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AGSO lournal of Australian Geology & Geophysics, 17(4),253-258 © Commonwealth of Australia 1998

Archaean lode-gold deposits


Christopher J. Yeats 1 & Fop Vanderhor
I CSIRO Exploration and Mining, PO Box 136, North Ryde , NSW 1670 Australia, 2 Rio Tinto, 37 Belmont Avenue, Belmont, WA
6104, Australia.

EXPLORATION MODEL
Examples peNasive foliation in volcanics
Golden Mile, Norseman, Sons ofGwalia, Mt C harlotte, younging dirjction of strata
Hill 50, Wiluna, Victory-Defiance, New Celebration, Jundee, pit outline
Kanowna Belle, Bronzewing, (Australia); ~~~~~~ff1f~ . :;-' '-' -' n ' "
Hollinger-McIntyre, Dome, Hemlo (Canada) base of o;rdatro~: ;:;:;:;:;:
Target 1111/1/1
//11111/
1/1/11.'''•
'/11/11,'

o Typical size: 0.5- 1600 tAu.


'/11/11,
/11/1';
/11/11
/1,11,

o Most common size: 1- 20 tAu.


'II/II

ultramafic;
o Grade: > I g/t (open cut); >5g/t (underground). schist
'/1/1

o Low Cu/ Au; low- medium Ag/Au; low- medium Te/ Au; rare
'/1//

high Sb/ Au ratio.


i~t ,:;:;:;:;:~
Mining and treatment
o Deep surface weathering allows low-cost open-cut mining of
otherwise uneconomic deposits.
{~\~ ~ ~;~:V\ 't"
\ \ --+1--1
, :basa'ltic<:=- -'"'-'
o Mineralisation generally free milling, but can be refractory
where gold is associated with fine-grained pyrite or
arsenopyrite. .:};~::~~~{ ;
o Low Cu content allows optimum treatment of ore. sedimentary unit <;:;:;:;:;:; I·,

Regional geological criteria 100 m o:::; ';:;::


o Generally hosted in greenstone part of Archaean granite
greenstone terrane, particularly in linear belts. Figure I. Hampton-Boulder (New Caledonia) deposit, cross•
o Structurally late, sy n- to post-peak metamorphic timing. section 3440 mN. Alteration and mineralisation (hatched
o In areas of sub-greensc hist to granulite-facies metamorphism, pattern) are hosted in a brittle-ductile shear zone (Boulder•
a lthough most sign ificant deposits are in areas of greenschist Lcfroy Fault) and localised near the margins of competent
felsic dykes "hich intruded parallel to the shear, but predate
facies.
Au mineralisation (modified from \'anderhor & Groves 1995)
o Diverse structural settings, but common ncar major regional
shear zones in secondary faults and ncar hinge areas of
gently plunging upright antiforms.
o Medium-T deposits in mafic host: biotite amphibole
Local geological criteria plagioclasc ± carbonate (prox imal); biotite ch lorite
o Potentially in any host rock, but noticeably common in hornblende ± carbonate (distal).
competent lithologies with high Fe, (Fc+Mg), such as BIF o J-1igh-T deposit in mafic host: diopside- Kfeldspar- garnct•
and granophyric gabbro. hornblende ± biotite.
o Sheared margins of competent lithologies, such as granitoid,
feldspar-porphyry, or dolerite. Deposit geochemical criteria
o Jogs or splays in brittle-ductile shear zones. o Subtle distal K-CO , metasomatism can be exp lored using
o Inte rsection of shear zone with favourable host rock (see alteration indices (3"K/ AI; CO/ Ca; CO / Ca+ Mg+ Fe) and
above) or other structures. trace-element distribution. " "
o Competent rock unit in less-competent rock sequence; exact o Trace elements include Ag, As, B, Bi, Mo, Pb, Sb, Te, W.
host depends on lithostratigraphy. oS isotopes -5.7 to 5.0%0 (Yilgarn Crato n) .
o C isotopes 8.1 to - 2.7%0 (Yilgarn Craton).
Mineralisation features o Pb isotopes (zircon) give ages of ca. 2630 2600 Ma in the
o Epigenetic , structurally control led, late-tec tonic. Yilgarn Craton.
o Quartz- carbonate gangue with typically 1-6°0 sulphide. o Typically, very low base-metal content, but some unusual
o Mineralisation may be present in veins and/or distinct deposits (e.g. Boddington- Cu, Mt Gibson-C u, Zn, Pb)
wallrock alteration zones. contain anomalous base-metal contents.
o Broad correlation between temperature of mineralisation and
regional metamorphic facies. Surficial geochemical criteria
o Pyrite (±arsenopyrite) main sulphide species at low o Exploration relies heavily on geochemiealmethods because
metamorphic grades with pyrrhotite (±arsenopyrite) of widespread deep weathering profiles (20- 100 m deep)
prominent at medium high grades. and the prescncc of lateritic horizons in the Yilgarn.
o Depletion of Au in soil profile is common to up to 40 m
Alteration depth, but redox fronts and in-situ lateritic horizons can
o Zoned alteration halo 0.2- 200 m wide; sma ller, poorly retain the mineralisation signature.
zoned halos near high- T deposits. o Soil, rock-chip, and regolith geochemistry surveys are the
o Alteration related to K 20 , S and CO 2 metasomatism most widely used regional exploration tools.
o Low-T deposits in mafic host: sericite- carbonate (proximal); o Au, As, Bi, Sb, Pb, Wand Mo are the main pathfinder
chlorite-carbonate (distal). elements.
254 C.J. YEATS & F. V ANDERHOR

