P-Block Elements & Compounds - 6

6 p- Block Elements &
Compounds
SECTION - 1 : STRAIGHT OBJECTIVE TYPE
6. 1 Which of the following statement about anhydrous aluminium chloride is correct?

(A) It fumes in moist air.
(B) It exists as dimer both in the vapour state below 350oC and in non-polar solvents
(C) It is prepared by heating Al2O3 in a stream of sulphur chloride (S2Cl2) vapour and chlorine.
(D) All of these
6.2 Aqueous solution of orthoboric acid can be titrated against sodium hydroxide using phenolphthalein
indicator only in presence of:
(A) trans-glycerol (B) catechol (C) cis-glycerol (D) both (B) and (C)
6.3 Which one of the following is the correct statement?
(A) Boric acid is a protonic acid.
(B) Both Ti3+ and Al3+ ions act as oxidising agent in aqueous solution.
(C) Hydrogen bonding in H3BO3 gives it a layered structure.
(D) B(OEt)3 imparts blue colour to the burner flamer.
6.4 HCN + H2O  [X] + NH3
[X] 
 [Y] + H2O
(Unbalanced equations)
[Y] May be prepared by which one of the following methods?
[A] By dehydration of malonci acid with P2O5
[B] By thermal decomposition of carbon sub-oxide in air.
[C] By heating potassium hyxacyaanoferrate (II) with conic. H2SO4.
[D] By the action of conc. HNO3 on charcoal.
6.5 The repeating structural units in silicone is:
R
|
(A) (R2SiO ( (B) SiO2 (C) (R — O — Si — O ) (D) ( Si — O — O — R)
| |
R R
6.6 Which of the following statements is correct about the water-gas shift reaction used for the commercial
preparation of hydrogen gas?
(A) It involves the selective oxidation of CO of water gas to CO2 with the help of steam in presence
of iron chromate as catalyst.
(B) It involves the separation of CO and H2 by solvent extraction method.
(C) It involves the absorption of CO in aqueous copper (l) chloride solution.
(D) It involves the removal of H2 through occlusion with Pd.
6.7 Select the correct statement about elements of group 15th.

(A) The order of stability of oxidation state for +3 is Bi3+ > Sb3+ > As3+ and for +5 is Bi5+ < Sb5+ < As5+
(B) In the case of nitrogen, all oxidation states from +1 to +4 tend to disproportionate in acid solution.
(C) There is considerable in crease in covalent radius from N to P but from As to Bi only a small
increase in covalent radius is observed.
(D) All of these.
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6.8 Which of the following compounds does not give nitrogen on heating?
(A) NaN2 (B)(NH4)2SO4 (C) NH4NO2 (D)(NH4)2Cr2O7
6.9 A brown coloured mixture of two gases is obtained by the reduction of 6N nitric acid with metallic
copper. This mixture on cooling condenses to a blue liquid which o freezing (-30oC) gives a blue solid.
The correct choice for blue liquid or solid is.
(A) It is referred to as the anhydride of nitrous acid.
(B) It is an acidic oxide and hence dissolves in alkalies producing nitrites.
(C) It can also be prepared by the action of 50% HNO3 on arsenious oxide and then cooling to 250 K.
(D) All of these.
6.10 Select the incorrect statement
(A) Nitrous oxide supports combustion more vigorously than air.
(B) Phosphorous pentaoxide dehydrates nitric acid forming nitrogen pentaoxide.
(C) Reactivity order of various allotropic forms of phosphorous is white > red > black.
(D) Red phosphorous changes to white phosphorus on heating in the atmosphere of CO2 or coal gas
at 573 K.
6.11 For H3PO3 and H3PO4 the correct choice is :
(A) H3PO3 is diabasic and reducing agent. (B) H3PO3 is diabasic and non-reducing agent.
(C) H3PO4 is tribasic and reducing agent. (D) H3PO4 is tribasic and non- reducing agent.
6.12 Phosphate rock (fluoroapatite) on reaction with orthophosphoric acid produces:
(A) Ca(H2PO4)2 + CaF2 (B) Ca3(PO4)2 + CaF2 + H2O
(C) Ca(H2PO4)2 + HF (D) Ca3(PO4)2 + HF + H2O
6.13 NH4ClO4 + HNO3 (dilute) 

