Hallando n

Tiempo:
t=3s

v=

Formula de los gases ideales

𝑷𝑽 = 𝒏𝑹𝑻

𝑷𝑽
𝒏=
𝑹𝑻

𝑷𝑽
𝒏=
𝑹𝑻

𝟎. 𝟖𝟒𝟒𝒂𝒕𝒎 ∗ 𝑽
𝒏=
𝒂𝒕𝒎 ∗ 𝒍
𝟎. 𝟎𝟖𝟐 ∗ 𝟑𝟎𝟎. 𝟏𝟓°𝑲
𝒎𝒐𝒍 ∗ °𝑲

𝟎. 𝟖𝟒𝟒𝒂𝒕𝒎 ∗ 𝟎. 𝟎𝟎𝟑 𝑳
𝒏=
𝒂𝒕𝒎 ∗ 𝒍
𝟎. 𝟎𝟖𝟐 ∗ 𝟑𝟎𝟎. 𝟏𝟓°𝑲
𝒎𝒐𝒍 ∗ °𝑲

𝒏 =0.00010 mol
 𝟎. 𝟖𝟒𝟒𝒂𝒕𝒎 ∗ 𝟎. 𝟎𝟎𝟖𝑳
𝒏=
𝒂𝒕𝒎 ∗ 𝑳
𝟎. 𝟎𝟖𝟐 ∗ 𝟑𝟎𝟎. 𝟏𝟓°𝑲
𝒎𝒐𝒍 ∗ °𝑲

𝟎. 𝟖𝟒𝟒𝒂𝒕𝒎
𝒏=
𝒂𝒕𝒎 ∗ 𝑳
𝟎. 𝟎𝟖𝟐 ∗ 𝟑𝟎𝟎. 𝟏𝟓°𝑲
𝒎𝒐𝒍 ∗ °𝑲

𝒏 = 𝟎. 𝟎𝟎𝟎𝟐𝟕mol

𝟎.𝟖𝟒𝟒𝒂𝒕𝒎∗𝟎.𝟎𝟏𝟐𝒍
n= 𝒂𝒕𝒎∗𝒍
𝟎.𝟎𝟖𝟐 ∗𝟑𝟎𝟎.𝟏𝟓°𝑲
𝒎𝒐𝒍∗°𝑲

n= 0.00041mol

Hallando la concentración del oxígeno ([O2 ] )

Formula de gases ideales = 𝑷 * V = n * R * T

𝒏 𝒎𝒐𝒍
Despejando se tiene: [O2 ] = =
𝑽 𝑻 (𝑳) 𝑳

Reemplazando datos en la fórmula en tiempo (3 s):

0.00010 (mol) mol

[O2 ] = = 0.00366
0.028 (L) L

Reemplazando datos en la fórmula en tiempo (6 s):

0.00027 (mol) mol

[O2 ] = = 0.00827
0.033 (L) L
Reemplazando datos en la fórmula en tiempo (9 s):

0.00041(mol) mol
[O2 ] = = 0.01107
0.037 (L) L

Hallando [𝐇𝟐𝐎]

t=3s
n=0.00366
𝐦𝐨𝐥
[𝐇𝟐𝐎] ( )=2*0.00366
𝐋
𝐦𝐨𝐥 𝐦𝐨𝐥
𝐇𝟐𝐎] ( )= 0.00731
𝐋 𝐋

t=6s
n=0.00827
𝐦𝐨𝐥
[𝐇𝟐𝐎] ( )==2*0.00827
𝐋
𝐦𝐨𝐥 𝐦𝐨𝐥
𝐇𝟐𝐎] ( )=𝟎. 𝟎𝟏𝟔𝟓𝟓
𝐋 𝐋

t=9s
n=0.00827
𝐦𝐨𝐥
[𝐇𝟐𝐎] ( )==2* 0.01107
𝐋
𝐦𝐨𝐥 𝐦𝐨𝐥
𝐇𝟐𝐎] ( )=0.02214
𝐋 𝐋

Hallando la concentración inicial del peróxido de hidrógeno en la

reacción química.

El peróxido de hidrógeno con un volumen de 10 mL.

