative permeability values W
are unknown at the lower saturation ranges. As a matter 1 .4
of practicality the curves are eyeballed in between S,,
and the first data point. Thus, comparisons of the curves
at the lower saturation ranges are dependent on the sub-
4 .3
w
w
jective way in which we choose to draw the curves. Before
comparing all of the results, we will first examine the .2
individual results from the three different methods.
.I
Ambient Condition Unsteady-State
Figure 2 shows the relative permeability curves for the 0
two ambient condition unsteady-state samples. The curves 0 .I .2 .3 .4 .5 .6 .7 .8 .9 1
are relative to KO@ Swi,as are all of the relative perme- WATER SATURATION
ability curves presented in this paper. The relative per- Figure 3: Ambient condition steady-state relative permeabil-
meability curves display an oil-wet character. Using ities with basis of K,, @ S,$,,.

366 The Log Analyst September-October,1989


Relative Permeability Measurement Methods

.9

.8
>-
t
1 .7
m
I .6
oi
W
a .5
w
L .4
4
w .3
oi

.2

.I
n "
"0 .I .2 .3 .4 .5 .6 .7 .8 .9 1 0 .I .2 .3 .4 .5 .6 .7 .8 .9 1
WATER SATURATION WATER SATURATION
Figure 4: Reservoir condition unsteady-state relative perme- Figure 5: Oil relative permeabilities for all three methods with
abilities with basis of KO@ S,,,,. basis of K , @ S,,,,.

Craig's (197 1) rules of thumb, the curves have very low from the relative permeability curves, is the same for all
values of S,,, the crossover point (where oil and water three methods. This indicates that the mineral oils used
relative permeabilities are equal) occurs at a water satu- in the ambient condition tests (Blandol and Isopar) did
ration less than 50%, and the curves show a high value not alter the wettability of the restored-state core. Results
of K,, Q So,. In fact, one of the curves is actually off the from all three methods will now be compared. Because
graph and goes to a value of 1.16 for K,, Q So,. there are so many curves, the oil and water curves will
be compared separately.
Ambient Condition Steady-State
Figure 3 shows the ambient condition steady-state rel- Oil Relative Permeability Curves
ative permeabilities. Again, there is some scatter in the Figure 5 shows all of the oil relative permeability curves
data, and the curves for the most part are oil-wet. Note, for all three methods. While there is some spread among
however, that the So, values are not as low, and the K,, the curves, they generally have the same shape, with dif-
Q So,values are not as high as for the ambient condition ferent values of So,.At this point, remember that these
unsteady-state measurements. are not repeat tests on the same exact piece of rock, but,
rather, rocks from the same formation that are miner-
Reservoir Condition Unsteady-State alogically similar. Therefore, the major differences among
The reservoir condition unsteady-state relative perme- the curves can probably be attributed to differences in
abilities are shown in Figure 4.There is some scatter in rock characteristics. Also, the differences in So,correlate
the data and, again, the curves appear oil-wet in nature. well with differences in test conditions, as will be ex-
Note that, like the ambient condition steady-state mea- plained later.
surements, the reservoir condition data have higher So,
values and lower K,, Q So, values than the ambient con- Water Relative Permeability Curves
dition unsteady-state curves. All of the water relative permeability curves for all three
methods are shown in Figure 6 . Again, there is some
CoMPARISoN OF ALL THREE spread in the data. The ambient condition unsteady-state
The wettability of the rocklfluid pairs, as estimated results generally give a slightly higher value of waier rel-

September-October,1989 The Log Analyst 367

I I
Hawkins

1 Table 4: Differences in experimental conditions.


Vis- Flow
.9 Viscosities (cp) :tt
Test Oil Water (p,,/pJ min.) Oil
.8
> AC USS 0.8 1.0 1.25 10.0 Decane
!= AC SS 2.0 1.0 0.50 3.3 Isopar/iododecane
=! .7 RC USS 0.725 0.27 0.37 2.0 Reservoir crude
m
a
I .6
nc Table 5: Values of Abrams number.
W
p. .5
Average
W Abrams S,,,
L
I-
.4 Method number (Yo PV)

4
w .3
Ambient condition unsteady-state
Ambient condition steady-state
250 x
47 x 10-7
6.9
18.4
nc Reservoir condition unsteady-state 7 x 10-7 24.8
.2

.1 Table 6: Approximate pore volumes injected.


