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Alternative Conceptions of
Chemical Bonding Held by
Upper Secondary and Tertiary
Students
Richard K. Coll & Neil Taylor
Published online: 25 Aug 2010.
To cite this article: Richard K. Coll & Neil Taylor (2001) Alternative
Conceptions of Chemical Bonding Held by Upper Secondary and Tertiary
Students, Research in Science & Technological Education, 19:2, 171-191, DOI:
10.1080/02635140120057713
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Research in Science & Technological Education, Vol. 19, No. 2, 2001
ABSTRACT Examination of senior secondary and tertiary level chemistry students’ descriptions of their mental
models for chemical bonding revealed prevalent alternative conceptions. In addition to some common alternative
conceptions previously reported in the literature, such as misunderstandings about intermolecular forces and
molecularity of continuous lattices, the inquiry found a surprising number of alternative conceptions about simple ideas
like ion size and shape. Some 20 alternative conceptions were revealed, the most common being belief that continuous
ionic or metallic lattices were molecular in nature, and confusion over ionic size and charge. It is posited that the
mass of curriculum material students encounter during their undergraduate and postgraduate studies may have some
inuence on the formation of alternative conceptions. Hence, it is recommended that tertiary level teachers in particular
consider the advisability of limiting the teaching of some abstract models for chemical bonding until an advanced stage
of the undergraduate degree.
Introduction
There has been something of a revolution in science education since the 1960s. Changes
in the way science education researchers, philosophers and others see the world has
resulted in a major rethinking of how science should be taught. Prior to the 1970s,
science teaching was dominated by a transmissive approach. Implicit in this approach
was a view that the learning of science was passive and that knowledge could be ‘piped’
from the full container of the teacher’s head to the empty vessel of the student’s head
(Tobin et al., 1990). Little account was given to students’ alternative conceptions of
science, which were considered to be easily extinguished or replaced by the teacher
through persuasive argument. This resulted, in general, in a very didactic approach to
the teaching and learning of science.
However, in the 1970s new cognitive theories began to emerge which challenged this
passive view of learning. An emphasis was placed upon the student as an active
individual reaching out to make sense of events and constructing knowledge through
social interaction and experiences with the physical environment (Driver & Easley, 1978).
These new theories acknowledged that, contrary to the view that students have blank
minds, they bring to their school learning in science ideas, expectations and beliefs
concerning natural phenomena which they have developed to make sense of their own
ISSN 0263-514 3 print; 1470-113 8 online/01/010171-2 1 Ó 2001 Taylor & Francis Ltd
DOI: 10.1080/0263514012005771 3
172 R. K. Coll & N. Taylor
past experiences. Furthermore, these ideas could differ from the currently accepted
scienti c view, and from the intended learning outcome, and could be extremely resistant
to change (Driver, 1981).
Such thinking led to the development of the constructivist paradigm which has as a
basic premise that knowledge is created in the mind of the individual rather than
absorbed or transmitted from an expert or teacher to a student (Driver, 1989). The
constructivist view of knowledge acquisition led to changes in the nature of teaching and
research. Much research into science teaching revealed that students hold many views
that are at variance with commonly accepted scienti c views. In fact so proli c has this
research been that there are now substantial bibliographies, with over 1000 references,
into investigations of students’ conceptions in science (e.g. Pfundt & Duit, 1997).
Despite the proliferation of studies into students’ understanding of various aspects of
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science, there has been relatively little investigation of their understanding of chemical
bonding, particularly amongst senior secondary and tertiary level students. In this article
we address this issue by identifying a range of alternative mental constructs of chemical
bonding and consider their origins and possible implications for teaching at this level.
arises from a worldview that building a structure requires energy input, whereas
destruction involves release of energy—that is, students believed that bond breaking
releases energy and bond making involves energy input.
Confusion about the concept of electronegativity is also widespread, resulting in a
number of alternative conceptions for chemical bonding; inability to establish the correct
polarity of polar covalent bonds, the view that non-polar molecules are only formed
between atoms of similar electronegativity and that the number of valence electrons, the
presence of lone pairs of electrons, or ionic charge determine molecular polarity
(Peterson et al., 1989; Harrison & Treagust, 1996; Boo 1998; Birk & Kurtz, 1999).
