Helping Make

Products Better™

Amines for Water Treatment

Safety and Handling
This bulletin is offered as a guide to the handling and storage of BASF Amines. The
information contained herein is the best available to BASF Corporation and is suppled as a
service to our customers. BASF CORPORATION CANNOT AND DOES NOT ASSUME ANY
WARRANTY OBLIGATIONS FOR THE ACCURACY OF INFORMATION CONTAINED HEREIN.
THE CUSTOMER IS ENCOURAGED TO USE THIS AND ALL OTHER PUBLICLY AVAILABLE
INFORMATION DEALING WITH THESE PARTICULAR PRODUCTS

For Material Safety data sheets go to:

www.worldaccount.basf.com

For more details on products go to:

basf.com/products
Contents

page
Physical Properties
3-Methoxypropylamine 1
Cyclohexylamine 1
Diethylethanolamine 2
Morpholine 2
Flash Point Dissolution Chart 3

Health and Physical Hazards

3-Methoxypropylamine 4
Cyclohexylamine 5
Diethylethanolamine 6
Morpholine 7

Ecotoxicity and Biodegradation

Measures of Aquatic Toxicity 8
Environmental Fate 8

Transportation-Storage-Handling
General 9
Shipping 9
Bulk Storage Tanks 10
Cleaning Storage Tanks 10
Ground Requirements 10
Storage Temperatures 11
Inert Gas Blanketing 11
General Tank Operating Recommendations 11
Spill Containment / Removal 11
Lines and pumps 12
Lubricants 12
Vapor Return Line 12
Vents 12
Level Indicators 12
Filters 12
Bulk Handling Facilities, Figures 1a, 1b 13
Safety Precautions during Tank Filling 14
Rail Car Unloading 14
Tank Truck Unloading 15
Drum Storage and Handling 16
Laboratory Handling 16
Storage 16
Work Area 16
Waste Disposal 16
Drumming Procedure 17
3-Methyoxypropylamine
Physical Property Data

Chemical Name: 3-Methoxy-1-propanamine CH3 O CH2 CH2 CH2 NH2

Cas Reg. No. 5332 - 73 - 0
Formula: C4H11NO
Molecular Weight: 89.1 g/mol

Property Units Values

Boiling Point @ 760 mm Hg °C / °F 118 / 224.4

Density, 20° C g / ml 0.87

Freezing Point °C / °F <-70 / -94

Flash Point (closed cup) °C / °F 27 / 80.6

Autoignition Temperature °C / °F 270 / 518

Flammability Limits Lower Limit Vol. % 2.3

Upper Limit Vol. % 12.3

Vapor Pressure @20° C mbar 16

Cyclohexylamine
Physical Property Data

Chemical Name: Cyclohexylamine

Cas Reg. No. 108 - 91 - 8
Formula: C6H13N NH2
Molecular Weight: 99.2 g/mol

Property Units Values

Boiling Point @ 760 mm Hg °C / °F 134 / 273.2

Density, @ 20° C g / ml 0.87

Freezing Point °C / °F -18 / -0.4

Flash Point (closed cup) °C / °F 27 / 80.6

Autoignition Temperature °C / °F 265 / 509

Flammability Limits Lower Limit Vol. % 1.6

Upper Limit Vol. % 9.4

Vapor Pressure @20° C mbar 14

1
Diethylethanolamine
Physical Property Data

Chemical Name: 2-Diethylaminoethanol CH3 CH2

Cas Reg. No. 100 - 37 - 8 N CH2 CH2 OH
Formula: C6H15NO CH3 CH2
Molecular Weight: 117.2 g/mol

Property Units Values

Boiling Point @ 760 mm Hg °C / °F 162 / 323.6

Density, @ 20° C g / ml 0.88

Freezing Point °C / °F -70 / -94

Flash Point (closed cup) °C / °F 51.5 / 124.7

Autoignition Temperature °C / °F 270 / 518

Flammability Limits Lower Limit Vol. % 0.7 (39° C)

Upper Limit Vol. % 10.1 (92.5° C)

