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’ Department of Chemical Engineering, Tokyo University of Agriculture and Technologv, Koganei, Tokyo 184, Japan
Department of Industrial Chemistry, Seikei University, Musashino-shi, Tokyo 180, Japan
A two-stage air blown entrained flow gasifier is being developed in Japan for the IGCC process. However, its scale-up
up faces significant difficulties because of ash/slag deposition problems. The ash/slag deposition in the gasifier depends
on both the ash properties and entrainment produced by the swirling gas flow. Therefore, the flow hydrodynamics are
critical issues for the control of the ash behavior. In this paper, a comprehensive simulation model is used to examine
the effects of the gasifier geometry and jet configuration on the flow hydrodynamics in order to control the ash deposi-
tion on the gasifier walls. A swirl number for the multi-stage injection swirling gas flow is defined and proved to be the
most important hydrodynamic scaling law for the entrained flow gasifier.
Un gazeificateur bi-etage a ecoulement entraine par de I’air souffle est en cours de mise au point au Japon pour le
procede IGCC. Cependant, son extrapolation pose des problemes serieux a cause du depBt de cendres ou de scories. Le
depBt de cendres ou de scories est lie a la fois aux proprietes des cendres et a I’entrainement produit par I’ecoulement
de gaz tourbillonnant. Par consequent, I’hydrodynamique de I’ecoulement est un aspect critique du contrde du
comportement des cendres. Dans cet article, on a recours a un modele de simulation complet afin d’examiner les effets
de la geometrie du gazeificateur et de la configuration du jet sur I’hydrodynamique de I’ecoulement dans le but de
contrder le depBt de cendres sur les parois du gazeificateur. Un nombre de tourbillons est defini pour I’ecoulement de
gaz tourbillonnant pour une injection multi-etagee et on demontre que celui-ci est la loi de mise a I’echelle hydro-
dynamique la plus importante pour un gazeificateur a ecoulement entraine.
Keywords: entrained flow gasifier, scale-up laws, numerical simulation, ash behavior control.
THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, VOLUME 77, AUGUST, 1999 145
and deposit on the walls before it cools down. Second, the 1986, Hargreaves and Silvester, 1990; Sloan et al., 1986;
vaporized, sticky fine ash particles may be entrained by the Zhang and Nieh, 1997), yet no model has addressed and been
gas flow and deposit on the surface of the coal particles applied to an entrained flow gasifier. In the present work, a
injected into the reductor, while the newly formed sticky comprehensive coal gasification model is developed to simu-
coal particles tend to easily deposit on the walls. To control late practical entrained flow gasification facilities, and one of
the ash deposition on the reductor walls, an ideal gas flow the main tasks is to model the turbulent flow field in the gasi-
field with the following characteristics is required: suffi- fier. The model uses conventional numerical methods and
ciently strong vortex motion to separate the heavier molten submodels recommended for the entrained flow coal com-
slag from the gas flow in the combustor, minimum up-flow bustion and gasification process (Smoot, 1993). In this model,
velocity in the diffuser to minimize the molten ash slag the gas phase is assumed to be a turbulent, reacting, continu-
carry-over into the reductor, and proper flow distribution in um field that can be describled by partial differential, conser-
the reductor to prevent the jets from rushing directly toward vation equations in Cartesian coordinates. The conservation
the reactor wall, so as to prevent sticky fine particles from equations are Favre averaged and solved by the SIMPLER
moving toward the diffuser wall before it cools down. (Patankar, 1980) method. Turbulence was modeled by the
As a result of failing to recognize the importance of the standard k-E model Launder and Spalding, 1972).
