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Organic Electronics for a Better Tomorrow:

Innovation, Accessibility, Sustainability

A White Paper from the Chemical Sciences and Society Summit (CS3)

San Francisco, California, United States

September 2012
Table of Contents

About the Chemical Sciences and Society Summit (CS3) ........................................................ 2


Foreword: Letter from the 2012 CS3 Chairs ................................................................................ 3
Executive Summary ............................................................................................................................... 4
Introduction .............................................................................................................................................. 7
Organic Electronics Today …………………………………………………………………………………10
Organic Electronics: The Vision for Tomorrow ....................................................................... 14
Research Pathway to the Future .................................................................................................... 20
Conclusion .............................................................................................................................................. 26
References .............................................................................................................................................. 27
2012 CS3 Participants ........................................................................................................................ 31

Organic Electronics for a Better Tomorrow / 1


ABOUT THE CHEMICAL
SCIENCES AND SOCIETY
SUMMIT (CS3)

The annual Chemical Sciences and societal needs. This white paper presents
Society Summit (CS3) brings together an international view on how the use of
some of the best minds in chemical organic materials in electronic devices
research from around the world and can contribute positively to creating a
challenge them to propose innovative more innovative, accessible, and
solutions to society’s most pressing sustainable electronic world.
needs in health, food, energy, and the The CS3 initiative is a
environment. This unique gathering collaboration between the Chinese
boasts an innovative format, aiming to Chemical Society (CCS), German
set the course of international science, Chemical Society (GDCh), Chemical
and rotates each year among Society of Japan (CSJ), Royal Society of
participating nations. Chemistry (RSC), and American
Organic Electronics for a Better Chemical Society (ACS). The annual
Tomorrow: Innovation, Accessibility, symposia are supported by the National
Sustainability summarizes the outcomes Natural Science Foundation of China
of the fourth annual 2012 CS3, which (NSFC), German Research Foundation
focused on organic electronics. Thirty (DFG), Japan Society for the Promotion
top chemists and other scientists from of Science (JSPS), UK Engineering and
China, Germany, Japan, the United Physical Sciences Research Council
States, and the United Kingdom (EPSRC), and U.S. National Science
assembled in San Francisco to identify Foundation (NSF).
major scientific and technological This white paper was prepared
research challenges that must be by science writer Leslie A. Pray, PhD, in
addressed to advance the field of organic consultation with the American
electronics in a way that best meets Chemical Society, and reviewed by 2012
CS3 participants.

Organic Electronics for a Better Tomorrow / 2


FOREWORD: LETTER FROM THE organic electronics and to offer research
2012 CS3 DELEGATION CHAIRS recommendations for advancing the field
in a way that will maximize its potential
We live in an electronic world. positive impact on society.
Economic, health, and national security Our hope is that our research
rely on and are positively impacted by recommendations will be recognized and
electronic technology. However, the considered by science policy-makers
resources and methodologies used to worldwide – not just in the field of
manufacture electronic devices raise chemistry, but also in the broad range of
urgent questions about the negative other scientific and engineering
environmental impacts of the disciplines that impact organic
manufacture, use, and disposal of electronics research and development.
electronic devices. The use of organic While chemists play a vitally important
materials to build electronic devices may role in synthesizing and transforming the
offer a more eco-friendly -- and organic “building block” materials that
affordable -- approach to growing our make organic electronics possible, our
electronic world. Moreover, and some vision for the future will not be realized
would say more importantly, organic without the cooperation of physicists and
small molecules, polymers, and other other scientists and engineers from
materials afford electronic structures across academia and industry.
unique properties impossible to obtain
with silicon alone, creating untold
potential for novel functionality.
However, the field of organic Xi Zhang
electronics is in its infancy with respect Chair, China Delegation
to devices on the market. Realizing the
vision of organic electronics as a more Peter Bäuerle
innovative, accessible, and sustainable Chair, Germany Delegation
approach to growing our electronic
world will require overcoming key Takuzo Aida
research challenges. Chair, Japan Delegation
Chemists, physicists, and other
scientists and engineers engaged in Peter Skabara
organic electronics research representing Chair, United Kingdom Delegation
China, Germany, Japan, the United
Kingdom and the United States gathered Cherie Kagan
in San Francisco in September of 2012 Chair, United States Delegation
to discuss their visions for the future of

Organic Electronics for a Better Tomorrow / 3


EXECUTIVE SUMMARY

Chemists, physicists, and other scientists Potential applications of organic


and engineers are synthesizing and electronics span a broad range of fields,
manipulating a wealth of new organic including medicine and biomedical
materials in ways that will change the research, environmental health,
way society interacts with technology. information and communications, and
These new materials create novel national security.
properties impossible to replicate with Because of the lower cost and
silicon, expanding the world of higher throughput manufacture of
electronics in ways unimaginable until organic-based electronic devices,
now. Organic Electronics for a Better compared to today’s silicon-based
Tomorrow: Innovation, Accessibility, devices, organic electronics also promise
Sustainability examines where organic to expand the use of electronic
electronics are today, where chemical technology in resource-limited areas of
scientists envision the field is heading, the world where supplies are limited or
and the scientific and engineering the necessary infrastructure is lacking.
challenges that must be met in order to Already, organic solar cells are being
realize that vision. installed on rooftops in African villages
Already, consumers are using that lack access to standard on-grid
organic electronic devices, such as smart electricity, providing rural populations
phones built with organic light emitting with a safer and cheaper alternative to
diode (OLED) displays, often without kerosene.
even being aware of the organic nature Not only do organic materials
of the electronic technology in hand. The promise more innovative and accessible
Samsung Galaxy line of OLED-based electronic technologies, they also
smartphones occupies a major share of promise more sustainable electronic
the global smartphone market. technologies. The potential for greater
Potential future applications are sustainability extends across the entire
enormous and untold. Organic materials life cycle of electronics, beginning with
are being studied and developed for their the use of materials that are synthesized,
potential to build devices with a rather than mined from the earth, and
flexibility, stretchability and softness ending with potentially biodegradable or
(“soft electronics”) not afforded by recyclable devices. It is not just the
silicon or any other inorganic materials – devices themselves that promise to be
that is, electronic devices that bend, more eco-friendly than silicon-based
twist, and conform to any surface. electronics, but also their manufacture.
Imagine a smartphone that folds like a Today, the major focus of
map. Devices made with organic research and development in organic
materials also have the potential to electronic is on three main types of
interface with biological systems in existing applications: displays and
ways not possible with inorganic lighting, transistors, and solar cells. The
materials. Imagine an artificial skin with vision for the future is to move beyond
a tactile sensitivity approximating real these already existing applications and
skin that can be used to treat burns or explore new realms of electronic use.
add functionality to prosthetic limbs. The intention is not that organic