Vapor Pressure @20° C mbar 1.9

Morpholine
O

Physical Property Data

Chemical Name: Tetrahydro-1,4-oxazine N

Cas Reg. No. 110 - 91 - 8
Formula: C4H9NO H
Molecular Weight: 87.1 g/mol

Property Units Values

Boiling Point @ 760 mm Hg °C / °F 129 / 264.2

Density, @ 20° C g / ml 1

Heat of Vaporization (20° C) cal / g 120.6

(128.3° C) cal / g 101.6

Freezing Point °C / °F -5 / 23

Flash Point (open cup) °C / °F 32 / 89.6

Autoignition Temperature °C / °F 275 / 527

Flammability Limits Lower Limit Vol. % 1.4

Upper Limit Vol. % 13.1

Vapor Pressure, @20° C mbar 10

2
Flash Point of Amine Solutions

200

180
Flash Point in Degree F

160

140

120

100

80
100

80
90

85

70

65
95

60

50
75

55
Percent of Amines in Aqueous Solutions
DEEA

Morpholine

CHA

3
Health Hazards
3-Methoxypropylamine

Toxicity

Acute Overexposure Effects Exposure Limits

• 3-Methoxypropylamine is corrosive
to body tissues.
• Skin contact with the liquid or vapors/mists
can cause deep burns.
• Eye contact can result in burns and
permanent injury.
• Ingestion may result in severe gastric
disturbances and corrosive damage.
• May cause sensitization by skin contact.
Chronic Overexposure Effects
There are no known chronic effects associated
with 3-methoxypropylamine.
First Aid Measures
Skin:
Remove contaminated clothing.
Wash affected areas with water.
Get immediate medical attention.
Launder contaminated clothing before reuse.
There are currently no regulatory exposure limits
established for 3-methoxypropylamine. The
American Industrial Hygiene Association has pub-
lished workplace environmental exposure levels
(WEEL). For 3-Methoxypropylamine, this guideline
value is 5 ppm, as an 8 hour time weighted average
and 15 ppm as a short term exposure limit (15min.).
General Personal Protection Data
Use the following personal protective equipment
when handling amines:
• Butyl rubber gloves, boots and aprons.
• Chemical splash goggles and full face shields
• If vapors or mists are generated wear a NIOSH
approved organic vapor/mist respirator.
• Safety showers and eyewash fountains should be
easily accessible.
• Tools used when handling amines should be
constructed of a non-sparking alloy.
• Exhaust fan motors should be explosion-proof.

Eyes:
Immediately wash eyes with running water for 15
minutes. Get immediate medical attention.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Dilute
with water or milk and get immediate medical
attention. Never give fluids or induce vomiting if
the victim is unconscious or having convulsions.

Inhalation:
Move to fresh air. Aid in breathing, if necessary,
and get medical attention.

4
Cyclohexylamine
Toxicity
Acute Overexposure Effects
• Cyclohexylamine is corrosive to body tissues.
It can be absorbed in toxic amounts through
the skin.
• Skin contact with the liquid or vapors/mists
may result in deep burns.
• Eye contact may result in burns and
permanent injury.
• Inhalation of cyclohexylamine may result in
irritation, lightheadedness, drowsiness, anxiety,
nausea, and vomiting.
• Cyclohexylamine is toxic by ingestion.
Chronic Overexposure Effects
• Cyclohexylamine has produced embryotoxicity,
low birth count, post-natal mortality, and
decreased body weight in laboratory animals in
high doses.
• Cyclohexylamine is embryotoxic, but not
carcinogenic or teratogenic. No effects have
been seen in humans.
First Aid Measures
Skin:
Remove contaminated clothing. Wash affected
areas with water. Get immediate medical attention.
Launder contaminated clothing before reuse.
Eyes:
Immediately wash eyes with running water for 15
minutes. Get immediate medical attention.
5
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Dilute
with water or milk and get immediate medical
attention. Never give fluids or induce vomiting if
the victim is unconscious or having convulsions.
Inhalation:
Move to fresh air. Aid in breathing, if necessary, and
get medical attention.
Exposure Limits
• The American Conference of Governmental
Industrial Hygients (ACGIH) Threshold Limit Value
(TLV) is 10 ppm as a time-weighted average.
General Personal Protection Data
When handling amines the following personal
protective equipment should be used:
• Butyl rubbers gloves, boots and aprons.
• Chemical splash goggles and full face shields.
• If vapors or mists are generated wear a NIOSH
approved organic vapor/mist respirator.
• Safety showers and eyewash fountains should be
easily accessible.
• Tools used when handling amines should be con-
structed of an non-sparking alloy.
• Exhaust fan motors should be explosion-proof.
Diethylethanolamine
Toxicity
Acute Overexposure Effects
• Diethylethanolamine is corrosive to body tissues.
• Skin contact with the liquid or vapors/mists may
result in deep burns.
• Eye contact may result in burns and
permanent injury.
• Ingestion may result in severe gastric
disturbances and corrosive damage.
• May cause sensitization by skin contact.
Chronic Overexposure Effects
Repeated inhalation exposures in rats for 14 weeks
at 76ppm showed respiratory irritation, corneal
opacities, nasal lesions and effects in the liver and
kidneys.
First Aid Measures
Skin:
Remove contaminated clothing. Wash affected
areas with water. Get immediate medical attention.
Launder contaminated clothing before reuse.
Eyes:
Immediately wash eyes with running water for
15 minutes. Get immediate medical attention.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Dilute
with water or milk and get immediate medical
attention. Never give fluids or induce vomiting if
the victim is unconscious or having convulsions.
Inhalation:
Move to fresh air. Aid in breathing, if necessary,
and get medical attention.
6
Exposure Limits
• The current NIOSH and OSHA exposure limit for
Diethylethanolamine is 10 ppm (50 mg/m3).
8 hour time weighted average.
• The ACGIH Threshold Limit Value (TLV) is 2 ppm
as a time-weighted-average.
• NIOSH/OSHA and ACGIH values also include a
“skin” notation, indicating the DEEA may be
absorbed through the skin.
General Personal Protection Data
When handling amines the following personal
protective equipment should be used:
• Butyl rubber gloves, boots and aprons.
• Chemical splash goggles and full face shields.
• If vapors or mists are generated wear a NIOSH
approved organic vapor/mist respirator.
• Safety showers and eyewash fountains should be
easily accessible.
• Tools used when handling amines should be
constructed of a non-sparking alloy.
• Exhaust fan motors should be explosion-proof.
Morpholine
Toxicity