molten ash behavior, the gasifiers developed in Japan to The model is then used to predict the flow field in a hvo-
date, have faced significant operational difficulties caused stage air blown gasifier. The flow domain is divided into
by slagging problems (Araki and Harai, 1996; Hara and rectangular cells bounded by a symmetry wall. The standard
Ichigawa, 1997; Kaneko et al., 1997; Koyama et al., 1996). flow grids consist of 25 cells in the x, y and 52 cells in the z
Since 1983, a 2 MPa 2 t/d bench scale gasifier at CRIEPI direction. Because a structured gridding approach is used,
(Center Research Institute of Electric Power Industry), an the cell boundaries are not laid parallel to the physical
atmospheric 8 t/d gasifier at MHI (Mitsubishi Heavy boundaries, and a jagged edge is thus used to approximate
Industries, Ltd.) and a 2.7 MPa 200 t/d pilot plant in Nakoso the curved boundary. Neglecting the effect of particles on
(IGC Research Association) have been tested. Twenty-two the gas flow field and the non-isothermal effects caused by
types of coals were tested in the 2 t/d gasifier with a total the gasifier walls, the inflow temperature is assumed to be
gasification time of 2220 h (Hara and Ichigawa, 1997). The constant. A uniform distribution of inlet velocity, fully
test in the 200 t/d pilot plant was started in March 1991 and developed flow conditions at the outlet, and no slip condi-
finished by February 1996. Three types of coals were tested tions at the wall are defined. For regions immediately adja-
with the total gasification time of 4770 h (789 continuous h) cent to the wall, the wall b c t i o n approximations are used
(Araki and Harai, 1996; Hara and Ichigawa, 1997). Due to for the near-wall grid nodes to modify the low Reynolds
the too small throat diameter in the original design, the slag- number effect. The turbulence of the nozzle inlet conditions
ging problem (sticking slag that built-up on the wall of the is 0.02 in inlet Reynolds mean stress (rms)/normal velocity
diffuser and occasional plugging of the throat) occurred in (mean inlet velocity 50 d s ) and 0.1 in turbulent length
the Nakoso 200 t/d pilot plant (Araki and Harai, 1996, Hara scalehquare root of nozzle area. A converged solution is
and Ichigawa, 1997). To solve this problem, some modifi- defined when the normalized residual (mean residuahormal
cations were made by changing the structural parameters and velocity) for each velocity component is less than 0.0001
operating conditions. Among them, increasing the ratio of the
throat diameter to combustor diameter (Dth/D,) from 0.4 to ABOUTTHE SIGNIFICANT DIMENSIONLESSGROUPS DERIVED
0.8 proved to be an effective measure for controlling the slag FROM BASIC EQUATIONS
growth, and the 200 t/d air blown gasifier has operated quite
succcsshlly under various operating conditions after the To develop a rational data correlation technique and
improvement. Further scaling of the gasifier up to a commer- scale-up procedures for the design of commercial size
cial scale plant is expected over the next several years. In plants, the significant dimensionless groups were derived
order to deal with slagging during the scale-up, the overall from basic equations (see Appendix).
design principles and scaling laws for the entrained flow gasi- Refering to the Appendix, the Reynolds, Froude and
fier should be established. Such scaling laws would provide Swirl numbers are significant dimensionless groups derived
us with not only a deeper confidence for the prediction of the from basic equations. In principle, the gas flow field simili-
effects of. the design variables on gasifier performance, but tude requires the same Re, Fr, and Sw numbers between the
also sufficient information on controlling of the ash deposi- model and the prototype systems. It should be noted that the
tion behavior. In the present paper, a comprehensive simu- Swirl number expressed in Equation (A-20) is deduced
lation model is used to examine the scaling-up issues for the under the condition of constant flow rate and nozzle radius
two-stage entrained flow coal gasifiers. The significance of for all jets. Considering a general multi-injection system
controlling the ash behavior in the entrained flow gasifiers with varied mass flow rate and nozzle size, it is easy to be
is demonstrated by controlling the gas flow distribution. understood that the Swirl number will include the flow rates,
jet orientations and nozzle sizes for all the jet nozzles.
Mathematical methods Therefore, for the multi-stage injection swirl/vortex flow, a
strict geometric similarity including jet orientation and flow
NUMI:KIC~\L
SIMULATION OF THE GAS FLOW FIELD IN ENTRAINED
proportional allotment to each jet is necessary to satisfy the
FLOW (iASIFIF.RS
hydrodynamic resemblance.
As described above, the gas flow field in the gasifier is a Results and discussion
strong swirl flow produced by the orientation of jets issuing
from the air, coal and char injection nozzles. Differing from GENERAL HYDRODYNAMICS OF THE TWO-STAGE ENTRAINED
the flow fields produced by swirling jets, such a swirl flow FLOW GASIFIER
is strictly classified as a ‘vortex’ flow field. Special computa-
tional efforts made in swirl and vortex flow fields are similar For the purpose of optimizing the gas flow field, it is very
and can be extensively found in the literature (Boysan ‘et al., important to study the effects of gasifier geometry and jet
Figure 2 - Effect of throat diameter ratio (DfhlD,) on gas flow Figure 3 - Effect of swirl diameter ratio for the combustor burners
field, 200 tJd, qFW,
: D,cw2: Drw3= 0.1 : 0.44 : 0. (DswllDpw2)on gas flow field, 200 t/d, DfhlD,. = 0.8, O,,.,lD< = 0.
