452 Thermodynamics and Thermochemistry

1. The internal energy change when a system goes from state A (c) Entropy (d) Free energy
to B is 40 kJ/mole. If the system goes from A to B by a reversible
path and returns to state A by an irreversible path what would be 9. Which of the following statements is true [KCET 2002]
the net change in internal energy
(a) E is always greater than H
[CBSE PMT 2003]
(a) 40 kJ (b) > 0 kJ (b) E is always less than H
(c) < 40 kJ (d) Zero (c) E may be lesser or greater or equal to H
2. The correct relationship is [DPMT 2002]
(d) E is always proportional to H
(a) H  PV  V (b) H  nRT  E
10. Mass and energy are conserved is demonstrated by
(c) E  nRT  P (d) None of these
[MH CET 2002]
3. For CaCO 3 (s) ⇌ CaO(s)  CO 2 (g) at 977 o C ; H  176 kJ
(a) First law of thermodynamics
mol, then E is [BVP 2003]
(a) 180 kJ (b) 186.4 kJ (b) Law of conservation of energy
(c) 165.6 kJ (d) 160 kJ (c) Law of conservation of mass
4. Values of H and S for five different reactions are given below. (d) Modified form of I law of thermodynamics
st

Reaction H (kJ mol 1 ) S (JK 1 mol 1 ) 11. The enthalpy of the reaction,
I +98.0 +14.8 1
H 2 (g)  O 2 (g)  H 2 O(g) is H 1 and that of
II – 55.5 –84.6 2
III +28.3 –17.0
1
IV – 40.5 +24.6 H 2 (g )  O 2 (g)  H 2 O(l) is H 2 . Then [KCET 2004]
2
V + 34.7 0.0
On the basis of these values predict which one of these will be (a) H 1  H 2 (b) H 1  H 2  0
spontaneous at all tempeature
[Kerala PMT 2004; KCET 1988,90] (c) H 1  H 2 (d) H 1  H 2
(a) Reaction I (b) Reaction II
12. A reaction occurs spontaneously if
(c) Reaction III (d) Reaction IV
[MP PET 2002; CBSE PMT 2005]
(e) Reaction V
5. Molar heat capacity of water in equilibrium with ice at constant (a) TS  H and both H and S are +ve
pressure is [IIT JEE 1997]
(b) TS  H and both H and S are +ve
(a) Zero (b) Infinity ()
(c) TS  H and both H and S are +ve
(c) 40.45 kJ K 1mol 1 (d) 75.48 J K 1
(d) TS  H and H is +ve and S is –ve
6. Internal energy does not include
[AIIMS 1999; CPMT 2000] 13. Which expression is correct for the work done in adiabatic reversible
(a) Nuclear energy expansion of an ideal gas [AMU 2002]
(b) Rotational energy V2 T2
(c) Vibrational energy (a) W  nRT ln (b) W  n e ln
V1 T1
(d) Energy arising by gravitational pull


2
7. Two moles of an ideal gas expand spontaneously into a vacuum. The (c) W  PV (d) W   PdV
work done is [AMU 2000] 1

(a) 2 Joule (b) 4 Joule 14. If an endothermic reaction is non-spontaneous at freezing point of
(c) Zero (d) Infinite water and becomes feasible at its boiling point, then
8. Heat exchanged in a chemical reaction at constant temperature and [AIEEE 2002]
constant pressure is called as H is ve , S is +ve
(a)
[BHU 1998; Pb. PET 2000; MP PET 2002]
(b) H and S both are +ve
(a) Internal energy (b) Enthalpy
 Thermodynamics and Thermochemistry 453