Acute Overexposure Effects Exposure Limits

• Morpholine is corrosive to body tissues.
• Skin contact with the liquid or vapors/mists
may result in deep burns.
• Eye contact may result in burns and permanent
injury.
• Acute overexposure to morpholine vapors results
in respiratory irritation and transient eye irritation.
• Temporary foggy vision has been reported.
Chronic Overexposure Effects
• Repeated skin applications with morpholine
caused skin, liver, and kidney injury in rabbits.
• Rats and guinea pigs exposed to 18,000 ppm
morpholine exhibited eye and respiratory
irritation. Repeated exposures caused lung,
liver and kidney injury.
• In a 13-week inhalation study with rats morpho-
line caused nasal lesions at 100 and 250 ppm; no
effects were seen at 25 ppm.
• In an industry sponsored study, morpholine was
carcinogenic to rats at 10, 50, 100 ppm; but
did cause ophthalmic and nasal lesions.
• The current NIOSH and OSHA exposure limits for
Morpholine are 20 ppm (70 mg/m3) TWA with a
skin notation.
• The current NIOSH short term exposure limit
(STEL) is 30 ppm.
• The ACGIH Threshold Limit Value (TLV) is
20 ppm TWA, with a skin notation.
General Personal Protection Data
When handling amines the following personal
protective equipment should be used:
• Butyl rubber gloves, boots and aprons.
• Chemical splash goggles and full face shields.
• If vapors or mists are generated wear a NIOSH
approved organic vapor/mist respirator.
• Safety showers and eyewash fountains should be
easily accessible.
• Tools used when handling amines should be
constructed of a non-sparking alloy.
• Exhaust fan motors should be explosion-proof.

First Aid Measures

Skin:
Remove contaminated clothing. Wash affected
areas with water. Get immediate medical attention.
Launder contaminated clothing before reuse.

Eyes:
Immediately wash eyes with running water for 15
minutes. Get immediate medical attention.

Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Dilute
with water or milk and get immediate medical
attention. Never give fluids or induce vomiting if
the victim is unconscious or having convulsions.

Inhalation:
Move to fresh air. Aid in breathing, if necessary,
and get medical attention.

7
Ecotoxicity and Biodegradation
Ecotoxic Effects

Ecotoxic Effects - Cyclohexylamine

Leuciscus idus / LC50 58 - 195 mg/l/96h
Daphnae (acute), EC/LC50 (24 h) 49 - 80 mg/l
Algae, EC/LC50 (96 h) 20 mg/l
Bacteria, EC/LC50 (24 h) 54 mg/l

Ecotoxic Effects - Diethylethanolamine

Leuciscus idus / LC50 >100 <200 mg/l/96h
Daphnae (acute), EC/LC50 (48 h) 83.6 mg/l
Algae, EC/LC50 (72 h) 30 mg/l

Ecotoxic Effects - Morpholine

Oncorhynchus / LC50 20 - 380 mg/l/96h
Daphnae (acute), EC/LC50 (24 h) 100 mg/l
Algae, EC/LC50 (96 h) 28 mg/l
Bacteria, EC/LC50 (16 h) >310 mg/l

Ecotoxic Effects - 3-Methoxypropylamine

Leuciscus idus / LC50 >100 <220 mg/l/96h
Bacteria, EC/LC50 (16 h) >10000 mg/l

Environmental Fate
Cyclohexylamine, Diethylethanolamine, Morpholine and 3-Methoxypropylamine
are alkalines. Before discharging into treatment plants be familiar with federal,
state and local regulations and your sites’ permits. Ensure any discharges
comply with your sites’ environmental operating procedures.