Students appear to have little appreciation of the underlying electrostatic nature of
chemical bonding (Taber, 1995b; De Posada, 1997; Boo, 1998). For example, attraction
between two oppositely charged species was thought to result in neutralisation rather
than bond formation, the likely source of confusion being the parallel with acid–base
chemistry (Schmidt, 1997; Boo, 1998). Similarly, students have a poor understanding of
the bonding in metals, seeing metallic bonding as unimportant or in some way inferior
to other forms of bonding, despite being able to use the common sea of electrons model
to explain the properties in metals (Taber, 1995a, 1998; De Posada, 1997). There are a
number of other alternative conceptions about covalent bonding reported in the
literature. Some students believe that the number of valence electrons and the number
of covalent bonds are one and the same; other conceptions include confusing resonance
forms with molecular structures and believing that covalent bond formation involves the
transfer of electrons (Taber, 1994, 1997, 1998).
Much of the research cited above was undertaken with students of school age. The
conceptions which tertiary level chemistry students hold about chemical bonding have,
in comparison, been researched infrequently. Perhaps by this stage in their academic
careers, students may be perceived as having a sound understanding of scienti c
concepts, and are therefore less prone to developing naïve mental models. In this article
we describe a study of senior secondary school and tertiary level chemistry students from
New Zealand and Australia. The study revealed a number of alternative conceptions for
chemical bonding and these, along with the implications of the study for the teaching and
learning of senior level chemistry are discussed.
Methodology
Theoretical Framework
The work reported here represents part of a larger study into students’ mental models
for chemical bonding (Coll & Treagust, in press). This inquiry is a naturalistic inquiry
174 R. K. Coll & N. Taylor
conducted within a constructivist paradigm. The authors believe inquiries into science
education such as that described in this work are best addressed using a methodology in
which the individual constructions of interest are elicited by interactive dialogue between
researchers and participants. Speci cally the authors subscribe to a social and contextual
constructivist belief system. Contextual constructivists assert that a crucial feature of
knowledge creation is that it is not carried out in isolation, but is subject to in uence by
an individual’s context; that is, his or her prior knowledge and experiential world
(Wheatley, 1991; Cobern, 1993; Good et al., 1993). Contextual constructivism and the
related social constructivism hold that personal constructivism is too limited as humans
are social beings, and knowledge creation is in uenced by the prior experiences and
social environment of the student. Wheatley (1991, p. 49) summarises the position by
claiming that ‘we continually negotiate the meaning of events in our lives so that we can
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bene t from the experiences of others as well as our own’. Social constructivists believe
that an important part of construction is social interaction through which we come to a
common understanding of knowledge, including scienti c concepts (Wheatley, 1991; von
Glasersfeld, 1993; Solomon, 1994). Tobin and Tippins (1993) put it this way ‘the
individual and social components [are seen as] being parts of a dialectical relationship
where knowing is seen dualistically as both individual and social, never one alone, but
always both’ (p. 20). However, we may appear to have the same view of concepts as
others, but our understanding is commonly discrepant, for example, when there is an
undetected communication breakdown (Johnson & Gott, 1996).
Data Collection
The researchers began the larger study by conducting an in-depth analysis of the
curriculum material that these students had encountered during their studies. This
entailed a thorough examination of lesson plans, textbooks, lecture notes and other
relevant documentation such as topic tests and nal examinations. These data were
synthesised into a summary of the mental models for chemical bonding. This summary
comprised some 40 pages and a total of eight models along with extensions and
modi cations of the models. The models identi ed, were, the sea of electrons model and
band theory for metals, a model based on electron transfer and a further model involving
the calculation of electrostatic charges for ionic substances, and the octet rule, the
molecular orbital theory, the valence bond approach, and ligand eld theory for covalent
substances. Students’ views were elicited from semi-structured interviews according to the
protocol detailed in Table I.