(D,JD,) on gas flow field, 200 t'd, D,,lDC = 0.8, D,,,,,lOC= 0.1,
Before the improvement, it was considered that the molten D,Fw.2/Dc= 0.44.
slag was carried by the up-flow to the diffuser, thrown to
and accumulated on the water cooled wall, and/or mixed
x - z cross section for various combinations of swirl diameter
with the injected fuel and condensed in the area near the
ratios for the lower combustor burners (D,tu,lID,.) and higher
reductor burners.
ones (D,,,,2/D,). With an increase in D,pwl/Dc, the region of
Effects of swirl diameter of lower and higher combustor flow reversal increased in the combustor, but the position of
burners flow reversal moved hrther down the combustor. The rela-
tive change in the flow reversal position shows that it would
The model was used to study the effects of swirl diameter be necessary to provide a smaller D,,u,lIDcthan D,cu,,IDc.to
ratio (diameter of undeflected jet circleldiameter of combus- maintain the positive axial velocity at the bottom in ordcr to
tor, D~,,/DC) on the gas flow field in the gasifier. With a prevent char particles from dropping out of the combustor.
Dlh/D, of 0.8 while keeping all other parameters constant, a On the other hand, the changes in Dpw2lDc show a signif-
simulation was conducted for swirl diameter ratios ranging icant effect on the flow field above the diffuser as seen in
from 0 to 0.5. Figure 3 compares the 2-D velocity vector at the Figure 3. As D,,,,/D, increases, the location of the axial
THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, VOLUME 77, AUGUST, 1999 147
TABLE1
The Operating Conditions and Parameters for Gasifiers Types
x-XIV
Type X XI x 11 x 111 x IV
Scale 1 114 1 114 114
Load ([Id) 200 model 8 model 2
DdDL 0.4 0.4 0.4 0.4 0.4
D F W , :r)cw,2:DFw3 0.1:0.44:0 0.1:0.44:0 0.1 :0.44:0 0.1:0.44:0 0.1:-:o
Temperature (K) I897 298 1897 298 1800
Pressure (MPa) 2.7 1.02 0.1 0.1 2.0
sw 11,s 11.5 11.5 11.5 7.2
Fr 7.96 x 1 ~ 3 7.96 x lC3 7.96 x I t 3 3.19 x 1C2 7.76 x IC3
Re 1 . 0 105
~ 1.0 105 3.7 x 103 2.0 104 8.4 x 103
the molten slag from the gas flow and char particles. ~ “iu”
--- vill
748 THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, VOLUME 77, AUGUST, 1999
The general hydrodynamics in an entrained flow gasifier From Equations (A-5) and (A-6), the Froude number Fr =
and the hydrodynamic scaling laws for the entrained flow U,,/(gI), the Reynolds number Re E Uo pllp, and the dimcn-
gasifiers were examined by calculating and comparing the sionless terminal velocity of particle ulUo are important
velocity distributions within the different scaled cold and dimensional groups derived from the motion equations of
hot gasifier models operating under various conditions. The gas and particles.
following useful conclusions can be drawn as guidelines for For the vortex flow field, the circumferential and axial
the scale-up of the two-stage entrained flow gasifiers: conservation equations of momentum are necessary. The
(1) The swirl flow is sensitive to the throat diameter. The integral forms are written as:
small throat diameter would be responsible for the sticky
molten ash particle carried over to the reductor.
jt
G, = pu, r2 xm, dr . . . . . . . . . . . . . . . . . . . . . (A-7)
(2) Special attention should be paid to determining the swirl G, = jt pu, r2 xruz dr ..................... (A-8)
diameter ratio in order to control the solid particle motion.
A small swirl diameter for the lower combustor burner, and According to the definition of Beer and Chigier (1972),
an intermediate swirl diameter for the reductor burner are the swirl number for the combustor system is given by:
recommended to prevent the sticky particles from moving
toward the reductor walls.