8
Transportation - Storage - Handling
General Handling
The storage, handling and use area for amines should
be well ventilated. Sparkproof motors and tools are
required. All equipment, tank car, truck and hose con-
nections not permanently set must be grounded . See
figure 1a and 1b.
The following publications are excellent references on
safe practices for the storage and handling of flamma-
ble and combustible liquids:
USDOT
The United States Department of Transportation
establishes rules for transporting chemicals. The DOT
information for these four amines is given in Table 1.
Shipping
Standard shipping containers for amines are:
• Rail Cars – Carbon Steel, lined with PLASITE™ 3070
or 3066 20,000 to 27,000 gals. capacity.

Health and Safety References • Tank Trucks – Stainless Steel 5,000 to 6,000 gals.
Available from www.osha.gov capacity.
US OSHA 1910.106 Flammable and Combustable
Liquids • Steel Drums – 55 gallon steel drums,
UN 1A1/X/1.33/300.
Available from www.cdc.gov/niosh
NIOSH Pocket Guide to Chemical Hazards

Available from www.hazmat.dot.gov

Office of Hazardous Materials Safety-Emergency
Response Guidebook

Table 1
DOT Information

3-Methoxypropylamine Diethylethanolamine Cyclohexylamine Morpholine

DOT Proper Amines, liquid, corrosive, Diethylaminoethanol, Cyclohexylamine, Morpholine,

flammable, N.O.S. (3-meth- 8, (3), UN 2686, PG II 8, (3), UN 2357, PG II 8, (3), UN 2054, PG I
Shipping Name oxypropyl amine), 8, (3),
UN 2734, PG I

Primary Hazard 8 8 8 8
(CORROSIVE) (CORROSIVE) (CORROSIVE) (CORROSIVE)
Class
3 3 3 3
Secondary Hazard (FLAMMABLE) (FLAMMABLE) (FLAMMABLE) (FLAMMABLE)
Class

DOT Placard CORROSIVE CORROSIVE CORROSIVE CORROSIVE

required

UN Number 2734 2686 2357 2054

Packaging Group I II II I

E/R Guide 132 132 132 132

9
Bulk Storage Tanks
The specific bulk storage layout for amines must
conform to Federal, state and local regulations.
The preferred material of construction
for amines is stainless steel, however, carbon steel
tanks are also widely used.
Consult 29CFR 1910.106 for applicable OSHA
requirements for flammable and combustible liquid
storage.
A new carbon steel tank should be thoroughly
cleaned by sand blasting, followed by vacuum
cleaning and wiping. If a carbon steel tank is not
filled within two days it should be kept dry by
padding with dry nitrogen. Underground tanks for
storage of amines are not recommended.
Storage tank containment should be constructed of
concrete bottoms and walls. The containment
basin must be large enough to accommodate a
tank’s entire contents. If one basin serves more
than one tank, its capacity must be sufficient to
contain 110% of the contents of the largest tank
plus the maximum rainfall in a 24 hour period over
the last 100 years.
Cleaning Storage Tanks
If it is necessary to clean or repair a storage tank,
both liquid and vapor must be removed from the
entire system including pumps, piping and associ-
ated equipment. Once the liquid is removed, top
and bottom manways can be opened for inspec-
tion. If an internal tank inspection is required, wash
the interior with water and allow the tank to vent for
at least 24 hours. Install blinds on all tank nozzles.
Refer to OSHA 1910.146 permit required confined
spaces.
Table 2
Recommended ground resistances
Service Max. allowed resistance, OHMS
Motor-hazardous area
Tanks and vessels
Pipelines
Tankcar and rails
Before permitting welding or burning operations on
the tank, make sure the vapor content of the tank
atmosphere is below the flammable limit. Before
permitting personnel to enter the tank, check tank
atmosphere for the amine vapor content and car-
bon monoxide and oxygen content as well as all
additional requirements for confined space entry.
Refer to OSHA’s standard of 29CFR 1910.146.
Personnel entering the tank should wear a full
chemical suit, butyl gloves and boots, and respira-
tory protection as defined by your site safety proce-
dures.
The aqueous waste generated during the cleaning
operation must be disposed of in accordance with
Federal, state and local requirements.
Testing
The bulk storage system, tanks and piping should
be hydrostatically tested for leaks before introduc-
ing product. Testing hydrostatically is preferred,
but nitrogen can be used if water contamination is
a concern. If water is used, the tank interior, lines,
pumps and valves should be thoroughly dried
before introducing product.
Ground Requirements
Each part of a bulk handling system including
tanks, pumps, hoses, platforms, tank cars and tank
trucks should be electrically grounded to a ground
rod or other approved ground system. Wire
jumpers should be installed at swivel joints and
other locations to provide an unbroken
low-resistance ground circuit. Recommended
ground resistances are shown in Table 2.
Grounding
3 Ground wire in conduit with circuit
connectors
2-5 Cable to ground
2-5 Driven rods, cables
2-5 Driven rods, cables
10
Storage Temperatures Spill Containment/Removal

