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Shipbuilding & Equipment | Propulsion & Manoeuvring Technology

Low sulphur diesel can lead


to extensive wear
FUEL LUBRICITY  The phenomenon of abnormal and high pump wear rates caused by the loss
of lubricity in low sulphur diesel fuels are not only well documented, but have been studied
extensively in Europe and North America. Lubricity improvers act to restore the natural lubricity
and reduces the risk of extensive wear.
Ian Crutchley

I
n recent years, international regions, is 0.10% (1,000ppm) ECA’s (emission control areas) ment. In the marine industry,
and regional legislation on by mass. Further to this it must will also reduce to 0.1% by lubricity has never been a fuel
emissions from shipping has be noted that another regula- mass. It should be noted that characteristic, which need be
driven the maximum permissi- tion is now in place on the emission control areas are set considered, until now.
ble sulphur content of marine Californian coast, that dictates to expand, with the Mediter- The definition of lubricity is
fuel down. In the near future that all vessels within 24 nau- ranean Sea and Coastal USA “The intrinsic ability of a fluid
these limits will become even tical miles must use fuel with a expected to follow in the com- to prevent wear on contacting
more stringent. maximum sulphur content of ing years. metal surfaces”. It is a common
From January 1 2010 the maxi- 0.1% by mass. This of course For the time being the use of misconception that lubricity
mum allowable sulphur con- requires the changeover of the heavy fuel oil is acceptable properties can be improved
tent of fuel oil used by ships main propulsion engine. providing the sulphur content simply by increasing viscosity.
“at berth” in EU ports, other In addition from January 1 is at the level required for the There are two distinct regimes
than those in the outermost 2015 to sulphur limit inside particular region where the of lubrication to consider
vessel is sailing. Ultimately when discussing fuel pump
though, except where abate- lubrication – hydrodynamic
ment technology such as ex- lubrication and boundary lu-
haust gas scrubbers have been brication.
employed, these limits could Hydrodynamic lubrication
force a gradual industry change relates to the oil film created
to distillate fuels, from the tra- between the moving compo-
ditional use of heavy fuel oil. nents. This area of lubrication
In any case, there are many im- is directly dependant on the
plications of using low sulphur viscosity of the fuel and is one
fuels that any vessel operator of the reasons the OEM’s are
must consider. One such im- recommending a minimum
plication is the effect sulphur viscosity of 2  cSt when oper-
removal has on the lubricating ating on distillate fuel. If the
properties of the fuel. viscosity is too low the oil film
It is also important to note that can become insufficient and
the International Standards seizure can occur. The other
Organisation has introduced reason for this is that with a
a new version of ISO 8217 – viscosity of less than 2 cSt, ex-
Specification for Marine Fuel. cessive fuel leakage occurs past
In the new version of the the fuel pump plunger and in
standard, released in July 2010, the nozzle needle valve. This
distillate fuels with a sulphur can lead to problems when
s: content of less than 500ppm starting engines and when op-
visit u g
Please 0 in Hambur (0.05%) must be subjected to erating at both high and low
2 0 1
SMM tand 141 the lubricity testing to ensure loads. Such problems on a ma-
,s
Hall B5 sufficient protection. Also, the rine vessel have serious safety
new places a stability limit on implications.
all distillate fuel grades. Lubricity however relates to
the boundary lubrication, and
Implications of poor lubricity to a huge extent the fuel injec-
The introduction of low sul- tion equipment relies on the
phur diesel fuel in automotive characteristics of the fuel for
application the early 1990’s lubrication. Where boundary
had catastrophic effects on lubrication really plays a part
vehicle fuel injection equip- is within fuel pumps where the