FACIES DEPOSIT STYLES RITICAL WALLROCK MINERALOGY EXAMPLES


• Au generally transported as bisulphide complex; chloride
complexes may be important for higher T deposits.
,00·-
cc\'& ",e\.1i# .~e\~" {fP~,&\.e ~c\\.e ~\e ~"f:\\'Oo\~'PJ\6.e • Au precipitation due to one or more of desulphidation
~~e ,,6\(\ ""'~ ~'t<e1; C~ r:,e~ tQ\O ",,<'" 0,0

SUB-
(reaction with Fe-rich host rock), phase separation, or fluid
GREENSCHIST Wiluna Group mixing.
• Metamorphic or magmatic origin postulated for hydrother•
Mt Pleasant Group mal fluids and Au. Isotopic data indicate deep crustal source
GREENSCHIST Mt Charlotte
Golden Mile
for primary ore fluid, although the fluid has been modified
New Celebration
by the wallrocks in hydrothermal conduits, and there is
Victory-Defiance evidence of mixing with surface waters at high crustal levels.
Crown-Mara rOB
AMPHIBOLITE • Magmatic fluids may be important for higher T deposits.
Frasers
Marvel loch

GRANULITE
Griffins Find
Geophysical criteria
I
• Orebodies normally have very weak (or absent) geophysical
i
signature.
Figure 2. Variation of deposit style, critical wall-rock alteration • Geophysical techniques mainly used to define host rocks
assemblages, and examples of lode-Au deposits at meta• and structural targets under cover.
morphic conditions ranging from snb-greenschist facies, near
surface «1 km depth) deposits to granulite facies, lower crustal
• Airborne and ground magnetics most widely used geophysical
exploration techniques.
(approx. 25 km depth) mineralisation (modified from Groves
et aI. 1992).

Fluid chemistry and source Comments on genesis


• Low-to moderate salinity. • Archaean lode-gold deposits occur in a broad range of
structural settings, and at different crustal levels, but they
• Near neutral fluids : HP-C0 2 ± CH4 • share a similarity in ore fluid characteristics and a relatively
• XC0 2 = 0.1- 0.2. late-orogenic timing of mineralisation, which occurs after the
• T = 200- 740°C; P = 0.5- 5 kbar. main phases of regional thrusting and folding and after, or
• Reduced to slightly oxidised primary fluids; late-stage fluids late-syn, peak metamorphism. Many deposits are related to
can be highly oxidised (e.g. Lawlers). the reactivation of earlier structures.

@ Amphibolite ~rj:~~~~~~1 LillJ ~~;;~~~hist


CO NTACT METAMORPHIC AUREOLE

III ~ (a p PfO)( _ )

ru
~ Gold deposit Deasa't
~ Conglomerates Komatiite

~ Felsic volcaniclastics • Porphyry

CHl BIF ~ Peralkaline granitoid

f=ill2] Shale IT] Post-kinematic granito id


~ Dolerite D Synkinematic granitoid

Figure 3. Schematic representation of the nature of Archaean lode-Au mineralisation, illustrating variable structural
styles, host rocks and metamorphic settings (from Groves et al. 1990).
ARCHAEAN LODE-GOLD DEPOSIT S 255

Introduction deformational timing has been suggested (Allibone et a1. 1996).