1. Morpholine The entire product handling area should be

Morpholine freezes at a temperature of –5° C/
23° F. It is therefore recommended to equip the
tank with a heating system for product storage in
climates where ambient temperatures can cause
freezing. External heating panels, (electric or low
pressure steam), a temperature controller as well
as sufficient insulation are recommended. The
same recommendations apply to transfer lines,
valves and pumps.
2. Cyclohexylamine
Cyclohexylamine freezes at a temperature of
–18° C / -0.4° F. The same recommendations as
tested for morpholine apply if ambient tempera-
tures could cause freezing of the product.
3. Diethylethanolamine
Diethylethanolamine freezes at a temperature of
–68° C / -90.4° F. Heating and insulation of
transfer equipment is not required.
4. 3-Methoxypropylamine
3-Methoxypropylamine freezes at a temperature
of –70° C / -94° F. Heating and insulation of
transfer equipment is not required.
Inert Gas Blanketing
Since the vapor concentration above the product
can be well within the flammable limits, it is essen-
tial to displace the atmospheric oxygen with an
inert gas, preferable dry nitrogen. The inert gas
should be introduced into the tank as a light purge
venting through the vapor line into the vapor control
device.
equipped with adequate spill containment facilities.
The containment area should be constructed of
sealed concrete in order to facilitate the removal of
an accidental spill. Any spill should not be allowed
to enter floor drains connected to sewer systems,
but should drain into spill pit or collection resevoir.
In the event of a spill:
1. Assign trained personnel, with the proper protec-
tive equipment, to clean up. Notify all appropri-
ate authorities. Follow your site’s spill response
and emergency plans.
2. Minimal protective equipment: butyl gloves,
chemical goggles, chemical splash suit and
boots. A self-contained breathing apparatus
(SCBA) maybe required based on the size and
nature of the spill.
3. If needed, use a water spray to reduce vapors.
Provide maximum ventilation until the area is
cleaned up.
4. For small spills, cover with sand, sawdust and/or
other absorbent material. The material can be
placed into containers for later disposal as per
Federal, state and local regulations.
5. Larger spills should be contained and
vacuumed into a vacuum truck for disposal.

General Tank Operating

Recommendations
As shown in figures 1a & b, a storage tank for
amines is normally vented through a line leading to
an emission control device such as a thermal oxi-
dizer. In addition the tank must be protected by a
secondary pressure/vacuum relief device which
can protect the tank if the vent line should become
restricted. It is essential to assure a free vent line
every time before loading or unloading the tank.