Organic Electronics for a Better Tomorrow / 3


electronics, or any specific type of the formation of many materials being a
organic electronics, will replace silicon- major problem. Until wide-scale
based electronics. Indeed, organic industry-level production is achieved,
molecules and materials are often used future visions for organic electronics
in combination with silicon materials. will remain just that – visions.
Rather, the vision for the future is one of CS3 participants identified four
an expanded electronic landscape – one major scientific and technology research
filled with new materials that make challenges that must be addressed in
electronics more functional, accessible, order to achieve high yield and
and sustainable. uniformity.
The 2012 CS3 participants
articulated three visions for the future of 1. Improve controlled self-
organic electronics: assembly. Chemists need to gain
better control over the self-
1. Organic electronic devices will assembly of organic electronic
do things that silicon-based molecules into ordered patterns
electronics cannot do, to ensure that the structures being
expanding the functionality and assembled are reproducible.
accessibility of electronics. Improved controlled self-
2. Organic electronic devices will assembly requires a better
be more energy-efficient and understanding of the electronic
otherwise “eco-friendly” than properties of organic materials,
today’s electronics, contributing especially when those materials
to a more sustainable electronic are in contact with other
world. materials (i.e., their interfacial
3. Organic electronic devices will behavior). Only with that
be manufactured using more knowledge will researchers be
resource-friendly and energy- able to predict how organic
efficient processes than today’s electronic materials actually
methods, further contributing to perform when integrated into
a more sustainable electronic devices, and only with those
world. predictions will engineers be able
to develop industry-scale
Arguably the greatest overarching synthetic processes.
challenge to realizing these visions is
creating electronic structures at industry- 2. Develop better analytical tools.
level scale with high yield and Better analytical tools are needed
uniformity. This is true regardless of to detect and measure what is
type of material or application. While happening with respect to
the electronics industry has already structure and chemical
achieved enormous success with some composition when organic
organic electronic structures, such as materials are assembled and
those being used to build OLED-based integrated into electronic
smartphones, most organic electronic structures and devices, ideally at
structures are being synthesized on only every step along the way. These
very small scales, with reproducibility in

Organic Electronics for a Better Tomorrow / 5


tools need to be non-destructive,
non-invasive, and high-speed. While chemical scientists have been
critical drivers of organic electronics and
3. Improve three-dimensional (3D) will continue to serve an essential role in
processing technology. Many expanding the landscape of organic
organic electronic structures can electronics, other areas of scientific and
be assembled on flexible engineering research are equally
substrates using existing printing essential. Chemists, physicists, material
technologies. However, scientists and other scientists and
fabrication of 3D organic engineers must combine their expertise
electronic structures with the and work together to realize the full
same precision achievable with potential of organic electronics.
two dimensional (2D) printing Multidisciplinary research and training
technology remains a major programs that bring together scientists
challenge to reliable high- and engineers from different fields of
throughput manufacturing of knowledge, as well as from different
organic electronic devices. sectors of activity (i.e., academia,
industry, government), will facilitate the
4. Increase multi-functionality of collaborative effort needed to meet these
organic electronic devices. As scientific and technological challenges
chemists gain better control over
the synthesis of organic
materials, they and their
engineering collaborators will be
able to build increasingly
sophisticated optoelectronic1 and
other devices with multiple
functions. However, in order to
fully realize the multifunctional
capacity of organic chemistry,
chemists need to broaden their
research focus beyond “charge-
carrier” transport (i.e., electrons
and holes, respectively) and gain
a better understanding of optical,
magnetic, thermal and other
properties.

1
An optoelectronic device is an
electronic device that produces or
interacts with light. Organic
optoelectronic devices already in the
marketplace include organic light-
emitting diodes (OLEDs) and organic
solar cells.

Organic Electronics for a Better Tomorrow / 6


INTRODUCTION

We live in an increasingly electronic replicate with silicon. These materials


world, with computers occupying a hold tremendous promise to expand our
central part of our lives. In 2012, there electronic landscape in ways that will
were an estimated 30-40 processors per radically change the way society
person, on average, with some interacts with technology. Organic
individuals surrounded by as many as Electronics for a Better Tomorrow:
1000 processors on a daily basis. While Innovation, Accessibility, Sustainability
silicon electronics has solved many of examines where organic electronics are
the challenges associated with our today, where chemical scientists
increased use of electronics, there are envision the field is heading, and the
limits to what silicon can do. Chemists scientific and engineering challenges
are synthesizing a wealth of new organic that must be met in order to realize that
materials for use in electronic devices vision.
that create novel properties impossible to

Figure 1. From silicon to carbon. Silicon (S) and carbon (C) may be in the same family
on the periodic table, but the properties they confer on electronic structures are anything
but similar. Source: Jin Zhang.

Organic Electronics for a Better Tomorrow / 7


Our Electronic World

While Moore’s prediction that the number of transistors per chip would double every 18
months has more or less borne true, many scientists and engineers speculate that such
growth is not indefinite and that a limit will be reached. While the miniaturization of
silicon-based electronic structures has created an electronic world full of affordable, high-
performing devices, still there are things that silicon-based electronics cannot do and will
never be able to do. Organic materials, whether used in combination with silicon or not,
hold the potential to expand our electronic world in ways unimaginable when Moore made
his prediction some forty years ago.