(3) The Swirl number was the most important hydrodynam-
ic scaling law for the multi-stage injecting swirl flow
gasifers. For scaling-up these types of gasifiers, a restricted It will be convenient for the analysis to define three char-
geometry similarity including jet orientation and flow pro- acteristic velocities of the circumferential, radial and axial
portional allotment to each jet is required. components of uecl u, and uzc. First, the characteristic cir-
(4) The Reynolds number has no effect on the swirl flow cumferential velocity is obtained from the steady state form
distribution similarity within the studied range. The Froude of the momentum equation. Referring to Figure 1 for the
number has little effect when the particle effect was neglected. definition of the geometrical parameters, the transfer of cir-
Further research is required to investigate the effects of parti- cumferential momentum from the jet nozzles entrances at
cles and its reaction on the gas flow hydrodynamics scaling the outer periphery of the gasifier to the gasifier itself can be
law, based on the coupled gas-particle simulations. expressed as:
Neglecting the effects of particles on the gas flow field where R, is the radius of the ith undeflected jet circle,
and the change in gas density, the Navier-Stokes equation is R, = R sin ai . . . . . . . . . . . . . . . . . . . . . . . . . . . (A-I 1)
written as:
The average jet circle radius (r?) for the multi-stage injcc-
=-pge, -Vp+pV u . . . . , 2 tion system is:
n
dv R, = i=l . . . . . . . . . . . . . . . . . . . (A-13)
- = g[( u - v ) 1 ut - e, ] . . . . . . . . . . . . . .. . . . 2
dt
Assuming a constant normal velocity V, and nozzle
Choosing a characteristic gasifier length I, a characteristic radius R, for all jets:
axial gas velocity Uo,and introducing the following dimen- mi = mln = pn V, R i . . . . . . . . . . . . . . . . . . . . . (A-14)
sionless dependent variables:
Substituting Equations (A-1 I), (A-13) and (A-14) into
P 3 p;(p u;),i = t /(I / u,),li= u / u,, 3 = v / u,, v 3 Iv Equation (A- lo), the characteristic circumferential velocity
........................................ is thus reduced to:
(A-4)
n
the dimensionless form of Equations (A-1) and (A-2) are 2Csinai / n
given by:
uec = V, i= I
n . . . . . . . . . . . . . . . . . . (A-15)
?+ 1 "
u.Vli=--ez-VP+-V
1 "2- -
u ...,.., 1+ C s i n a i / n
'at
li (* * ) Fr Re (A-5)
i= I
Secondly, the characteristic axial velocity is obtained
from the mass flow rate of the gas leaving the gasifier and
thc gasifier geometry:
THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, VOLUME 77, AUGUST, 1999 749
Reynolds number
particle Reynolds number
swirl radius of jet, (m)
(A- 16) Swirl number
characteristic axial gas velocity, ( d s )
normal velocity at nozzle outlet, (m/s)
Finally, the characteristic radial velocity can be expressed particle diameter, (m)
as the radial component of the mass flow through the noz- (O,O, 1)
zles divided by the larger flow area of the gasifier: gravity acceleration, (m/s2)
turbulent kinetic energy, (m2/s2)
,I n characteristic gasifier length, (m)
total mass flow rate, (kg/s)
pressure, (Pa)
(A- 17) dimensionless pressure
radius of combustor or reductor, (m)
time, (s)
G, and G7 defined in Equations (A-7) and (A-8) can b e dimensionless time
approximated as: velocity vector, ( d s )
dimensionless velocity
G, zz puHcR,2 xruz dr = m Rc u,, . . . . . . . . . . (A- 18) particle terminal velocity, (m/s)
velocity components at 8, z, and r directions. (m/s)
. ,
G- = jg pu; 2 nmz dr = muzc . . . . . . . . . . . . . . . (A-19) uOr uzc, u,, = characteristic velocity at 8, z, and r direction, (m/s)
V = particle velocity, (m/s)
By substituting Equations (A- 15), (A-1 6), (A-1 8) and 0 = dimensionless particle velocity
(A-19) into Equation (A-9), the Swirl number is reduced to: x, y , z = coordinates, (m)
n Greek symbols
ai = jet angle with radius
E = rate of dissipation of, (k)
P = viscosity, (Pa.s)
P>PP = gas density, particle density, (kg/m3)
Equation (A-20) indicates that the Swirl number of the References
multi-stage injecting swirl flow in the gasifier is a function
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velocities. The interpretation of the velocity ratio in terms of Science Publisher, Ltd., London, England (l972), pp. 70-120.
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Shinada, “Operational Results of the Air Blown Entrained Flow
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Koyama, S., T. Morimoto, A. Ueda, and H. Matusoka, “A
Acknowledgement Microscopic Study of Ash Deposits in a Two-stage Entrained-
bed Coal Gasifier”, Fuel 75, 45%65 ( 1 996).
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CD = particle drag coefficient Turbulent Flow Systems”, Prog. Energy Combustion Science
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Rl = characteristic swirl radius, (m)
Rn = nozzle radius, (m) Manuscript received July 7, 1998; revised manuscript received
R = average radius of jet circle, (m) May 13, 1999; accepted for publication May 25, 1999.
750 THE CANADIAN JOURNAL OF CHEMICAL ENGINEERING, VOLUME 77, AUGUST, 1999