11
Lines and Pumps
Centrifugal pumps with mechanical seals or canned
pumps are recommended for transfer service with
amines. Suitable materials for the seals on tanks,
equipment and pipelines required for handling
amines are polytetrafluroethylene (PTFE), polyethyl-
ene, and high-molecular weight polypropylene. All
pipes, pumps, etc. should be made of the same
material as the tank to avoid galvanic corrosion.
The inlet dip tube on the amine storage tank should
extend to 6” from the bottom. A 1/4” diameter hole
should be drilled near the top of the dip tube to act
as a siphon break. Welded or flanged joints are
preferred. Screwed joints should be wrapped with
gasket tape or Teflon® PTFE fluorocarbon fiber to
minimize leaks.
Lubricants
A suitable lubricant for moving parts in contact with
amines is graphite. Oils and grease are unsuitable
and should not be used.
Vapor Return Line
The vapor return line connects the vapor space in
the tank to the vehicle being unloaded. It serves a
double function, i.e. environmental protection and
adherence to product specification, because it does
not allow the product to come into contact with
atmospheric moisture and oxygen.
Vents
Vents to the atmosphere should be fitted with a
flame arrestor. All storage tanks require some
means of preventing vacuum or pressure buildup
as liquid is withdrawn or added and atmospheric
conditions change. Amine tanks should have a
conservation vent with a flame arrestor. An emer-
gency vent must be provided, having sufficient
venting capacity to protect the tank in the event of
fire.
12
Level Indicators
A level indicator should be on each tank.
Differential pressure-type gauges or float-type indi-
cators can be used for measuring tank levels.
Level gauges can be calibrated to indicate depth,
pounds or gallons in the tank. A transmitter can be
connected to the level indicator and tied to one or
more level gauges installed on the plant site. The
installation of a high-level warning device may be
advisable where the carrier unloading spot is at a
distance from the tank. Overflow prevention
devices will automatically shut off the delivery of
product into the tank whenever certain predeter-
mined levels are exceeded. “No load” protection
ensures that the pump for discharging the contents
of the tank is automatically shut off when the level
is a tank falls to a certain minimum.
Filters
Product transferred into the tank as well as product
discharged from the tank should pass through a fil-
ter. Cartridge or bag filters may be used. The
material of contruction of the filter housing and
the filter element should be compatible with the
product. For amine service, stainless steel hous-
ings and cotton for the construction for the filter
cartridges or bags is suggested. The pore size of
the filter element should be 10 micron or less.
13
Safety Precautions during
Tank Filling
1. Upon arrival of bulk-transported amines, the
tanks on the vehicle must be checked to ensure
that the flanged covers, bolts, and seals on the
domed head are intact. Attach the required
grounding cable(s) to the bulk transport vessel.
The recommended ground resistance should not
exceed 2-5 Ohms. Before the flanged cover is
opened, any dirt adhering to its outer surface
must be removed.
2. Rail tank cars and tank trucks must be chocked
during the entire unloading operation, because
any movement of the vehicle may break the con-
nection to the tank.
3. A safety zone of 15 ft. radius must be secured
around the vents on any road tankers, rail tank
cars, or tank containers that have to be dis-
charged.
4. All pipe and hose connections should be pres-
sure tested. Use spill pans under hose connec-
tions or flanges to catch leaks and drips. Dispose
of collected material in accordance with Federal,
state and local regulations.
Rail Car Unloading
General
Assure that the recommended personal protective
equipment is used before proceeding with the
unloading operation. See the products’ MSDS for
recommendations.
Unloading Procedure
1. Set “blue flags.” Chock the wheels of the rail
car. Attach a certified grounding cable to the
frame of the car. See table 2 of this section for
recommended ground resistances.
2. Compare the rail car number with the bill of lad-
ing to ensure that the proper shipment is to be
unloaded. Follow your sites’ quality and operat-
ing procedures.
3. Record the current product temperature if
required.
4. Connect the transfer hose to the bottom outlet
of the rail car.
14
5. All transfer hoses should be equipped with “dry
disconnect couplings”. This type of coupling
significantly reduces product losses/spillage
should accidental disconnection of coupler and
adapter occur, or when disconnecting the hose
after product transfer.
6. Connect the vapor return line to the top flange
of the rail car (if the storage facility is so
equipped).
7. For unloading facilities not equipped with a spill
containment system, place a spill pan under the
bottom outlet of the rail car.
8. Open all vapor return line valves to assure free
vapor flow between the storage tank and the
rail car.
9. Do not loosen the bolts on the dome cover.
10. Open the bottom valve of the rail car and check
for leaks at the hose connections.
11. Open all valves in the product discharge line.
12. Start the transfer pump and check for leaks.
13. If the storage tank is not equipped with a vapor
return line, connect the rail car vent with a
regulated nitrogen supply applying and
maintaining a slight pressure to exclude oxygen
and to prevent the tank car from collapsing.
14. The entire unloading operation should be
continuously supervised by the responsible
operating personnel. Follow your sites’ operat-
ing procedures.
15. Once the car is empty secure the pump and
close all valves on the product discharge line,
