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Page 8 Revise water specification based on the latest spec agreed with GTG vendor
Contents
1. 0BINTRODUCTION......................................................................................................................... 4
2. REFERENCES............................................................................................................................ 6
3. SCOPE........................................................................................................................................ 7
4. DEFINITION................................................................................................................................ 7
Appendices
Appendix 1 – Calculation – Chemical Consumption
Appendix 2 – Simplified PFD
Appendix 3 – Well and Well-pad Design Rates – Table 10-3 Facilities Design Basis
Appendix 4 – Heat and Mass Balance Flow Summary by Case – Table 10-9 Facilities Design Basis
Appendix 5 – Well Fluid Composition – Table 8.1 ~ Table 8.2 and Table 10-4 ~ Table 10-6 Facilities
Design Basis
1. INTRODUCTION
0B
This report summarizes chemical injection system in the Banyu Urip Central Field Facility (CFF).
Calculation result in this report is based on chemical dosage injected to a certain point based on
vendor information.
Chemicals vendors approved by COMPANY are contacted to provide required information for the
chemical tank sizing, pump sizing and allocation of the area for the chemical tanks.
Contingency of 10% to the calculation is added to cover any uncertainties information that could have
different dosage between selected vendor and current information from contacted vendor. Chemical
consumption shown here in this report may change subject to dosage used by the selected vendor.
To mitigate the risk of production flowline plugging due to crude oil gelling.
- Demulsifier
- H2S Scavenger
To meet H2S content specification (not exceed 10 ppm), injected during process upset
conditions
- Scale Inhibitor
- Methanol
To avoid hydrate formation at choke valves during start-up and blowdown of gas
injection/cap gas production flowlines
- Corrosion Inhibitor
- Oxygen Scavenger
Injected to achieve a dissolved oxygen level of less than about 20 ppb for adequate
control of corrosion rates in the carbon steel injection water flowlines and well tubing
Injected to remove acid gases from a hydrocarbon process flow such as hydrogen sulfite
and carbon dioxide
- Phosphoric Acid
Is recommended to install provision points for batch treatment of the Lean Amine Inlet
lines to the AGRU and AGE Absorber
- Glycol pH Control
To maintain pH of the tri-ethylene glycol (TEG) between 6.5 and 7.5 for proper
performance
- Water Clarifier
Injected to help to settle out solids suspended in the fluid stream by means of
coagulation ; i.e Iron(III) Chloride and Lime
- Polyelectrolyte
Is added to water to aid the chemical coagulation process by increasing the speed of
particle charge neutralization and physical combination of small particles into masses
sufficiently large to be filtered out.
To avoid excessive corrosion of topsides pipework and other process equipment with
which it may come into contact
- Hypochlorite
To limits the effect of organic material and protection from contact with pathogenic
organism
To neutralize water from sulfur pelletizer system if direct contact type of pelletizer is
utilized.
For Sodium hydroxide injection package of Neutralization Pit, make up of day tank
- Sulfuric Acid
For Sulfuric acid injection package of Neutralization Pit, make up of day tank
- Morpholine
To maintain pH of BFW system between 8 and 9.5 for HRSGs, SRU WHB & TO WHB
and Package Boiler
- Sodium Metabisulfite
Most of the chemicals for the Banyu-Urip facility are injected continuously, such as corrosion Inhibitor
due to the corrosive nature of the Banyu Urip produced fluids, and a desire to use carbon steel for the
FWS flow-lines and much of the hydrocarbon and produced water process trains
2. REFERENCES
[1] FACILITY DESIGN BASIS IDBU-ED-BBPDB-000002_Rev 3
[2] HEAT AND MASS BALANCE – NON LICENSOR IDBC-TS-PCCAL-C00011_Rev 0
[3] HEAT AND MASS BALANCE – LICENSOR IDBC-TS-PCCAL-C00013_Rev 1
[4] PROCESS FLOW DIAGRAM – NON LICENSOR IDBC-TS-PDPFD-XXXXX_Rev 0
[5] PROCESS FLOW DIAGRAM – LICENSOR IDBC-TS-PDPFD-XXXXX_Rev 0
3. SCOPE
The scope of this study is stated at the Exhibit A – Scope of Work, chapter 3.3.1.2 item no.7,”
Chemical Injection Systems: The P&IDs reflect the chemicals and their injection locations in IDBU-
ED-RBPDB-000009, Recommendations for Chemical Treatment and Corrosion Monitoring of Oil and
Gas Production Facilities, in Exhibit E. However, equipment vendors may have chemical treatment
requirements that are different that what is shown on the P&IDs, especially with the boiler feed water
and raw water treatment systems.”
