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Table of Contents
Table of Contents .......................................................................................................... 1
MODULE 3 INTRODUCTION TO ENERGETIC MATERIALS – Administration Page . 2
Duration ....................................................................................................................... 2
Scope Statement ......................................................................................................... 2
Terminal Learning Objectives (TLO) ............................................................................ 2
Enabling Learning Objectives (ELO)............................................................................ 2
Resources ................................................................................................................... 2
Instructor to Participant Ratio ...................................................................................... 3
Reference List ............................................................................................................. 3
Assessment Strategy ................................................................................................... 3
ICON MAP ...................................................................................................................... 4
MODULE INTRODUCTION ............................................................................................ 5
R.A.I.N. = RECOGNIZE, AVOID, ISOLATE, NOTIFY .................................................. 10
BASIC DEFINITIONS ................................................................................................... 15
EXPLOSIVE REACTION COMPONENTS: THE CHEMISTRY OF EXPLOSIVES ....... 26
FIRING TRAIN .............................................................................................................. 42
CATEGORIES OF EXPLOSIVES ................................................................................. 57
EXPLOSIVE EFFECTS................................................................................................. 68
SUMMARY .................................................................................................................... 86
ICON MAP
Question: Used when there is an opportunity to ask a question or start a class
discussion.
First Responder Safety: Used to highlight information that relates directly to the
personal safety of first responders.
MODULE INTRODUCTION
Slides 3-3 and 3-4 contain the Enabling Learning Objectives and
should be summarized by the instructor.
3-5 Define the acronym FISHED and identify examples of the five
stimuli that can be used to release energy from energetic
materials
First responders are often among the first to arrive at the scene of a
pre- or post-blast event. Being able to recognize the threat, take
appropriate steps to avoid and isolate the hazard, and notify trained
experts and bomb technicians, could save a first responder’s life.
By following the four simple steps of R.A.I.N., you, your colleagues,
and other citizens will remain safe.
1
United States District Court Northern District of Georgia, (2015, Mar 20). Criminal Complaint, Case Number 1:15-
MJ-00226-JFK, Retrieved from http://talkingpointsmemo.com/livewire/michael-sibley-bombs-atlanta-
georgia
2
FBI Atlanta Division Press Releases. (2015). Retrieved from https://www.fbi.gov/atlanta/press-releases/2015/arrest-
made-in-investigation-of-explosive-device-left-in-vickery-creek-park
BASIC DEFINITIONS
ELO 3-1
Identify the three forms of energy released during explosive
and incendiary events.
The temperatures generated produce the heat and light while the
accompanied shock produces the sound, which equates to
overpressure. When describing an explosion or detonation, we do
2
Urbanski, T. & Vasudeva, S., K. (1981). Explosions and Explosives: Fundamental Aspects. Journal of Scientific and
Industrial Research, 40, 512-519. http://www.cem.de/documents/pdf/publikation/digestion/rd089.pdf
so by describing the heat and light as the thermal effect, and the
sound as overpressure.
ELO 3-2
Define key terms: deflagration, detonation, deflagration-to
detonation transition (DDT), low-order detonation, high-order
detonation, homemade explosive, precursors, incendiary
device, and hypergolic reaction.
3
Burke, R. A. (2006). Counter-Terrorism for Emergency Responders, Second Edition. Taylor and Francis.
https://books.google.com/books?id=6xPNBQAAQBAJ&printsec=frontcover&source=gbs_ge_summary_r&
cad=0#v=onepage&q&f=false
On April 17, 2013 a citizen called 911 and reported smoke and fire
coming from the West Fertilizer Company which housed 30 tons of
ammonium nitrate fertilizer and numerous other fertilizers. One of
the first responders on scene was a West, Texas police officer who
was on patrol. He smelled smoke but was unable to locate where it
was coming from until a citizen pointed out the smoke coming from
the West Fertilizer Company plant. The officer observed fire and
notified dispatch of a structural fire at the plant and requested the
West Volunteer Fire Department. The fire department arrived with
two engines, two brush trucks and a water tender truck. The initial
police officer at the scene began evaluating a city park next to the
plant and requested assistance in blocking traffic. The firefighters
began to fight the fire with water hoses in an attempt to extinguish
the fire. The fire continued to grow causing the fire chief and assist
chief to discuss a withdrawal, however, 20 minutes after the 911
call was made a massive explosion erupted. The explosion killed a
total of 15 people, 12 of them being first responders.