 HCIO4 + [X]
[X]  
 Y(g)
[X] and [Y] are respectively.
(A) NH4NO3 and N2O (B) NH4NO2 and N2 (C) HNO4 and O2 (D) None
6.14 The following flow diagram represents the industrial preparation of nitric acid from ammonia.
(P) (P)
NH3 + O2 (from excess of air ) 
850°C
 NO 
air
 (r) 
(s)
 NHO3 (D) + NO
Which of the following options correctly describes the underlined reagents, products and reaction
condition?
Option (p) (q) (r) (s)
(A) Catalyst and high pressure Cool NO2 H2O and O2
(B) Catalyst Cool N2O HNO3 and O2
(C) Catalyst and high pressure High pressure NO2 H2O and O2
(D) High pressure Catalyst N2O3 HNO3
6.15 One of the products of the following reaction KCNO + (NH)4 SO4 is:
(A) NH4NO2 (B) NH4 NO3 (C) NH2 – CO – NH2 (D) N2 and NO2 both
6.16 Which Of the following orders is correct?
(1) SbH3 > NH3 > AsH3 > PH3 – Boiling Point (2) NH3 > PH3 > AsH3 > SbH3 – Thermal Stability
(3) NH3 > PH3 > AsH3 > SbH3 – Basic Character (4) NH3 > PH3 > AsH3 > SbH3 – Bond Angle
(A) (1), (2) and (3) only (B) (2), (3) and (4) only (C) (1), (3) and (4) only (D) (1), (2), (3) and (4).
6.17 Which Of the following is correct?
(A) S3O9 – contains no S - S linkage. (B) S2O62- – contains – O - O linkage.
(C) (HPO3)3 – contains P – P linkage (C) S2O82- contains S – S linkage.
6.18 The oxidation states of S atom in S4O62- from left to right respectively are:
O O
|| ||
O–S–S–S–S–O
|| ||
O O
(A) + 6, 0, 0, +6 (B) +5, +1, +1, +5 (C) +5, 0, 0, +5 (D) +3, +1, +1, +3
6.19 One of the methods of manufacture of H2O3 involves the auto-oxidation of:
(A) 2-ehtylanthraquinol (B) Hydrated barium peroxide.
(C) An alkali solution (D) 50% H2SO4.
6.20 Which of the following statements in incorrect for hydrogen peroxide?
(A) It is stored in plastic bottles in dark (B) It acts as an oxidising as well as a reducing agent.
(C) It is used as a bleaching agent. (D) It has acidic as well as basic properties.
6.21 One gas bleaches the coloured matter by reduction temporary while the other one by oxidation
permanently. The gases are respectively:
(A) SO2 and Cl2 (B) O3 and Cl2 (C) H2S and CO2 (D) Cl2 and SO2
6.22 H2SO4 cannot be used to prepare HI from KI as:
(A) Its reaction with KI is very slow. (B) It oxidizes HI to iodine.
(C) It disproportionates HI. (D) It reduces HI.
6.23 Which of the following statements is false?
(A) Conc. HCl + KMnO (B) NaCl + Conc. H2SO4
(C) NaCl + MnO (D) NaCl + Conc. HNO3
6.24 Which of the following statements is false?
(A) H3PO2, H3PO3 and H3PO4 all are tribasic and reducing in nature.
(B) Amongst anions NO3-, SO32-, CO32- and BO33-, only SO32- have p– d bonding.
(C) Amongst anions SO32-, SO42-, S2O42- and HSO4-, SO32- is basic and reducing in nature.
(D) Number of lone pair(s) of electrons on X3 atoms in XeF2, XeF4 and XeF6 are 3, 2 and 1 respectively.
6.25 Which one of the following statements regarding helium is incorrect?
(A) It is used to produce and sustain powerful superconducting magnets.
(B) It is used as a cryogenic agent for carrying out experiments at low temperatures.
(C) It is used in filling balloons for meterological observations because it is lighter and non-inflammable.
(D) It is used as dilute for oxygen in modern diving apparatus because of its high solubility in blood.
SECTION – II : MULTIPLE CORRECT ANSWER TYPE
6.26 Ca2B6O11 + Na2CO3  
 [X] + CaCO3 + NaBO2 (unbalanced equation)
Correct choice(s) for [X] + CaCO3 + NaBO3 (unbalanced equation)
(A) Structure of anion of crystalline [X] has one boron atom sp3 hybridised and other three atoms sp2
hybridised.
(B) [X] with NaOH (aq.) gives a compound which on reaction with hydrogen peroxide in alkaline
medium yields a compound used as brighter in soaps.
(C) Hydrolysic of [X] with HCl or H2SO4 yields a compound which on reaction with HF gives
fluoroboricacid.
(D) [X] on heating with chromium salts in oxidising flame gives green coloured bead.
6.27 On the basis of structure of graphite which of the following is (are) true for it?
(A) It is diamagnetic substance.
(B) It behaves like metallic as well as semiconductor.
(C) C – C bond length in it is more than the diamond.
(D) It is thermodynamically more stable as well as more dense than diamond.
6.28 Which of the following order(s) is (are) incorrect?
(A) H3PO4 > H3PO3 > H3PO2 (Reducing character)
(B) N2O < NO2 < N2O3 < N2O5 (Oxidation state on nitrogen atom.)
(C) NH3 > PH3 > AsH3 > SbH3 (Basicity.)
(D) SbH3 > NH3 > AsH3 > PH3 (Reducing character.)
6.29 Which of the following statement (s) is (are) incorrect?
(A) Ammonia is oxidized to NO2 by oxygen at 800oC in presence of a catalyst platinum.
(B) Nitric acid on standing slowly turns yellow.
(C) Colloidal sulphur is formed when H2S gas is passed through nitric acid solution.
(D) N2O3 gas dissolves in water giving a pale blue solution.
6.30 Which of the following statement (s) is (are) false for sulphurdioxide?
(A) It reacts with dry chlorine in presence of charcoal to form sulphuryl chloride.
(B) It reduces KIO3 to iodine in acidic medium.
(C) It when passed through a solution of sodium sulphide, produces Na2SO3.
(D) It oxidizes SnCl2 to SnCl4 in presence of HCl.
6.31 Which of the following statement (s) is (are) correct?
(A) Marshall’s acid on partial hydrolysis gives caro’s acid and sulphuric acid.
(B) Conc. Sulphuric acid on reaction with potassium chlorate gives chlorine dioxide.
(C) Iodine solution is decolourised by sodium thiosulphate solution.
(D) Aqueous solution of SO2 liberates iodine from an iodate solution and decolourizes iodine solution.
6.32 Which of the following statements regarding hydrogen peroxide is (are) incorrect?
(A) The two hydroxyl groups in hydrogen peroxide lie in the same plane.
(B) Aqueous solution of H2O2 turns blue litmus red.
(C) When H2O2 behaves as a reducing agent, the O – O bond in its molecules is not broken down.
(D) Aqueous solution of H2O2, is stored in plastic bottles and some urea, phosphoric acid or glycerol
is added to that solution.
6.33 The compound(s) which (have) peroxo linkage is (are):