Peso molecular del H2O2 = 34.0146g/mol
Densidad molar = 1.45g/mL,
Donde la molaridad [M] se expresa de la siguiente manera.
 masa
𝐃𝐞𝐧𝐬𝐢𝐝𝐚𝐝 =
volumen

Despejando: 𝐌𝐚𝐬𝐚 = ρ ∗ V
Reemplazando datos:
g
[H2 O2 ] = 1.45 H O × 10 mL H2 O2 = 14. 5 g
mL 2 2

moles de soluto
𝐅𝐨𝐫𝐦𝐮𝐥𝐚 𝐝𝐞 𝐥𝐚 [M]=
litros de solucion

gramos de soluto
[M] = PM de soluto
litros de soluto

14.5 g H2 O2
g
34.0146 H O
[𝐇𝟐 𝐎𝟐 ] = mol 2 2
1 L solución

mol H2 O2
[𝐇𝟐 𝐎𝟐 ] = 0.4262875
1 L de solución

[𝐇𝟐 𝐎𝟐 ] = 0.426 mol / L

Donde la reacción química balanceada es:

𝐶𝑎𝑡𝑎𝑙𝑎𝑠𝑎
2 𝐻2 𝑂2 (𝑙) → 𝑂2 (𝑔) + 2 𝐻2 𝑂(𝑙)

Donde la cantidad de moles en la reacción es:

2 𝑚𝑜𝑙 → 1 𝑚𝑜𝑙 + 2 𝑚𝑜𝑙

 Donde el valor inicial de moles en la reacción era:

0.426 𝑚𝑜𝑙 → 0 𝑚𝑜𝑙 + 0 𝑚𝑜𝑙

Hallando la [H2O2] (mol/L)

La concentración inicial del peróxido de hidrogeno es = 0.426 mol / L

[H2O2] = [H2O2]o - [O2 ]1

[H2O2] en tiempo 3s

[H2O2] t = 3 s = 0.42600 - 0.00366 = 0.42234

[H2O2] en tiempo 6s

[H2O2] t = 6 s = 0.42234 - 0.00827 = 0.41407

[H2O2] en tiempo 9s

[H2O2] t = 9 s = 0.41407 - 0.02214 = 0.40300

Δ[H2O2] (mol)

𝜟[𝑯𝟐𝑶𝟐](𝒎𝒐𝒍) = [𝑯𝟐𝑶𝟐]𝟐 − [𝑯𝟐𝑶𝟐]𝟏

𝜟[𝑯𝟐𝑶𝟐](𝒎𝒐𝒍) = 0.42234 − 0.42600 = −0.00366

𝜟[𝑯𝟐𝑶𝟐](𝒎𝒐𝒍) = 0.41407 − 0.42234 = −0.00827

𝜟[𝑯𝟐𝑶𝟐](𝒎𝒐𝒍) = 0.40300 − 0.41407 = −0.01107

Hallando velocidad inicial (mol/s)

𝜟[𝑯𝟐 𝑶𝟐 ]𝒕=𝟎𝑺 = 0
Δt=3
𝜟[𝑯𝟐 𝑶𝟐 ]
𝑽=
𝜟𝒕
−0.00122
𝑽=
3
𝑽 = 𝜟[𝐻2 𝑂2 ]𝑡=3𝑆 = −0.00366