Over 260 people were injured and 150 buildings were damaged or
destroyed. The force felt of the explosion was the equivalent of a
magnitude-2.1 earthquake and the explosion was within the range of
10,000 to 21,500 pounds of TNT. The explosion caused an
asymmetric crater that was 75 feet in diameter and 8 feet deep.
4
West Fertilizer Explosion and Fire. U.S. Chemical Safety Board. Retrieved from
http://www.csb.gov/west-fertilizer-explosion-and-fire-/
ELO 3-3
Identify the components of an explosive reaction: fuel,
oxidizer, and stimulus (heat).
Oxidizers
A fuel is any substance or item that can burn. Fuels are divided into
three categories: hydrocarbons, energetic hydrocarbons, and non-
hydrocarbon fuels.
This slide displays the back, or page two, of the card shown on the
previous slide. It lists the various groups of fuels that can be
combined with the oxidizer to produce an explosive mixture.
5
Mackay, P. (Sept. 2013). Hazardous Cargo Bulletin: 30 Years Ago. Retrieved from
http://www.hazardouscargo.com/content/30-years-ago-40.
6
NOTE: Explosives are classified as primary, secondary, or tertiary. Primary explosives are the least stable and
easiest to ignite, secondary explosives are moderately stable, and tertiary explosives are more stable and typically
used as the main charge in larger explosives. We will discuss these different categories in depth later in this lesson.
The left column of this chart lists common precursors that can be
used to develop Homemade Explosives (HME). The middle and
right columns of this chart list different types of HME: Nitrated
explosives, which contain nitric acid as the oxidizer, and peroxide
explosives, which use hydrogen peroxide as the oxidizer.
Precursors can be easily obtained and are used for many legitimate
purposes. However, first responders should learn to identify
these materials and recognize when large quantities of
precursors or precursors in an unrelated setting (Ex: multiple
gallon jugs containing urine in a location that has a functioning
bathroom) may indicate attempts to produce explosives.
Recognizing these red flags can help prevent the completion
of terrorist bomb plots, and can protect first responders and
civilians.
7
Vince, G. (2005). Explosives Linked to London Bombings Identified. New Scientist. Retrieved from:
https://www.newscientist.com/article/dn7682-explosives-linked-to-london-bombings-identified/
8
United States District Court Eastern District of New York, (2009). Memorandum of Law Support of the
Government’s Motion for A Permanent Order of Detention, Retrieved from
http://www.justice.gov/sites/default/files/opa/legacy/2009/09/24/zazi-detention-memo.pdf
9
United States District Court Eastern District of New York, (2009). Memorandum of Law Support of the
Government’s Motion for A Permanent Order of Detention, Retrieved from
http://www.justice.gov/sites/default/files/opa/legacy/2009/09/24/zazi-detention-memo.pdf
FIRING TRAIN
ELO 3-4
Order the components of a firing train.
firing trains.
Firing trains can also be initiated electrically, if the fire and the time
fuse are replaced with an electric wire and a current.
ELO 3-5
Define the acronym FISHED and identify examples of the five
stimuli that can be used to release energy from energetic
materials.
This slide shows three graphics that depict friction. One graphic of
a pipe wrench spinning a nipple, one graphic showing the end caps
on a pipe bomb being twisted off and the resulting explosion, and
one graphic showing a jar having the lid twisted off and its
relationship to a pepper grinder.
This slide shows three photos that depict impact: A soldier holding
a hammer while sitting on a large bomb, a series of photos showing
the impact of a bullet on a solid object, and a hammer striking a
piece of glass.
This slide shows one of the stimuli that can severely impact first
responder safety. The two photos depict electrostatic discharge.
One photo shows visible energy arcing between two contacts, and
the other photo shows an Electronic Control Device (ECD),
commonly referred to as a Taser.
10
7/26/2013 “Sensitivity of TATP to a Taser EMRTC quick look report”.
11
National Bomb Squad Commanders Advisory Board. (April 2016). National Guidelines for Bomb Technicians,
CATEGORIES OF EXPLOSIVES
ELO 3-6
Categorize examples of low explosives and high explosives.
This slide contains images and lists key definitions associated with
the safe use of low explosives or propellants. The top image shows
a cross-section of a shotgun shell and how it is propelled out of the
barrel; the bottom image shows propellants deflagrating in a
controlled laboratory burn.