14  Ship & Offshore | 2010 | No 4


Fig. 2: Diesel pump rig test Fig. 3: Condition of components relative to pump wear rating

clearance between the plunger primary function is to reduce ing this experience directly to a fuels to be assessed for lubric-
and body is extremely small fuel sulphur content, and is marine engine, illustrates that ity behaviour. This necessitat-
and can decrease further when an essential refinery process in the supply of one bunker of ed the need for a rapid labo-
the components reach opera- order to produce the low sul- poor lubricity fuel could po- ratory bench test which could
tional temperature. Boundary phur content fuels the specifi- tentially result in the failure of discriminate between fuels of
lubrication dictates that to a cations demand. However, the fuel injection equipment. good and poor lubricity.
certain extent the substance processing not only removes The experience in automotive
penetrates the surface of the the sulphur, it also removes the application led the industry to Test for lubricity
moving components creating naturally occurring polar com- investigate diesel lubricity in The standard way to measure
a mono molecular layer. This ponents which give a fuel in- detail and provide means for lubricity of a fuel is the 
reduces the friction between herent lubricity. Therefore sul-
the contacting metal surfaces phur content is not necessarily
and prevents excessive wear. a direct correlation with re-
Therefore boundary lubrica- spect to fuel lubricity although
tion is just as, if not more im- there is a strong likelihood that
portant than hydro dynamic a low sulphur fuel or one of its
lubrication in the case of fuel blend components has been
pumps. hydro-processed. Equally fuels
With insufficient boundary lu- of a higher sulphur content,
brication within fuel injection i.e. > 500 ppm can potentially
equipment excessive and ac- exhibit poor lubricity depend-
celerated wear can be expected ing on the crude oil source and
and premature failures there- the processing which the fuel
after. The areas most affected has undergone.
by this are fuel pumps without Lubricity was little understood
external lubrication sources. or appreciated until the early
Typically this applies to indi- 1990’s when low sulphur die-
vidual cylinder reciprocating sels (< 500 ppm) appeared in
fuel pumps or common rail the market for automotive use.
pumps. Failures such as this Very quickly thereafter vehicles
would be extremely costly, not using such fuels experienced �1�0�0
only in financial terms, but problems, with excessive wear
also in terms of safety and lost and failure of the rotary fuel �9�5
time. injection pumps. Across all
Another common miscon- manufacturers it is estimated �7�5
ception is that the sulphur in up to 65 million pumps were
the fuel provides the lubric- affected by this. Failures oc-
ity characteristics. This is not curred quickly and it was re-
strictly correct and the sulphur ported that fuel pump failure �2�5
content itself is not the main was occurring after only 5,000
cause of poor lubricity. In fact – 10,000 kilometres, which at �5
it is the processing used in a an average speed of 50 km/hr
refinery for removing sulphur, equates to 100 – 200 hours of �0
commonly termed hydro- operation. In terms of a ma-
processing which impacts fuel rine engine this is a very short
lubricity. Hydro-processing’s operating period and translat-

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Ship & Offshore | 2010 | No 4   15
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Shipbuilding & Equipment | Propulsion & Manoeuvring Technology

HFRR (High Frequency Reciprocating Rig) against a horizontally mounted station- stroke length are specified. The ambient
test as per IP450 / ASTM D6079 / CEC F- ary steel plate with an applied load. The conditions are used to correct the size of
06-A-96. In the HFRR test a sample of the test ball is oscillated at a fixed frequency the wear scar generated on the test ball to
fluid under test is placed in a test reser- and stroke length while the interface with a standard set of ambient conditions. The
voir which is maintained at the specified the plate is fully immersed in the fluid corrected wear scar diameter (WSD) is a
test temperature. A fixed steel ball is held reservoir. The metallurgies of the ball and measure of the fluid lubricity.
in a vertically mounted chuck and forced plate, temperature, load frequency and The HFRR test has been adopted in many
fuel specifications as the standard method
to evaluate lubricity. During its develop-
ment correlation with the more time con-
suming diesel pump rig test, conducted
using a Bosch pump known to have expe-
rienced problems in the field was estab-
lished.
This test consists of a Bosch pump driven
by an electric motor at varying specific
speeds. Forty litres of fuel is continuously
cycled through the pump for 100 hours,
at which time the fuel is replaced with
a further 40 litres of fresh fuel. This test
is repeated with the same components
10 times, making a total of 1,000 hours
testing using 400 litres of fuel. Upon
dismantling of the rig the critical wear
components are rated between 1 and 10,
using a visual rating system developed by
Fig 4: Correlation between pump wear rating and HFRR  Source: Robert Bosch GmbH Bosch. An overall rating below 3.5 was
deemed a pass and demonstrated life-
time performance (100%). A rating of 4
– 6 indicated a reduced lifetime (20%)
and a rating of 7 – 10 was a fatal break-
down (1%).
Figure 3 illustrates the condition of com-
ponents relative to the pump wear rating
and HFRR. Figure 4 shows the results of
the above described tests and the clear
correlation between the two methods.