(A) H2S2O3 (B) H2SO5 (C) H2S2O7 (D) H2S2O8
6.34 Sodium thiosulphate is prepared by :

(A) Boiling Na2SO3 solution with elemental sulphur in alkaline medium.
(B) Boiling Na2SO3 solution with elemental sulphur in acidic medium.
(C) Oxidation of poly sulphides, Na2S3 with air.
(D) Reduction of bisulphate solution plus SO2 with zinc dust.
6.35 State then correct statement.

(A) Ferric bromide is obtained when chlorine gas is babbled through a solution of ferrous bromide.
(B) Sodium sulphate is obtained when SO2 (g), H2O (g) and air are passed over heated sodium chloride.
(C) H2S gas is liberated when aluminium sulphide becomes damp.
(D) Nitrogen dioxide gas is liberated by the reaction of ammonia with neutral KMnO4.
6.36 A solution containing Br- ions is treated with each of the following. Which of these will not liberate
bromine gas?
(A) Cl2 (B) HI (C) I2 (D) SO3
6.37 Select the incorrect order(s) from the following.

(A) CIO- < BrO- < IO- - disproportionation (B) CIO4- < BRO4- < IO4- - oxidising power.
(C) HCIO < HCIO2 < HCIO3 < HCIO4 – acid strength (D) HOCL > HOI > HOBr- acid strength
6.38 XeF4 + O2F2 [X] + O2(Unbalanced equation)
Select the correct statement(s) for [X].
(A) Partial hydrolysis of [X] gives XeOF4 as one of the product.
(B) [X] gives yellow liquid on melting.
(C) [X] reacts with SiO2 to form XeOF4 and SiF+
(D) [X] reacts with XeO3 to form XeOF4
SECTION – III : ASSERTION AND REASON TYPE
6.39 Statement–1 : In water, orthoboric acid behaves as a weak monobasic acid.

Statement–2 : In water, orthoboric acid behaves as a proton donor.
(A) Statement- 1 is True, Statement- 2 is True; Statement- 2 is a correct explanation for Statement- 1.
(B) Statement- 1 is True, Statement- 2 is True; Statement- 2 is NOT a correct explanation for Statement- 1.
(C) Statement- 1 is True, Statement- 2 is False.
(D) Statement- 1 is False, Statement- 2 is True.
6.40 Statement–1 : Tetrachlorides of group 14th elements except CCl4 are easily hydrolysed by water.
Statement–2 : The central atoms of these chlorides can accommodate the lone pair of electrons from
oxygen atom of water molecule in d – orbitals.
6.41 Statement–1 : Zeolite, which is hydrated sodium aluminium silicate is used as water softner.
Statement–2 : The sodium ions of Zeolite are exchanged with calcium and magnesium ions when
hard water is passed through it.
6.42 Statement–1 : PbI4 is not known probably because of the oxidising power of Pb(IV) and reducing
power of I-.
Statement–2 : Iodide stabilizes higher oxidation state.
6.43 Statement–1 : P4O10 is not used to dry NH3.

Statement–2 : P4O10 is acidic and NH3 is basic.
6.44 Statement–1 : Reddish brown gas, NO2 when passed through alkalies gives nitrite only.
Statement–2 : NO2 is acidic in nature and is a mixed anhydride of nitric and nitrous acis.
6.45 Statement–1 : HNO3 is stronger acid than HNO2.
Statement–2 : In HNO3 there are two nitrogen to oxygen bonds where as in HNO2 there is only one.
6.46 Statement–1 : HNO3 oxides sulphur to H2SO4 acid ( S + VI) but only oxidizes selenium to H2SeO3
(Se + IV).
Statement–2 : In Selenium atoms, the electrons are more tightly held by the nucleus on account of
increased nuclear charge.
6.47 Statement–1 : Aqueous solution of hydrogen peroxide is kept in glass or metal container containing
some urea or phosphoric acid.
Statement–2 : Urea or phosphoric acid acts as a negative catalyst for the decomposition of hydrogen
peroxide.
6.48 Statement–1 : Sulphur dioxide is more powerful reducing agent in alkaline medium than in acidic
medium.
Statement–2 : Sulphur dioxide reacts with hydrogen sulphide in presence of moisture and sulphur is
precipitated.
6.49 Statement–1 : SF6 is used as a gaseous insulator in high voltage generators.