12
Report of the Presidential Commission on the Space Shuttle Challenger Accident, (1986). U.S. Government
Printing Office. Retrieved from: http://er.jsc.nasa.gov/seh/explode.html
13
USS Iowa Turret Explosion, (No Date). World Public Library. Retrieved from:
http://www.worldlibrary.org/articles/uss_iowa_turret_explosion
Black powder does not deteriorate with age, and while water may
temporarily desensitize it, once dry, it returns to its original
flammable composition. Black powder is extremely sensitive to
all forms of heat created by these five stimuli (friction, flame,
impact, shock, and static electricity). This characteristic makes
black powder one of the most dangerous explosives to handle.
Smokeless powders vary in form and color. Some are formed into
rods, grains, wafers, or round or square flakes and may vary in
color from black, gray, orange, or green. Double-base smokeless
powders and other special purpose smokeless powders differ from
single-base in that they contain nitroglycerine or other organic
nitrates added to the nitrocellulose.
14
USS Iowa Turret Explosion, (No Date). World Public Library. Retrieved from:
http://www.worldlibrary.org/articles/uss_iowa_turret_explosion
ELO 3-7
Classify high explosives as primary, secondary, or tertiary.
This slide lists the three classes of high explosives. These photos
are examples of the three types of high explosives— primary,
secondary, and tertiary.
15
After Action Report: Alfred P. Murrah Federal Building Bombing. The Oklahoma Department of Civil
Emergency Management.
16
U.S. Department of Homeland Security, (No Date). IED Attack, Improvised Explosive Devices, News &
Terrorism, Communicating in a Crisis. Retrieved from:
https://www.dhs.gov/xlibrary/assets/prep_ied_fact_sheet.pdf
EXPLOSIVE EFFECTS
ELO 3-8
Given images depicting explosive effects, label the following:
incendiary effect, blast-pressure effect, fragmentation effect,
shrapnel effect, positive pressure, peak overpressure,
negative pressure, reflected pressure, impulse, shock wave,
shock front, detonation velocity, brisance, and heave.
The term shrapnel was first applied to an artillery shell that was
17
Lipscombe, N. (2013). Shrapnel/s Shell- A Force Multiplier. Retrieved from: http://www.nick
lipscombe.net/Shrapnel%20Shell%20Paper.pdf
18
After Action Report: Alfred P. Murrah Federal Building Bombing. The Oklahoma Department of Civil
Emergency Management.
This slide contains a shock front video. The test (Divine Buffalo
Test #1) was conducted to evaluate the effect of an explosion on a
structure and different types of construction materials. The bottom
floor contains different types of frame and masonry construction,
while the second through fourth floors test different types of glazing
materials as well as blast curtains in one of the top floor rooms.
The shock front or leading edge of the shock wave can be visually
likened to the outer ripple of the ring created by a pebble being
thrown into a pond. The shock front is the front line of the blast
effect. Often the shock wave and its leading edge (the shock front)
can be seen from a distance traveling across the earth. The shock
wave is present on both the ground and in the air. Ground effects
are similar to an earthquake. In air, the shock wave is a front of hot
compressed gases. The shock wave causes damage by exerting
an intense wind and overpressure on structures.
19
After Action Report: Alfred P. Murrah Federal Building Bombing. The Oklahoma Department of Civil
Emergency Management.
This slide shows images from the Khobar Towers incident in 1996.
Clockwise from left: Building 131 after the blast; the crater where
the truck bomb had been; Khobar Towers complex before the blast.
On June 25, 1996, Khobar Towers was being used as quarters for
foreign military personnel (including U.S. Air Force personnel).
Operatives from Hezbollah Al-Hejaz converted a large sewage
tanker truck into a truck-bomb and detonated it across from an
eight-story structure, causing 19 deaths and 498 injuries. The truck
bomb utilized 5,000 pounds of plastic explosives and detonated
with the force of at least 20,000 pounds of TNT according to the
Defense Special Weapons Agency. The truck itself was parked
approximately 72 feet away from the building, but actually shaped
the charge by directing the blast toward the building. The relatively
high clearance between the truck and the ground gave it the more
lethal characteristics of an air burst. The blast was so powerful that
it was felt 20 miles (32 km) away. The size of the explosion created
an intense dust storm as the forces of the high-pressure blast wave
and the subsequent negative pressure forces caused considerable
20
United States District Court Eastern District of Virginia Alexandria Division, (2001). Criminal Complaint No: 01-228-
A. Retrieved from http://nsarchive.gwu.edu/NSAEBB/NSAEBB318/doc05.pdf
21
FEMA, (2003). Reference Manual to Mitigate Potential Terrorist Attacks Against Buildings. Risk Management
Series FEMA 426, Ch 4. Retrieved from http://www.fema.gov/media-library-data/20130726-1455-20490-
7465/fema426_ch4.pdf
SUMMARY