This comprised a description of a given model chosen by the students during the
interview, followed by probing of their understanding by the use of focus cards that
depicted model use in some way (Table I). For example, for metals, this involved showing
the participants samples of metallic substances (aluminum foil and steel wool), along with
focus cards depicting the conductivity and malleability of a metal (examples of the cards
for metallic bonding are provided in the Appendix). The student models revealed in
interviews were then compared with the models found in the curriculum material; this
revealed the alternative conceptions that form the focus of the present paper.
Alternative conceptions were compiled into inventories and expert-validated by the
teachers involved in this study. The expert’s principal contribution consisted of validation
of the description of the models and of the researchers’ constructions and interpretation
of the students’ alternative conceptions for chemical bonding reported here. It is
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Metallic bonding
Shown sample of aluminium foil—please describe the bonding in this substance
Shown sample of steel wool—please describe the bonding in this substance
Shown focus card depicting conductivity of copper wire—please explain this process
Shown focus card depicting malleability of copper metal—please explain this process
Shown focus card containing depictions of the bonding in lithium metal—which of these models appeals most/least to you?
Ionic bonding
Shown sample of sodium chloride—please describe the bonding in this substance
Shown sample of lithium chloride—please describe the bonding in this substance
Shown focus card depicting the conductivity of molten sodium chloride—please explain this process
Shown focus card depicting the friability of sodium chloride—please explain this process
Shown focus card containing depictions of the structure of sodium chloride—which of these models appeals most/least to you?
Covalent bonding
Shown sample of molecular iodine—please describe the bonding in this substance
Shown sample of chloroform—please describe the bonding in this substance
Shown focus card depicting reaction of copper chloride with ammonia solution—please explain this process
Shown focus card containing a graphical depiction of the relationship between boiling point and Period number for a series of related
hydrides—please explain this process
Shown focus card containing depictions of the structure of benzene—which of these models appeals most/least to you?
Alternative Conceptions of Chemical Bonding Held by Students
175
176 R. K. Coll & N. Taylor
important to note that the research question in this work is subordinate to the aim of the
larger study; namely, to establish the students’ preferred mental models for chemical
bonding. Consequently, the results reported herein should not be deemed as an
exhaustive catalogue of the students’ alternative conceptions for chemical bonding.
Rather, these data represent a compilation of alternative conceptions revealed when the
students discussed their mental models for chemical bonding.
a particular model for chemical bonding. For example, to describe the bonding in ionic
compounds, the students typically described the size and shape of ions as well as the
packing. Hence views at odds with the scienti c view about ion size, shape or nature of
packing, have been classi ed as alternative conceptions However, during discussions
centred on a focus card which compared the electrical conductivity of metallic copper
with that of glass, there was evidence that some of the students held alternative
conceptions about electrical conductivity. Because such alternative conceptions did not
pertain to chemical bonding, they have not been included in the report of this work.
Sample Description
The study involved 30 participants from three academic levels; Year 12 secondary school
students (age range 17–18 years), second and third year undergraduates (age range 19–20
years) and postgraduates (age range 23–26 years). The secondary school students formed
two cohorts—two females (Natalie and Linda) from a private school in a middle class
area of an Australian city, and four females (Anne, Anita, Claire and Frances) and four
males (Neil, Keith, David and Richard) from single-sex schools in a middle class suburb
of a small New Zealand city. The male secondary school students were, in general, less
con dent and outspoken than their female counterparts, although all students spoke
freely during interviews. The participants were interested to pursue science-based careers
and stated that they enjoyed chemistry. Eight of the undergraduate participants were
intending BSc chemistry majors from a New Zealand university. Because the interviews
for these undergraduates were conducted late in the year after the completion of lectures,
undergraduate students had, at a minimum, completed 2 years of tertiary chemistry
instruction. There were two male (Bob and Steve) and two female (Renee and Kim)
second year undergraduate participants and two male (Alan and Mike) and two female
(Jane and Mary) third year undergraduate participants. In addition to the New Zealand
undergraduates there was one Australian male (Mike) and one female (Rosaline), both
second year students from an Australian university. There were 10 postgraduate students,
four New Zealand PhD candidates two being male (Jason and Kevin) and two female
(Grace and Christine), and four MSc level candidates, two male (James and Brian) and
two female (Jenny and Rose), from the same New Zealand university as the undergrad-
uates. In addition there were two Australian PhD candidates, both male (John and
Nigel). All the postgraduates were high academic achievers—a re ection of the entry
requirements for postgraduate studies. In spite of this, there was a considerable spread
in academic ability even within this cohort, with some students possessing outstanding
academic records. All MSc candidates were purposefully chosen from the second year
Alternative Conceptions of Chemical Bonding Held by Students 177
class. The intention was to distinguish these postgraduates from nal year BSc students:
these selection criteria ensured that the masterate students had completed all of their
MSc courses.
