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LESSONS A new series of articles inspired by IChemE’s Loss Prevention Bulletin and

re LEARNED the BP Process Safety Series: sharing lessons learned from accidents.

Recurring accidents:
inadequate isolations

Geoff Gill examines the


I
N any facility that processes hazardous Isolation may be needed from any of the
materials, any intrusive activity hazards routinely encountered in industry,
lessons we should be could allow the escape of hazardous namely electrical; pressurised systems;
learning substances. Implementing adequate suspended loads; chemical/radiological/
isolation practices is critical to avoiding loss biological; and mechanical.
of containment. The list is, of course, easy to compile.
Some of industries’ most serious accidents However, a trawl through the history of
have been as a result of inadequate isolation. accidents where inadequate isolation played
The primary cause of the Piper Alpha disaster a part reveals that, even though the presence
was due to switching on a pump which had of a hazard was often recognised, an accident
been taken out of service for maintenance still occurred due to shortcomings including:
and had not been adequately isolated. The • an inadequate understanding of the system
BP Texas City disaster happened because being worked on;
operatives started up a raffinate splitter tower, • operators and/or supervisors not being
while ignoring open maintenance orders on suitably qualified or experienced;
the tower’s instrumentation system (an alarm • plant not being adequately decontaminated;
meant to warn about the quantity of liquid in
• lack of supervision to ensure permits to work
the unit was disabled).
(PTWs) are correctly followed;
Alongside these headline-making incidents
• deviations from work plans not being
there are many more that have caused injury
adequately risk assessed;
or death because safety management systems
• the work area not being closely inspected
for isolating plant are either inadequate
prior to the job;
or, even where they are robust, poorly
• workers inadequately briefed prior to work;
implemented.
• failing to carry out checks to ensure all
the nature of inadequate required safeguards are in place prior to job;
• precise nature of work, status of plant and
isolation accidents referencing of plant components not clearly
When remedial or maintenance work needs
specified on permits;
to be done on plant or equipment, the
• other plant personnel not fully aware of work
question of safe isolation invariably arises.
being carried out;
Tony Fishwick’s article on recurring accidents
Free to share from confined spaces (tce 854) highlighted
• plant inadequately labelled;
some of the tragic consequences which • workers not personally checking that
IN the spirit of this series, you are
can arise from inadequate awareness and isolations are in place;
permitted to print, photocopy
and redistribute this article as isolation of confined space hazards. The need • contingency plans not available
many times as you like. Feel for robust isolation procedures and practice • operators working under PTW not reading
free to share it with your boss, in industry is generally well established and and understanding the permit conditions;
colleagues and reports. understood. However, regardless of whether it • inadequate control of contractors;
Together we can help to is due to a combination of inadequate, and/or • inadequate communication between all
reduce the number of poorly-implemented procedures, or possibly involved in work;
workplace accidents.
lack of training and/or supervision, accidents • inadequate justification and safeguards for
continue to occur. work on live systems; and

52 www.tcetoday.com december 2013/ january 2014 For more information and a sample copy of LPB visit: www.icheme.org/lpb
A new series of articles inspired by IChemE’s Loss Prevention Bulletin and LESSONS
the BP Process Safety Series: sharing lessons learned from accidents.
re LEARNED

An example Case study 1


An operator was carrying out a routine
pigging operation. On conclusion of
Phenol burns during maintenance (LPB 129)
the interlock sequence he opened
the telltale bleed valve to ensure that To charge rooms
the launcher was free of toxic and To phenol tank

flammable gases. The gas test was


negative. He then realised that he had
omitted part of the procedure, requiring
10 cm phenol pipe From
the interspace between the kicker
pumphouse
line isolation valve and the pipeline and tank area
isolation valves to be vented to flare.
This procedure is normally carried
out at the beginning of the operation. Ball valve
being removed 5 4 2 3
He opened the kicker line isolation
valves and the pipeline isolation valves Transition pipe
without closing the telltale door. This which had
caused a gas release from the telltale been removed