Golden Grove and Mount Gibson in the Murchison Province of
Archaean lode-Au deposits are sited in the greenstone belts of
the Yilgarn Craton are the only known significant Australian
all Archaean shield areas, and account for almost 20% of cumu•
Archaean Au-rich VHMS deposits. However, textural studies
lative world Au production (Roberts , 1987). In Au strali a, this
at Mount Gibson (Yeats & Groves 1998) have shown that the
sty le of mineralisation is the single most important source of
majority of the Au was introduced late in the tectonic history of
Au , with annual productio n in 1994 cl ose to 180 t from
the greenstone belt and that the syngenetic massive sulphides
approximately 100 mines. The m ajority of Australian deposits
only provided a rheologically favourable horizon for later Au
are located in the Yilgam Craton of Western Australia. However,
deposition.
a small but significant number of deposits al so occur in the
The vast majority of known Australian Archaean lode-Au
Pilbara Craton and in small Archaean outliers between the Yilgarn
deposits fall into the category of qu artz-carbonate vein- style
and Pilbara Cratons. G iven the focus of mini ng (and ex ploration)
A u-ri ch deposits and, consequently, much of th e foll owin g
on the Yil garn Craton, much of the fo ll ow ing disc ussion is biased
d isc ussion re lates to this grou p . In the Yil garn Crato n, th e
to lode-A u m inera li sation in that craton. Howeve r, references
deposits are interpreted to re present a coherent ge netic gro up
are made to oth er areas w here appropriate .
deposited late in the tecton ic and structural history of the craton
under metamorphic conditions wh ich range from sub-greensc hist
Size and grade to granu lite facies (Groves et al. 1995). The deposits are structur•
The giant Go lden Mil e deposit at Kalgoor lie in the Norseman• a lly contro lled and genera ll y occ ur in or adjace nt to late or reac•
Wiluna Belt of the Yilgarn Craton is the best-known Archaean tivated structures. They are consistently enriched in Au, Ag,
lode-A u deposit in Australi a. The deposit has an estimated content As, and W, variably enriched in Bi , Sb, Te, and B and, typ icall y,
(mined and resou rces) of 1600 t Au, maki ng it one of the largest only slig htly enric hed (ifat all ) in Cu, Pb and Zn (Perring et al.
Au deposits in the world. The size of the Golden Mi le, however, 1991 ). Lateral zonat ion of hydrotherma l alteration is characteris•
is somewhat anomalous in the Australian context, and the average tically present on the scale of centimetres to tcns of metres.
Au content of currently mined Western Australian Archaean However, vertical zonation, where recognised, is nornlally more
lode-Au deposits is approximately 2 t (Yanderhor & Groves subtle and on a scale of hundreds of metres (e.g. Mikucki et al.
1995). 1990). In addition, as dctcrmincd from fluid-inclusion studics, a
Since the first discovery of Au hosted by Archaean rocks in low-salinity, H,O- CO, ± CH. fluid is important at most of
the late 19th century, the average grade of the dcpo sits has fallen these depos its. Although H,O:CO,:CH. ratios are variable lor
steadily, from more than 40 glt in the 1890s to less than 5 glt Au d ifferent deposits, most havc a calculated XCO , of O. I 0.2
in 1988 (Groves et al. 1990). Current major underground mincs before phase separation or mixing with other fluids (cf. Groves
typicall y havc head grades of 4-9 glt, with the noticcable et al. 1992). Alteration assemblages vary in mineralogy with
exception of the Mt Charlotte mine at Kalgoorlie , which oper• host rock and metamorphic setting, but enrichment in CO" S
ates economically at an average head grade of 2.7 glt Au. The and K(±Na), plus the ore mctals, is characteristic. -
majority of near-surface deposits that can be exploited by open•
cut mining have gradcs below 5 glt Au and the eco nomic cut-off Structural setting and tim ing
ma y be as low as 0.5 glt in stro ngl y oxid ised surfac e material.
There is a gross relationship bctween thc location of Archaean
