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Liquid Paraffins
White Oils
Isoparaffins
Polydecenes
Vaselines
Paraffin Waxes
H&R Group
White oils
All grades are odourless, colourless (colour ASTM < 0,5), tasteless and comply fully with purity re-
quirements under DAB, CODEX, BP, USP and all other pharmacopoeias.
PIONIER® Liquid Paraffins are produced in many standard grades covering the viscosity range from
3.5 to 100 cSt/40°C (approx. 38 to 470 SUS/100°F).
Main Applications
These applications are only a few of a wide range of possibilities for the use of Liquid Paraffins.
H&R Group
White oils
PIONIER® Colour Specific Flash Point Pour Point Viscosity Structural Group
ASTM Gravity COC mm²/s Analysis
DIN 51757 DIN 51376 DIN 51597 DIN 51562 DIN 51378
Purity:
H&R Group
White oils
White Oils
Technical Grades
Purity:
H&R Group
White oils
Applications: White Oils Technical - isoparaffinic - PIONIER® are suitable for use in
products with indirect “food contact”. Through their colour and UV-
absorbance performance these products fulfil the requirements for
technical white oils of FDA 21 CFR Ch (4-1 Edition 96); §178.3620 (b).
Solubility
- in water insoluble insoluble insoluble insoluble
- in oil n.a. n.a. n.a. n.a.
Boiling Range Begin
ASTM D 86 °C 304 270 400 ---
760 Torr
Boiling Range End
ASTM D 86 °C 360 400 600 ---
760 Torr
H&R Group
White oils
Colour Hazen / Apha DIN ISO 6271 < 10,0 < 10,0 < 10,0
DIN 51 757
Density at 15°C kg/m³ ASTM D 4052 817 816 820
DIN 51 562 P.1
Viscosity at 25°C mPa*s ASTM D 445/446 1,47 2,1 3,15
DIN 51 423
Refractive Index at 20°C ASTM D 1747 1,446 1,447 1,450
DIN EN ISO 3405
Boiling Range Begin °C ASTM D 86 183 194 234
5 Volume % °C “ 189 201 240
10 Volume % °C “ 192 205 242
50 Volume % °C “ 202 215 245
90 Volume % °C “ 211 224 251
95 Volume % °C “ 213 226 253
Boling Range End °C “ 222 232 261
DIN ISO 3016
Pour Point °C ASTM D 5985 < - 36 < - 36 < - 30
DIN EN 22 719
Flash Point PM °C ASTM D 93 64 74 104
DIN ISO 2977
Aniline Point °C ASTM D 611 64 68 78,4
Aromatics UOP 495-75 < 50 < 50 < 50
DIN 51 378-K
CA / CN / CP % ASTM D 2140 0 / 49 / 51 0 / 45 / 55 0 / 40 / 60
Evaporation Number Ether = 1 DIN 53 170 140 400 ---
Purity FDA 178.3620 a passes passes passes
H&R Group
Isoparaffins
Isoparaffins
Producing Industries:
Applying Industries:
Building industry
Wood working industry Impregnating agent, dewaxing agent
Ceramics and glass industry Mould release agent, static inhibitor, foaming agent (PU)
Metal industry Cleaning, degreasing, anticorrosive solvent
Automobil industry Waxing and dewaxing agent, static inhibitor
Textil and leather industry Surface cleaning agent, impregnating and care agent
Electronic industry Surface cleaning agent, static inhibitor
Printing industry Detergent for rolls, printing-blanket cleaner
Hygiene industry Sanitary field: Solvent for additives
Detergents, cleaning and care sector: Solvent for tensides
H&R Group
Isoparaffins
Isoparaffins
Colour ASTM - DIN ISO 2049 < 0,5 < 0,5 < 0,5 < 0,5 < 0,5
DIN 51 757 P.4
Density 15°C kg/m³ ASTM D 4052 759,5 781 790 808 837
DIN 51 562 P.1
Viscosity 20°C mm²/s ASTM D 445/446 1,82 2,43 3,40 6,65 27,9
3,81
Viscosity 40°C mm²/s “ 1,4 1,69 2,21 12,1
DIN 51 423 S.2
Refractive Index - ASTM D 1747 1,426 1,4337 1,4385 1,4471 1,4608
DIN ISO 2977 Vers.1
Anilin Point °C ASMT D 611 81 82,8 86,6 92,2 102,2