Statement–2 : It is inert and has good dielectric properties.
6.50 Statement–1 : Finely divided iron does not form ferric chloride with hydrochloric acid.
Statement–2 : Hydrochloric acid produces hydrogen gas with iron.
6.51 Statement–1 : All halogens except F2 are more reactive than interhalogens.
Statement–2 : Bond in the interhalogens (X – Y) is weaker than X – X bond in the halogens.
6.52 Statement–1 : XeF6 reacts with small quantity of water to form XeOF4.
Statement–2 : XeF6 reacts with glass and form XeOF4.
SECION – IV : TRUE AND FALSE TYPE
6.53 S1: Oxides of boron (B2O3) and silicon (SiO2) are acidic in nature.
S2: Oxides of aluminium (Al2O3) and gallim (Ga2O3) are amphoteric in nature.
S3: Oxides of indium (In2O3) and thallium (Ti2O3) are basic in nature.
S4: Oxides of germanium (GeO2) and tin (SnO2) are acidic in nature.
(A) T F T T (B) F F T T (C) T T T F (D) T F T F
6.54 S1: Ammonia on heating with concentrated solution of sodium hypochlorite gives nitrogen gas.
S2: The phosphine gas dissolves in water in presence of sunlight and produces phosphonium hydroxide like
ammonium hydroxide.
S3: Barium azide on heating gives pure nitrogen gas.
S4: The oxo-acids of phosphorus in which phosphorous has lower oxidation state less than +5 contain either
P – P or P – H bonds but not both in addition to P = O and P – OH bonds.
(A) T F T T (B) F F T T (C) T T T F (D) T F T F
6.55 S1: N2O with sodium metal in liquid ammonia forms sodium azide and nitrogen gas is liberated.
S2: Ammonium dichromate on heating decomposes to give nitrogen and a green coloured compound.
S3: CaNCN on hydrolysis produces a white precipitate and a gas which turns filter paper moistened with
copper sulphate solution deep blue.
(A) T T T (B) T F T (C) F F T (D) F T T
6.56 S1: (HPO3)n can be prepared by heating phosphorous acid and bromine in a sealed tube.
S2: Dry iodine reacts with ozone and forms a yellow solid, I4O9
S3: Oxides of indium (In2O3) and thallium (Ti2O3) are basic in nature.
S4: Oxides of germanium (GeO2) and tin (SnO2) are acidic in nature.
(A) F T F (B) T T F (C) T T T (D) T F F
6.57 S1: 2Se2Cl2 SeCl4 + 3Se
S2: Dioxides like MnO2, PbO2 do not form H2O2 with dilute acids but they evolve O2 with conc. H2SO4-.
S3: Sodium thiosulphate of with FeCl3 solution develops a pink or violet colour which soon vanishes.
S4: Xenon fluorides react with fluoride ion acceptor to form cationic species and fluoride ion donors to form
fluoro anions.
(A) F F F F (B) T F T F (C) T T T T (D) F T F T
6.58 S1: Argon is used in arc welding of metals or allows to provide and inert atmosphere.
S2: XeF2, XeF4 and X3F6 are colourless crystalline solids and sublime readily at 298K.
S3: XeF2, XeF4 and X3F6 are readily hydrolysed.
S4: Xenon fluorides react with fluoride ion acceptor to form cationic species and fluoride ion donors to
form fluoro anions.
(A) F F F F (B) T F T F (C) T T T T (D) F T F T
SECTION – V : COMPREHENSION TYPE
Comprehension #1
Compound (A) on reduction with LiAlH4 gives a hydride (P) containing 21.72% hydrogen along with other
products. The one mole of hydride (P) and 2 mole of ammonia at higher temperature gives a compound (Q)
which is known as inorganic benzene. (A) hydrolyses incompletely and forms a compound (R) and H3BO3.
6.59 In hydride (P) (select correct statement) :
(A) The central atom has trigonal planar geometry.
(B) All H-atom lie in the same plane.
(C) All four terminal B-H bond lengths are equivalent but that of four bridging B-H bond lengths are no
equivalent.
(D) a three-centre two-electron bond (3c - 2e) is formed by overlap of an sp3 hybrid orbital from each boron
atom with the 1s orbital of hydrogen atom.
6.60 The hybridisation of central atom of compound (R) is:
(A) sp2 (B) sp3 (C) sp (D) sp3d
6.61 Which of the following statement is incorrect for the compound (A)?
(A) It has trigonal planar geometry.
(B) The bond length between the central atom and the substituent atom is short than the sum of the covalent
radii.
(C) The coordination geometry around central atom of compound (A) and N atom is 1 : 1 complex of (A) and
NH3 is same.
(D) In compound (A), there is p - d bonding.
Comprehension # 2
About 95% of the earth’s crust is composed of silicate minerals, aluminosilicate clays, or silica. The majority