lode-Au deposits and crustal-scale deformation zones in the
Classification and general characteristics Yilgarn Craton. A similar relationship has been noted in the
As a direct result of the surge in Au exploration in the 1980s, the Superior Province of Canada, whcre lode-Au mineralisation is
understanding of Archaean lode-Au deposits has increased associated with the so-cal led 'breaks' (Robert 19(0). Despite
dramatically in the last decade. The Archaean lode-Au style of this large-scale association, AUlllineralisation is rarcly hosted in
mineralisation has traditionally been associated \\ ith Au-only, first-order structures, and deposits arc instead hosted in second
brittle-ductilc shear-related 'mesothenna l' deposits that formed and lower order struc tures, whi ch mayor Illay not show a di rect
at mid-crusta l levels, typica lly at greenschist-facies metamorphic geometric re lationsh ip to the largc-scale deformati on zo nes (e.g.
conditions (e.g. Groves et al. 1989). Although corrcct for the Eisen lo h r et a l. 1987, Wi tt 1993). T he ge ne ra l lack of
majority oflode-Au deposits, recent stud ies (e.g. Ilagemann et Illineralisation within the major structures suggests that, if the
al. 1992 , Knight et al. 1993, Neumayr et a l. 1993, Bloem et al. structures are interlinked and the major structures acted as fluid
1994) have described an increasing number of deposits from a conduits, they did so at deeper crustal levels than those currently
wider range of crustal conditions, varying from sub-greenschist ex posed in Illost Au deposits.
to granulite facies. Less commonly, Au deposits have been The structural styles of individual Au deposits broadly
described with genctic affinities to other styles ofmineralisation, reflect the metamorphic conditions under which they formed.
such as volcanic-hosted massive sulphide (YHMS) deposits At low Illctalllorphic grades, brittle tensional quartz vcins and
and porphyry deposits . breccias dominate (e.g. Wiluna: Hagemann ct al. 1992). These
Based on Canadian examples, Robeli (1996) recognised two give way to brittle-ductile laminated quartz veins at mid to
broad groups of deposits, based on the composition of their ore: uppcr greenschist-facies conditions (e.g. Kalgoorlic: Phillips
Ag-rich deposits, in which the concentration of Ag exceeds that 1986) and ductile shear-zone-hosted mineralisation at amphibolite
of Au, and Au-rich deposits, in which thc concentration of Au and granulite-facies conditions (e.g. Southern Cross: Blocm ct
exceeds that of Ag. Ag-rich deposits are furthe r subdivided into al. 1994). Au mincralisation occurs syn- to post-peak regional
three styles of mineralisation which can be regarded as auriferous mctalllorphism and is synchronous with major fault or shear•
end-members of other deposit types: YHMS, Cu-Ag-Au veins, zone Illovcment. Importantly, however, it is commonly associated
and porphyry deposits (Robcrt 1996). All these three styles are with the last significant movement on these structures (Groves
generally rich in sulphides, particularly chalcopyrite, which et al. 1995), meaning that the geometry of the host scquences
furth er scts them apart from the typically Cu-poor Au-rich (or has not changed significantly since the time of mineralisation.
Au-only) deposits, which Robert (1996) subdivided into two The majority of published geochronological data for the
styles: quartz-carbonate veins and disscminated- replacement Yilgarn (summarised in Yeats & McNaughton 1997) is consistent
deposits. with -2640- 2630 Ma Au mineralisation. Several studies, how•
The Ag-rich styles of mineralisation are rare among the ever, suggest that Au may have been introduced at other times.
known Australian Archaean lode-Au deposits. Thc Boddington Yeats & McNaughton (1997) presented new data for the Jundee
deposit in thc SW Yilgarn is possibly an Australian example of and Mount McClure deposits in the Yandal greenstone belt,
a porphyry-style Ag-rich deposit (Roth et al. 1990), but a post- which require Au mineralisation to have occurred prior to -2660
256 C.l YEATS & F. V ANDERHOR