Aromatics UOP mg/kg UOP 495-75 2 23 4 38 140
DIN EN 22 719
Flash Point PM °C ASTM D 93 64 86 101 125 167
DIN ISO 3016
Pour Point ASTM D 97 -70 < -57 < -57 < -45 < -36
Evaporation Rate Ether = 1 DIN 53 170 150 > 500 > 500 > 500 > 500
Sulphuric Acid Test Ph.Eur. passes passes passes passes passes
Carbon Chain % GC C10 - C13 C10 - C14 C13 – C16 C13 - C19 C17
Length
DIN EN ISO 3405
Boiling Range Begin °C ASTM D 86 185 210 231 262 308
Boiling Range End °C “ 210 235 262 303 393
Stand: 07.08.2006
H&R Group
Polydecenes
Polydecene
PIONIER® 0030 SYN FG
1. Description
PIONIER® 0030 SYN FG is a mixture of iso-paraffins which are produced synthetically. This product
is pure, inert, colourless and odourless. It was authorized under the denomination “Hydroge-
nated poly-1-decene” as a food additive according to the Directive 2004/457/EC. This means a
real alternative to the medicinal and vegetable oils in the foodstuffs industry. Also the pharma-
ceutical and cosmetic industries can profit of the versatile characteristics of this oil. Compared
to vegetable oils which oxidize very quick becoming rancid and viscous,
PIONIER® 0030 SYN FG is thermal- and UV-stable.
2. Chemical Denomination
3. Production
Basic material is usually the synthetic gas ethane which is polymerized up to by passing the in-
termediate stage of the Alpha-Decene. Contrary to mineral oil this production procedure results
in a highly pure and in its composition exactly defined chemical compound of isoparaffins with
carbon-chain lengths of C20, C30, C40, C50 and C60. Afterwards the mixture is distillated and
hydrogenated twice. Due to its chemical connection with mineral oils the purity of this product
can be reviewed in accordance with the monography “Paraffinum liquidum” Ph.Eur. The test
results are excellent in particular the behaviour against sulphuric acid.
4. Product Declaration
CTFA-Trade name: Polydecene / PIONIER® 0030 SYN FG (CTFA File Number: 1943)
INCI-Name: Hydrogenated polydecene
CAS-Nr.: 68037-01-4
EINECS-Nr.: No longer polymer list 500-183-1
JAPAN: Alpha-Olefin Oligomer no. 502029 (Sho-Gai-Ki, all categories)
E-No.: 907
H&R Group
Polydecenes
Polydecene
PIONIER® 0030 SYN FG
The purity criteria for E 907 “Hydrogenated Poly-1-decene” were published in the Directive
2004/45/EC.
The Food Additive Approval Regulation regulates the use of this product as coating agent
(Part B, Pt. kk E 907) for confections, dried fruits and nuts with a limit of 2 g/kg.
6. Analytical Values
Viscosity / 20 °C 60 - 85
Viscosity / 40 °C 29 - 34 mm2/s DIN 51 562
Viscosity 100 °C 5,5 - 6,2
H&R Group
Polydecenes
Polydecene
PIONIER® 0030 SYN FG
Oral Administration: A 14/28 day oral administration did not give any signs of toxic effects.
Polydecene PIONIER® 0030 SYN FG proved to be non- toxic. (Mecon 96, 3 month Oral Toxicity Study,
No.: 20-04-0154/00-96). Polydecene food grade proved to be non-toxic on rats even when admin-
istered in very high concentrations in the food (90 day oral administration in dietary concentrations
of up to 5 %). Under the microscope no treatment related effects were found and no evidence
of hepatotoxicity or deposition in lymphoid tissue or liver. This is a remarkable contrast to findings of
white oils where 2 % added to food caused significant changes in the liver and lymphatic glands.