Research Findings
The alternative conceptions identi ed in this study are detailed in Table II. Many of
these alternative conceptions were not widely evident, several alternative conceptions
being evidenced by a sole individual. Because the inquiry does not comprise a systematic
attempt to uncover students’ alternative conceptions, a given alternative conception may
have been identi ed for only one student, but this does not necessarily mean only one
student held this alternative conception.
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AC 1 AC 11
Metallic bonding is weak bonding Metallic lattices contain neutral atoms
AC 2 AC 12
R. K. Coll & N. Taylor
Intramolecular covalent bonding is weak bonding Electronegativity comprises attraction for a single electron
AC 3 AC 13
Ionic bonding is weak bonding Molecular iodine is metallic in nature
AC 4 AC 14
Continuous metallic or ionic lattices are molecular in nature Ionic bonding comprises sharing of electrons
AC 5 AC 15
The bonding in metals and ionic compounds involves intermolecular bonding Ionic and metallic bonding contain an element of directionality
AC 6 AC 16
The ionic radius of the sodium ion is greater than the chloride ion Ions in close-packed metal lattices possess other than eight nearest neighbours
AC 7 AC 17
The ionic radius of the lithium ion is greater than the sodium ion Metal to non-metal bonding in alloys is electrostatic in nature
AC 8 AC 18
Polar covalent compounds contain charged species Ionic shape and packing is inuenced by pressure
AC 9 AC 19
Molecular iodine contains 1 minus ions Intermolecular forces are inuenced by gravity
AC 10 AC 20
The charged species in metallic lattices are nuclei rather than ions Glass is an ionic crystalline substance
Alternative Conceptions of Chemical Bonding Held by Students 179
electrons from owing on through the sodium because the molecules are held tightly
together by the bonds in the sodium chloride, so they can’t move around’. Keith also
introduced the concept of molecules when describing the conductivity of metallic copper
stating, ‘the copper molecule, it’s owing. Like it’s going from positive to negative so the
electrons can ow along’ and Bob when describing a ball-and-stick depiction of bonding
in the metal lithium stating ‘I like the way you can see the packing together of the
molecules in a regular fashion’.
Some caution is necessary in the interpretation of these data as it is possible that these
statements merely represent inappropriate or careless use of nomenclature. However,
some of the students identi ed speci c molecular species in metals and ionic substances,
suggesting that their use of the term molecule is purposeful, as for example, in the
description of the structure of sodium chloride and caesium chloride by Alan, ‘the
caesium atom makes contact with all these chlorides in the middle. That sort of
interaction between the caesium and chloride, like how you are taught NaCl, the NaCl
molecule’.
A related alternative conception, that metals and ionic compounds possess intermolec-
ular bonds, was evident for three students (AC 5, Table II). David stated ‘I suppose there
is always the van der Waals things with just the attraction of the electrostatics and stuff’,
and as seen in a drawing (Fig. 1) and writing used by Keith to describe the bonding in
the ionic substance LiCl.
Then there is bonding between another, and another [draws wavy lines
between units of LiCl, writes van der Waals next to wavy line].
The notion of molecularity may have led to this alternative conception, in that the
students felt it necessary to explain why the structure was held together, and drew upon
the concept of van der Waals forces to do so.
consider lithium to slightly larger than the sodium’, and Mary said ‘the lithium maybe
a little bit bigger than sodium’. It is noteworthy that the respondents were in possession
of a Periodic Table at the time. The responses above reveal the tentative nature of the
students’ views when the size difference is described at being ‘slightly larger’ and ‘maybe
a little bit bigger’.