of silicate minerals are very insoluble, because they have an infinite ionic structure and because of the great
strength of the Si – O bond. The basic structural units of silicate is (SiO4)4- tetrahedral. The (SiO4)4- tetrahedral
may polymerize into larger units by sharing atoms.
6.62 Pyroxenes and amphiboles cleave readily parallel to the chains forming fibers because:
(A) The Si – O bonds in the chains are strong and directional.
(B) The adjacent chains are held together by the metal ions present.
(C) Pyroxene is single chain silicate while amphibole is a double chain silicate.
(D) (A) and (B) both.
6.63 Phyllo-silicates are formedby the sharing of the O atoms on ……………. corners of each tetrahedron with
other tetrahedral.
(A) One (B) Two (C) Three (D) Four
6.64 Which of the following statements in incorrect?
(A)Silicates are wide spread in the earth crust because they are very insoluble in water.
(B) The Si – O, bonds are weaker than C – O bonds because of bigger size of silicon atom.
(C) Zeolites are used as ion exchange materials. And as molecular sieve.
(D) Sharing of all four corners of a SiO4 tetrahedron results in a three dimensional lattice of formula SiO2.
Comprehension # 3
Nitrogen forms the largest number of oxides as it is capable of forming stable multiple bonds with oxygen.
They range from N2O (O. S of nitrogen +1) through NO, N2O3, NO2, N2O4 to N2O5 (O. S of nitrogen +5).
Following points are important regarding the study of oxides of nitrogen.
(a) All oxides of nitrogen except N2O5 are endothermic as a large amount of energy is required to dissociate
the stable molecule of oxygen and nitrogen.
(b) The small eletronegativity difference between oxygen and nitrogen make N – O bond easily breakable to
give oxygen and hence oxides of nitrogen are said to be better oxidising agents.
(c) Except N2O5, all are gases at ordinary temperature. N2O3 is stable only at lower temperature 9253K).
(d) Except N2O and NO which are neutral oxides, all are acidic oxides which dissolve in water forming
corresponding oxy acids.
(e) They are also good example for illustrating the concept of resonance.
6.65 The gas which is acidic in nature is:
(A) NO (B) N2O (C) NO2 (D) both (A) and (C)
6.66 Which of the following statement (s) is correct for the oxides of nitrogen?
(A) Dinitrogen trioxide dissolves in potassium hydroxide forming potassium nitrate.
(B) Aqueous solution of nitrogen dioxide behaves both as a reducing agent and as an oxidising agent.
(C) Nitrous oxide is fairly soluble in cold water and turns blue litmus red.
(D) Nitrogen dioxide is an odd electron molecule and in the liquid phase, exists in equilibrium with
the dimmer N2O4.
6.67 Identify the incorrect statement.
(A) In N2O2 the N-N bond length is longer than the usual N-N single bond distance.
(B) NO2 molecule is angular with N – O distance equal to the intermediate distance between a single
and double bond.
(C) N2O is a linear molecule and has a small dipole moment.
(D) None of these.
Comprehension # 4
Ozone is an unstable, dark blue diamagnetic gas. It absorbs strongly in the UV region, thus protecting
the people on the earth from the harmful UV radiation from the sun. The use of chlorofluorocarbon
(CFC) in aerosols and refrigerators, and their subsequent escape into the atmosphere is blamed for
making holes in the ozone layer over the Antarctic, and Arctic.
Ozone acts as a strong oxidising agent in acidic and alkaline medium. For this property ozone is used
as a germicide and disinfectant for sterilizing water and improving he atmosphere of crowded places.
6.68 CFC damages ozone layer by reactions:
(A) O3 + hv O + O2 (B) Cl + O3  ClO + O2
(C) ClO + O Cl + O2 (D) All of the above.
6.69 Identify the incorrect statement with respect to ozone.
(A) Ozone is formed in the upper atmosphere by a photochemical reaction involving dioxygen.
(B) Ozone protects the earth’s inhabitants by absorbing UV radiations.
(C) Ozone can also be made by heating O2 over 2500oC and quenching.
(D) Chlorine gas is preferred over ozone for the purification of drinking water and for water treatment
in swimming pools.
6.70 Which of the following statements in correct?
(A) The dark blue colour of ozone is due to intense absorption of green light.
(B) Oxides of nitrogen and the halogen cannot damage the O3 layer.