Deposition of mineral oil in a grain-like form is characteristic. There was also a proof for a damage
of the liver (Baldwin et al. 1992, Toxicologic Pathalogy 20; 426.435)
Instillation of hydrogenated polyalphaolefin in rabbits eyes did not produce any corneal opacity,
nor congestion, swelling or discharge of iris or conjunctivae when observed at 1, 24, 48 or 72 hours
postinstillation regardless of whether the eyes were flushed with water after instillation of the test
agent.
7.4. Inhalation
As for all oils, inhalation of oil mist is toxic and harmul for the lungs.
No erythema, edema or necrosis was observed in any of the rabbits upon examination immedi-
ately following a 4, 24, 48, and 72h dermal contact with the hydrogenated polyalphaolefin.
25 % of hydrogenated polyalphaolefin in white mineral oil did not produce any erythema or
edema after a test containing 10 days of sensitization dosing, two weeks of rest following chal-
lenge treatment. The hydrogenated polyalphaolefin is classified as non-sensitizer. A test with 75 %
of PIONIER® 0030 SYN FG in PEG 400 covering an observation time of 24 and 48 h respectively did
not produce any irritation. This concentration of PIONIER® 0030 SYN FG is classified as non sensitizer
(RCC, OECD Number 406 ‚‘Skin Sensitization‘‘ Project 669622).
H&R Group
Polydecenes
Polydecene
PIONIER® 0030 SYN FG
7.7. Microbiology
7.8. Ecotoxicity
PAO‘s and polydecene have been tested for fish (rainbow trout), algae (Selenastum Capricomu-
tum), and daphnia (Daphnia Magna).
The SCF Commission (Scientific Committee for Food) in its function as advisory board of the
European Commission for Food Additives has effected extensive evaluations of the toxicologic
surveys published by the CONCAWE.
The SCF Commission (Scientific Committee for Food) in its function as advisory board of the
European Commission for Food Additives has effected extensive evaluations of the toxicologic
surveys published by the CONCAWE.
Also the JECFA (Expert Committee on Food Additives), an organization of the Joint FAO (Food and
Agriculture Organization of the United Nation) and the WHO (World Health Organization) publish
ADI-values.
A comparison of the ADI-values published by the mentioned boards says that PIONIER 0030 SYN
FG, with an ADI-value of 0-6 mg/kg / body weight, is comparable with high-viscous medicinal
white oils based on mineral oil. Such oils show ADI-values of 0-10 mg/kg / body weight (JECFA) or
0-4 mg/kg / body weight (SCF). Extra liquid mineral oils show even lower ADI values in compari-
son with PIONIER® 0030 SYN FG.
Considering that high viscous medicinal white oils were recommended by the IKW for lip care
products due to the ADI-values, it argues for the substitution of this substance by the well-compat-
ible PIONIER® 0030 SYN FG.
H&R Group
Polydecenes
Polydecene
PIONIER® 0030 SYN FG
For this reason PIONIER® 0030 SYN FG is qualified with its ADI-value of 0-6 mg/kg / body weight as
recommendable substitute for this application area.
SCF
ADI 4 mg/kg for medicinal white oils with following specification:
Viscosity > 8,5 mm²/s at 100 °C
C-Number after 5% distil off > 25 after 5% distil off
Molecular Weight > 480
H&R Group
Polydecenes
Polydecene
PIONIER® 0030 SYN FG
9. Cosmetic Recommendations
PIONIER® 0030 SYN FG is moisturizing, not occlusive and harmless from the toxicological and allergological
point of view. Topical administered polydecenes are reabsorbed quickly, remaining in the horny layer.