Ma. Mueller et al. (1996) dated the main Au mineralising event greenschist facies, respectively (Mikucki et al. 1990). In tholeiitic
at Big Bell in the Murchison Province at 2662±5 Ma, using U• mafic rocks (by far the dominant hosts to Au mineralisation),
Pb in garnet thought to have formed during Au mineralisation, chlorite-muscovite stable alteration is typically characterised
and a later, secondary event (±Au) has been dated at 2614±2 by distal chloritic alteration which grades into proximal carbonate
Ma, using titanite . However, the structural timing of (ankerite ± siderite)-sericite-pyrite ± pyrrhotite alteration
mineralisation at the Big Bell Au deposit remains controversial adjacent to mineralisation. Alteration patterns in mafic-hosted
and the textural relationship between the minerals used for the biotite- muscovite stable alteration zones broadly parallel those
geochronology and the Au mineralisation is equivocal. At Lawlers, in the lower temperature types, with the notable differences
a SHRIMP U-Pb titanite study by Fletcher et al. (submitted) that up to 40% biotite may be developed in intermediate alter•
has dated the later of two Au mineralising events at 2592±9 Ma, ation zones (cf. Phillips & Groves 1984, Clark et al. 1989) and
distinctly younger than any other mineralisation reliably dated that sericite is much less extensively developed. Deposits which
elsewhere in the Yilgarn. A number 0[39 Ar-40Ar plateau ages for are hosted in ultramafic, intermediate, felsic or metasedimentary
hydrothermal muscovite from the eastern part ofthe craton also rocks show alteration assemblages that reflect the same chemical
give younger ages for Au mineralisation. However, given the uncer• changes as those noted for the mafic-hosted examples. However,
tain cooling history of the Yilgarn, the validity of this method mineral species and absolute abundances reflect the nature of
remains a matter of debate. Nevertheless, clear evidence is emerg• the host rock. For example, highly magnesian phases, such as
ing that lode-Au mineralisation occurred in the Yilgarn Craton at talc and tremolite, are commonly present in alteration assemblages
times other than -2640-2630 Ma. At this early stage of re• in ultramafic rocks (Mikucki et al. 1990).
search, pre- and post- -2640-2630 Ma mineralisation appears Lode-Au deposits hosted in amphibolite and granulite-facies
to be much less widespread than the main event. However, domains exhibit wall-rock alteration assemblages which are
further work is needed to confirm this. geochemically consistent with those in lower metamorphic grade
At Mount York in the Pilbara Craton, Neumayr et al. (1993) deposits, although alteration is less extensive and lateral zonation
recorded similar general structural and relative temporal relation• is generally poorly developed or absent. Carbonate species are
ships to those observed for lode-Au mineralisation in the Yilgarn. not major alteration minerals under these conditions, reflecting
However, no research has been done on the absolute timing of the instability of ankerite-quartz-bearing assemblages at higher
Au mineralisation in the Pilbara. temperatures and pressures (Ridley & Barnicoat 1990). In the
Southern Cross greenstone belt, mafic-hosted Au mineralisation
Host rocks in an amphibolite-facies domain is associated with quartz- pyrite•
pyrrhotite ± plagioclase veins with diopside- calcite or fibrous
Any lithology may host lode-Au mineralisation within an indi• tremolite ± chlorite rims, which are surrounded by biotite•
vidual greenstone sequence, but spatial analysis of Au pyrrhotite ± amphibole ± chlorite alteration haloes, several
mineralisation on a district or craton scale reveals that specific centimetres wide, in the wall rock (Bloem et al. 1994). The
rock types are preferential hosts (Groves et al. 1990). Two deposits of the Coolgardie Goldfield display similar alteration
factors are considered to be important in the mineralising process. assemblages, with the addition of garnet (Knight et al. 1993). Au
The rheological properties of the host rock may physically mineralisation in a granulite-facies domain at Griffins Find is
localise fluid flow, with relatively brittle lithologies more prone associated with a quartz- diopside-microcline- pyrrhotite•
to fracturing and veining and, consequently, mineralisation. The arsenopyrite-Ioellengite assemblage (Barnicoat et al. 1991), again
chemical properties of the rock may also play an important reflecting similar chemical changes to those seen at lower meta•
role. For example, Fe-rich rocks and/or rocks with a high Fe/ morphic grades.
Fe+Mg ratio are capable of destabilisingAu bisulphide complexes,
causing the formation of Fe sulphides and coprecipitation of
Au. Not surprisingly, the contribution to total Au production Exploration strategies
from deposits in relatively Fe-rich mafic volcanic and intrusive Exploration for Archaean lode-Au deposits relies heavily on
rocks is by far the most significant in the Yilgarn Craton, although geochemical methods in Western Australia (in particular the
this figure is strongly influenced by the giant mafic-hosted Yilgarn Craton), owing to widespread deep weathering (generally
deposits at Kalgoorlie and, to a lesser extent, Kambalda. In these 20-100 m deep) and the presence of surficial laterite. Lode-Au
districts, granophyric zones in thick layered gabbroic intrusions mineralisation generally has a poor geophysical signature. Air•
combine a high degree of competency with a high Fe/Fe+Mg, borne and ground magnetics have been used extensively as a
providing a physically and chemically ideal site for Au mapping tool, to define exploration targets such as Fe-rich host
mineralisation. BIF and other Fe-rich sedimentary units are also rocks and favourable structures by designating areas of pro•
relatively important contributors as host rocks (e.g. the Hill 50 spective geology beneath residual or transported cover. In addition,
deposit at Mount Magnet), particularly when their low overall at some localities, there may be positive magnetic anomalies
abundance in greenstone belts is taken into account. associated with Au mineralisation (owing to the presence of
In contrast to the Yilgarn Craton, sedimentary and ultramafic magnetite as an alteration phase), or negative anomalies due to
rocks are the major hosts to known Au mineralisation in the sulphidation of primary magnetite in strongly magnetic host
Pilbara Craton (Groves et al. 1990). However, as stated earlier, rocks (e.g. BIF).
Au mineralisation in the Pilbara is minor, when compared to Soil, rock-chip, and regolith geochemistry are the most
that in the Yilgarn Craton. widely used regional exploration tools, followed by shallow
RAB drilling of surface targets (cf. AMF 1995). In areas overlain
by transported regolith, exploration may proceed directly from
Wallrock alteration regional magnetic target generation to RAB drilling. Au itself,
Wallrock alteration associated with Archaean lode-Au analysed to low (Ppb) levels, is generally the most effective
mineralisation, as stated above, varies according to host rock pathfinder element. However, As, Bi, Sb, Wand Mo have also
and metamorphic grade. However, mineral assemblages indica• been utilised in exploration. Au is commonly depleted within
tive of carbonation, K±Na metasomatism and sulphidation are the saprolitic profile up to 40 m depth, but both in-situ and
common across a broad range of metamorphic conditions, ranging transported lateritic material may retain the signature of primary
from sub-greenschist to granulite facies. mineralisation (Butt et al. 1993, Lawrance 1993). Consequently,
In lode-Au deposits in sub-amphibolite-facies domains, an understanding of regolith evolution and chemistry is of vital
laterally zoned alteration assemblages may be split into chlorite• importance to lode-Au exploration in Western Australia. More
muscovite and biotite-muscovite stable sequences, broadly sophisticated geochemical techniques, such as the mobile metal
reflecting formation at the chlorite and biotite subzones of the ion (MMI) method (cf. Mann et al. 1993), are beginning to be
ARCHAEAN LODE-GOLD DEPOSITS 25 7