(C) Ozone oxidizes dry iodine to I2O5.
(D) Ozone forms orange coloured compound KO3 with potassium hydroxide.
Comprehension # 5
All neutral halogens are diatomic and readily reduced to halide ions.
All combine with hydrogen to form gases which except for HF, are strong acids in aqueous solution.
The chemistry of the halogens is governed in large part by their tendency to acquire an electron to
attain a noble gas electron configuration.
Except, fluorine, all halogens disproportionate in sodium hydroxide (dilute) forming halides and
hypohalites. All the hypohalite ions are unstable with respect to the disproportionation; 3 OX-  XO3-
+ 2X-.
6.71 Which of the following product is formed when one more periodate ion (IO4-) reacts with excess of
iodide ions followed by the acidification of solution?
(A) IO (B) IO3- (C) I2 (D) I2O5
6.72 Which of the following statements is incorrect?
(A) At ordinary temperature, the rate of disproportionation of hyphohalites of chlorine, bromine and
iodine follows the order IO- > BrO- > CIO-
(B) Fluorine can not be prepared in aqueous medium by electrolysis since it decomposes water with
liberation of ozonised oxygen.
(C) HI is a stronger acid than HBr because of the low dissociation energy of HI.
(D) In aqueous solution chlorine is a strong oxidising agent than fluorine.
6.73 Consider the following statements;
(I) Amongst HCl, HBr, HI and HOCl, HCl is most stable to heat.
(II) Chlorine gas is evolved when potassium chlorate reacts with iodine.
(III) The basicity of F , Cl , Br , and I follows the order F > Cl > Br > I-.
(IV) Sodium hypochlorite is used as a bleaching and sterilizing agent.
of these,
(A) ( I), (II) and (III) are correct (B) (I), (II) and (IV) are correct
(B) (I), (III) and (Iv) are correct (D) All of these.
Comprehension # 6
A crystalline solid (A) reacts with hydrogen gas to form a monoatomic gas (B) and a highly associated
liquid (C). (A) is soluble in water and undergoes hydrolysis slowly to form (B), (C) and a diatomic gas
(D). When pure and dry (D) is subjected to a silent electric discharge an another pale blue gas (E) is
produced which like (A) also acts as a strong oxidising agent. (E) dissolves in potassium hydroxide
forming an organge compounds. (C) forms an addition compounds (F) with KF when electrolysed in
molten state forms a most reactive gas (G). (B) and (G) (taken in 2 : 1 ratio) when heated in nickel
tube at 400oC and 6 atm pressure forms (A). The first ionization energy (IE1) of (B) is fairly close to
(D).
6.74 Gas (G) is produced by reacting K2 MnF6 with:
(A) SbF5 (B) MnF3 (C) KSbF6 (D) MnF5
6.75 Which of the following statements is correct for (A)?
(A) The central atom of (A) is sp3d hybridised with three lone pairs of electrons.
(B) (A) reacts with S8 molecules in presence of (C) to form a compound in which the S atom is sp3 d2
hybridised.
(C) (A) reacts with SbF5 as a lewis base.
(D) All of these.
6.76 Which is correct choice for (D) and (E):]
(A) (E) reacts with dry iodine to form I2O5.
(B) A filter paper soaked in alcoholic benzidine becomes brown when brought in contact with (E).
(C) (D) is prepared by Brin’s process.
(D) (B) and (C) both.
6.77 Which of the following statements is true?
(A) Gas (G) reacts with conc NaOH to form OF2.
(B) Pale blue gas (E) oxidizes alkaline KI to KIO3 and KIO4.
(C) Pale blue gas (E) in acidic medium reacts with K2Cr2O7 to form a bright blue coloured compound
(CrO5).
(D) (B) and (C) both.
SECTION – VI : MATRIX – MATCH TYPE
6.78 Match the reactions listed in column - I with the product(s) listed in column - II.
Column – I Column – II
(A) B2O3 + H2O (p) H3BO3
(B) B2H6 + H2O (q) H2
(C) B3N3H6 + H2O (r) HCl
(D) BCl3 + H2O (s) NH3
(t) N2
6.79 Match the acids in Column - I with their properties / type of hybridised listed in Column - II.
(A) Hypophosphorus acid. (p) All hydrogen are ionisable in water.
(B) Orthoboric acid (q) Monobasic acid.
(C) Hypophosphoric acid (r) sp3 hybridised central atom(s).
(D) Pyrosulphurous acid. (s) Lewis acid.
6.80 Match the reactions mentioned in column – I with the nature of reaction / characteristic(s) of the
products mentioned in Column – II.
(A) (NH4)2 S2O8 + H2O 
distillation
 (p) Hydrolysis
(B) NaBO2 + H2O + H2O2 OH (q) One of the product has peroxide linkage.
 