Organic Materials for Electronics: A Polymer electronic materials in


Primer particular are one of the most active
areas of organic electronic research, so
Chemical scientists work with several much so that polymer-based organic
different types of organic materials in electronic devices (and device
their research on electronics. These prototypes) have significantly improved
materials include small molecules2 and in performance over the past decade. For
polymers; fullerenes, nanotubes, example, power conversion efficiencies
graphene, and other carbon-based (PCEs) of organic photovoltaics (OPVs)
molecular structures; ensembles of have increased from 5 percent in 2005 to
molecules and molecular structures; and > 10 percent in 2012. This increased
hybrid materials. They use these performance is being driven by newly
materials to build electronic structures developed polymers with improved solar
and then integrate those structures into light absorption properties and superior
electronic devices. Many of these mobilities. For organic transistor
devices are early-stage prototypes, with devices, charge-carrier mobilities3 have
major scientific and engineering increased from less than 0.01 centimeter
challenges still to be surmounted before squared per Volt-second (cm2/Vs) in
the prototypes can become real-world 2000 to greater than 1.0-3.0 cm2/Vs in
products. But others are already 2010. Some high-performance polymers
commercial realities, some being used exhibit as great as 5.0-10.0 cm2/Vs
on a widespread basis. For example, mobility. Increasing charge-carrier
both small molecules and polymers are mobility and thereby improving device
being used in the manufacture of OLED performance even further poses one of
displays (e.g., TV and cell phone the greatest challenges to the field of
displays), solar cells, and transistors. polymer electronics. An additional
concern is that most reported charge-
2 “Small molecule” is used in this White
Paper in reference to organic molecules 3“Charge-carrier” mobilities
that are smaller than polymers, that is, characterize how quickly charged
both monomers and oligomers. particles move through a semiconductor.

Organic Electronics for a Better Tomorrow / 8


carrier mobility values are for isolated and other flexible devices. But they are
and optimized systems and that mobility also being investigated for their charge
decreases when such systems are storage potential, conducting ink
integrated into actual devices. capacity (e.g., graphene-based inks are
Carbon-based materials hold being investigated for their use in
tremendous promise for the field of security packaging such that tampering
organic electronics because carbon breaks the printed circuit, sounding an
comes in so many different forms, with a alarm), and other applications. Multi-
wealth of chemistries associated with walled carbon nanotubes are being
those different forms. Fullerenes were produced on a large scale (e.g.,
the first carbon nanostructures produced, Hyosung, Inc., South Korea, produces
in 1990. Carbon nanotubes were more than one ton daily) and being used
produced shortly thereafter and then, in as electrically conductive plastic parts in
2004, graphene was isolated. Carbon- ATM machines and other devices. But
based materials are being researched and single-walled carbon nanotube
developed mostly to create bendable, or production has yet to be scaled up to an
rollable, electronic displays, solar cells, industrial level.

Figure 2. Improved electronic performance in devices made with organic polymer


materials, 2000-present. Top: Continued research on polymer materials has led to a
steady increase in charge-carrier mobilities in organic field effect transistors (OFETs)
(top) and increased photoconversion efficiencies (PCEs) for organic solar cells (bottom).
Source: Lixiang Wang.

Organic Electronics for a Better Tomorrow / 9


Single Molecule Organic Electronics: Illusion or Insight?

The field of single molecule organic electronics has made great strides since the world’s
first single-molecule organic electric device, the molecular rectifier, was envisioned in the
mid-1970s. Researchers have learned how to alter structures of single molecules in ways
that change conductance and other electronic properties. However, they still face daunting
challenges to integrating those structures into macroscopic circuitries and into actual
usable devices. The field is still occupied largely by academic researchers, with some
scientists speculating that the notion of single-molecule electronics is but an illusion. Or at
least the notion of a single-molecule computer is but an illusion. There are other potential
applications. Because single molecule devices involve constricting all electrical current to
flow through a single molecule such that anything perturbing the molecule is sensed by
the device, single molecule devices could make for fantastically sensitive sensors. At the
very least, while no single molecule electronic device has yet become a commercial
reality, research in the field has yielded a wealth of new knowledge about the chemistry of
organic electronics. By shrinking electronic systems down to a single molecule, chemical
scientists are learning about charge movement through molecules, molecule-electrode
interfacial activity, and other phenomena that help to understand how organic molecules
function as electronic device components.

ORGANIC ELECTRONICS TODAY

Organic electronics is not a new field. electroluminescence and therefore they


Electronic devices made with organic do not require backlights. They require
materials already have multiple less power and are more energy-efficient
applications and have been widely than backlight-dependent display
commercialized, mostly in display (e.g., technology.
smart phone displays), photovoltaic, and OLEDs are already widely
transistor technologies. commercialized in many Samsung and
other smartphone models. The Samsung
Organic Display Technology Galaxy line of OLED-based
smartphones occupies a significant
Organic light-emitting diodes (OLEDs) portion of the global smartphone market.
are built from one or more layers of Additionally, Samsung and LG
organic and hybrid material (either small Electronics have both announced
molecules or polymers) sandwiched forthcoming launches of large-screen
between two electrodes (e.g., indium tin OLED TVs. The new TVs are expected
oxide), all on a plastic or other substrate. to not only be more spectacular than
Unlike other display technologies, which today’s TV technology, with respect to
require a backlight in order for the crisper colors and sharper contrasts, but
display to show, OLEDs generate their also lighter, thinner, and more energy-
own light via efficient.

Organic Electronics for a Better Tomorrow / 10


Figure 3. Building better OLED displays. Left: Samsung has announced the near-future
release of a foldable smartphone built with a flexible plastic OLED display; the phone can
be folded to an eighth of its size. Source: Josh Miller/CNET. Right: Both Samsung and
LG Electronics have announced near-future releases of 55-inch, 4-mm thick OLED
display TVs. Source: LG Electronics.

Organic Photovoltaics (OPVs) occur at these various interfaces,


engineers will be able to build interfacial
Organic photovoltaics (OPVs), or structures that drive energy conversion
organic solar cells, are generally viewed even more efficiently than today’s
as one of most exciting near-future devices do. While current OPV
applications of organic electronics, not technology boasts conversion
necessarily as a replacement for silicon- efficiencies that exceed 10 percent,
based PVs, rather because of unique reaching even 12 percent, some
ways that OPVs can be used due to their researchers predict organic solar cells
flexibility, large-area coverage, and low will reach 15-20 percent efficiency.
cost. However, a key challenge to
expanding solar cell production is Transistor Technology
industry-scale reproducibility.
The harvesting of solar energy Transistors are considered a fundamental
relies on chemical and physical “building block” of modern electronic
interactions at the interfaces between devices, either amplifying signals or
materials that harvest the light and operating as on-off switches. There are
materials that transport electrical current. many different types of transistors. Most
These interfaces can be either organic- organic transistors are organic field-
organic or organic-inorganic. As effect transistors (OFETs). OFETs have
chemical scientists gain a better several unique properties not shared by
understanding of the processes that silicon transistors, most notably their

