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IEEE MICROWAVE AND WIRELESS COMPONENTS LETTERS 1

Simple High-Performance Metal-Plating Procedure


for Stereolithographically 3-D-Printed
Waveguide Components
Marco Dionigi, Cristiano Tomassoni, Giuseppe Venanzoni, and Roberto Sorrentino, Life Fellow, IEEE

Abstract— This letter presents a simple and cheap metal- cheap and can also be very accurate. The plastic resins
plating procedure for plastic 3-D printed microwave components. employed are also cheap and offer advantageous features, such
The devices are built using a Stereolithographic printer and as high mechanical robustness or high temperature resistance,
then metalized by a two-step process consisting in a silver-
painted substrate followed by copper electrodeposition. The depending on their formulations [13]. This technique can be
method achieves good adhesion of the metal to the plastic body effectively used to make RF components, such as waveguide
and high conductivity. Resonators and X-band filters have been filters, and antennas. [5]–[9]. The mechanical accuracy of the
fabricated and tested, showing excellent performance in terms of printed devices depends on the thickness of the deposited
dimensional accuracy and low loss, with quality factors better layers—which can usually be controlled to some extent with
than 6500. The technique can be usefully employed for fast and
cheap prototyping of microwave components at least up to the the print software—and the width of the laser beam. The
X-band. orientation of the component during the process also affects
the resulting accuracy.
Index Terms— Additive manufacturing (AM), stereolithogra-
phy, waveguide filters. After the printing phase, SLA-made RF components, such
as filters and couplers, need metallization of at least the inter-
I. I NTRODUCTION nal surfaces in order to confine and guide the electromagnetic
field. The quality of the metallization affects the response of
I N THE recent years Additive Manufacturing (AM),
or 3-D printing, has received increasing attention in many
fields, such as aerospace, bioengineering, and also microwave
the devices in terms of losses and power handling. The metal
deposition should be as smooth as possible and must be thick
and millimeter wave technology. The main advantage of enough depending on the operating frequencies. The adhesion
AM techniques is that a 3-D object, even complex, can be of the metal layer on the plastic must also be considered in
rapidly fabricated, using a very fast process from the digital order to avoid peeling phenomena.
design to the printer. In the earlier adoption, in fact, these tech- Geterud et al. [10] propose a complex metallization proce-
niques were used mainly for rapid prototyping, but nowadays, dure, derived from the industrial plating of plastic material.
with the growing accuracy and refined materials, they can also It uses several steps and many potentially dangerous chemical
be used for the final production of many components. products making the method quite expensive and not easy to
Many AM technologies are currently available [1], [2], all implement. On the contrary, Périgaud et al. [7] simply apply
of them sharing the same principle, in which a 3-D object a multilayer silver painting of the surfaces, which appears to
is built by incrementally adding a suitable material, either be the simplest method. In between there are methods that
plastic or metal, using a layer-by-layer procedure. use a dual layer deposition. In [11], a combination of spray
Considering plastic deposition, the resin can be solid plating and electrolytic deposition was proposed, although the
(usually a thread which is melted and deposited as in authors did not address the idea for RF devices. Zhu et al. [12]
fused deposition modeling printers), or a liquid, which is grow an electro-less copper substrate covered with an elec-
polymerized using a laser beam with a process called trolytic copper plating, followed by an antioxidation finishing
Stereolithoghrapy (SL or SLA). In metal deposition, the laser bath.
beam melts a metal powder which is used to make 3-D In this letter, a simple and reliable method for the metalliza-
objects [3]. The main drawback of metal deposition is that tion of RF components made with an SLA printer is proposed,
printers are very expensive, usually in the range of hundreds based on a combination of silver painting and electrolytic
of thousands of dollars. copper deposition. The method needs a limited number of
SLA printing [4] is one of the earliest methods appeared steps and can be easily executed in a small laboratory since
in the market. In contrast with metal 3-D printing, it is it uses easy-to-find materials and low-hazard reagents. The
method leads to a good adhesion of the conductive layer with
Manuscript received July 6, 2017; accepted August 9, 2017. (Corresponding
author: Marco Dionigi.) the plastic body of the device. Filters and resonators up to
The authors are with the University of Perugia, 06125 Perugia, Italy (e-mail: X-band were selected as test structures because of their high
marco.dionigi@unipg.it). sensitivity to metal conductivity and mechanical tolerances.
Color versions of one or more of the figures in this paper are available
online at http://ieeexplore.ieee.org. Experimental results were highly satisfactory as illustrated
Digital Object Identifier 10.1109/LMWC.2017.2750090 below.
1531-1309 © 2017 IEEE. Personal use is permitted, but republication/redistribution requires IEEE permission.
See http://www.ieee.org/publications_standards/publications/rights/index.html for more information.
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2 IEEE MICROWAVE AND WIRELESS COMPONENTS LETTERS