The P&IDs for chemical systems, especially for the boiler feed water and raw water treatment
systems will be updated wherever applicable.
4. DEFINITION
COMPANY COMPANY is defined as Mobil Cepu Limited (MCL)
CA Antifoams
CD Demulsifiers
CE Polyelectrolytes
CH Biocides
CM Methanol, Morpholine
CW Water Clarifier
CX Caustics
Well fluid composition as shown in the table 10-4 of Facilities Design Basis (Appendix 5) is also
considered in determining type and dosage of chemicals to be injected.
Water for Boiler and GTG NOx control is requiring treatment to achieve below specification:
pH = 8.0–9.5 for HRSGs, SRU WHB & TO WHB, Package Boiler / pH = 6.0-8.5 for GTG
Ammonia (ppm) = -
6. CHEMICAL CONSUMPTION
Chemical consumption for CFF is summarized in the table below. Total consumption rate could be
changed depend on the dosage recommended by selected vendor. This total consumption is
including 10% margin.
Continuous or as
5 20 0.4 1.6
required
Containers with 4 L
Antifoam volume will be
5 20 provided on pumps Batch for AGRU, AGE
suction at the Gas
Treating system
Continuous and
Intermittent
Biocide/Hypochlorite 0.5 2 18.43 29.02
concentration 8000
ppm
Continuous for pH
Morpholine (Note1) 10 20 0.02 0.03
control of BFW
Manually dosed
depend on the water Batch (for Potable
Calcium Chloride As Required
quality to meet WHO Water Dosing Unit)
standard quality
Manually dosed
depend on the water Batch (for Potable
Sodium Bicarbonate As Required
quality to meet WHO Water Dosing Unit)
standard quality
Note.1. Special chemicals to achieve required pH with negligible impact to conductivity and TDS. To be confirmed later.
The detail calculation of the chemical consumption can be found in the attachment 1 of this report.
In the package items, chemicals are also required such as to keep Feed and make-up Water for
Boiler and HRSG in the specification.
Quantity of the chemicals for the package item is shown in table below:
Chemical
Total Consumption
Dosage Level
Description Rate (m3/day) Remarks
(ppm)
HRSG Continuously
Scale Inhibitor
(same chemical
with scale Injected to Reverse Osmosis Unit (RO)
5 0.156
Continuously
inhibitor for
hydrocyclone)
Styrene – Maleic
Pour Point 0.89 – 0.95
Anhydride 33 – 35 Yes
Depressant (@15.6 oC)
Copolimer
Naphtalene,
Demulsifier 0.94 – 0.98 28 – 30 Yes
Aromatic Naphta
Tetrahydro-2H-
Morpholine 0.85 – 0.95 35 – 38 Yes
1,4-oxazine
0.8 – 1.1
Antifoam Glycol Base 22.9 No
(@21.1 °C)
Alkylamine
Benzyl-(C12-C16
Linier Alkyl)- 66 – 69 (ASTM D-
H2S Scavenger 1 – 1.18 (@15 °C) Yes
Dimethyl- 93) (Note 1)
Ammonium
Chloride
1.0 – 1.1
Biocide Glutaraldehyde Not Flammable No
(@20 °C)
Dimethylamine –
1.14 – 1.18
Polyelectrolyte Epichlorohydrin Not Flammable No
(@25 °C)
Copolymer
103 – 106
pH Control Water, Amines 1 – 1.1 (@16 °C) No
(PMCC)
1.48 – 1.54
Sodium
pH Control (@25 °C) ASTM Not Flammable No
Hydroxyde
D-1298
Potasium
pH Control 2.044 (Water = 1) Not Flammable No
Hydroxyde
2.1 – 2.3
Calcium Chloride CaCl2, powder Not Flammable No
(@68 °F)
Methanol 12 Yes
Sodium
Not Flammable Yes
Hypochlorite
Sodium
Not Flammable No
Metabisulfite
7. CHEMICAL STORAGE
Storage that are provided in the Banyu Urip facility, such as iso tank which has a capacity of 25 m3
and tote tank with capacity of 2 m3 for each tank will be used to store chemicals required.