They could not be proved in epidermis or corium. The skin does not become fatty, however pleasantly
smooth with a silky, fresh feeling. Therefore the oil is optimally suitable as super-fatting and glossing agent.
Also excellent is the compatibility with a wide spectrum of cosmetic components, such as emulsifiers,
pigments, antioxidants, thickeners, UV-filters and other active agents. The product is suited for sun care
products, creams, cleaning and care lotions, lipsticks, baby and massage oils, etc.
Test conditions: 10 women with an average age of 43,2 tested PIONIER® 0030 SYN FG simultaneously with
PIONIER® 6301 CN 40 (a white medicinal oil of the same viscosity class) during 29 days. The depth of the
wrinkles was measured with a 3D-PRIMOS equipment.
Conclusion: PIONIER® 0030 SYN FG causes a noticeable reduction of the wrinkle depth in comparison to
medicinal oil.
Biological degradability: PAO‘s/Polydecene show a better biodegradability than conventional mineral oils.
WGK: 1
H&R Group
Polydecenes
Polydecene
PIONIER® 0030 SYN FG
12. Pollution
Heavy metal: As-, Cd-, Sb-, Hg-, Pb-, Ni- content: < 1 ppm DIN 396 TI
PCA‘s: The PCA‘s value reads < 10 ppb
Other harmful substances: under detection limit / n.a.
Pesticides: n.a.
Liquid product, bulk in road tankers or packed in containers with 25-850 kg.
H&R Group
Vaselines
Main Applications
Softeners, lubricants, preservatives, isolating compounds, release agents, glossing agents, plasti-
cizers, anti-corrosion agents, sealing compounds, carrier for pigments, etc.
H&R Group
Vaselines
CODEX/Ph.Eur.
17004 53 60 < 1,0 white 155 7,1
BP/USP
5,2
17146 Ph.Eur./BP/USP 52 55 160 5,8
light yellow
22
5353 Ph.Eur./BP/USP 51 59 164 7,0
yellow
H&R Group
Paraffin waxes
Paraffin Waxes
Pharmaceutical-Cosmetic / Technical
Drawing Paraffins
H&R WAX 54/56 P 472 55 0,7 22 4,2
H&R WAX 56/58 P 527 DAB 57 0,5 18 4,0
Specialties
H&R WAX 45/47 46 0,7 45 2,7
H&R WAX 48/50 49 0,5 25 3,1
Microwaxes
H&R Micro 75 76 1,2 21 18
H&R Micro SLV 73 2,0 25 15
H&R Micro S 2530 74,5 1,2 27 18
H&R Group
Hansen & Rosenthal KG Tel. +49 (40) 432 18-0
Klaus Dahleke KG Fax +49 (40) 432 18-400
Tudapetrol KG export.sales@hansen-rosenthal.de
H&R WAX Company Vertrieb GmbH
H&R Vertrieb GmbH
Am Sandtorkai 64
D-20457 Hamburg, GERMANY
H&R GSP Co. (HK) Ltd. Tel +86 (20) 3618 2975
Guangzhou Repr. Office Fax +86 (20) 8666 0658
Suite 433, Parkview Square info.asia@hur-gsp.com
906 Jie Fang Bei Road
Guangzhou 510040 CHINA
H&R GSP Pty (New Zealand Branch) Ltd. Tel +64 (9) 919 2402
Building 2, Suite B, Unit 2b, 5 Ceres Court Fax +64 (9) 919 2404
Mairangi Bay
Aucklang, NEW ZEALAND
H&R Group
H&R Group
Am Sandtorkai 64
D-20457 Hamburg
Germany
E-Mail export.sales@hansen-rosenthal.de
Web www.hansen-rosenthal.com
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tion is free of errors. However, Hansen & Rosenthal KG cannot accept any liability nor can they guarantee that the informa-
tion provided is up-to-date, accurate or complete.
Hansen & Rosenthal KG reserves the right to make amendments or additions to the information provided without notice.
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with information provided on this documentation.
H&R Group