Average
0 Pore volumes S,,,
0 .I .2 .3 .4 .5 .6 .7 .8 .9 1 Method injected (O/o PV)

WATER SATURATION Ambient condition unsteady-state 120 6.9


Figure 6: Water relative permeabilities for all three methods Ambient condition steady-state 40 18.4
with basis of K,, d S,,,#. Reservoir condition unsteady-state 18 24.8

ative permeability at a given saturation. The results from


the other two methods essentially overlap. ues. Therefore, the differing values of So,are due to the
Generally the curve shapes are similar for the three different experimental conditions.
methods of measurement with the main differences being Abrams (1975) published a paper where he correlated
in So,and K,, @ Sor. Differences in experimental condi- an expanded capillary number with Sor.The higher the
tions, as discussed below, have led to the different So, Abrams number, the lower the So,for a given rock. Table
values. 5 contains Abrams expanded capillary number for the
various methods.These numbers correlate with the gen-
FACTORS AFFECTING RESIDUAL eral trend in the So,values from the three methods. The
OIL SATURATION ambient condition unsteady-state tests have the largest
The factors affecting So,have been investigated and Abrams number and the lowest average So,. Correspond-
reported in the literature (Abrams, 1975). These factors ingly, the reservoir condition unsteady-state tests have
include fluid viscosities, flow rate, and interfacial tension the smallest Abrams number and the highest average So,.
(IFT). The effect these factors have are 1) the higher the Based on Abrams work we would expect only a 5-10
flow rate the lower the Sor;2) the larger the viscosity ratio saturation O/o difference in So, for this range of Abrams
(p,,,/po)the lower the So,;3) the higher the water viscosity, number. In addition to differences in Abrams number,
the lower the So,; and 4)the lower the IFT, the lower the different volumes of throughput probably help explain
So,.Table 4 summarizes the differences in experimental the rather large differences in So,.Particularly for an oil-
conditions for the three methods. wet rock like this, the final oil saturation achieved during
The flow rate for the steady-state test is the final flow a flood is largely dependent on how much water has flowed
rate when only water was being injected at the end of the through the core. Table 6 shows the approximate pore
test. The higher flow rate, larger viscosity ratio, and higher volumes of water injected during each of the three dif-
water viscosity of the ambient condition unsteady-state ferent tests.
test explain their lower So,values. The lower water vis- Due to varying test conditions there were significant
cosity and lower flow rate of the reservoir condition un- differences in the number of pore volumes injected for
steady-state tests are consistent with their higher So,val- the three different methods. The combination of the dif-

368 The Log Analyst September-October,1989


Relative Permeability Measurement Methods

1 1

.8 .8
c >.
k
-
7
m
-
-I
m
6 a
I .6 z .6
E c
W w
a a
W W
L .4 1 .4
4
w
&
4
W
gr
.2 .2

n
OO .2 .4 .6 .a 1 -0 .2 .4 .6 .8 1

ferences in Abrams numbers along with differences in relative permeability curves uses the equation (Schneider,
pore volumes injected caused the differencesin So,.While 1987)
the values of So, vary in general, the curve shapes are
very similar over most of the saturation range. Labastie
s*= ( S W - S w i )
(1 - Swz - s o r ) .
and co-workers (1 980) found a similar phenomenon while
varying flow rate in relative permeability experiments. This method starts and ends all the curves at normal-
They found that while So,changed with flow rate in gen- ized saturations of 0.0% and 100.0%, respectively. Figure
eral, curve shape remained the same. 7 shows two sets of data from each of the three mea-
surement methods, normalized with the standard meth-
SELECTION OF APPROPRIATE RESIDUAL od. Comparing Figure 7 with Figure 6 we see that this
OIL SATURATION normalization technique actually spreads the water rel-
The reservoir condition tests were selected as the best ative permeability curves farther apart. By making all of
model for field performance. These tests most closely the curves start at 0% normalized saturation we are mak-
approximate the field conditions both in terms of flow ing the assumption that they all have similar S , values,
rate and viscosity ratio and, also, the number of pore Examining Table 2, we see that this is a fairly reasonable
volumes injected. Averaging the reservoir condition re- assumption in that all the plugs had similar Sw,values.
sults we come up with an So,of 24.8%. However, forcing all the curves to end at a normalized
saturation of 100% is making the assumption that they
NORMALIZING OF THE RELATIVE all have the same So, value. Examining Table 2, again,
PERMEABILITY CURVES we see that this assumption is not valid. Because of dif-
If core plugs are of similar wettability, similar lithology, ferences in test conditions and differencesin pore volumes
and similar pore structure, and they have similar Sw,Val- injected, the different methods gave substantially different
ues, it is reasonable to expect that they would have similar So, values.
relative permeability curves. To compare the relative per- To take into account varying So,values, a new equation
meability curves on an equivalent basis, the curves need was developed for normalizing relative permeability
to be normalized. The standard method of normalizing curves. The new equation starts all the curves at a nor-