fusion
(C) Na2SO3 
temperature
 (r) Disproportionation
3
(D)2 – Ethylanthraquinol + air 
 (s) In one of the products the central atom has sp hybridisation
6.81 Match the reactions mentioned in column – I with the use of product / characteristic(s) of the products
mentioned in column - II
(A) HSO3- + SO2 Zn (p) In one of theh products the central atom(s) is(are) in +3 oxidation

state.
(B) Na2Cr2O7 + C  
 (q) One of the products acts as a reducing agent.
(C) P4 + Cl2 (g) + H2O  (r) One of the products or its anion has trigonal planar geometry.
(D) H2SO4 + HI  (s) One of the products is a gas which is used in the purification of nickel
metal.
6.82 Match the reactions mentioned in column – I with the nature of reaction / characteristic(s) of the
products mentioned in column - II
(A) HNO2 (a)  (p) One of the product is a diamagnetic colourless gas.
(B) NH4Cl (aq) + NaNO2 (a)  (q) One of the product is a colourless paramagnetic gas.
(C) HN3 + Li  (r) Redox reaction
(D) Mg + HNO3 (cold and dilute)  (s) One of the product gives brown ring test.
6.83 Match each of the reactions mentioned in column – I with the corresponding product (s) given
in column - II.
(A) Sn + conc. HNO3 (p) NO
(B) Sn + dil. HNO (q) NO2
(C) Ag + conc. HNO3 (r) NH4NO3
(D) Ag + dil. HNO3 (s) Sn(NO3)2
6.84 Match the compounds listed in column – I with characteristic(s) / type of reaction(s) listed in column
- II
(A) XeF2 (p) Undergoes hydrolysis with water.
(B) XeF4 (q) Acts as oxidising agent.
(C) XeF6 (r) Undergoes addition reaction.
(D) XeO3 (s) Has lone pair(s) of electrons.
(t) Gives disproportionation reaction with H2O or OH-.
SECTION – VII : SUBJECTIVE ANSWER TYPE
SHORT SUBJECTIVE:
6.85 The number of two center – two center – two electron bonds i.e. 2c – 2e in diborane is:
6.86 How many oxygen atoms are shared per SiO2 tetrahedral in Beryl?
6.87 What amount of CaO (in kilograms) is required to neutralize 852 g of P4O10?
6.88 The number of hydrogen atom(s) attached to phosphorus atom in hypophosphorus acid is
6.89 How many mole(s) of phosphine is obtained when one more of calcium phosphide reacts with excess
water.
6.90 XeF4 disproportionates in water giving reduced and oxidized products. What is the ratio of oxidation
states of X3 in the reduced and the oxidized products:

