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Lec-03, AE-210
Isentropic Flow
Free Energy
• Helmholtz Free Energy : A=U-TS
Z for Nitrogen
Properties of a Gaseous Mixture
• Molecular Weight :
• Gas Constant:
• Cp:
• 𝐶𝑣 = 𝐶𝑝 − 𝑅
𝐶𝑝
•𝛾=
𝐶𝑣
Thermally Perfect Gas
Variation of Cp Variation of γ
Air mixture Composition
Species considered Molecular weight (m) Gas constant Mass fraction of each
(g/mol) R = Runi/m species
(J/Kg-K)
H2 2.01588 142.3993 ̴0
H2 200-1000 4.08E+04 -8.01E+02 8.214702 -1.27E-02 1.75E-05 -1.20E-08 3.37E-12 0.00E+00 2.68E+03 -3.04E+01
1000-6000 5.60E+05 -8.37E+02 2.975363 1.25E-03 -3.74E-07 5.94E-11 -3.61E-15 0.00E+00 5.34E+03 -2.20E+00
N2 200-1000 2.21E+04 -3.82E+02 6.082738 -8.53E-03 1.38E-05 -9.63E-09 2.52E-12 0.00E+00 7.11E+02 -1.08E+01
1000-6000 5.88E+05 -2.24E+03 6.066943 -6.14E-04 1.49E-07 -1.92E-11 1.06E-15 0.00E+00 1.28E+04 -1.59E+01
O2 200-1000 -3.43E+04 4.85E+02 1.119012 4.29E-03 -6.84E-07 -2.02E-09 1.04E-12 0.00E+00 -3.39E+03 1.85E+01
1000-6000 -1.04E+06 2.34E+03 1.819729 1.27E-03 -2.19E-07 2.05E-11 2.34E+03 0.00E+00 -1.69E+04 1.74E+01
Xe 200-1000 6.61E-03 -9.54E-05 2.500001 -1.50E-09 2.21E-12 -1.65E-03 4.85E-19 0 -7.45E+02 6.164417
1000-6000 1.10E+03 -3.32E+00 2.503878 -2.25E-06 6.87E-10 -1.05E-13 6.29E-18 0.00E+00 -7.24E+02 6.14E+00
CO2 200-1000 4.94E+04 -6.26E+02 5.301725 2.50E-03 -2.13E-07 -7.689988780e-I0 2.85E-13 0.00E+00 -4.53E+04 -7.04828
1000-6000 1.18E+05 -1.79E+03 8.291523 -9.22E-05 4.86E-09 -1.89E-12 6.33E-16 0.00E+00 -3.91E+04 -2.65E+01
200-1000
1022.5023
72 -0.20772 0.000481 -3.91E-08 -1.19E-10 -304303 895.722
1000-
6000
886.29058
78 0.352172 -0.00012 1.88E-08 -1.11E-12 -285881 1527.381
Variation of 𝐶𝑝 and γ with Temperature
(K) (5 constant form)
𝐶𝑝 v/s T γ v/s T