𝜟[𝑯𝟐 𝑶𝟐 ]
𝑽=
𝜟𝒕
𝜟[𝑯𝟐 𝑶𝟐 ]𝒕=𝟔𝑺 = −𝟎. 𝟎𝟎𝟏𝟐𝟐
𝜟[𝑯𝟐 𝑶𝟐 ]
𝑽=
𝜟𝒕
𝜟[𝑯𝟐 𝑶𝟐 ]𝒕=𝟗𝑺 = −𝟎. 𝟎𝟎𝟖𝟐𝟕
𝜟[𝑯𝟐 𝑶𝟐 ]
𝑽=
𝜟𝒕
 Volumen Volumen n=PV/RT O2 n/V [H2O2] Δ[H2O2] Δ[H2O2]/Δt
t(s) V (mL) Δt 2[H2O]
(L) total (mol) (mol/L) (mol/L) (mol) (mol/s)
0 0 0 0 0.025 0 0 0 0.42600 0 0
3 3 3 0.003 0.028 0.00010 0.00366 0.00731 0.42234 -0.00366 -0.00122
6 8 3 0.008 0.033 0.00027 0.00827 0.01655 0.41407 -0.00827 -0.00103
9 12 3 0.012 0.037 0.00041 0.01107 0.02214 0.40300 -0.01107 -0.00092
12 15.7 3 0.0157 0.0407 0.00054 0.01317 0.02633 0.38984 -0.01317 -0.00084
15 19 3 0.019 0.044 0.00065 0.01474 0.02948 0.37510 -0.01474 -0.00078
18 22.5 3 0.0225 0.0475 0.00077 0.01617 0.03233 0.35893 -0.01617 -0.00072
21 24 3 0.024 0.049 0.00082 0.01672 0.03343 0.34221 -0.01672 -0.00070
24 26 3 0.026 0.051 0.00089 0.01740 0.03480 0.32482 -0.01740 -0.00067
27 27 3 0.027 0.052 0.00092 0.01772 0.03544 0.30709 -0.01772 -0.00066
30 27.5 3 0.0275 0.0525 0.00094 0.01788 0.03575 0.28922 -0.01788 -0.00065
33 28 3 0.028 0.053 0.00096 0.01803 0.03606 0.27119 -0.01803 -0.00064
36 28.5 3 0.0285 0.0535 0.00097 0.01818 0.03636 0.25301 -0.01818 -0.00064
39 29 3 0.029 0.054 0.00099 0.01833 0.03666 0.23468 -0.01833 -0.00063
42 29.2 3 0.0292 0.0542 0.00100 0.01839 0.03677 0.21629 -0.01839 -0.00063
45 29.5 3 0.0295 0.0545 0.00101 0.01847 0.03695 0.19782 -0.01847 -0.00063
48 30 3 0.03 0.055 0.00102 0.01862 0.03723 0.17920 -0.01862 -0.00062
51 30.5 3 0.0305 0.0555 0.00104 0.01876 0.03751 0.16044 -0.01876 -0.00061
54 30.8 3 0.0308 0.0558 0.00105 0.01884 0.03768 0.14161 -0.01884 -0.00061
57 30.8 3 0.0308 0.0558 0.00105 0.01884 0.03768 0.12277 -0.01884 -0.00061
𝜟𝒕 = 𝒕𝒇 – 𝒕𝒊

𝜟𝒕 = 𝟑 − 𝟎 = 𝟎

𝜟𝒕 = 𝟔 − 𝟑 = 𝟎

𝜟𝒕 = 𝟗 − 𝟔 = 𝟑

𝑯𝒂𝒍𝒍𝒂𝒏𝒅𝒐 𝒆𝒍 𝑽𝒐𝒍𝒖𝒎𝒆𝒏 (𝑳)

𝟏𝑳
𝟑𝒎𝒍 ∗ = 𝟎. 𝟎𝟎𝟑𝑳
𝟏𝟎𝟎𝟎 𝒎𝒍

𝟏𝑳
𝟖𝒎𝒍 ∗ = 𝟎. 𝟎𝟎𝟖𝑳
𝟏𝟎𝟎𝟎 𝒎𝒍

𝟏𝑳
𝟏𝟐𝒎𝒍 ∗ = 𝟎. 𝟎𝟏𝟐𝑳
𝟏𝟎𝟎𝟎 𝒎𝒍

𝑯𝑨𝑳𝑳𝑨𝑵𝑫𝑶 𝑬𝑳 𝑽𝑶𝑳𝑼𝑴𝑬𝑵 𝑻𝑶𝑻𝑨𝑳 𝑨𝑺𝑼𝑴𝑬𝑰𝑵𝑫𝑶 𝟐𝟓 𝒎𝒍 𝑬𝑵 𝑳𝑨 𝑴𝑨𝑵𝑮𝑼𝑬𝑹𝑨

𝑺𝒖𝒎𝒂𝒎𝒐𝒔 𝒄𝒐𝒏 𝒆𝒍 𝒗𝒐𝒍𝒖𝒎𝒆𝒏.

𝟎. 𝟎𝟐𝟓𝑳 + 𝟎. 𝟎𝟎𝟑𝑳 = 𝟎. 𝟎𝟐𝟖𝑳

𝟎. 𝟎𝟐𝟓𝑳 + 𝟎. 𝟎𝟎𝟖𝑳 = 𝟎. 𝟎𝟑𝟑𝑳

𝟎. 𝟎𝟐𝟓𝑳 + 𝟎. 𝟎𝟏𝟐𝑳 = 𝟎. 𝟎𝟑𝟕𝑳