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Mortar (masonry)

Mortar is a workable paste used to bind building blocks such as stones, bricks, and
concrete masonry units together, fill and seal the irregular gaps between them, and
sometimes add decorative colors or patterns in masonry walls. In its broadest sense
mortar includes pitch, asphalt, and soft mud or clay, such as used between mud
bricks. Mortar comes from Latin mortarium meaning crushed.

Cement mortar becomes hard when it cures, resulting in a rigid aggregate structure;
however the mortar is intended to be weaker than the building blocks and the
sacrificial element in the masonry, because the mortar is easier and less expensive to Mortar holding weathered bricks
repair than the building blocks. Mortars are typically made from a mixture of sand, a
binder, and water. The most common binder since the early 20th century is Portland
cement but the ancient binder lime mortar is still used in some new construction. Lime and gypsum in the form of plaster of Paris are
used particularly in the repair and repointing of buildings and structures because it is important the repair materials are similar to the
original materials: The type and ratio of the repair mortar is determined by a mortar analysis. There are several types of cement
mortars and additives.

Ancient mortar
Ordinary Portland cement mortar
Polymer cement mortar
Lime mortar
Pozzolanic mortar
Firestop mortar
Radiocarbon dating
See also

Ancient mortar
The first mortars were made of mud and clay. Because of a lack of stone and an abundance of clay, Babylonian constructions were of
baked brick, using lime orpitch for mortar. According to Roman Ghirshman, the first evidence of humans using a form of mortar was
at the Mehrgarh of Baluchistan in Pakistan, built of sun-dried bricks in 6500 BCE.[1] The ancient sites of Harappan civilization of
third millennium BCE are built with kiln-fired bricks and a gypsum mortar. Gypsum mortar, also called plaster of Paris, was used in
the construction of the Egyptian pyramids and many other ancient structures. It is made from gypsum, which requires a lower firing
temperature. It is therefore easier to make than lime mortar and sets up much faster which may be a reason it was used as the typical
mortar in ancient, brick arch and vault construction. Gypsum mortar is not as durable as other mortars in damp conditions.

In early Egyptian pyramids, which were constructed during the Old Kingdom (~2600–2500 BCE), the limestone blocks were bound
by mortar of mud and clay, or clay and sand.[3] In later Egyptian pyramids, the mortar was made of eithergypsum or lime.[4] Gypsum
mortar was essentially a mixture ofplaster and sand and was quite soft.
In the Indian subcontinent, multiple cement types have been observed in the sites of
the Indus Valley Civilization, such as the Mohenjo-daro city-settlement that dates to
earlier than 2600 BCE. Gypsum cement that was "light grey and contained sand,
clay, traces of calcium carbonate, and a high percentage of lime" was used in the
construction of wells, drains and on the exteriors of "important looking buildings."
Bitumen mortar was also used at a lower-frequency, including in the Great Bath at

Historically, building with concrete and mortar next appeared in Greece. The
excavation of the underground aqueduct of Megara revealed that a reservoir was
coated with a pozzolanic mortar 12 mm thick. This aqueduct dates back to c. 500
BCE.[7] Pozzolanic mortar is a lime based mortar, but is made with an additive of
volcanic ash that allows it to be hardened underwater; thus it is known as hydraulic
cement. The Greeks obtained the volcanic ash from the Greek islands Thira and
Nisiros, or from the then Greek colony of Dicaearchia (Pozzuoli) near Naples, Italy.
The Romans later improved the use and methods of making what became known as
pozzolanic mortar and cement.[4] Even later, the Romans used a mortar without
pozzolana using crushed terra cotta, introducing aluminum oxide and silicon dioxide Roman mortar on display at
Chetham's School of Music.
into the mix. This mortar was not as strong as pozzolanic mortar, but, because it was
denser, it better resisted penetration by water.[8]

Hydraulic mortar was not available in ancient China, possibly due to a lack of volcanic ash. Around 500 CE, sticky rice soup was
mixed with slaked lime to make an inorganic−organic composite sticky rice mortar that had more strength and water resistance than
lime mortar.[9][10]

It is not understood how the art of making hydraulic mortar and cement, which was perfected and in such widespread use by both the
Greeks and Romans, was then lost for almost two millennia. During the Middle Ages when the Gothic cathedrals were being built,
the only active ingredient in the mortar was lime. Since cured lime mortar can be degraded by contact with water, many structures
suffered from wind blown rain over the centuries.

Ordinary Portland cement mortar

Ordinary Portland cement mortar, commonly known as OPC mortar or just
cement mortar, is created by mixing powdered Ordinary Portland Cement, fine
aggregate and water.

It was invented in 1794 by Joseph Aspdin and patented on 18 December 1824,

largely as a result of efforts to develop stronger mortars. It was made popular during
the late nineteenth century, and had by 1930 became more popular than lime mortar
Laying bricks with Portland cement
as construction material. The advantages of Portland cement is that it sets hard and
quickly, allowing a faster pace of construction. Furthermore, fewer skilled workers
are required in building a structure with Portland cement.