vapor line, tank car and storage tank.
16. Secure the nitrogen supply line and disconnect
the hose at the nitrogen inlet of the rail car, and
relieve the pressure on the tank car.
17. Verify that the tank car is completely empty, per
your sites’ unloading procedures.
18. Before closing the manway and tightening the
bolts, assure that an undamaged gasket is in
place.
Tank Truck Unloading
Recommendations for unloading using a pump, are
given below. Since the actual conditions of unload-
ing and handling may vary consult your sites’ oper-
ating procedures.
Assure that the recommended personal protective
equipment is used before proceeding with the
unloading operation. See the products’ MSDS.
Transfer Hose Recommendations
For amines, a stainless steel flex-hose of a
minimum inner diameter of two (2) inches or a
Teflon®- lined chemical hose is recommended.
Vapor line hose connections should follow the
same recommendations. All product transfer
hoses should be equipped with “dry disconnect
couplings”. This type of coupling significantly
reduces product losses/spillage, should accidental
disconnection of coupler and adapter occur, or
when disconnecting the hose after product transfer.
Unloading Procedure
1. Chock the wheels of the tank truck. Attach a
grounding cable to the frame of the truck. See
table 2 of this section for recommended ground
resistances.
2. Compare the trailer number with the bill of
lading to ensure that the proper shipment is to
be unloaded. Follow your sites’ quality and
operating procedures.
3. Record the current product temperature as
shown on the built-in dial thermometer, if
required.
4. Assure that the internal as well as the external
valve is in a closed position. Carefully remove
the cap from the product outlet nozzle of the
compartment and inspect for cleanliness.
15
5. Connect the product transfer hose to the truck
compartment outlet nozzle.
6. Connect the vapor line of the storage tank with
the vent nozzle of the tank truck compartment.
7. If the storage tank is not equipped with a
vapor line, connect the tank truck vent with
a regulated nitrogen supply applying and
maintaining a pressure of 1 to 5 psig.
8. If a vapor line is used, open all valves to assure
free vapor flow between the tank truck com-
partment and the storage tank.
9. Open the internal valve and the external valve of
the truck compartment and check for leaks at
the transfer hose connections.
10. Start transfer pump. Check for leaks.
11. The entire unloading operation should be
continuously supervised by the responsible
operating personnel. Follow your sites’
operating procedures.
12. Once the truck compartment is empty secure
the pump and close all valves on the product
discharge line, vapor line, tank truck and stor-
age tank.
13. Secure the nitrogen supply line and disconnect
the hose at the nitrogen inlet of the truck com-
partment, and relieve the pressure on the tank
truck.
14. Verify that the truck compartment is completely
empty, per your sites’ operating procedures.
16. Before closing the manway and tightening the
bolts, assure that an undamaged gasket is in
place.
Drum Storage and Handling
Drums should be stored in a cool place, protected
from damage and protected from access by
unauthorized persons.
Since morpholine, cyclohexylamine,
diethylethanolamine and 3-methoxypropylamine are
flammable, NFPA guidelines for storage of flammable
materials should be consulted. OSHA also has stan-
dards concerning storage of flammable liquids at 29
CFR 1910.106.
These products can be pumped or transferred by
gravity (if storage is elevated) to the receiving vessel
using standard approved equipment. Precautions for
the handling of flammable or combustible liquids must
be observed. Grounding requirements have to be met
(Table 2).
16
Laboratory Handling
Laboratory personnel assigned to work with amines
should be thoroughly familiar with the physical and
toxicological properties and with the recommended
“safe handling procedures” and the MSDS.
The following techniques are suggested when
handling amines on a small scale in the laboratory.
Storage
Laboratory supplies (bulk quantities) should be stored
outside the laboratory building in closed, grounded
safety cabinets that can be locked. Daily chemical
requirements should be brought into the laboratory in
glass or compatible plastic or metal containers. The
minimum protective equipment should be safety gog-
gles, respirator and neoprene gloves. All traces of
spilled liquid should be washed or removed from the
outside of the container before bringing it into the lab-
oratory.
Work Area
All operations involving amines should be carried out
in a well ventilated area. Any operations carried out in
open containers should be done under a hood. The
hood should have a separate exhaust system such
that exhaust vapors are prevented from being pulled
into the building through the air intakes.
Waste Disposal
Facilities should be provided for safe handling of
amines waste and to prevent their vapors from escap-
ing in the laboratory work area. Portable flammable
solvent waste containers with tightly fitting self closing
lids that are satisfactory for this operation. Laboratory
amines waste should be disposed of in accordance
with local, state and federal requirements. Follow
your state’s waste handling procedures.
Amines Drumming Procedure
Product Certification:
The tank or tank truck to be drummed must be verified.
If a truck shipment is used for drumming, the written
certificate of analysis that accompanies the shipment
should be used for the drummed material. The lot num-
ber shown on the certificate of analysis should be used
for the drummed lot as well, unless otherwise specified.
If a storage tank is used for drumming, the tank should
