COEFICIENTES DE ACTIVIDAD A DILUCION INFINITA

Componente N° Asig Y

Acetato de metilo 61 1 2.79

Metanol 30 2 3.02

Estimacion de los coeficientes binarios Tao Valores de τ

τ12 0.71073926 τ12 0.545
τ 21 0.4517809 τ 21 0.5819
α 12 0.3

Lado 1 Lado2 Fobj

1.0260415958 1.02604182 5.0058E-14
1.1052568314 1.10525658 6.1214E-14
1.1127E-13

Calculo de las constantes G

G12 0.80797693
G21 0.87324924
 Tao 12 0.71073926
Tao 21 0.4517809
G12 0.80797693
G21 0.87324924

x x
1 2
Acetatp de metilo Mteanol g-acetato de metilo g-metanol Ing-acetato de metilo
0.0001 0.9999 2.7894531131 1.00000001 1.0258455598
0.005 0.995 2.7628198277 1.00002454 1.0162518349
0.036 0.964 2.6028279073 1.00127408 0.9565985106
0.1 0.9 2.3142590489 1.00989861 0.839089571
0.23 0.77 1.8654535482 1.05389637 0.6235042129
0.27 0.73 1.7565364081 1.07524593 0.5633439201
0.329 0.671 1.6159039643 1.11431025 0.4798945303
0.41 0.59 1.4558945565 1.18455759 0.3756205271
0.545 0.455 1.2568673837 1.35510698 0.2286224218
0.664 0.336 1.1360939592 1.58168453 0.1275960274
0.75 0.25 1.0746004109 1.80919777 0.0719488817
0.85 0.15 1.0268624351 2.17050602 0.0265079737
0.92 0.08 1.0077014436 2.50960851 0.0076719389
0.94 0.06 1.0043470792 2.62330158 0.0043376579
0.98 0.02 1.0004871647 2.8776493 0.0004870461
0.99 0.01 1.0001220948 2.94746291 0.0001220874
0.9999 0.0001 1.0000000122 3.01926 1.22413179340099E-08
 3
Ing-metanol
9.81348564910679E-09 2.8
2.45371974378481E-05
2.6
0.0012732723
0.0098499391 2.4
0.0524941239
2.2
0.0725494049
0.1082356059 2
0.1693693654
0.3038804045 1.8

0.4584904394 1.6
0.5928835268
0.774960331 1.4

0.9201267687 1.2
0.9644336705
1.0569737455 1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
1.0809447707
g-a cetato de metilo g-meta nol
1.1050117682
 Tao 12 0.7107392605
Tao 21 0.4517808969
Alfa 12 0.3
G12 0.8079769257
G21 0.6941768387

x x
1 2
Acetato de metilo Metanol g-acetato de metilo g-metanol Ing-acetato de metilo
0.0001 0.9999 2.7893786799 1.0000000111 1.0258188757
0.005 0.995 2.7591877478 1.0000278214 1.0149363422
0.036 0.964 2.5804013534 1.0014280755 0.9479449502
0.1 0.9 2.2688076905 1.0108523183 0.819254447
0.23 0.77 1.8103312205 1.0568049394 0.5935098233
0.27 0.73 1.7035158033 1.0784432691 0.5326942351
0.329 0.671 1.5679557157 1.1173533243 0.449772679
0.41 0.59 1.4167297346 1.1857605544 0.3483512118
0.545 0.455 1.2325942633 1.3466456187 0.2091211054
0.664 0.336 1.1226531573 1.5534636774 0.1156947743
0.75 0.25 1.067092028 1.7559879438 0.0649372179
0.85 0.15 1.0241200704 2.0702413452 0.0238337759
0.92 0.08 1.0069094933 2.3590447387 0.0068857321
0.94 0.06 1.0038992267 2.4547928867 0.0038916444
0.98 0.02 1.0004367924 2.6672986495 0.000436697
0.99 0.01 1.0001094589 2.7252491535 0.0001094529
0.9999 0.0001 1.000000011 2.7846874446 0.000000011
 3

Ing-metanol
1.1147653392E-08
0.000027821
0.0014270568
0.0107938545
0.0552501481
0.0755185838
0.1109627855
0.1703843868 2
0.2976167735
0.4404870684
0.5630316295
0.7276651924
0.8582567654
0.8980423938
0.9810662185
1.0025598564
1.0241356389

1
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

g-a cetato de metil o g-metanol

.7 0.8 0.9 1

nol
 x x
1 2
Acetato de metilo Metanol g-acetato de metilo NTRL g-metanol NTRL
0.0001 0.9999 2.7894531131 1.0000000098
0.005 0.995 2.7628198277 1.0000245375
0.036 0.964 2.6028279073 1.0012740833 3.5
0.1 0.9 2.3142590489 1.0098986095
0.23 0.77 1.8654535482 1.0538963692
0.27 0.73 1.7565364081 1.0752459272 3
0.329 0.671 1.6159039643 1.1143102525
0.41 0.59 1.4558945565 1.1845575927
0.545 0.455 1.2568673837 1.3551069817 2.5
0.664 0.336 1.1360939592 1.5816845333
0.75 0.25 1.0746004109 1.8091977713
0.85 0.15 1.0268624351 2.1705060236
2
0.92 0.08 1.0077014436 2.5096085095
g-acetato de metil o NTRL
0.94 0.06 1.0043470792 g-meta nol NTRL
2.6233015827
g-acetato de metil o NRTL-C
0.98 0.02 1.0004871647 2.8776492998
g-meta nol NRTL-C 1.5
0.99 0.01 1.0001220948 2.9474629127
0.9999 0.0001 1.0000000122 3.0192599999

0.5

0
0
 NTRL-C
g-acetato de metilo NRTL-C g-metanol NRTL-C
2.7893786799 1.0000000111
2.7591877478 1.0000278214
2.5804013534
3.5 1.0014280755
2.2688076905 1.0108523183
1.8103312205 1.0568049394
1.7035158033
3 1.0784432691
1.5679557157 1.1173533243
1.4167297346 1.1857605544
1.2325942633
2.5 1.3466456187
1.1226531573 1.5534636774
1.067092028 1.7559879438
1.0241200704 2.0702413452
2
acetato de metil o NTRL 1.0069094933 2.3590447387
meta nol NTRL 1.0038992267 2.4547928867
acetato de metil o NRTL-C
1.0004367924 2.6672986495
meta nol NRTL-C 1.5
1.0001094589 2.7252491535
1.000000011 2.7846874446

0.5

0
0 0.2 0.4 0.6 0.8 1 1.2