Views expressed by some of the secondary school students offered clues to the origin
of the alternative conception that the chloride ion is smaller than the sodium ion. It
seems that students at this level at least, may have confused ionic size with the Periodic
trend in atomic size.
David: I would say the Na would be bigger and the Cl would be smaller, I
imagine they would be.
Interviewer: Why do you see it that way?
David: The explanation I have had of that is that as you move across the
Periodic Table, well there’s more electrons in the same shell with an increasing
number of protons as well, and that like attracts them closer which just means
it is smaller.
It is common to illustrate the structure of ionic substances such as sodium chloride in
lectures and curriculum material using space- lling and ball-and-stick models; informal
interviews of all of the instructors in this inquiry indicated that this formed part of their
teaching strategy; likewise, the textbooks used by the students contained diagrams that
showed the ions to be similar in size. The ball-and-stick models often have the ion size
depicted as similar; whereas there is a signi cant difference in ion size in space- lling
models.
Alternative Conceptions for the Ionic and Covalent Character of Chemical Bonds
As mentioned above the inappropriate use of nomenclature may be instrumental in the
formation of some alternative conceptions, and this is particularly evident in the case of
the rather esoteric notion of the ionic–covalent continuum. Jason, one of the most
academically able and most erudite of the postgraduate participants in the study,
exempli es the situation. His academic ability coupled with his extensive tutoring of
undergraduate chemistry suggest that he is likely to be aware of the importance of
nomenclature. Upon describing the formation of the chloride ion from neutral chlorine,
he clearly showed that he understands the difference between an ion and a neutral atom,
Alternative Conceptions of Chemical Bonding Held by Students 181
that is, chlorine and chloride. However, he frequently made inappropriate use of
nomenclature in subsequent explanations.
I see the chlorine as being not a chlorine atom but a chlorine ion, so a chlorine
which has gained an electron from the sodium atom so that the chlorine atom
has a negative charge. The sodium has a positive charge. It’s like this structure
is essentially held together by electrostatic interactions. Now there’s also
repulsions as well because you also have another chlorine atom which is
reasonably close to that chlorine atom so there’s repulsions between the two.
Because of his expertise and experience, it seems that Jason is clear in his own mind of
the difference between the terms chlorine and chloride; thus interchanging the terms may
not be particularly detrimental for his understanding of chemical bonding. However, it
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is possible that the interchanging of such terms for novices may lead to alternative
conceptions. To illustrate, consider another highly prevalent alternative conception
found—that polar covalent compounds contain charged species (AC 8, Table II). Frances
indicated that chloroform contains a proton, and Anita identi ed Cl minus in the same
compound.
Frances: Because these two have Hs in them and H with the Cl, and the highly
electronegative ones like chlorides and things like that that gives the hydrogen
bonding whereas they can readily donate a proton away to the hydrogen.
Anita: Yeah because H is plus and Cl is minus, but I don’t know why, I just
know it is different but I don’t know why.
Similarly, Mary, an undergraduate, stated explicitly that she viewed the bonding in
hydrogen halides as ionic in nature, rather than polar covalent, or possessing of some
ionic character, stating ‘I think of them as being ionic’. Jenny, a postgraduate, articulated
her views about the bonding in chloroform in greater detail drawing on previous
experience of the bonding in carboxylic acids; part of her MSc research project.
However, the value of doing this seems dubious, as she confused the donation of protons
in carboxylic acids with a perception of lability of the chlorine atom in chloroform
(CHCl3). The fact that she used the term chloride, rather than chlorine, may indicate
that inappropriate nomenclature has in part contributed to her alternative conception.
I know that to remove an atom from chloroform is quite dif cult. But if you
look at other organic molecules will, um … I mean if you think, like your
carboxylic acid it’s quite easy to remove the proton and the same for the
chloride, like a halide. It’s quite easy to remove chlorine from a long sort of
carbon chain.
The fact that Jenny described the chlorine in chloroform as chloride, indicative of an
ionic species, may have led her to make an inappropriate link to her own experience with
the ionisation of carboxylic acids. An examination of interview transcripts revealed that
it was routine across all academic levels for the students to interchange terms pertaining
to halogens with the charged halide. Students used the terminology for neutral atoms
when describing the bonding in ionic compounds, and similarly described halides as
halogens, as seen in Keith’s description of the bonding in sodium chloride and Steve’s
for lithium chloride.