Organic Electronics for a Better Tomorrow / 11


flexibility. Because OFETs can be using simple and relatively inexpensive
manufactured at or near room techniques, such as solution processing.
temperature, they enable the By 2020, with the synthesis of even
manufacture of integrated circuits on more advanced materials, mobilities
plastic or other flexible substrates that could increase to as much as 100
would otherwise not withstand the high- cm2/Vs. As with small-molecule OFETs,
temperature conditions of silicon-based polymer OFETs have also increased in
device manufacture. OFETs are also performance, with typical mobilities
highly sensitive to specific biological increasing from about 0.01 cm2/Vs in
and chemical agents, making them 2000 to greater than 1.0-3.0 cm2/Vs in
excellent candidates for biomedical 2010.
sensors and other devices that interface Despite this progress, several
with biological systems. challenges remain before OFETs will
With the synthesis of new become a widespread commercial
organic materials, chemists have reality. For example, only recently have
improved charge-carrier mobilities for scientists demonstrated the fabrication of
small-molecule OFETs from < 1 cm2/Vs thermally stable flexible OFETs. High
in 2000 to 8-11 cm2/Vs today. Initially, thermal stability is prerequisite to
the improved mobilities were obtained integrating OFETs into biomedical
only under very clean conditions in devices; otherwise they won’t survive
ultrahigh vacuum chambers. However, high-heat sterilization.
recent results suggest that high-
performance OFETS can be fabricated

From Chemist to Consumer: OLED Displays

The touch-screen display on the Galaxy S series of smartphones manufactured by


Samsung Electronics is testament to the tremendous progress already achieved in the field
of organic electronics. Most other smartphones, as well as computers, tablets, high
definition television sets and other similar devices, use liquid crystal display (LCD)
technology, an organic-inorganic hybrid electronic technology that requires a backlight to
produce the image displayed on the screen. But the Galaxy S uses a technology that
doesn’t require a backlight: organic light-emitting diode (OLED) display technology.
OLEDs emit their own colored light to produce images. Because they do not need
backlights, OLED displays are thinner and lighter than LCD displays. They have other
potential advantages as well, including flexibility, with efforts underway to develop and
commercialize foldable OLED display smartphones and other devices. Other similar
devices are emerging in the marketplace. For example, the PlayStation (PS) Vita, a
handheld game console, boasts a 5-inch touchscreen OLED display.
These and other future OLED devices exemplify how fundamental research in
organic chemistry, including the chemical synthesis of new organic materials and the
characterization of those materials, can evolve into mass production of a novel
technology. To advance the technology even further, chemists, physicists, and other
scientists are collaborating to develop yet more advanced organic materials with even
better electronic and other properties. Researchers predict that OLED lighting technology,
including large-area (white) lighting, will become a commercial reality within the next
five years.

Organic Electronics for a Better Tomorrow / 12


Organic Chemists Outsmart Counterfeiters

Organic thin-film transistors (OTFTs) create a wealth of innovative opportunities for


electronic applications. For example, scientists are fabricating OTFTs on banknote
surfaces as an anti-counterfeiting feature. Not only are OTFTs thinner than even the
thinnest silicon-based transistors (less than 250 nanometers [nm], compared to 20
micrometers [µm]), making it possible to embed them into the banknote paper, they also
operate at a low enough voltage (about 3 volts [V]) that they do not cause any damage to
the paper. Most importantly, because they are made with organic materials, the OTFTs are
flexible enough that they can withstand repeated crumpling, creasing, and sharp folding.
OTFTs on banknotes exemplify how research on organic materials, in this case
with German and Japanese chemists collaborating on the use of very thin polymer
substrates as the starting material for fabrication of the OTFTs, can eventually lead to
development of a novel device otherwise impossible to build with silicon-based electronic
structures. Flexible organic thin-film transistors are also being studied and developed for
their potential applications in a wide range of other types of bendable devices, such as
rollable solar cells.

Figure 4. OTFTs make for good anti-counterfeiting features in banknotes. Left:


Polymer substrate with functional OTFTs wrapped around a cylinder with a radius of 300
µm. Source: Sekitani et al. 2010. Right: Banknote with OTFTs embedded as a
counterfeiting feature. Source: Zschieschang et al. 2011.

Organic Electronics for a Better Tomorrow / 13


ORGANIC ELECTRONICS: THE electronics cannot do, expanding the
VISION FOR TOMORROW functionality and accessibility of
electronics.
As chemists continue to synthesize and
functionalize new and improved organic Organic materials give electronic
materials for use in electronic structures devices unique properties impossible to
and devices, the field of organic achieve with silicon-based electronic
electronics will likely expand in ways structures, enabling a broad range of
not even imaginable today. Some innovative “out-of-the-box”
applications have already been realized, applications. These properties include
like the OLED smartphones and the low- sensing, biocompatibility, and flexibility.
cost solar cells being installed on Because of the unique structural
rooftops in rural off-grid communities in and functional variation of organic
South Sudan. Some, like the ultra-thin materials, arguably one of the greatest
OLED TVs and foldable smartphones, areas for innovation in the field of
are expected to be launched in the near organic electronics is in sensing -- that
future. Others, like electronic skin that is, the use of electronic devices to sense
mimics human skin with its tactile chemical or biological substances in the
sensitivity, will take longer. Still others environment, in or on the human body,
cannot be foreseen. The potential future in food and water, or elsewhere. For
applications are many and varied, example, chemical scientists envision
spanning across multiple fields: diagnostic sensors that detect changes in
medicine and biomedical research, biomarker levels (e.g., changes in
energy and the environment, national glucose levels in people with diabetes);
security, communications and environmental sensors that detect toxins
entertainment, home and office in food or water; and national security
furnishings, clothing and personal sensors that detect trinitrotoluene (TNT)
accessories, and more. or other explosives. Biosensors are
Not only will the field of organic among the most exciting near-future
electronics yield innovative applications applications of organic electronics. As
not even imaginable today, it also has just one example, chemical scientists
the potential to make electronics envision biosensors that not only detect
production, use, and disposal more glucose levels in people with diabetes,
environmentally sustainable. Chemists but also actually dispense the
and their colleagues are seeking ways to appropriate dose of insulin at the right
make organic electronics – both the time.
devices themselves and the manufacture Not only are organic electronic
of those devices – more resource- structures more chemically compatible
conservative and energy-efficient than with biological systems than silicon-
today’s silicon-based electronic world. based devices are, they also enable a
CS3 participants identified three flexibility, stretchability and mechanical
overarching visions for the future of “softness” not possible with silicon.
organic electronic materials: Together, these properties create the
potential for innovative bio-electronic
Vision #1: Organic electronic devices sensors that can conform to the curvature
will do things that silicon-based and moving parts of the human body.