As a general rule, however, Portland cement should not be used for the repair or repointing of older buildings built in lime mortar,
which require the flexibility, softness and breathability of lime if they are to function correctly

In the United States and other countries, five standard types of mortar (available as dry pre-mixed products) are generally used for
both new construction and repair. Strengths of mortar change based on the ratio of cement, lime, and sand used in mortar. The
ingredients and the mix ratio for each type of mortars are specified under the ASTM standards. These premixed mortar products are
designated by one of the five letters, M, S, N, O, and K. Type M mortar is the strongest, and Type K the weakest. These type letters
are taken from the alternate letters of the words "MaSoN wOrK".
Polymer cement mortar
Polymer cement mortars (PCM) are the materials which are made by partially
replacing the cement hydrate binders of conventional cement mortar with polymers.
The polymeric admixtures include latexes or emulsions, redispersible polymer
powders, water-soluble polymers, liquid thermoset resins and monomers. It has low
permeability, and it reduces the incidence of drying shrinkage cracking, mainly
designed for repairing concrete structures. One brand of PCM is MagneLine.

Lime mortar
Mortar mixed inside a 5-gallon
The setting speed can be increased by using impure limestone in the kiln, to form a bucket using clean water and mortar
hydraulic lime that will set on contact with water. Such a lime must be stored as a from a bag. When it's the right
dry powder. Alternatively, a pozzolanic material such as calcined clay or brick dust consistency as in the photo (trowel
stands up) it's ready to apply.
may be added to the mortar mix. Addition of a pozzolanic material will make the
mortar set reasonably quickly by reaction with the water

It would be problematic to use Portland cement mortars to repair older buildings originally constructed using lime mortar. Lime
mortar is softer than cement mortar, allowing brickwork a certain degree of flexibility to adapt to shifting ground or other changing
conditions. Cement mortar is harder and allows little flexibility. The contrast can cause brickwork to crack where the two mortars are
present in a single wall.

Lime mortar is considered breathable in that it will allow moisture to freely move through and evaporate from the surface. In old
buildings with walls that shift over time, cracks can be found which allow rain water into the structure. The lime mortar allows this
moisture to escape through evaporation and keeps the wall dry. Re−pointing or rendering an old wall with cement mortar stops the
evaporation and can cause problems associated with moisture behind the cement.

Pozzolanic mortar
Pozzolana is a fine, sandy volcanic ash. It was originally discovered and dug at Pozzuoli, nearby Mount Vesuvius in Italy, and was
subsequently mined at other sites, too. The Romans learned that pozzolana added to lime mortar allowed the lime to set relatively
quickly and even under water. Vitruvius, the Roman architect, spoke of four types of pozzolana. It is found in all the volcanic areas of
Italy in various colours: black, white, grey and red. Pozzolana has since become a generic term for any siliceous and/or aluminous
additive to slaked lime to create hydraulic cement.[14]

Finely ground and mixed with lime it is a hydraulic cement, like Portland cement, and makes a strong mortar that will also set under

Firestop mortar
Firestop mortars are mortars most typically used to firestop large openings in walls and floors required to have a fire-resistance
rating. They are passive fire protection items. Firestop mortars differ in formula and properties from most other cementitious
substances and cannot be substituted with generic mortars without violating thelisting and approval use and compliance.

Firestop mortar is usually a combination of powder mixed with water, forming a cementatious stone which dries hard. It is sometimes
mixed with lightweight aggregates, such as perlite or vermiculite. It is sometimes pigmented to distinguish it from generic materials
in an effort to prevent unlawful substitution and toenable verification of thecertification listing.
Mortar constituents.
Firestopped cable tray penetration. Cable tray cross barrier firestop
The cables and the tray are test, full scale wall

Radiocarbon dating
As the mortar hardens, the current atmosphere is encased in the mortar and thus provides a sample for analysis. Various factors affect
the sample and raise the margin of error for the analysis [15] , [16] , [17] . [18] The possibility to use radiocarbon dating as a tool for
mortar dating was introduced as early as the 1960’s, soon after the method was established (Delibrias and Labeyrie 1964; Stuiver and
Smith 1965; Folk and Valastro 1976). The very first data were provided by van Strydonck et al (1983), Heinemeier et al.(1997) and
Ringbom and Remmer (1995). Than the methodological aspect were developed by different groups (an international team headed by
Åbo Akademi University, and teams from CIRCE, CIRCe, ETHZ, Poznań, RICH and Milano-Bicocca laboratory. To evaluate the
different anthropogenic carbon extraction methods for radiocarbon dating as well as to compare the different dating methods, i.e.
[19] . [20]
radiocarbon and OSL, the first intercomparison study (MODIS) was set up and published in 2017

See also
Cement accelerator Thick bed mortar (technique)
Concrete Thinset
Energetically modified cement Tuckpointing

Technical data sheets, Mortar Industry Association, www

1. "Ancient Bricks" (https://www.academia.edu/1285495/Bricks_and_urbanism_in_the_Indus_Valley_rise_and_decline).