The material required for the chemical storage will be based on MSDS required by selected vendor.
Chemical requirement for one month consumption is shown in the table below:
One Month
Consumption Containers
3
Storage
Chemicals Dosage (ppm) (m /month), Required for
Location
Including batch 30-day Storage
injection
Note. Chemical consumption may change subject to dosage used by selected vendor. Chemical consumption here in this table
is including 10% margin.
And for the package vendor, below table is shown one month consumption:
One Month
Dosage Consumption Containers Required for Storage
Chemicals 3
(ppm) (m /month), Including 30-day Storage Location
batch injection
Caustics will be
Area “P” and
Caustics 500 – supplied from Sodium
84.5 chemical
30% 40,000 Hydroxide Tank
shelter
(ABJ678511)
Appendix - 1
CHEMICAL CONSUMPTION
Continuous Injection
Total for Wellpad s 185 29,413 200 922.7 6.38 191.3
500 922.7 15.94 478.2
Low Producing Well 1 159 200 922.7 0.03 NA
500 922.7 0.09 NA
High Producing Well 20 3,180 200 922.7 0.69 NA
500 922.7 1.72 NA
* 1month=30days
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. PPD dosage is based on Styrene - Maleic Anhydride Copolymer
3. Total Chemical Required is including 10% Margin
4. Range required for each well control valve to cover cases 1 - 4 flows
CALCULATION SHEET
Continuous Injection
Total for Wellpads 200.1 31,813 10 994 0.32 9.6
30 994 0.96 28.8
Low Watercut Well 1.0 159 10 994 0.002 0.05
30 994 0.005 0.14
High Watercut Well 10.0 1,590 10 994 0.02 0.5
30 994 0.05 1.4
* 1month=30days
C. Total CI Required
CI Dosage (ppm) m3/day m3/month Margin (%) Iso Tanks/Month
10 0.6 18.6 0.7
10
30 1.7 55.9 2.2
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
CALCULATION SHEET
B. Total CI Required
CI Dosage (ppm) m3/day m3/month Margin (%) Iso Tanks/Month
5 0.1 4.1 0.2
10
30 0.8 24.8 1.0
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
3. Pump Capacity is recommended to reduce (to be confirmed after chemical vendor selected)
CALCULATION SHEET
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
CALCULATION SHEET
Demulsifier (CD)
Page 1 of 1
B. Total CD Required
CD Dosage (ppm) m3/day m3/month Margin (%) Iso Tanks/Month
10 0.76 11.1 0.4
10
50 3.80 55.3 2.2
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
CALCULATION SHEET
Antifoam (CA)
Page 1 of 1
B. Total CA Required
CA Dosage (ppm) Continuous Injection Batch Injection
Margin (%) Iso Tanks/Month
m3/day m3/month
5 0.4 13.0 Container with 4 L capacity of antifoam will be provided on 0.5
AGRU and AGE reflux pump that required batch injection 10
20 1.6 52.1 of antifoam 2.1
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Antifoam for Amine System is Glycol Base (Recommended by LICENSOR (SHELL))
3. Total Chemical Required is including 10% Margin
CALCULATION SHEET
B. Total CS Required
CS Dosage (ppm) m3/day m3/month Margin (%) Remarks
2 0.4 NA
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Using Maximum Concentration, chemical will be injected at one point only
3. Total Chemical Required is including 10% Margin
CALCULATION SHEET
O2 Scavenger (CS)
Page 1 of 1
B. Total CS Required
CS Dosage (ppm) m3/day m3/month Margin (%) Tote Tanks/Month
2 0.28 8.46 4.2
10
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
CALCULATION SHEET
Biocide/Hypochlorite (CH)
Page 1 of 1
Potable Water Tank Inlet 10.0 240 0.5 1,072 0.6 0.014 0.4
Continuous Injection
0.5 1,072 0.6 0.014 0.4