September-October, 1989 The Log Analyst 369


Hawkins

malized saturation of O.Oo/o, and extends them to a final REFERENCES


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Abrams, A. ( 1 975), The Influence of Fluid Viscosity, Inter-
facial Tension, and Flow Velocity on Residual Oil Saturation
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Figure 8 shows the curves normalized with the new Amaefule, J. 0. and Handy, L. L. (1982), The Effect of Inter-
method. Comparing Figure 7 and Figure 8, we see that facial Tensions on Relative Oil/Water Permeabilities of Con-
overall the new method gives considerably less scatter solidated Porous Media, SOC.Pet. Eng. J., v. 22, no. 3, pp.
37 1-38 I , June.
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Craig, F. F. (1 97 l), The Reservoir Engineering Aspects of Wa-
variation in So,,we have found the new method a superior terflooding, Society of Petroleum Engineers Monograph Se-
way of normalizing relative permeability curves, resulting ries, No. 3, Dallas, Texas.
in less scatter. Cuiec, L. E. (19 7 9 , Restoration of the Natural State of Core
Samples, SPE 5634, presented at the 50th Annual Fall Meet-
ing of the SPE, Dallas, Texas, 28 September-1 October.
CONCLUSIONS ( 1 977), Study of Problems Related to the Restoration
1. The shapes of the relative permeability curves were of the Natural State of Core Samples, J. Can. Pet. Tech., v.
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, Longeron, D., and Pacsirzky, J. ( I 979), On the Ne-
2. Because of variations in test conditions the three meth-
cessity of Respecting Reservoir Conditions in Laboratory Dis-
ods gave different values of Sorand K,., @ So,, dem- placement Studies, SPE 7785, presented at the SPE Middle
onstrating the importance of measuring these param- East Oil Technical Conference, Bahrain, 25-29 March.
eters at reservoir conditions. Donaldson, E. C. (198 l), Oil-Water-Rock Wettability Mea-
3 . A new method of normalizing relative permeability surement, Proc. American Chemical Society, Division of Pe-
curves has been introduced that takes into account the troleum Chemistry, v. 26, no. l , pp. 110-122, 29 March-3
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test conditions. Edmonson, T. A. (1 965), Effect ofTemperature on Waterflood-
4. The mineral oils used in the experiments did not alter ing, J. Can. Pet. Tech., no. 11 1, pp. 236-242, October-
the wettability of the restored-state core. December.
Gant, P. L. and Anderson, W. G. (1986), Core Cleaning for
This study was not a detailed parametric study conducted Restoration of Native Wettability, SPE 14875, presented at
on many combinations of rock and fluid; thus, the con- the SPE Rocky Mountain Regional Meeting, Billings, Mon-
clusions of this study are not universally applicable. How- tana, 18-21 May.
ever, the conclusions are probably applicable for reser- Honarpour, M., Koederitz, L., and Harvey, A. H. (1986), How
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1 1 1, pp. 116-126, May.
Hjelmeland, 0. S. and Larrondo, L. E. (1986), Experimental
ACKNOWLEDGEMENTS Investigation of the Effects of Temperature, Pressure, and
Crude Oil Composition on Interfacial Properties, SPE Res-
I am grateful to Ken Weissenburger, Jeff Meyers, and AndrC ervoir Engineering, v. 1, pp. 321-328, July.
Bouchard for their review of the manuscript. I also thank the
Johnson, E. F., Bossler, D. P., and Naumann, V. 0. (1959),
management ofConoco Inc. for permission to publish the paper.
Calculations of Relative Permeability from Displacement
Experiments, Trans. AZME, v. 2, pp. 216, 370.
NOMENCLATURE Josendal, V. A., Sandford, B. B., and Wilson, J. W. (1952),
Improved Multiphase Flow Studies Employing Radioactive
KC] @ Swi = Oil permeability at irreducible water satu- Tracers, Trans. AIME, v. 195, 65, p. 195.
ration, millidarcies.
Labastie, A., Guy, M., Delclaud, J. P., and Iffly, R. (1980),
Ki-w @ So, = Water relative permeability at residual oil Effect of Flow Rate and Wettability on Water-Oil Relative
saturation. Permeabilities and Capillary Pressure, SPE 9236, presented
So, = Residual oil saturation, Yo pore volume. at the Fall Technical Conference, Dallas, 2 1-24 September.
sw, = Irreducible water saturation, O/o pore vol- Levine, J. S. (1 954), Displacement Experiments in a Consol-
ume. idated Porous System, Trans. AIME, v. 201, p. 57.
sw = Normalized water saturation. Miller, M. A., and Ramey, J. J., Jr. (1985), Effect ofTemper-
ACUSS = Ambient condition unsteady-state. ature on Oil/Water Relative Permeabilities of Unconsolidat-
ACSS = Ambient condition steady-state. ed Sands, SPEJ, AIME, v. 25, p. 279, December.
RCUSS = Reservoir condition unsteady-state. Patel, P. D., Christman, P. G., and Gardner, J. W. (1985), An
Po = Oil viscosity, centipoise. Investigation of Unexpectedly Low Field-Observed Fluid
P W = Water viscosity, centipoise. Mobilities During Some CO, Tertiary Floods, SPE 14308,