bleed valve.
If a process isolation deviates
Pump no.2 Plug Pump no.1
from the plan, whether controlled
which had fitted Tank
by PTW or operating procedure, been removed under
then STOP! Re-evaluate the stand
task. In this case, the interlock
arrangements which permitted Layout of phenol pumps, main pipes and valves
the human error to occur should
then have been reviewed with a
An engineering fitter was badly burned by phenol spilling from a pipe attached
view to modification.
to a valve that he was removing.
A phenol transfer system consisted of two pumps, overhead pipework and a
drainage system from the pump bodies as shown in the above figure.
• long delays between atmosphere testing and
work beginning. Number 2 pump was removed for overhaul three weeks prior to the incident
because of a leaking gland assembly. The resulting open pipework was blanked off.
the legal section Maintenance work was planned to coincide with the annual holiday shutdown
Countries with extensive, well-regulated when various pieces of plant were being overhauled. The discharge valve of
industries all have legislation that is similar number 2 pump (“number 5 ball valve”) required overhauling as it was passing.
in principle to that in the UK1,2,3. Factors to Process operators had blown the line clear with inert gas and drained the lines
be considered include the nature of plant to the draindown tank via number 1 pump. Steam was turned off the valve once
to be worked on together with associated the lines had been blown out and electrical heating turned off. The plant was then
hazards that require isolation, contingency handed over from production to maintenance staff and on the following day the full
plant shutdown started.
arrangements, and the need to define safe
systems of work. A fitter was instructed to remove the number 5 ball valve. The bobbin below the
valve was removed and six of eight bolts removed from the top flange of the valve.
In the UK there are no specific regulations
At this moment the joint broke and around 5–10 l of phenol ran out of the pipework
relating to isolation of plant and equipment,
causing burns to the fitter’s shoulder, body, hands and legs. The fitter was, at one
but, as is the case with all UK health
stage, unconscious and critically ill.
and safety legislation, the underpinning
legal requirements are enshrined in the The investigation found that:
Management of Health and safety at Work • the plant had not been handed over to maintenance staff using any formal hand-
Regulations 1999. Practical guidance on safe over procedure;
process isolations is given in HSG253 – The
• the maintenance supervisor lacked knowledge of the precise state of the plant
Safe isolation of Plant and Equipment4. For
and his subsequent verbal instruction to the fitter was inadequate;
electrical isolations, guidance can be found
in HSG85 – Electricity at Work – Safe Working • the line in question had not been drained. The relevant engineering personnel did
Practices5. not recognise that blowing down of this system would be ineffective when number
The following practical guidance is based 2 pump was removed;
on HSG253. • there was no PTW for the job and therefore the possible hazards and risks had
not been recognised;
the detailed legal requirements
• only gloves and goggles had been provided and it is not clear if these had been
Using the UK as an example, a “suitable and
worn by the fitter; and
sufficient” assessment of all the risks for all
work activities for the purpose of deciding • no formal general training on hazard awareness, nor on the hazards of phenol
what means are necessary for safety must be was provided for employees.
carried out in accordance with regulation

For more information and a sample copy of LPB visit: www.icheme.org/lpb december 2013/ january 2014 www.tcetoday.com 53
LESSONS A new series of articles inspired by IChemE’s Loss Prevention Bulletin and
re LEARNED the BP Process Safety Series: sharing lessons learned from accidents.