P-Block Elements & Compounds - 6

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6 p- Block Elements &

6. 1 Which of the following statement about anhydrous aluminium chloride is correct?

6.7 Select the correct statement about elements of group 15th.

6.13 NH4ClO4 + HNO3 (dilute) 

6.33 The compound(s) which (have) peroxo linkage is (are):

6.34 Sodium thiosulphate is prepared by :

6.35 State then correct statement.

6.37 Select the incorrect order(s) from the following.

SECTION – III : ASSERTION AND REASON TYPE

6.39 Statement–1 : In water, orthoboric acid behaves as a weak monobasic acid.

6.43 Statement–1 : P4O10 is not used to dry NH3.

6.49 Statement–1 : SF6 is used as a gaseous insulator in high voltage generators.

SECTION – VI : MATRIX – MATCH TYPE

SECTION – VII : SUBJECTIVE ANSWER TYPE

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6 p- Block Elements &

6. 1 Which of the following statement about anhydrous aluminium chloride is correct?

6.7 Select the correct statement about elements of group 15th.

6.13 NH4ClO4 + HNO3 (dilute) 

6.33 The compound(s) which (have) peroxo linkage is (are):

6.34 Sodium thiosulphate is prepared by :

6.35 State then correct statement.

6.37 Select the incorrect order(s) from the following.

SECTION – III : ASSERTION AND REASON TYPE

6.39 Statement–1 : In water, orthoboric acid behaves as a weak monobasic acid.

6.43 Statement–1 : P4O10 is not used to dry NH3.

6.49 Statement–1 : SF6 is used as a gaseous insulator in high voltage generators.

SECTION – VI : MATRIX – MATCH TYPE

SECTION – VII : SUBJECTIVE ANSWER TYPE

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P-Block Elements & Compounds - 6

P-Block Elements & Compounds - 6