Aurangzeb Khan. Retrieved 2013-02-16.
2. "Introduction to Mortars" Cemex Corporation(http://www.cemex.co.uk/Userfiles/datasheets/mortar-intro-to-mortar.pd
3. "Egypt: Egypt's Ancient, Small, Southern, Step Pyramids"(http://www.touregypt.net/featurestories/smallstep.htm).
Touregypt.net. 2011-06-21. Retrieved 2012-11-03.
4. "HCIA - 2004" (http://www.hcia.gr/3a.html). Hcia.gr. Retrieved 2012-11-03.
5. O. P. Jaggi, History of science and technology in India, V
olume 1 (https://books.google.com/books?id=Qm3NAAAAM
AAJ), Atma Ram, 1969, "... In some of the important-looking buildings, gypsum cement of a light gray colour was
used on the outside to prevent the mud mortar from crumbling down. In a very well constructed drain of the
Intermediate period, the mortar which was used contains a high percentage of lime instead of gypsum. Bitumen was
found to have been used only at one place in Mohenjo-daro. This was in the construction of the great bath"...
6. Abdur Rahman, History of Indian science, technology, and culture (https://books.google.com/books?id=4bnaAAAAM
AAJ), Oxford University Press, 1999,ISBN 978-0-19-564652-8, "... Gypsum cement was found to have been used in
the construction of a well in Mohenjo-daro. The cement was light grey and contained sand, clay
, traces of calcium
carbonate, and a high percentage of lime ..."
7. [1] (http://www.iwaponline.com/ws/00701/0165/007010165.pdf)
8. "American Scientist Online"(http://www.americanscientist.org/template/AssetDetail/assetid/17236/page/5).
Americanscientist.org. Retrieved 2012-11-03.
9. "Revealing the Ancient Chinese Secret of Sticky Rice Mortar"(http://www.sciencedaily.com/releases/2010/05/10053
0093704.htm). Science Daily. Retrieved 23 June 2010.
10. Yang Fuwei, Zhang Bingjian, Ma Qinglin (2010). "Study of Sticky Rice−Lime Mortar T
echnology for the Restoration of
Historical Masonry Construction".Accounts of Chemical Research. 43: 936–944. doi:10.1021/ar9001944 (https://doi.
11. Masonry: the best of Fine homebuilding.. Newtown, CT: Taunton Press, 1997. Print. 113.
12. "Information about Lime - LimeWorks.us" (http://limeworks.us/info-all.php). limeworks.us. Retrieved 2016-11-02.
13. "ASTM C 270-51T" (http://www.astm.org/SNEWS/DECEMBER_2006/p_melander_dec06.html). ASTM International.
Retrieved 10 September 2015.
14. "pozzolana." Collins English Dictionary - Complete & Unabridged 10th Edition
. HarperCollins Publishers. 14 May.
2014. <Dictionary.com http://dictionary.reference.com/browse/pozzolana>
15. Folk RL, Valastro S. (1979). Dating of lime mortar by 14C(Berger R, Suess H. ed.). Proceedings of the Ninth
International Conference: Berkeley: University of California Press. pp. 721–730.
16. Hayen R, Van Strydonck M, Fontaine L, Boudin M, Lindroos A, Heinemeier J, Ringbom A, Michalska D, Hajdas I,
Hueglin S, Marzaioli F, Terrasi F, Passariello I, Capano M, Maspero F, Panzeri L, Galli A, Artioli G, Addis A, Secco M,
Boaretto E, Moreau C, Guibert P, Urbanova P, Czernik J, Goslar T, Caroselli M. (2017). "Mortar dating methodology:
intercomparison of available methods".Radiocarbon. 59 (6).
17. Hayen R, Van Strydonck M, Boaretto E, Lindroos A, Heinemeier J, Ringbom Å, Hueglin S, Michalska D, Hajdas I,
Marzaoili F, Maspero F, Galli A, Artioli G, Moreau Ch, Guibert P
, Caroselli M (2016). Absolute dating of mortars –
integrating chemical and physical techniques to characterize and select the mortar samples . Proceedings of the 4th
Historic Mortars Conference - HMC2016. pp. 656–667.
18. Dating Ancient Mortar (http://www.americanscientist.org/issues/feature/2003/2/dating-ancient-mortar)- American
Scientist Online vol. 91, 2003
19. Hajdas I, Lindroos A, Heinemeier J, Ringbom Å, Marzaioli ,FTerrasi F, Passariello I, Capano M, Artioli G, Addis A,
Secco M, Michalska D, Czernik J, Goslar T , Hayen R, Van Strydonck M, Fontaine L, Boudin M, Maspero ,FPanzeri
L, Galli A, Urbanova P, Guibert P. (2017). "Preparation and dating of mortar samples—Mortar Dating Inter-
comparison Study (MODIS)".Radiocarbon. 59 (6).
20. Hayen R, Van Strydonck M, Fontaine L, Boudin M, Lindroos A, Heinemeier J, Ringbom A, Michalska D, Hajdas I,
Hueglin S, Marzaioli F, Panzeri L, Galli A, Artioli G, Addis A, Secco M, Boaretto E, Moreau C, Guibert ,PUrbanova P,
Czernik J, Goslar T, Caroselli M, (2017). "Mortar dating methodology: intercomparison of available methods".
Radiocarbon. 59 (6).

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