Basin Water Intake 2,200.0 52,800 1 1,072 275 6.600 198.0
Continuous Injection
2 1,072 550 13.200 396.0
Media Filter Sump 2,040.0 48,960 1 1,072 255 6.120 183.6
Continuous Injection
1 1,072 255 6.120 183.6
Water Deaerator Inlet 1,810.0 43,440 1 1,072 0.000 0.0 to be
to be confirmed by
confirmed by 24,000.0 Intermittent Injection (Provision)
1 1,072 0.000 0.0 vendor
vendor
Waste Water Treatment Unit 200.0 4,800 1,072 0.000 0.0
Intermittent Injection
2 1,072 50 1.200 36.0
Diesel Fuel Inlet Filter 40.0 960 1,072 0.000 0.0
Intermittent Injection
2 1,072 10 0.240 7.2
Discharge of Recycle Pumps 2.0 48 1,072 0.000 0.0
Intermittent Injection
2 1,072 1 0.012 0.4
LP Degassing Vessel Inlet 1,406 33,750 1 1,072 3.937 118.1
Intermittent Injection
2 1,072 7.873 236.2
Riverwater Lift Pumps 1 1,072 0.000 0.0
Via tote tank N/A N/A Intermittent Injection
2 1,072 0.286 8.6
* 1month=30days
B. Total CH Required
3 3
CH Dosage (ppm) m /day m /month Remarks Margin (%)
0.5 18.34 550.15
10
2 28.95 955.20
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
3. Generator sized for 24 m 3 /day with 0.8% concentration
4. Biocide for Sewage Treatment Unit to be provided as a tablet feeder(capa : 60days feeding).
CALCULATION SHEET
* 1month=30days
B. Total CE Required
CE Dosage (ppm) m3/day m3/month Margin (%) Tote Tanks/Month
0.5 0.08 2.32 1.2
10
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
CALCULATION SHEET
Clarifier (CW)
Page 1 of 1
* 1month=30days
B. Total CW Required
3
CW Dosage (ppm) m /day m3/month Margin (%) Remarks Iso Tanks/Month
12 1.82 56.4 CW Injected to the 2.3
10 Hydrocyclone is provision
only 0
Note:
Methanol (CM)
Page 1 of 1
Total Gas CM injected Total Chemical Injected CM Tank Capacity CM Supply Pump Capacity CM Supply Pump Capacity
Remarks
3 3 3 m3 3 m3/hour (Normal) l/d (Normal)
MSCFD ppm m /day m /month m m /hour (Normal) l/d (Normal)
(Recommended) (Recommended) (Recommended)
Gas Injection to wellpad A 20 (Note 3) 3.606 NA Batch as Required
0 - 7,500 0 - 3,600
Gas Injection to wellpad C 20 (Note 3) 3.606 NA 10.0 2.0 10.0 0.2 Batch as Required
(2x100%) (2x100%)
Maximum Capacity of AGRU 39 (Note 4) 7.031 NA Batch as Required
* 1month=30days
B. Total CM Required
3 3
CM Dosage (ppm) m /day m /month Margin (%)
3.61 NA
7.03 NA
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. MSCFD = 106 SCFD
3. Max. Start-up rate requiring Methanol
4. Design Case of AGRU
CALCULATION SHEET
Morpholine (CM)
Page 1 of 1
BFW pump suction 145.0 3,480 0.15 0.0017 0.1 Continuous Injection
2.0 - 100.0 Dosage 0.15 ppm for pH 8 /
45 0.5220 15.7 45ppm for pH 9.5
* 1month=30days
Note:
1. Actual injected concentration may change upon chemical supplier selection
2. Total Chemical Required is including 10% Margin
CALCULATION SHEET
H2SO4 (98%) Regeneration 40000 8.6 200 500 12,000 25 Once per day 84 30 2520
NaOH (30%) Regeneration 40000 7.7 900 1500 36,000 25 Once per day 376 30 11280
H2SO4 (98%) UF cleaning 1470 58 48 100 2,400 0.83 8 times a day 1.4 240 336
NaOH (30%) UF cleaning 1200 58 175 220 5,280 0.83 8 times a day 2.4 240 576
RO units
NaOCl (2%) UF cleaning 10 58 29 150 3,600 0.83 8 times a day 0.4 240 96
Antiscalant
RO operation 5 108 5.4 10 240 - continuous - - 3888
(*)(10%)
SMBS (30%) RO operation 5 108 1.8 5 240 - continuous - - 1296
* Antiscalant is same chemical with scale inhibitor for hydrocyclone. / concentration to be confirmed later
* For NaOH, allowable maximum concentration is 30% due to viscosity and freezing point (solidification).
