F.

Sc - XI CHEMISTRY Ch # 5, 6, 8

27-02-2016 12 10 MINUTES
Q#1 Encircle the best option. 1x12=12
i. The velocity of photon is:
(a) Independent of its wavelength (b) Depends on its wavelength
(c) Equal to square of its amplitude (d) Depends on its source
ii. In the ground state of an atom, the electron is present:
(a) (b) (c) (d)
(iii) By combining “N” atomic orbitals the number of hybrid orbitals are:
(a) 2n (b) N (c) 3n (d) Impossible to predict
(iv) Paired electron is a molecule give character of:
(a) Ferromagnetism (b) Paramagnetism (c) Diamagnetism (d) Ferrimagnetism
(v) Ionic bonds are:
(a) Unidirectional (b) Bidirectional (c) Multidirectional (d) Non-directional
2
(vi) Bond angle in sp hybridization:
(a) 120º (b) 180º (c) 109.5º (d) 107.5º
(vii) An ionic compound A+B- is most likely to be formed when
(a) The ionization energy of A is high and electron affinity of B is low.
(b) The ionization energy of A is low and electron affinity of B is low.
(c) Both the ionization energy of A and electron affinity of B are high.
(d) Both the ionization energy of A an electron affinity of B are low.
(viii) The number of bonds in nitrogen molecule is
(a) One 𝜎 and one 𝜋 (b) One 𝜛 and two 𝜋 (c) Three sigma only (d) Two 𝜎 and one 𝜋
(ix) Which of the following statements is not correct regarding bonding molecular orbitals?
(a) Bonding molecular orbitals possess less energy than atomic orbitals from which they are formed.
(b) Bonding molecular orbitals have low electron density between the two nuclei.
(c) Every electron in the bonding molecular orbitals contributes to the attraction between atoms.
(d) Bonding molecular orbitals are formed when the electron waves undergo constructive interfere.
(x) Which of the following molecules has zero dipole moment?
(a) NH3 (b) CHCl3 (c) H2O (d) BF3
(xi) Which of the Hydrogen halides has the highest percentage of ionic character?
(a) HCl (b) HBr (c) HF (d) HI
(xii) Which of the following species has un paired electrons in anti-bonding molecular orbitals?
(a) O2+2 (b) N2-2 (c) B2 (d) F2
SUBJECTIVE TYPE Total Marks 28 Time Allowed 50 MINUTES

Q.No.2.Write short answer of the following questions. 𝟏𝟎 × 𝟐 = 𝟐𝟎

i. CO2is non-polar but SO2is polar. Why?
ii. Why He do not exist in diatomic form? Justify according to MOT.
iii. Draw Lewis structure of Ag (NH3)2 NO3.
iv. The abnormality of bond length and bond strength in HI is less prominent than that of HCl.
v. The distinction between a coordinate covalent bond and a covalent bond vanished after bond formation in
NH4+, H3O+ and CH3NH3+
vi. Why cationic radius is smaller that its parent atom?
vii. Bond distance is also called compromise distance justify.
viii. Define dipole moment with example.
ix. Draw hybrid geometry of BF3.
x. How electronegativity difference decides the nature of bond?
Q#3 a) Define ionization Energy. Give its periodic trends and factors affecting. 04
b) Give basic postulates of VSEPR Theory. 04