370 The Log Analyst September-October, 1989


Relative Permeability Measurement Methods

presented at the SPE 60th Annual Technical Conference and


Exhibition of the SPE, Las Vegas, Nevada, 22-25 September.
Richardson, J. G., Perkins, F. M., and Osoba, J. S. (1955),
Differences in the Behavior of Fresh and Aged East Texas
Woodbine Cores, J. Pet. Tech., v. 7 ,pp. 86-9 1; Trans. AZME,
June.
Schneider, F. N. (1 987), Three Procedures Enhance Relative
Permeability Data, Oil and Gas Journal, v. 85, no. 18, pp.
45-5 1. 4 May.
Sharma, M. M. and Wunderlich, R. W. (1 987), The Alteration
of Rock Properties Due to Interactions with Drilling-Fluid
Components, J. Pet. Sci.Eng., no. 1, pp. 127-143.
Treiber, L. E., Archer, D. L., and Owens, W. W. (1972), A
Laboratory Evaluation of the Wettability of Fifty Oil Pro-
ducing Reservoirs, SPEJ, pp. 531-540; Trans. AZME, v.
253, p. 531, December.
Wendel, D. J., Anderson, W. G., and Meyers, J. D. (1985),
Restored-State Core Analysis for the Hutton Reservoir, ABOUT THE AUTHOR
SPE 14298, presented at the 60th Annual Technical Confer-
ence of the SPE, Las Vegas, Nevada, 22-25 September. Jeff Hawkins is a Research Engineer at Conocos Pro-
Yan, J. N., Menezes, J. L., and Sharma, M. M. (1988), Wetta- duction Research facility where he conducts research in
bility Alteration Due to Interaction with Oil-Based Mud the area of special core analysis. He earned his B.S. in
Components, SPE 18162, in Proc. SPE. Ann. Tech. Conf. Chemical Engineering from the University of Nebraska
and Exhib. v. Omega, pp. 557-570. and his M.S. in Petroleum Engineering from the Uni-
versity of Houston. Previously, he conducted research
and patented methods for improving sweep efficiency in
steamfloods and miscible floods. He is a member of the
SPE and the Society of Core Analysts.

September-October, 1989 The Log Analyst 371

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