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Parcial 1
PRIMER PROBLEMA
1. Tabla
Zn 0
𝑍𝑛2+ -35.184
ZnO -76.88
(𝑍𝑛𝑂𝐻)+ -133.63
H2O -56.69
2. Ecuaciones y cálculos
𝒁𝒏𝟐+ + 𝟐𝒆 → 𝒁𝒏
∆𝐺 ° = ∆𝐺°𝑧𝑛 − ∆𝐺°𝑧𝑛2+
∆𝐺 ° = 0— (−35.184)
∆𝐺 ° = 35.184
35184
∆𝐺 ° = 2(23062)
∆𝐺 ° = −0.7628𝑉
0.0592
𝐸° = −0.7628 − ln 𝑄
2
0.0592
𝐸° = −0.7628 − ln 102
2
𝐸° = −0.822
𝒁𝒏 + 𝟐𝑯 → 𝒁𝒏 + 𝑯𝟐 𝑶
∆𝐺 ° = 0 + (−56.69) − (−76.88 − 0)
∆𝐺 ° = 22.19
2219
𝐸 ° = 2(23062)
𝐸 ° = −0.481
0.0592
𝐸 = 𝐸° − ln 𝑄
2
[𝑍𝑛][𝐻2 𝑂]
𝑄=
[𝑍𝑛𝑂][𝐻]2
0.0592
𝐸° = −0.481 − ln[𝐻]2
2
0.0592
𝐸° = −0.481 − (−2 ln[𝐻])
2
𝐸° = −0.481 + 0.0592𝑝𝐻
𝒁𝒏 + 𝑯𝟐 𝑶 → 𝒁𝒏(𝑶𝑯)+ + 𝑯
∆𝐺 ° = (−76.88 + 0) − (−59.69)
∆𝐺 ° = 22.06
2206
𝐸 ° = 2(23062)
𝐸 ° = −0.478
0.0592
𝐸 = 𝐸° − ln 𝑄
2
[𝐻][𝑍𝑁(𝑂𝐻)+ ]
𝑄=
[𝑍𝑛][𝐻2 𝑂]
0.0592
𝐸 = −0.478 − (ln 102 + log[𝐻])
2
0.0592
𝐸 = 𝐸° − 0.39956 − 𝑝𝐻
2
0.0592
𝐸 = −0.7844 − 𝑝𝐻
2
𝒁𝒏𝑶 + 𝟐𝑯 → 𝒁𝒏𝟐+ + 𝑯𝟐 𝑶
∆𝐺 ° = −12.994
−129994
𝐸 ° = 2(23062)
∆𝐺°
𝑒 =𝐾
𝑅𝑇
3.391𝐸9 = 𝐾
[𝐻2 𝑂][𝑍𝑛2+]
𝐾=
[𝑍𝑛𝑂][𝐻]2
102
𝐾=
[𝐻]2
102
[𝐻]2+ =
𝑘
102
[𝐻] = √
𝑘
[𝐻] = 1.71𝑥10−4
𝑝𝐻 = − log[𝐻] = 3.765
𝒁𝒏(𝑶𝑯) + 𝑯 → 𝒁𝒏𝟐+ + 𝑯𝟐 𝑶
∆𝐺 ° = −13.174 𝑘𝑐𝑎𝑙
−∆𝐺°
𝑒 =𝐾
𝑅𝑇
𝐾 = 4.597𝑥109
[𝐻2 𝑂][𝑍𝑛2+]
𝐾=
[𝑍𝑛𝑂][𝐻]
102
𝐾=
102 [𝐻]
1
𝐾=
[𝐻]
𝑝𝐻 = 9.66
𝒁𝒏(𝑶𝑯) + 𝑯 → 𝒁𝒏𝟐+ + 𝑯𝟐 𝑶
∆𝐺 ° = −78.7 − (−76.88)
∆𝐺 ° = 1.82 𝑘𝑐𝑎𝑙
−∆𝐺°
𝑒 =𝐾
𝑅𝑇
𝐾 = 21.62
[𝑍𝑛(𝑂𝐻)+ ] 102
𝐾= =
[𝑍𝑛𝑂][𝐻] [𝐻]
102 102
𝐾= = [𝐻] = = 4.63𝑋10−4
[𝐻] 𝐾
𝑝𝐻 = −𝐿𝑜𝑔 [𝐻]
𝑝𝐻 = 6.30
𝑯𝟐 𝑶
𝐻2 𝑂 ⟷ 𝑂2
𝐻2 ⟷ 2𝐻
SEGUNDO PROBLEMA
1.- Tabla
Ag 0
𝐴𝑔2+ 64.1
AgO 2.6
H2O -56.69
2.- Ecuaciones
Ag
Ag 2+ +2e ⟶ 𝐴𝑔
𝑨𝒈𝟐+
𝐴𝑔𝑂 + 2𝐻 ⟶ 𝐴𝑔+ + 𝐻2 𝑂
𝑨𝒈𝑶
𝐴𝑔𝑂 + 2𝐻 ⟶ 𝐴𝑔2+ + 𝐻2 𝑂
𝑯𝟐 𝑶
𝐻2 𝑂 ⟷ 𝑂2
𝐻2 ⟷ 2𝐻
3.- Calculo
Ag
∆𝐺 ° = ∆𝐺°𝑎𝑔 − ∆𝐺°𝑎𝑔2+
∆𝐺 ° = 0 − (64.1)
∆𝐺 ° = −64100
−64100
∆𝐺 ° = 2(23062)
∆𝐺 ° = −1.39
0.0592
𝐸° = −1.39 − ln 𝑄
2
𝐸° = −1.45
𝑨𝒈𝟐+
∆𝐺 ° = (−56.69 + 0) − (2.6)
∆𝐺 ° = −59.27
−(−59.27)
∆𝐺 ° =
2(23062)
∆𝐺 ° = 1.29
𝐸° = 1.29 + 0.0592𝑝𝐻
𝐸° = 2.1188
AgO
∆𝐺 ° = 4.83
−(4.830)
∆𝐺 ° =
2(23062)
∆𝐺 ° = 0.106
∆𝐺°
𝑒 =𝑄
𝑅𝑇
𝑄 = 1.0002
[𝐴𝑔2+ ][𝐻2 𝑂]
𝑄=
[𝐴𝑔𝑂][𝐻]2
102
𝑄=
[𝐻]2
[𝐻] = 0.9999
𝑝𝐻 = 0.9995
𝑝𝐻 = 1.00004