Keith: OK the sodium has got one electron in its outer shell, and the chlorine
has got seven. So the chlorine requires one more electron. The bonds in the
sodium chloride I don’t think are as strong between the sodium and the
182 R. K. Coll & N. Taylor
chlorine so they are not attracted to each other, the sodium and the chloride
ions.
Steve: Well basically it’s going to be easier for the chlorine’s wait a sec., um
because the chlorine’s are still, the chloride’s have still got the same size.
An underlying origin of this view may be misunderstandings about the notion of the
ionic–covalent continuum. The students are told that there is no such thing as pure ionic
bonding and that atoms in polar covalent compounds hold partial charges. It is possible
that this notion reinforces the view in the students’ minds that chlorine is charged,
causing confusion between the notion of a partially charged chlorine atom in a polar
covalent compound and the negative chloride ion. In support of this proposition,
inappropriate use of terminology seems to be in uential in the formation of alternative
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conceptions about the bonding in pure molecular covalent substances like molecular
iodine (I2) (AC 9, Table II). It is perhaps more likely that the students confuse chloride
and chlorine in a substance like chloroform which they are told is polar covalent and
where the chlorine atom carries a partial charge. However, this is not the case for
non-polar molecular covalent species like homonuclear diatomics such as molecular
iodine. The fact that the same alternative conception is seen for such substances adds
credence to this view. Mary and Rose seemed to believe that the iodine atoms in I2 carry
a negative charge, although they both subsequently stated that the bonding comprised
sharing of electrons, that is, a covalent bond.
Mary: Iodine well I know iodine as being I2 that’s how I remember it. Iodine
is, um, I minus so therefore it’s got one extra electron I guess sitting there,
that’s not doing anything [respondent laughs] and it’s able to pair up with
another iodine which also has a spare, and those two electrons come together
and form a bond.
Rose: In iodine, well it’s like two atoms of iodine, they would be equally
contributing from the covalent bonds because each I minus, each iodine would
be like lacking one electron. So they join together to form a more stable I2,
donating an electron each and they are shared between the two atoms.
Interviewer: So that’s a combination of two I minuses is it?
Rose: Yeah.
In a similar way students seemed to confuse ions with neutral species and nuclei in
metallic bonding (AC 10–11, Table II). Two alternative conceptions of this nature were
identi ed, namely, that metallic lattices contain neutral atoms and that the positive ions
present are nuclei.
Interviewer: Do you see this here as being lithium plus here?
Steve: No I don’t. I just see that as just being a lithium.
Mary: I guess that’s the nucleus [indicating the 1 symbols in the sea of
electrons model, see focus card MB01 in the Appendix].
Kevin: Well my conception anyway is the fact that the charges of all the nuclei
are very positively charged. The electrons are negatively charged. That will
make the whole thing sort of stay together.
Another possible origin of this alternative conception maybe the nature of visual clues
used in the diagrams depicting the sea of electrons model, in which spheres enclose a
positive sign (focus card MB01, Appendix).
Alternative Conceptions of Chemical Bonding Held by Students 183
Steve: It’s the electron attracting ability of a species. So in the case of uorine
for instance being the most electronegative element, because it has only one
space left to ll in its 2p orbital, then it would very strongly attract an electron
to ll that orbital, to attain a stable lled valance orbital.
Claire: It’s still ionic because the lithium has a stronger attraction.
Claire: To the lithium. So the one electron they are sharing it will still spend
most of the time around the chlorine or chloride.
Although a de nition of electronegativity was not explicitly elicited, if a given student
introduced the term, he or she was asked to explain what the term meant to them.
Electronegativity is not an aspect of chemical bonding per se. However, students’
understanding of electronegativity impacts upon their understanding of bonding. Most of
the students produced a de nition of electronegativity that was in general agreement with
the scienti c view. However, Steve seemed to believe that the attraction was for a single
electron rather than a greater attraction for the shared pair. His statement that there is
‘only one space left’ resulting in greater attraction suggests that the lled valence shell
concept of the octet rule is in uential in his view of electronegativity.