Organic Electronics for a Better Tomorrow / 14


Flexible organic thin-film transistors makes them mechanically compliant not
(OTFTs) are being used to develop just with biological systems, but also
electronic skins with tactile sensitivity with a wide range of other types of
and other sensing capabilities. The hope curved surfaces and movable parts.
is that this technology will be used to Scientists envision flexible displays,
build artificial skin for burn patients, solar cells, sensors, and batteries with
prosthetics with tactile capabilities, and applications in automobiles, clothes and
other touch-sensitive devices impossible other fabrics, and machinery. As just one
to build with silicon-based electronic example, the Smart Forvision Concept
structures. In the very distant future, Car has been proposed as a futuristic car
some scientists wonder whether such that would boast, among many other
“robotic skin” might even be capable of weight and energy-saving features, a
detecting emotional states. transparent organic solar cell roof for
The flexible (“soft”) nature of fueling the car’s climate control system
carbon-based and other organic materials and OLED lighting.

Figure 5. Flexible organic semiconductors. Circuits fabricated on a flexible and


transparent organic substrate. Flexibility is an important advantage of organic materials.
Source: Sun et al. 2011.

Organic Electronics for a Better Tomorrow / 15


Figure 6. Using organic materials to create artificial skin. Scientists are using organic
field-effect transistor (OFET) architecture to build electronic material that mimics human
skin. The electronic skin is a stretchable two-dimensional (2D) array of tactile sensors that
collect environmental signals and translate those signals into information. Source:
Sokolov et al. 2012.

Vision #2: Organic electronic devices Northern Europe where long spells of
will be more energy-efficient and sunlight are but a dream.
otherwise “eco-friendly” than today’s As with organic solar cells,
electronics, contributing to a more chemical scientists and engineers hope
sustainable electronic world. to improve the energy efficiency of
organic transistors as well, in the case of
As chemical scientists and engineers OFETs by lowering their operating
continue to improve the synthesis and voltages. Lowering OFET operating
characterization of organic materials for voltages is more than an energy
use in electronics, their hope is that the efficiency goal. It will also allow
use of such materials will lead to more chemists to take advantage of the
energy-efficient electronic displays and biocompatibility of OFETs; high-voltage
lights, solar cells, transistors, and other FETs generate fatal levels of heat.
electronic devices. For example, while In addition to increasing energy
organic solar cells are already very efficiency, as chemists continue to study
energy efficient, with an energy and improve their understanding of the
“payback” time of less than six months, electronic behavior of organic materials,
their energy efficiency needs to continue engineers will be able to build devices
to improve in order to succeed as a that last longer and that are recyclable or
widespread technology in places like perhaps even biodegradable.

Organic Electronics for a Better Tomorrow / 16


Off-the-Grid Organic Electronics: Making Electronics More Accessible

While we live in an increasingly electronic world, access to that world is limited. An


estimated 1.3 billion people have no access to electricity, with many people relying on
kerosene, batteries, or diesel-fueled generators. Because of their cheaper manufacturing
costs, organic electronics promise not only to change the way people use technology, but
also to expand the use of technology to populations without access to on-grid electricity.
For example, in 2011, Eight19, a Cambridge, UK-based company dedicated to the
development and manufacture of organic solar cells, launched a program called Indigo to
provide off-the-grid solar-powered energy to rural markets. The pay-as-you-go program
eliminates the high initial purchase cost of solar power systems (customers pay for the
system with scratch cards on a week-by-week basis until they own the product outright),
costs less than kerosene (after the customer has paid for the product, usage is free), and is
environmentally safer than kerosene (kerosene emits poisonous fumes). The technology
being used in the Indigo program -- indeed all organic solar cell technologies -- would not
be possible without ongoing work by organic chemists to synthesize and functionalize
new materials.

Vision #3: Organic electronic devices which involves removing materials and
will be manufactured using more disposing of those excess materials. In
resource-friendly and energy-efficient addition to using fewer materials,
processes than today’s methods, further chemists are seeking ways to use safer
contributing to a more sustainable materials. For example, many polymers
electronic world. require carcinogenic solvents, including
some solvents not even allowed in the
The use of organic materials to build EU printing industry because of their
electronic devices holds the promise that toxicity. Chemists are hoping to design
future electronic manufacturing methods polymers that are soluble in non-toxic
will rely on fewer, safer, and more solvents and that rely on more benign
abundant raw materials. The vision is for methodologies in general. Finally, the
resource-efficient synthetic resource-friendly vision is for reliance
methodologies, whereby both the on more abundant starting materials,
devices themselves and the thereby conserving precious and
manufacturing of those devices use less endangered resources. For example,
material than today’s silicon-based graphene is being investigated as a
electronic methodologies require. For replacement for indium tin oxide (ITO),
example, materials can be saved by as indium is considered a limited
relying on less wasteful processes, such resource.
as printing, whereby materials are added In addition to becoming more
to structures or devices layer by layer as resource-friendly, organic electronic
they are built, in contrast to spin-coating manufacturing methods will also become

Organic Electronics for a Better Tomorrow / 17


more energy-efficient as materials and intensive, with the scale of production
process engineers continue to learn and being too small to invest in the
improve methodologies for synthesizing infrastructure necessary for recovering
organic materials and assembling lost heat. As the manufacture of carbon-
electronic structures. The vision is for based electronics expands in scale and
manufacturing processes with fewer the volume of material being processed
steps and with methods for recovering increases, the hope is that process and
lost heat. Currently, both carbon materials engineers will develop ways to
nanotube and graphene synthesis build the infrastructure needed to
methodologies are highly energy- reclaim heat.

Figure 7. Accessible electronics. Pay-as-you-go organic solar cell technology is being


distributed throughout rural areas of southern Africa and elsewhere, providing a low-cost
and safe alternative to kerosene. Source: Eight19.