be sampled and analyzed in order to establish a certifi-
cate of analysis. This certificate is used for the entire
drummed lot and a lot number is assigned as specified
by the drumming batch sheet.
Drum Specifications:
A 55 gal steel drums, UN 1A1/X/1.33/300.
is recommended.
Drumming Station Requirements:
1. The drumming station should be located in a well ven-
tilated area indoors with ample access provided for
drum and pallet movement by forklifts or other materi-
al handling equipment.
2. A drumming station should consist of the following
major components:
-Gravity conveyor for empty drums
-Bung alignment machine
-Drum filling machine
-Palletizing machine
-Control instrumentation
3. In order to eliminate amine vapor releases into the
environment and to minimize human exposure, the
drum filling machine should be equipped with a fume
hood and an exhaust system conveying the amine
vapors to a fume scrubber or vapor incinerator.
4. A drumming check list should be used as a guideline
to help eliminate potential problems. All sections of
the list should be addressed during the drumming
operation. The check list should be signed and
returned to supervision along with the drumming
batch sheet.
Drumming Procedure
Operating personnel assigned to the drumming opera-
tion should be thoroughly familiar with the physical and
toxicological properties and with the recommended
“safe handling procedures” outlined in this brochure and
the product’s MSDS.
Initial Preparations.
• Assure that an adequate supply of drums,
pallets, labels, bung seals, as well as the required
personal protective equipment is available.
17
• Inspect drums for physical damage and assure that
the bungs are closed.
• Tighten the 3/4 inch bung to the torque as specified in
the batch sheet and install a shipping seal.
• Attach the product label and the certificate of analysis
label (if required).
• Line up the drumming line from the appropriate tank or
truck.
• Allow the first few drums to enter the staging area and
remove the 2 inch bung.
• Inspect each drum internally for cleanliness using a
flashlight.
• Start purging the first drum with nitrogen until oxygen
free. This can take several minutes depending on the
nitrogen flow rate.
• Set up the drumming instrumentation to the required
net weight as per batch sheet.
• Before filling the first drum for a customer shipment
flush the entire line through the drumming nozzle. The
required amount of flush depends largely on the local
piping system and has to be determined by analytical
methods.
• Sequentially number each drum (starting with #1) on
the top near the 3/4 bung.
• Proceed with the filling operation.
• If automated drumming equipment is utilized, follow
the manufacturer’s operating instructions.
• Draw drum samples as required by the sampling
schedule.
• Immediately after a drum is filled and sampled install
the 2 inch bung and tighten to the required torque as
specified in the batch sheet. Note: In order to apply
the correct torque to the 3/4” and 2” bungs it is essen-
tial to use a torque wrench. Improperly torqued bungs
tend to leak.
• Check the top of the drum for any traces of product
and wipe clean using a cloth. It is recommended to
use portable flammable waste containers with tightly
fitting self closing lids for the temporary waste storage.
Final disposal of the contaminated cloth should be
done in accordance with state, local and Federal
requirements.
Scale Weight Verification
In order to confirm the accuracy of the drum filling
weight, the scale accuracy should be verified on a bi-
monthly basis and if necessary, re-calibrated using certi-
fied calibration weight standards.
Technical Service and Product Stewardship
BASF Corporation believes that product responsibility
includes both quality control of its products and techni-
cal service regarding safe handling and proper use of
these products. We are prepared to assist customers
with concerns pertaining to the storage and handling of
these products.
BASF: Helping Make Products Better™
BASF is the world’s leading chemical company,
offering its customers a range of high-performance
products, including chemicals, plastics, perform-
ance products, agricultural products, fine chemicals
as well as crude oil and natural gas. Its distinctive
approach to integration, known in German as
“Verbund,” is its strength. It enables BASF to
achieve cost leadership and gives the company a
competitive advantage. BASF conducts its business
in accordance with the principles of sustainable
development. In 2002, BASF had sales of $34 bil-
lion and more than 89,000 employees worldwide.
BASF Corporation is the North American affiliate of
BASF AG, Ludwigshafen, Germany. In North
America, 2002 sales were approximately $8.2 bil-
lion and the company employs approximately
13,000 people. For more information or to receive
news releases by e-mail, visit www.basf.com/usa.

While the descriptions, designs, data and information contained

herein are presented in good faith and believed to be accurate, it
is provided for your guidance only. Because many factors may
affect processing or application/use, we recommend that you
make tests to determine the suitability of a product for your par-
ticular purpose prior to use. NO WARRANTIES OF ANY KIND, EITHER
EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MER-
CHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE
MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS,
DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE
INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL
THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED
BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE.

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©2004 BASF Corporation

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