Total chemical consumption for water H2SO4 98% 4,636 liter/month 5,563 liter/month Note 1
packages NaOH 30% 13,964 liter/month 16,757 liter/month Note 2
NaOCl 2% 96 liter/month 115 liter/month
Antiscalant 10% 3,888 liter/month 4,666 liter/month
SMBS 30% 1,296 liter/month 1,555 liter/month
CaCl2 5% 14,400 liter/month 17,280 liter/month
NaHCO3 5% 14,400 liter/month 17,280 liter/month
Note
1. 7.2 m3 of H2SO4 98% with 20% margin would be applied to consumption for Neutralization Pit.
Total consumption of H2SO4 98% would be 12.8 m3/month.
2. 1 m3 of NaOH 30% would be applied to consumption for Neutralization Pit.
Total consumption of NaOH 30% would be 18 m3/month.
3. Mixing facility for powder chemicals such as SMBS, CaCl2 and NaHCO3 shall be supplied.
CALCULATION SHEET
- Normal Daily consumption : Dosing rate x normal steam production rate = 36.0 g/day
Normal Daily consumption of phosphate solution of 1 % concentration 3.6 liter / day
=> Consumption of liter/month (30days) 108.1 liter / month
=> Consumption of liter/hr 0.2 liter / hr
- Chemical Day Tank capacity : 1 m3
=> Total Consumption with 20% margin 752 liter / month (1 Tote tank)
IDBC-TS-PRZZZ-C00004
CHEMICAL SYSTEM STUDY 02 Nov 12
BANYU URIP
Rev 2
PROJECT
MPI: Not Classified APPENDIX
Appendix - 2
SIMPLIFIED PFD
Appendix – 3
WELL AND WELL-PAD DESIGN RATES –
TABLE 10-3 FACILITIES DESIGN BASIS
Wellpad 10 2 (4) 4 1
1 68 93 65 700 16" 20 112 14"
A (20,26) (3 , 16) (28) (51)
Wellpad 10 1 5
0 0 94 116 50 700
2x
20 140 14"
B (20,17) (2 , 7) (28) 14"
Wellpad 10 1 4 1
0 75 96 50 2000 20" 20 112 14"
C (20,27) (3, 5) (28) (45)
Notes:
1. The 4th or spare injection pump and facility can be used for downtime makeup to 440 kbwpd if
needed.
2. Maximum water injection rate is 28 kbwpd per well.
3. Tentative flowline sizes to be confirmed during flow assurance simulations.
4. Existing BU-A2 well at Wellpad A was formerly earmarked as a fourth Clastic Producer but is now
a "Future Use" well.
5. Water injection lines to be sized for maximum water injection capacity on wellpad.
6. Predicted peak rates were from reservoir simulation results, which are subject to uncertainty and
future adjustment. They were intended to be used as guideline for facility design basis. Consult
with Subsurface group when considering revise / optimize facility design based on the numbers
shown in the table.
Appendix – 4
HEAT AND MASS BALANCE FLOW SUMMARY
BY-CASE –
TABLE 10-9 FACILITIES DESIGN BASIS
Appendix – 5
WELL FLUID COMPOSITION
TABLE 8-1 ~ TABLE 8-2 – AND TABLE 10-4 ~
TABLE 10-6 FACILITIES DESIGN BASIS
Notes:
(1) Non-Solution Gas is an assumed composition to be used for design simulations and represents a
weighted average combined composition of about 15% original Clastic cap gas and 85% Case-1
injection gas.
Table 10-6 below provides an analysis of the initial formation water. With break through of the
injection water and increasing water cuts, the following composition will change over time as it is
diluted with injection water.