applied to Au exploration, but their effectiveness is yet to be Hagemann, S.G., Hronsky, J.M.A. , Knight, J.T., McNaughton,
proven. N .J., Ojala, 1. , Vielreicher, R.M ., McCuaig T.C. & Holyland,
The late tectonic timing of Archaean lode-Au mineralisation P.w. , 1995. Lode-gold deposits of the Yilgarn block: prod•
allows the possibility of geomechanical modelling (or 'stress ucts of Late Archaean crustal-scale overpressured hydro•
mapping ' ) as a targeting tool in camp-scale lode-Au exploration. thermal systems. Geological Society, Special Publication 95 ,
Au mineralisation is associated with areas of high fluid flow, 155- 172.
which is focussed in areas of low mean stress (Ridley 1993). Hagemann, S.G. , Groves, OJ. , Ridley, J.R. and Vea rncombe,
Geomechanical modelling at Kalgoorlie (Holyland 1990), Granny J.R., 1992 . The Archaean lode-gold deposit at Wiluna, West•
Smith (Ojala et al. 1993) and Coolgardie (Knight et al. 1993) has ern Australia: high level, brittle-style mineralization in a
illustrated a good correlation between known lode-Au strike-slip regime. Economic Geology, 87, 1022- 1053 .
minerali sati on and modelled areas of low mean stress. Th is Ho, S.E ., G roves, 0 .1. & Bennett, J .M . (edito rs), 1990. Go ld
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Received 5 November 1996; accepted 11 June 1998

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