used to control work which is identified as


Case study 2 potentially hazardous. For defined categories
of less hazardous work of a ‘routine’ nature,
authorisation via operating procedures/
TiCl4 release kills two contractors (LPB 200)
work instructions may be acceptable.
Two contractors died while carrying out an inspection of the level Comprehensive guidance has been published
measurement device of a titanium tetrachloride (TiCl4) evaporator. On by HSE in Guidance on Permit-to-Work Systems
disconnecting the signal wiring of the level measurement device, the process HSG 250 (ISBN 9780717629435).
computer responded to this signal as “empty” and opened the control valve to fill
the evaporator. The evaporator was not isolated prior to the start of the work, so 2. Documentation
it started to fill with TiCl4, without anyone noticing. Meanwhile the work continued Accurate up-to-date reference information on
and the level measurement device was removed. At this moment the evaporator all plant modifications should be accessible
overflowed releasing TiCl4 on the first and second level of the reactor building. to all relevant workers (including short-
The high level alarm was silenced by the panel operator. On contact with water term contractors) involved in planning and
(including air humidity), TiCl4 produces hydrogen chloride and TiO2, so a thick toxic conducting the work. This includes:
white cloud was rapidly formed inside the reactor building. Two contractors working • piping and instrumentation diagrams
on the first floor could not locate an emergency ladder. Both were new to the (P&IDs);
installation and were trapped with very little visibility due to the thick white cloud.
• process system schematics – unlike a P&ID
Both were later found dead. The main lessons to be learned from this accident are:
these provide an overall view of the plant;
• the PTW system has to be used strictly. The installation was not properly isolated • piping general arrangements and/or piping
prior to the work; isometrics;
• adequate training and supervision are necessary. This must include adequate • cause-and-effect diagrams; and
information for contractor workers about safety in the installation, such as the use
• loop diagrams.
of safe evacuation routes;
• contractors cannot be relied upon to inform their personnel about the on-site Separate isolation certificates can be used
safety information; a strict control system is necessary; as part of a PTW system, for example, where
• improvement of control and alarm systems. There should be a clear difference the isolation required is not detailed on
between ‘no signal’ and ‘zero signals’ in the process computer. Also, an interlock the PTW. It is good practice to use separate
system should be used to prevent overflow of the evaporator, and a better isolation certificates for separate disciplines
management of alarms should be introduced, to avoid neglecting critical alarms; such as electrical, mechanical, process and
and inhibits of control and safety systems. The key
issue is to enable effective communication,
• a management crisis team is necessary to ensure communications with external
avoiding miss-understanding and confusion.
emergency services. A prompt alert for these services is also necessary.
Certificates and permits should be cross
referenced.

3 of the Management of Health and Safety 3. Controlling interactions with


at Work regulations6. For intrusive work on other work/systems
hazardous plant and equipment this means Adequate control, security, monitoring and
the identification of all the hazards which communication are needed, particularly:
are likely to be present, and implementing
• at shift handovers
adequate means of isolating them.
• where support groups rely on the same
Key stages of process isolation are: isolation
• hazard identification; • in areas where there is multiple
• risk assessment and selection of isolation responsibility for plant.
scheme;
• planning and preparation of equipment; 4. Controlling changes
• installation of the isolation; It is vital that any changes to the planned
isolation scheme are both recognised and
• draining, venting, purging and flushing;
fully assessed. Changes to an isolation scheme
• testing and monitoring effectiveness of the
It is good practice to isolation; and
could arise for a variety of reasons such as:
• changes imposed by the condition of the
use separate isolation • reinstatement of plant. plant;
certificates for separate • changes to the scope of intrusive work as the
disciplines such as safe systems of work for work proceeds; and
electrical, mechanical, isolation activities • inability to complete a job (eg due to an
The following safe systems are required to increase in the scope of work once it is under
process and inhibits of ensure that isolation activities deliver the way, or the non-availability of spares).
control and safety systems. appropriate protection to workers. Any change to isolation arrangements
The key issue is to enable should be reviewed, reassessed and
1. Work control systems authorised. The modified scheme should be
effective communication, captured in the work control documents (eg
Control of isolations for higher hazard
avoiding miss-understanding activities is normally part of a PTW system. isolation certificates and P&IDs) to ensure full
and confusion. A PTW system is a formal recorded process reinstatement at the end of the job.