Fig. 2. Waveguide cavity resonator.

range from 10 and 20 μm, a dc conductivity in the range


of 5.7–2.86 × 105 S/m has been calculated for the dried paint.
The electroplating process was performed in a glass con-
tainer filled by commercial acid solution of copper sulfide by
connecting the structure through copper wires to the negative
connector of a dc power supply and a copper rod to the positive
connector. The electrical current should be kept low in order to
obtain a slow copper deposition and to avoid potential surface
defects such as excessive roughness or spikes. A 100-mA
current was found to be a suitable value for obtaining a very
uniform deposition.
We have used a deposition time of 1.5 h to obtain the
copper layer of 20 μm. The resulting X-band filter is shown
Fig. 1. (a) Silver painted and (b) copper plated X-band third-order filter.
in Fig. 1(b). A remarkable adhesion of the copper layer to the
plastic surface was found thanks to the paint solvent which
II. SLA M ANUFACTURING AND M ETALLIZATION partially dissolves the plastic underneath. From mechanical
In this Section, the fabrication of waveguide components by pull-off measurement of the copper substrate, an adhesion
an SLA 3-D printing associated with the metal-plating process strength between 137 and 206 N/m2 has been measured. It is
is described. The procedure is illustrated at the example of an interesting to note that the copper layer detached from the
X-band third-order bandpass filter. paint underneath, but the paint did not pull-off from the plastic
The first step is the SLA printing process using a Formlabs structure.
Form 2 3-D printer [13] that produces an accurate plastic
object from a digital model. In order to facilitate the deposition III. R ESULTS
of the silver paint, the structure has been split into halves, Several filtering structures have been designed, manufac-
which are then joined together using screws. tured, and measured to test the fabrication process.
The next step is the creation of the metal-plated layer As shown in Fig. 2, the first structure was a cavity resonator
covering the inner surfaces of the component. The proce- in WR-90 waveguide. The sidewalls of the irises have a
dure proposed in this letter consists of the deposition of a slope of 60° in order to make the painting process easier.
conductive paint layer which activates a subsequent copper The resulting hexagonal cavity is slightly longer than a rec-
electroplating. The final quality of the metal layer depends tangular one with the same resonant frequency. Electromag-
both on the current intensity in the electroplating process netic computations showed no significant difference of the
and on the conductivity of the preactivated surfaces. A silver unloaded Q-factors. The resonator is fed through very narrow
conductive ink combined with the copper electrodeposition irises resulting in a very narrowband and a high external
was found to yield an excellent metallization layer. Q-factor. No compensation for the metal coating thickness
A commercial silver conductive paint [14] was spread over was adopted in the design of the resonator. The measured
the filter inner surfaces by an airbrush. Fig. 1(a) shows the frequency response is compared in Fig. 3 with the HFSS
painted surface of the X-band third-order filter. simulation. An excellent agreement between the measured and
Conductivity tests were performed by measuring the resis- simulated responses is observed. The frequency shift between
tance between various points on the painted surface using the measured (10.197 GHz) and simulated (10.207 GHz)
rounded probe tips in order to avoid the piercing of the resonant frequencies is only 10 MHz, thus proving the good
paint layer. A rectangular sample of the painted plastic has mechanical accuracy. Moreover, the unloaded Q-factors asso-
been cut and the dimensions of the conducting area and ciated with the experimental and simulated responses are
section have been measured. By measuring the resistance very close. For the experimental results the unloaded Q-factor
between the probes at different distances along the sample is 6600, whereas for the simulation results, considering copper
we have obtained a linear regression that gives us the contact conductivity, the unloaded Q-factor is 7600 [15].
resistance of 0.251  and a resistivity of 35.64 m. Due From these data, the equivalent conductivity has also
to difficulty of measurement of the paint thickness that can been evaluated. The resonator’s dimensions and the surface
This article has been accepted for inclusion in a future issue of this journal. Content is final as presented, with the exception of pagination.

DIONIGI et al.: SIMPLE HIGH-PERFORMANCE METAL-PLATING PROCEDURE 3

IV. C ONCLUSION
A simple and cheap metal-plating procedure for plastic
stereolithographically printed microwave structures has been
presented. The technique has been applied on waveguide
resonators and filters up to the X-band showing excellent per-
formance in terms of dimensional tolerances and conductivity
of the metal. Q-factors up to the order of 6500 along with a
conductivity higher than 4 × 107 S/m have been found. The
technique lends itself to the fast and cheap prototyping of
microwave components at least up to the X-band.

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