Limits for lubricity


For the automotive industry, the correla-
tion chart in figure 4 demonstrates the
correlation between a pump wear rating
limit of 3.5 and a typical HFRR limit of
460μm included in many automotive fuel
Fig. 5: Working mechanism of OctamarTM lubricity improver specifications. It is important to note that
in terms of test precision, the repeatability
of this test is +/- 60μm.
European specification for automotive
diesel fuel EN590 specifies the maximum
at 460μm. The American ASTM standard
states a maximum of 520μm Fuel injec-
tion manufacturers recommend a maxi-
mum of 400μm. The new version of ISO
8217 (Specification for Marine Fuels)
states a maximum of 520μm.
The ISO committee has clearly recog-
nised that lubricity is a characteristic
which must be considered when dealing
with low sulphur marine distillate fuels.
However there is still debate around the
proposal in this standard. The ISO has
adopted the ASTM limit of 520μm but it
is possible that this limit may be unsatis-
factory in order to protect fuel systems. It
can be argued that the conditions inside a
Fig. 6: Sulphur content Vs HFRR wear scar Vs OctamarTM lubricity improver treat rate marine engine fuel pump are much more

16  Ship & Offshore | 2010 | No 4


matically reducing the WSD. Bearing
in mind that the proposed ISO 8217
indicates that the lubricity limit is not
required for fuels with above 500  ppm
(0.05%) it is important to note that this
diagram clearly indicates that fuels with
500 ppm sulphur (0.05%) can measure
above this limit.

The author:
Ian Crutchley, Technical Coordinator
Marine, Innospec Specialty Chemi-
cals, Ellesmere Port, UK
Left: Unaged base fuel
Middle: Aged base fuel
Right: Aged fuel containing
Innospec FOA Additive

severe than those within an automotive


engine, and therefore perhaps the pro-
posed limit should be lower. In addition
the proposal states that only fuels with
less than 500 ppm require testing, which
is clearly suggesting that fuels above this
level are safe, and that lubricity and sul- Precision
phur content correlate. This is not the case
and to reinforce this point Innospec has
tested fuels with sulphur contents above is our
500 ppm which have failed the proposed
limit of 520μm (see figure 6).
It is interesting to note that the addition strength
of the requirement for HFRR lubricity
testing, and the other additional test re-
quirements of the proposed ISO 8217, HEINZMANN Common Rail Solutions are
will require additional investment by ma-
rine fuel testing laboratories. This in turn the best choice for your engine application
could result in the price and time required
for ISO 8217 fuel testing to increase dra-
matically. ODYSSEUS Common Rail
Lubricity improvers Solutions
Innospec has been supplying lubricity im-
 System pressure up to 2000 bar
provers for use in transport fuel globally
for almost 20 years and has unparalleled  Various sizes of injectors and pumps
knowledge on the subject of lubricity. This
proven technology has now been redevel-  Applicable for different diesel fuel
oped to be suitable for low sulphur ma- qualities, including heavy fuel oil
rine fuel and has been integrated into the
Innospec OctamarTM product range.  All components from one supplier:
OctamarTM lubricity improvers act to Complete package of common rail
restore the natural lubricity of middle fuel injection equipment, EFI control
distillate fuels with low intrinsic lubric-
units, application software and
ity, or in fuels that have been affected by
sulphur removal processes at the refinery. spare parts
This works by addressing the boundary  Long term experience in EFI
lubrication regime, re-forming the mono-
technology and in EFI engine
molecular layer which is absorbed on the
surface of the components. commissioning Heinzmann GmbH & Co. KG
Am Haselbach 1
Figure 6 illustrates the HFRR response D-79677 Schönau/Germany
of various sulphur content marine dis- Phone: +49 7673 8208 - 0
tillate fuels, at increasing dosage rates Fax: +49 7673 8208 - 188
Email: info@heinzmann.de
of OctamarTM lubricity improver. In all
See us at Booth No. 411 in Hall A3 www.heinzmann.com
cases, ranging from 500 ppm to 10 ppm
the HFRR response is excellent, dra-

Ship & Offshore | 2010 | No 4   17

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