54 www.tcetoday.com december 2013/ january 2014 For more information and a sample copy of LPB visit: www.icheme.org/lpb
A new series of articles inspired by IChemE’s Loss Prevention Bulletin and LESSONS
the BP Process Safety Series: sharing lessons learned from accidents.
re LEARNED

An example Case study 3


A fatal accident occurred when
contract workers were installing pipe
Explosion at the Phillips’ Houston Chemical Complex,
from two production tanks to a third. Pasadena, 23 October 1989 (LPB 97)
Welding sparks ignited flammable
On 23 October 1989, the
vapour escaping from an open-ended
Phillips 66 Petroleum
pipe about 1.2 m from the contractors’ Typical piping settling
Chemical Plant near
welding activity on tank 4. The leg arrangement
Pasadena, Texas, then
explosion killed three workers who
producing approximately
were standing on top of tanks 3 and 4.
6.8m t/y of high-density
A fourth worker was seriously injured.
polyethylene (HDPE) plastic,
The contract workers did not suffered a massive series of
isolate tanks 2 and 3, which contained explosions. 23 people died Reactor loop
flammable vapour, prior to beginning and hundreds were injured in
the welding operation. Additionally, the Demco valve
an explosion that measured at Flushing
open-ended pipe of tank 3 was left isobane line
least 3.5 on the Richter scale
uncapped and provided the source and destroyed much of the
of hydrocarbon vapour. Workers plant. 
did not clean tanks 2 and 3 prior to Ethylene
The subsequent OSHA line
beginning the welding job on tank Vent (purge)
investigation highlighted
4. If the residual oil in tank 2 had valve
numerous errors. Firstly, the air
been removed and both tanks
hoses used to pneumatically
flushed with water, the flammable
activate the valve (see Figure,
vapour source could have been
right) were left near the
eliminated. LPB 213
maintenance site. When the
air hoses were connected
backwards, this automatically Product take off
opened the valve, releasing a
so why do accidents recur? huge volatile gas cloud into the
valve
Safety guru Trevor Kletz examined this atmosphere. It is unknown why
subject in detail and provided a number of the air hoses were reconnected
reasons. Principal amongst these are: at all. Secondly, a lockout
• organisations fail to record and circulate device had been installed by
the lessons learned from past accidents, and Phillips personnel the previous
fail to encourage a search for past relevant evening, but was removed at
accidents either for design purposes or for some point prior to the accident. A lockout device physically prevents someone
operator training; from opening a valve. Finally, in accordance with local plant policy but not Phillips
• experience and skills are lost when staffing policy, no blind flange insert was used as a backup. The insert would have stopped
is reduced, long-term employees retain the flow of gas into the atmosphere if the valve had been opened. Had any of those
memories of abnormal plant behaviour, three procedures been executed properly, there would not have been an explosion
near misses and, most importantly, why that day. According to the investigation, contract workers had not been adequately
modifications were made; trained in the procedures they were charged with performing.
• hazards are not reassessed often enough.
What was safe in the past is not necessarily
safe now. Plant modifications may have
affected the plant capacity to handle easy steps to help avoid
excursions safely;
repetitions
• supervisors are overloaded. They are
To prevent repetitions, consider the following:
the interface between management and
• describe accidents in safety bulletins,
workforce, ensuring that work flows
smoothly. They should not be distracted emphasising reasons why they happened;
with unnecessary tasks and detail, diverting • follow up accident recommendations to
attention away from safety; ensure that they have been put into effect; Organisations fail to
• change of design can lead to fatal • never change a procedure until the reason for record and circulate
it is fully approved and understood;
conditions. There should be a formal system the lessons learned
for assessment of proposed changes to plant • learn from accidents in other organisations,
and they should only be implemented after particularly those with similar processes;
from past accidents,
they have met the appropriate criteria. This • emphasise the importance of risk and fail to encourage
should be enforced for field modifications; assessments and make sure that they are a search for past relevant
and carried out;
accidents either for
• taking short cuts is a readily recognisable • put this into effective practice using
human behaviour but will result in unsafe techniques such as safety information design purposes or for
working. notes and emails; committee meetings; operator training.