Organic Electronics for a Better Tomorrow / 18


Sustainable Electronics

What is “sustainable electronics”? And how can organic electronics help to make
electronics more sustainable? The meaning of sustainability is open to interpretation. The
2012 CS3 participants considered several different definitions of sustainable electronics.
Environmental sustainability. For most people, mention of “sustainable
electronics” brings to mind images and concerns about energy efficiency, resource use,
and waste disposal or recycling – that is, building an electronic world that enables
sustainable management of natural resources. For example, how can electronic devices be
built that operate more energy efficiently than today’s silicon-based devices? Creating
more sustainable electronic products is not just about building a more “eco-friendly” solar
cell or other device, but also using more “eco-friendly” manufacturing methods to do so.
In fact, sustainability cuts across the entire life cycle of an electronic product, from raw
resources to disposal. Chemists and other scientists and engineers are using organic
materials to steer electronics into the future in a more environmentally sustainable way
than is possible in today’s electronic world, for example by using carbon-based materials
instead of precious earth-mined resources and by relying on safer and less energy-
intensive manufacturing methods than silicon-based electronic processing methods.
Social sustainability. More broadly, “sustainable electronics” also implies
building an electronic world that enables a more sustainable society – that is, as described
in the United Nations 2012 report Realizing the Future We Want for All, one that ensures
“inter-generational justice and a future world fit for children … in which children will be
able to grow up healthy, well-nourished, resilient, well-educated, culturally sensitive and
protected from violence and neglect …” Organic electronics is helping to steer electronics
into the future in a way that ensures such justice and in a way not possible with today’s
silicon-based electronics. Specifically, organic electronics is making electronics in general
more accessible to people worldwide. Chemists are using organic materials to develop
“off-the-grid” solar cells, low-cost water sensors, and other devices for use in areas where
people otherwise do not have the resources or infrastructure to light their homes or
monitor water quality. Even in resource-rich areas where electronics are already
pervasive, organic materials hold the potential to expand the use of electronic products in
ways that will benefit society. One of the potential advantages of organic electronics is its
more cost-effective large-scale manufacture, compared to silicon electronics, which
creates opportunities for high-throughput production of item-level sensors and other
devices that could be used to monitor and protect our environment, including our food
supply, in ways not possible until now. For example, chemists envision item-level food
spoilage sensors that would significantly reduce the amount of wasted food.
Technology sustainability. Finally, “sustainable electronics” implies that
electronics itself is long lasting – not just the actual devices, but also organic electronic
technology in general. Chemical, materials, and other scientists and engineers have only
just begun to tap the vast potential for innovative functionality made possible through the
use of organic materials in electronic devices. The way that organic electronic structures
interact with biological systems opens up a vast world of possibility with respect to
medical, sensing, and other human interface applications. The versatile nature of organic
electronics, combined with the promise the field holds forth for environmental and social
sustainability, point the way to a very long-lived set of technologies.

Organic Electronics for a Better Tomorrow / 19


RESEARCH PATHWAY TO THE be able to predict how organic
FUTURE electronic materials actually
perform when integrated into
Realizing the visions articulated in the devices, and only with those
previous section will require overcoming predictions will engineers be able
several major scientific and engineering to develop industry-scale
research challenges. Arguably the synthetic processes.
greatest overarching challenge to the
field of organic electronics is to create (2) Develop better analytical
electronic structures at industry-level tools. Better analytical tools are
scale with high yield and purity. This is needed to detect and measure
true regardless of the type of material what is happening with respect to
used or application. Until industry-level structure and chemical
production of well-controlled structures composition when organic
is achieved, the visions for organic materials are assembled and
electronics will remain just that – integrated into electronic
visions. Only by addressing these structures and devices, ideally at
challenges will the field of organic every step along the way. These
electronics expand the functionality, tools need to be non-destructive,
accessibility and sustainability of our non-invasive, and high-speed.
electronic world: Additionally, highly sensitive
analytical methods are necessary
(1) Improve controlled self- to detect degradation products of
assembly. Chemists need to gain organic materials under operating
better control over the self- conditions in order to better
assembly of organic electronic understand the break-down
molecules into ordered patterns mechanism of such materials and
to ensure that the structures being eventually increase their lifetime
assembled are reproducible. in electronic devices.
Today, a lack of reproducibility
in the formation of many (3) Improve three-dimensional
materials precludes industry- (3D) processing technology.
scale processing. To overcome Many organic electronic
this, chemists need to gain better structures can be assembled on
control of the self-assembly of flexible substrates using existing
organic electronic molecules into printing technologies. However,
ordered patterns. Improved fabrication of 3D organic
controlled self-assembly requires electronic structures with the
a better understanding of the same precision achievable with
electronic properties of organic two dimensional (2D) printing
materials, especially when those technology remains a major
materials are in contact with challenge to reliable high-
other materials (i.e., their throughput manufacturing of
interfacial behavior). Only with organic electronic devices.
that knowledge will researchers

Organic Electronics for a Better Tomorrow / 20


(4) Increase multi-functionality fully realize the multifunctional
of organic electronic devices. As capacity of organic chemistry,
chemists gain better control over chemists need to broaden their
the synthesis of organic research focus beyond “charge-
materials, they and their carrier” transport (i.e., electrons
engineering collaborators will be and holes, respectively) and gain
able to build increasingly a better understanding of optical,
sophisticated optoelectronic and magnetic, thermal and other
other devices with multiple properties.
functions. However, in order to

Organic Electronics: The Role of Chemistry

Chemistry research plays a critical role in the development and commercialization of


organic electronics. After all, it is chemists who synthesize and functionalize the organic
materials being used in the OLED smartphones, organic solar cells, and other devices
either already on the market or in the development pipeline. Without those materials, these
devices would not exist. Not only do chemists provide the raw starting materials, but they
also play a key role in improving the performance of those materials over time. For
example, charge-carrier mobilities of polymer-based OFETs have increased dramatically
over past 10 years, from 0.01 cm2/Vs in 2000 to greater than 1.0-3.0 cm2/Vs in 2010,
largely because scientists know a great deal more about the chemistry of the polymers
than they did in the past. Still, there is a great deal more to learn. Many high-performance
polymers being developed for use in organic electronics show non-textbook behavior,
making it difficult to predict and control how polymeric structures will actually pack and
perform once integrated into electronic systems. The reasoning behind this chemical
behavior, and the possible uses of these polymers are still unknown. Continued research
will help chemists to gain a better understanding of how these materials behave when they
are integrated into electronic systems and hopefully point the way to even better-
performing polymer-based OFETs.