Jason stated that ‘iodine has some sort of metallic properties’. The origins of this view
may lie in the lustrous, rather metallic, appearance of the crystalline appearance of the
sample used during the interviews. Upon probing it seemed that Jason did not believe
molecular iodine is a metal, yet he persisted with his statement that it will possess metallic
properties.
Jason: Just looking at it. It looks metallic it’s somewhat shiny. It’s even grey in
184 R. K. Coll & N. Taylor
colour and you have sort of discrete little crystals of it. I don’t know. When I
say it looks like a metal, I don’t expect it to behave as a metal.
Interviewer: So you are saying it is metallic in appearance?
Jason: Yeah. It obviously has some sort of metallic characteristics to it.
Jason seems oblivious to the contradiction in his account. On one hand he states ‘I don’t
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expect it to behave as a metal’ and then ‘it obviously has some sort of metallic
characteristics’. His view may be in uenced by notions of Periodic trends. Although this
has not been articulated by Jason, it is common to state that there is an increase in
metallic character as one goes down a group in the Periodic Table (Chang, 1991, p. 167).
This, along with the metallic appearance of I2 may be the cause of the alternative
conception.
An interesting alternative conception was related to the bonding in ionic compounds
like sodium chloride (AC 14, Table II). A number of the students seemed to become
confused between ionic bonding and covalent bonding. Two secondary school students,
Anne and Frances, identi ed the bonding in ionic compounds as covalent, despite
initially describing a process of electron transfer. Anne stated ‘the electrons are sharing
between the caesium and the chloride’ and Frances likewise stated ‘the chloride is
electronegative which means it can give away an electron and Na plus means it can
accept the electron’.
The comments made by Frances in particular provide clues to the origins of this
alternative conception. Frances mentioned electron transfer, but went on to state that the
bonding is covalent in nature. Such a description possesses elements of the theory
employed to explain the ionic–covalent continuum.
under. The pressure might make a difference’. Neil possessed a novel view of intermolec-
ular forces, believing that they were affected by gravity (AC 19, Table II) ‘it moves a little
bit, but it must be that the charges on each side would not be as strong I would imagine.
It may be also because it’s affected more by gravity that the others’. In addition, Steve
seemed to believe glass was a crystalline substance stating ‘glass is basically a silica
structure, that’s silicon covalently bonded in a silica structure with SiO4 units’. Although
these views were only expressed by one individual, as mentioned previously, it is possible
that these views are not idiosyncratic and were also held by the other students.
Summary
The interview data revealed prevalent alternative conceptions for chemical bonding
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students may not have encountered such theories explicitly, they may harbour other
alternative conceptions that impact upon their ability to understand such complex and
abstract models.
The students in this study seemed to nd great dif culty remembering details of
models and concepts despite, in some cases, having encountered them in relatively recent
instruction. The amount of material that the students encounter in an undergraduate
science course is formidable. This, coupled with the mass of advanced material encoun-
tered during their postgraduate studies, may offer some explanation for the surprising
number of alternative conceptions revealed for the advanced level students in this study.
It would seem reasonable to conclude that confusion and careless use of terminology is
in uenced by the sheer mass of material the students encounter at the tertiary level. We
have argued previously that it is not feasible to consider removing the teaching of these
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models from the undergraduate chemistry curriculum (Coll & Treagust, in press).
Modern chemistry teachers at the senior secondary and tertiary level face a tension in
the competing aims of teaching, that is, the desire to provide adequate chemistry
knowledge for those seeking specialist careers as chemists, typically chemistry majors, and
yet avoiding overloading non-specialists with unnecessary material that will be of limited
value in their own studies and subsequent careers (Fensham, 1980). However, tertiary
chemistry teachers may wish to consider the advisability of limiting the teaching of such
models until an advanced stage of the undergraduate degree, say the third year of a
conventional 3 year bachelors degree. This proposition is offered as chemistry non-ma-
jors will have little need for models in their subsequent studies. Hence, the value of
teaching, for example, biology majors, sophisticated complex and highly abstract mental
models is in our view dubious.
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Appendix
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190
R. K. Coll & N. Taylor
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191