For more information and a sample copy of LPB visit: www.icheme.org/lpb december 2013/ january 2014 www.tcetoday.com 55
LESSONS A new series of articles inspired by IChemE’s Loss Prevention Bulletin and
re LEARNED the BP Process Safety Series: sharing lessons learned from accidents.

on- and off-the-job training courses;


formal apprenticeships; computerised
learning modules; and Toolbox Talks.
Case study 4
Designers should be included in these
communications.
Multiple fatality incident at the Tosco Avon refinery,
Martinez, California (LPB 167)
practical action
On 23 February 1999, To overhead accumulator
Toolbox Talks are an excellent practical way
a fire occurred in the Layout of the unit
of reinforcing key messages regarding safe 11.0 psig
crude unit at Tosco
working practices and hazard awareness. Naptha
Corporation’s Avon oil draw tray
The IChemE’s Loss Prevention Panel has
refinery in Martinez, CL Elev. 112’ 3”
produced a number which have particular
California. Workers
relevance to safe isolation of plant7. They are First cut CL Elev. 104’ 6”
were attempting
designed to act as a stimulus for generating
to replace piping Naptha 8” Naptha vapour
discussion about local situations and release return line
attached to a 45 m
accidents. They are generally used as a short
tall fractionator tower Crude Second cut CL Elev. 78’ 7”
team-based exercise at the beginning of fractionation
while the process tower
a shift. However, they can also be used in
unit was in operation.
safety workshops to generate discussion, 6” Naptha piping
During removal of the
and can be followed up with a plant visit to
piping, naphtha was 12.0 psig
understand more fully the circumstances of
released onto the Flange 2
events experienced on the plant. CL Elev. 38’ 1”
hot fractionators and Plastic Naphtha
ignited. The flames sheeting stripper
conclusion engulfed five workers B
Plastic
As with any aspect of operating a major located at different pan CL35’
Elev.

hazard facility, avoiding accidents due to heights on the tower.


2-3/8”
E
inadequate isolation of plant equipment Four men were killed, Hose
suctioning C D I
depends upon a number of factors. and one sustained material F Indicates
It depends upon the plant being well serious injuries.
from pan to
plugged
vacuum truck
maintained to ensure hazardous materials area
Among other things, Vacuum truck CL – Centerline
drawing not to
always remain where they should be. It
the subsequent enquiry scale
depends on high quality and up-to-date
found that:
processes and procedures being readily
available and understood by the users. It • Tosco Avon management did not recognise the hazards presented by sources of
depends upon all parts of the workforce ignition, valve leakage, line plugging, and inability to drain the naphtha piping;
– executives, managers, supervisors and • management did not conduct a hazard evaluation of the piping repair during the
operators, each understanding their part in job planning stage. This allowed the job to be executed without proper control of
ensuring safety management systems remain hazards;
fit for purpose and rigorously applied. And • Tosco’s reliance on individual workers to detect and stop unsafe work was an
last but by no means least, it depends upon a ineffective substitute for management supervision of hazardous work activities; and
safety culture where such things as learning,
questioning, reporting and challenging are all • Tosco’s procedures and PTW programme did not require that sources of ignition
part of the daily routine. tce be controlled prior to opening equipment that might contain flammables, nor did it
specify what actions should be taken when safety requirements such as draining
could not be accomplished.
Geoff Gill (geoff.gill@live.co.uk) is an
independent safety consultant

further reading
1. European Framework Directive 89/391/EEC Our Loss Prevention Bulletin (LPB) is the leading source
2. EU-OSHA (2010), Safe Maintenance in of process safety case studies with a 40+ year archive of
Practice lessons learnt.
3. Government of Western Australia,
Department of Commerce. Guidance Note, Take a look at www.icheme.org/lpb
Isolation of Plant, 2010
4. The Safe Isolation of Plant and Equipment
HSG 253. ISBN: 9780717661718
5. Electricity at Work: Safe Working Practices Chemical Engineering Matters
HSG 58 ISBN: 9780717665815 The topics discussed in this article refer to the following lines on the vistas of IChemE’s technical strategy
6. The Management of Health and Safety at document Chemical Engineering Matters:

Work Regulations 1999


7. IChemE Toolbox Talks: Isolation of Health and wellbeing Lines 1, 11–15
Equipment for Maintenance; Identification
Visit www.icheme.org/vistas1 to discover where this article and your own activities fit into the myriad of grand
of Equipment for Maintenance; Isolation of challenges facing chemical engineers
Electricity-Driven Equipment for Maintenance

56 www.tcetoday.com december 2013/ january 2014 For more information and a sample copy of LPB visit: www.icheme.org/lpb

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