Organic Electronics for a Better Tomorrow / 21


industrial scale-up of polymer-based
Research Challenge #1: Improve electronics will require a more robust
Controlled Self-Assembly understanding of polymer self-assembly.
For all organic materials,
Organic chemistry enables a vast array chemists need to be able to model
of complex structures and large-scale structure-property relationships at the
molecular assemblies to be built. molecular level so that they can design
However, the actual self-assembly4 systems with more controlled self-
process is complex and still very poorly assembly, regardless of whether that
understood. Some design rules are self-assembly occurs in solution (i.e., in
beginning to emerge for small molecule ink) or on a surface. In other words, they
self-assembly, but for the most part must develop a more predictive science
chemists are still operating on a largely of organic electronics. Otherwise,
trial-and-error basis. While it is known synthesis will continue to yield
that small changes in microstructure can decidedly non-uniform mixtures of
significantly impact self-assembly in the structures that behave in unpredictable
solid state, in most cases it is difficult or ways.
impossible to predict how. Without The issue of batch variation and
controlled self-assembly of organic reproducibility, or lack thereof, raises
electronic structures, the manufacture of questions about whether some defects or
devices built from those structures will impurities might be tolerable. It appears
be hindered and visions for the future of that most are not, with defects occurring
organic electronics thwarted. at frequencies of less than one percent
For polymer materials in having significant impact on
particular, improved control of performance, especially for small
morphology is arguably among the molecule aggregate electronic devices.
greatest challenges to moving the field Whether defect-tolerant molecular
forward. This is true even for P3HT architectures exist and, if so, under what
[poly(3-hexylthiophene-2,5-diyl)], the conditions, remain a matter of
well-studied of polymeric electronic investigation.
materials, especially for OPVs. Even The challenge of reproducibility
though the mechanism of P3HT is especially acute for large-scale
polymerization is well understood, synthesis of carbon-based materials.
recent research has demonstrated how Currently, only gram quantities of semi-
certain defects that significantly impact conducting carbon nanostructures can be
electronic performance emerge even manufactured. Even then, defects are
with the most commonly used synthetic pervasive, with typical batches being
protocol. Even for commercial polymer heterogeneous mixtures of forms with
materials already available for purchase, varying electronic and other properties.
batch variation is significant. Thus, A better understanding of self-assembly,
including a better understanding of
kinetic versus thermodynamic control
4In this White Paper, self-assembly is during the self-assembly process, would
defined as the spontaneous ordering of help chemical engineers to develop the
patterned building blocks at a necessary selective synthesis tools for
macroscopic scale. separating semi-conducting carbon

Organic Electronics for a Better Tomorrow / 22


nanostructures from other types of The need for a greater
molecular structures. understanding of interfacial behavior,
especially interfacial self-assembly, is
The Importance of Understanding true of all organic-organic interfaces
Interfacial Behavior (e.g., assemblages of multiple layers of
organic materials, single molecules in
Improved self-assembly requires not contact with a carbon nanotube) and all
only a greater understanding of the organic-inorganic interfaces (e.g., single
electronic properties of any given organic molecules in contact with an
organic material, but also how those electrode). While molecule-electrode
properties manifest when the material is interfaces are key to increasing the
in contact with another material. energy efficiencies of many devices, any
Chemical scientists need to gain a better or all of these different points of contact
understanding of interfacial chemistry can impact electronic behavior.
and the impact of the interface on device The significance of the interface
performance. For example, graphene is not limited to the electronic structures
materials have charge-carrier mobilities or devices themselves. Interfacial
on the order of 200,000 cm2/Vs in a behavior also impacts manufacturing.
vacuum environment. But those Chemists need to gain a better
mobilities drop orders of magnitude understanding of the various molecule-
when the same materials are assembled solvent interactions that occur during
on substrates. The mechanism and solution processing (e.g., inkjet or screen
interfacial chemistry responsible for printing).
driving this drop in mobility is still
unknown.

Organic Electronics for a Better Tomorrow / 23


Figure 8. The complexity of self-assembly calls for a complexity science approach: The
self-assembly of well-ordered patterns of organic electronic materials, whether those
materials are molecules, polymers, carbon-based or not, is very difficult to predict and
control. Until such self-assembly is better understood, such that well-controlled structures
can be synthesized repeatedly and reliably, large-scale production of many of the
envisioned applications for organic electronics will not be possible. Chemists need to gain
a better understanding of self-assembly in order to achieve the prediction and control
needed for industry-level production. Some chemists are calling for a systems-level
approach to studying the complexity of self-assembly. Source: Würthner and Meerholz
2010.

Research Challenge #2: Develop Better molecular environments of the structures


Analytical Tools they are building. Better tools are needed
for analyzing the molecular composition,
Reliable analytical tools are key to molecular organization, and local
building a predictive science of organic electronic and other properties of the
electronics. Only when scientists are organic electronic systems they are
able to better characterize the electronic building.
and other properties of their systems at A stronger fundamental
the highest possible resolution will they measurement science would not only
be able to predict how molecular help with developing a more predictive
structure impacts performance. science of organic electronics, it is also
Currently, chemists have limited key to scaling organic electronic
capabilities to characterize the local processing up to an industry level. In

Organic Electronics for a Better Tomorrow / 24


order to guarantee quality control,
process engineers need to know what is Research Challenge #4: Increase
happening at every point in the process. Multi-Functionality of Organic
They need non-invasive, non- Electronic Devices
destructive, high-speed analytical tools.
Organic electronic devices can do more
Research Challenge #3: Improve than transport electronic information.
Three-Dimensional (3D) Processing They can also transport optical,
Technology magnetic, and thermal information.
Indeed, many of the organic electronic
In order to scale organic electronic devices already on the market are multi-
processing up to an industry-level functional. For example, organic light-
standard, chemical scientists and emitting diodes (OLEDs) and organic
engineers need improved three- solar cells are multi-functional
dimensional (3D) fabrication optoelectronic devices, that is, electronic
technologies. An important advantage of devices that use or produce light in
many organic electronic structures and addition to using or producing electrons.
devices is that they can be assembled on As chemists gain better control over the
plastic, paper and other flexible synthesis of organic materials, they and
substrates using existing low-cost, high- their engineering collaborators will be
throughput inkjet printing technologies. able to build increasingly sophisticated
Printing also enables large-area optoelectronic and other multi-tasking
fabrication of OLEDs, organic solar devices with multiple inputs and
cells, OFETs and other organic multiple outputs. For example,
electronic devices. Moreover, its researchers envision multi-tasking
additive approach makes for more window glazings that function as solar
sustainable production (i.e., necessary cells that generate electricity and as
resources are added as needed rather OLEDs that generate light. In order to
than excess resources being subtracted fully realize the multifunctional capacity
and removed as waste). However, of organic electronics, chemists need to
defect-free 3D processing of organic broaden their research focus beyond
electronic structures remains a major charge transport and gain a better
challenge to industry-scale manufacture. understanding of how molecular
Engineers need to build on what has structure and interfacial behavior
already been done with 2D lithography impacts not just electronic but also
so that they can fabricate uniform 3D optical, magnetic, thermal and other
structures in a controlled manner on a properties.
nano-level, not just micron-level, scale.