(c) H and S both are –ve (a)  68.0 kJ mol 1 (b)  43.8 kJ mol 1
(d) H is +ve, S is –ve
(c) 68.0 kJ mol 1 (d) 43.8 kJ mol 1
1 1
JK mol
15. What is the entropy change (in ) when one mole of ice 21. Equilibrium constant of a reaction is related to
o
is converted into water at 0 C (The enthalpy change for the [AIIMS 1991]
1 o
conversion of ice to liquid water is 6.0 kJ mol at 0 C )[CBSE PMT 2003] (a) Standard free energy change G o
(a) 21.98 (b) 20.13
(b) Free energy change G
(c) 2.013 (d) 2.198
(c) Temperature T
30.5 kJ
16. One mole of NaCl (s) on melting absorbed of heat and (d) None
28.8 JK 1
its entropy is increased by . The melting point of 22. The standard Gibbs free energy change G o is related to
NaCl is [DPMT 2004] equilibrium constant K p as [MP PET/PMT 1998]
(a) 1059 K (b) 30.5 K
G o
(c) 28.8 K (d) 28800 K  e 
(a) K p   RT ln G o (b) Kp   
(H )  RT 
17. The enthalpy change for the process
1
N 2 H 4 (g)  2 N (g)  4 H (g) 1724 KJ mol G o 
G o
in . If the bond
(c) K p   (d) K p  e RT
1 RT
391 KJ mol
energy of N  H bond in ammonia is . What is the
23. The standard enthalpy or the decomposition of N 2 O 5 to NO 2 is
bond energy of N  N bond is 2 4
N H
58.04 kJ and standard entropy of this reaction is 176.7 J / K .
[MP PMT 2004]
The standard free energy change for this reaction at 25 o C is [DCE 2004]
(a) 160 KJ mol 1 (b) 391 KJ mol 1
(a) –5.38 kJ (b) 5.38 kJ
(c) 1173 KJ mol 1 (d) 320 KJ mol 1
(c) 5.38 kJ (d) –538 kJ
18. Liquid ammonia is used in refrigeration because of its
24. For the equilibrium H 2 O(l) ⇌ H 2 O(g) at 1 atm and 298 K
[DCE 2003]
(a) High dipole moment [AIIMS 2004]
(b) High heat of vaporisation (a) Standard free energy change is equal to zero (Go  0)
(c) High basicity
(b) Free energy change is less than zero (G  0)
(d) All of these
19. A cylinder of gas supplied by Bharat Petroleum is assumed to (c) Standard free energy change is less than zero (G o  0)
14 kg 20,000 kJ
contain of butane. It a normal family requires
(d) Standard free energy change is greater than zero (G o  0)
of energy per day for cooking, butane gas in the cylinder last for ….
Days [Kerala PMT 2004] 25. For reaction Ag 2 O(s)  2 Ag(s)  (1 / 2)O 2 (g) the value of
( H c of C4 H10  2658 KJ per mole )  H  30.56 kJ mol 1 and S  0.066 k JK 1 mol 1 .
(a) 15 days (b) 20 days Temperature at which free energy change for reaction will be zero,
is [MH CET 1999]
(c) 50 days (d) 40 days
(e) 32 days (a) 373 K (b) 413 K
(c) 463 K (d) 493 K
20. The heat of neutralization of HCl by NaOH under certain
condition is – 55.9 kJ and that of HCN by NaOH is –12.1 kJ. the
heat of ionization of HCN is [MP PET 2001]

(SET -10)

40
1. (d) A 
 B
40
A 
 B
 Thermodynamics and Thermochemistry 437
H  40  40  0 . means their energy  391  4  1564
2. (b) H  E  nRT . so the bond energy of N  N in N 2 H 4

3. (c) n  1  0  1  1724  1564  160 KJ / mol

18. (b) Ammonia has high heat of vaporisation hence is used in
E  H  nRT refrigeration.
8.314 19. (e) Calorific value of butane
E  176  1   1240  165.6 kJ .
1000 H c 2658
   45.8 KJ / gm
4. (d) A spontaneous process is accompanied by decrease in enthalpy mol. wt. 58
and increase in entropy means H is negative and S is Cylinder consist 14 Kg of butane means 14000 gm of
positive.
butane
 H   1gm gives 45.8 KJ
5. (b) C P    , At equilibrium T is constant i.e.  T  0,
 T  P
14000 gm gives 14000  45.8
thus C P   .
 641200 KJ
6. (d) E  Eele.  Enucl.  Echemical  Epotential
Family need 20,000 KJ / day
 Ekinetic(Et  Ev  Er ) .
641200
So gas full fill the requirement for  32.06 days
7. (c) An ideal gas under going expansion in vacuum shows, 20,000
E  0, W  0 and q  0 . 20. (d)
8. (b) H  q p . 21. (a) G o  2.303 log k .

E may be greater or lesser or equal to H .

o
9. (c) 22. (d) K p  e  G / RT
.
 H  E  PV  E  nRT. 23. (d)
10. (d) It is a modified form of Ist law of thermodynamics. It is a 24. (b) For reaction H 2 O(l) ⇌ H 2 O(g)
conservation law of mass and energy.
n  1 means positive
11. (a) for reaction (i) n1  0.5
so when n is positive then G  0 .
for reaction (ii) n 2  1.5 25. (c) G  H  TS
So, H 1  H 2 G  0 at equilibrium
 H  TS or 30.56  T  0.066
12. (b) For spontaneous reaction G should be negative
G  H  TS  (ve )  T (ve ) T  463 K .

If TS  H then G will be negative and reaction will be ***

spontaneous.
13. (b) W  PV .
14. (b) H and S both are +ve than reaction is spontaneous.
q rev 6000
15. (a) S    21.98 JK 1 mol 1
T 273

16. (a) NaCl(s) ⇌ NaCl(l)

Given that : H  30.5 KJ mol 1

S  28.8 JK 1  28.8  10 3 KJ K 1
H
By using S 
T
30.5
  1059 K
28.8  10 3
H H
| |
17. (a) H  N  N  H (So, 4 N  H bond present)