Ka1= 1.50E-02 Ka2= 7.

50E-08 ka3=
pH [H+] Denominador α0 α1
0 1 1.02E+00 0.9852216738 0.0147783251
0.5 0.3162278 0.033122777 0.9547139312 0.045286058
1 0.1 0.0011500001 0.8695651323 0.1304347698
1.5 0.0316228 4.662281217731E-05 0.6782683224 0.3217309145
2 0.01 0.0000025 0.3999982 0.5999973
2.5 0.0031623 1.816263341641E-07 0.1741089845 0.8258714282
3 0.001 0.000000016 0.0624956058 0.9374340867
3.5 0.0003162 1.531978532839E-09 0.0206417883 0.9791259916
4 0.0001 1.511125000005E-10 0.0066175862 0.9926379353
4.5 3.1623E-05 1.506719840082E-11 0.0020987828 0.9955400865
5 0.00001 1.51225000054E-12 0.0006612663 0.9918994872
5.5 3.1623E-06 1.535891856843E-13 0.0002058919 0.9766312604
6 0.000001 1.612600054E-14 6.201165612E-05 0.9301748417
6.5 3.1623E-07 1.855788399546E-15 1.704007666E-05 0.8082818065
7 0.0000001 2.6250154E-16 3.80950146E-06 0.5714252191
7.5 3.1623E-08 5.057619529967E-17 6.252502074E-07 0.2965822144
8 1E-08 1.2750541E-17 7.842804474E-08 0.1176420671
8.5 3.1623E-09 3.708102399312E-18 8.528021396E-09 0.0404519573
9 1E-09 1.140540001E-18 8.76777666E-10 0.013151665
9.5 3.1623E-10 3.577962368006E-19 8.838208273E-11 0.0041923303
10 1E-10 1.13190000001E-19 8.834702712E-12 0.0013252054
10.5 3.1623E-11 3.613062367693E-20 8.752347284E-13 0.0004151603
11 1E-11 1.17915E-20 8.480685239E-14 0.0001272103
11.5 3.1623E-12 4.097712367689E-21 7.717178212E-15 3.6605790388E-05
12 1E-12 1.665015E-21 6.005951898E-16 9.0089278475E-06
12.5 3.1623E-13 8.957577367689E-22 3.530282274E-17 1.6745599155E-06
13 1E-13 6.5250015E-22 1.532566697E-18 2.2988500462E-07
13.5 3.1623E-14 5.755756386769E-22 5.494113106E-20 2.6060866708E-08
14 1E-14 5.512500015E-22 1.814058952E-21 2.721088428E-09
 Grafica de fraccion molar vs. pH para un acido debil triproti
Disociacion del aciado
H₃PO₄ → H₂PO₄⁻ + H⁺ Ka1 = 1.10 x 1
4.80E-13 H₂PO₄⁻ → HPO₄⁻² + H⁺ Ka2 = 7.5 x 10
α2 α3 HPO₄¯² → PO₄⁻³ + H⁺ Ka3= 4.8 x 10
1.108374383E-09 5.32019704E-22
1.074053173E-08 1.63029809E-20
9.782607739E-08 4.69565171E-19
7.630518627E-07 1.15823129E-17
Grafica de frac
0.0000045 2.15999028E-16 1.2
1.958726076E-05 2.97313714E-15
7.03075565E-05 3.37476271E-14
0.0002322201 3.52485357E-13
0.0007444785 3.57349657E-12
0.0023611306 3.58394431E-11
1
0.0074392462 3.57083815E-10
0.0231628441 3.51587254E-09
0.0697631131 3.34862943E-08
0.1917008625 0.000000291
0.4285689143 2.05713079E-06
0.7034064833 0.000010677 0.8
0.8823155033 4.23511442E-05
α (FRACCION DE CADA FORMA)

0.9594024071 0.000145627
0.9863748742 0.0004734599
0.9942984307 0.0015092389
0.9939040551 0.0047707395 0.6
0.9846390695 0.0149457702
0.9540770894 0.0457957003
0.8681825488 0.1317808454
0.6756695886 0.3243214025
0.3971567559 0.6028415696 0.4
0.1724137535 0.8275860166
0.0618087724 0.9381912015
0.0204081632 0.9795918341

0.2

0
0 2 4
ara un acido debil triprotico. H₃PO₄

H⁺ Ka1 = 1.10 x 10 -2
H⁺ Ka2 = 7.5 x 10 -8
H⁺ Ka3= 4.8 x 10 -13

Grafica de fraccion molar vs. pH para un acido debil triprotico. H₃PO₄

2 4 6 8 10 12 14 16

pH
o. H₃PO₄

a1=H3PO4

a2=(H2PO4)-

a3=(HPO4)--

a4=(PO4)-3

14 16
 Calculo de Ph con progresiones suesivas
Concentracion = 0.01 Ka= 1.75E-05
PH [HOAc] log[HOAc] [OAc-] log[OAc-] log[H+] log[OH-]
0 0.01 -2 -6.756962 0 -14
4 0.01 -2 -2.756962 -4 -10
4.76 0.005 -2.30103 0.005 -2.30103 -4.76 -9.24
5.5 -2.743038 0.01 -5.5 -8.5
12 -9.243038 0.01 -12 -2