Organic Electronics for a Better Tomorrow / 25


CONCLUSION the market and a multitude of device
prototypes in development.
The field will continue to grow,
In 2004, it was predicted that chemists changing the way society interacts with
would soon synthesize organic technology, as chemists, physicists, and
semiconductors with charge-carrier other scientists and engineers address the
mobilities greater than 10 cm2/Vs and research challenges identified by the
organic photovoltaic cells with 10 2012 CS3 symposium participants.
percent power conversion efficiencies. Multidisciplinary research and training
Those predictions have come true. More programs that bring together scientists
recently, it was predicted that organic and engineers from different fields of
electronics would become a US$30 knowledge, as well as from different
billion industry by 2015. While this sectors of activity (i.e., academia,
more recent prediction may have been industry, government), will facilitate the
overly optimistic, nonetheless the field collaborative effort needed to meet these
of organic electronics clearly has made challenges.
tremendous strides over the past few
decades, with some devices already on

Organic Electronics for a Better Tomorrow / 26


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2012 CS3 Participants

Name Institution Title

China Delegation

Xi Zhang (Chair) Tsinghua University, Professor of Chemistry


Beijing
He Tian East China University of Professor of Chemistry and
Science and Technology, Molecular Engineering
Shanghai
Lixiang Wang Chinese Academy of Professor, Changchun
Sciences, Changchun Institute of Applied
Chemistry
Jian Pei Peking University, Beijing Professor of Chemistry
Jin Zhang Peking University, Beijing Professor of Chemistry
Zhigang Shuai (liaison) Tsinghua University, Professor Chemistry
Beijing
Yunqui Liu Chinese Academy of
Sciences, Beijing

Germany Delegation

Peter Bäuerle (chair) Ulm University, Ulm Director, Institute of


Organic Chemistry II and
Advanced Materials
Frank Würthner University Würzburg, Professor, Institute of
Würzburg Organic Chemistry
Klaus Meerholz University of Cologne, Professor, Institute of
Cologne Physical Chemistry
Stefan Hecht Humboldt-Universität zu Professor, Laboratory of
Berlin, Berlin Organic Chemistry and
Functional Materials,
Department of Chemistry
Andreas Hirsch University Erlangen- Professor/Chair, Organic
Nuremberg, Erlangen Chemistry
Horst Hahn Karlsruhe Institute of Executive Director
Technology, Eggenstein-
Leopoldshafen
Hans-Georg Weinig German Chemical Society Head Education and
(liaison) Science

Organic Electronics for a Better Tomorrow / 31


Markus Behnke German Research Program Director
Foundation (DFG)

Japan Delegation

Takuzo Aida (chair) University of Tokyo, Professor, Departments of


Tokyo Chemistry and
Biotechnology, School of
Engineering
Yoshiharu Sato Mitsubishi Chemical Senior Researcher,
Group Science and Photovoltaics Project
Technology Research
Center, Inc., Tokyo
Mitsuo Sawamoto Graduate School of Professor, Department of
Engineering, Kyoto Polymer Chemistry
University, Kyoto
Takao Someya School of Engineering, Professor, Department of
University of Tokyo, Electrical Engineering
Tokyo
Kazuo Takimiya Graduate School of Professor, Department of
Engineering, Hiroshima Applied Chemistry
University, Higashi-
Hiroshima
Masahiro Yamashita Graduate School of Professor, Department of
Science, Tohoku Chemistry
University, Sendai, Miyagi
Nobuyuki Kawashima Chemical Society of Japan, Executive Director and
(liaison) Tokyo Secretary General
Mitsuhiko Shionoya Japan Society for the Graduate School of
Promotion of Science Science, University of
(JSPS), Tokyo Tokyo

United Kingdom Delegation

Peter Skabara (chair) University of Strathclyde, Professor of Materials


Glasgow, Scotland Chemistry
Stephen Yeates University of Manchester, Professor of Polymer
Manchester, England Chemistry
Karl Coleman Durham University, Reader, Department of
Durham, England Chemistry
Martin Heaney Imperial College London, Reader of Materials
London, England Chemistry, Department of
Chemistry

Organic Electronics for a Better Tomorrow / 32


Andrew Monkman Durham University, Director, Photonic
Durham, England Materials Centre,
Department of Physics
Richard Walker (liaison) Royal Society of Science Executive
Chemistry, Cambridge,
England
Clare Bumphrey Engineering and Physical Physical Sciences Portfolio
Sciences Research Council, Manager
Swindon, England

United States Delegation

Cherie Kagan (chair) University of Professor, Departments of


Pennsylvania, Philadelphia, Chemistry, Electrical and
Penn. Systems Engineering, and
Materials Science and
Engineering
Lynn Loo Princeton University, Professor, Department of
Princeton, New Jersey Chemical and Biological
Engineering
Claudia Arias University of California, Acting Associate
Berkeley Professor, Department of
Electrical Engineering and
Computer Sciences
Colin Nuckolls Columbia University, New Professor, Department of
York, New York Chemistry
James Batteas Texas A&M University, Professor, Department of
College Station, Texas Chemistry
Jiwoong Park Cornell University, Ithaca, Asst. Professor,
New York Department of Chemistry
and Chemical Biology
Dat Tran (liaison) American Chemical International Activities
Society, Washington, D.C. Manager, Office of
International Activities
Francisco Gomez American Chemical Assistant Director, Office
Society, Washington, D.C. of International Activities
Zeev Rosenzweig National Science Program Director
Foundation, Arlington,
Virginia
Leslie Pray (science writer) Independent Consultant,
Los Angeles, California

Organic Electronics for a Better Tomorrow / 33

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