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Article history: The cooling and freezing of stagnant water in cylindrical pipes were investigated under conditions of
Received 11 January 2014 varying ambient air temperatures. Experiments were conducted to measure the transient temperature of
Accepted 17 July 2014 water in a 50.8 mm nominal Schedule 80 steel pipe that was exposed to stagnant and forced air at
Available online 25 July 2014
temperatures ranging from 25 C to 5 C. There was a 10 vol.% air gap in the pipe to avoid excessive
increase of fluid pressure during the freezing process. A one-dimensional transient heat conduction
Keywords:
mathematical model was developed to estimate the freezing time of the liquid in the pipe. The model
Ice thickness
was based on the separation of variables method for a finite length-scale solidification problem, and was
Moving boundary problem
Separation of variables
verified with the experimental transient temperature data. It was found that the model predicted the
Solidification solidification time of the water in the pipe to within 15% of that which was measured by experiments for
Water most of the tests that were conducted. The model was applied to predict the cooling and freezing be-
haviors of water in steel and copper pipes of various inner diameters and in insulated pipes. The results
of the model and their agreement with experimental data suggest that a separation of variables method
for a finite length-scale heat conduction problem may be applied to moving or free boundary problems to
predict phase change phenomena.
© 2014 Elsevier Ltd. All rights reserved.
1. Introduction as dendritic ice, which forms in advance of the annular solid ice.
The consequence of the formation of either dendritic ice or solid
The phenomenon of solidification of stagnant water in cylin- annular ice in the pipe is the possibility of flow blockage and
drical pipes has received attention from numerous investigators bursting of the pipe due to the generation of large internal pres-
given the detrimental effects of freezing such as the possible sures. It has been shown that dendritic ice formation may be
blockage and bursting of the pipes. When pipes are exposed to low- responsible for early blockage of the water pipes under certain
temperature environments, the water will experience cooling, conditions [2]. Sugawara et al. [3] and Oiwake et al. [4] conducted
supercooling of the liquid phase below the fusion temperature, both numerical analyses and experimental studies to quantify the
solidification at the fusion temperature, and further cooling of the changes in internal pipe pressure during the freezing process, while
solid ice [1]. Gilpin [2] has shown that supercooled water in pipes is Gordon [1] presented experimental results of pressures required to
characterized by the growth of thin plate-like solid crystals known cause bursting of a variety of pipes used in building applications.
The numerical analyses of Sugawara et al. [3] and Oiwake et al. [4]
and the experimental work of Gordon [1] included the case where
* Corresponding author. Tel.: þ1 780 4922675; fax: þ1 780 4922200. the pressure increase in the freezing fluid depressed the fusion
E-mail address: andre.mcdonald@ualberta.ca (A. McDonald). point. They admitted that the continuous freezing point depression
http://dx.doi.org/10.1016/j.applthermaleng.2014.07.046
1359-4311/© 2014 Elsevier Ltd. All rights reserved.
A. McDonald et al. / Applied Thermal Engineering 73 (2014) 140e151 141
rendered analysis of the problem difficult, forcing the use of in- food material, they do not enable the determination of the transient
cremental time steps and numerical code. temperature distribution in the material or estimation of the
Further experimental studies on the freezing of stagnant water transient solidification front during freezing.
in pipes have explored the effects of internal free convective motion The objectives of this study were to: (1) develop an analytical
during the solidification process. Due to the decrease in the density heat conduction model to estimate the freezing time of liquids in
of water as it freezes [5], complicated flow patterns may emerge, pipes; (2) conduct experiments to validate the model; and (3)
which may have an effect on the rate of formation of dendritic and extend the use of the model to cases of practical interest.
solid annular ice [6e8]. Gilpin [8] has shown specifically that for
quiescent water with supercooling less than 2 C, free convection 2. Experimental method
produces non-uniform ice distribution. For greater amounts of
supercooling, relatively uniform ice distribution is formed since the The freezing of water in cylindrical pipes was used as a basis to
velocity of the advancing dendritic ice front exceeds that of the free gather data for validation of the mathematical model that was
convective motion. developed in this study. In order to mitigate the risk of brittle
The modeling of solidification phase change problems has been fractures, all piping material and components were rated for low
the subject of extensive research investigations [9e16]. Initial temperature service. A 50.8 mm (2 in) Schedule 80 carbon steel
model studies focused on this phase change in slabs with semi- pipe (ASTM A333 Grade 6) that was approximately 305 mm (12 in)
infinite extent [9] or in liquids that were initially at the fusion long was used for all the tests and is shown in Fig. 1. Thread-o-lets
temperature [9,10], with the intent of finding the temperature were welded at each end of the pipe as well as one in the middle to
distribution in the material during phase change and the location of create a closed system and to allow insertion of instrumentation for
the moving boundary. The non-linearity of the interface energy temperature measurements. The total system volume was
equation made analytical solutions of the temperature distribution approximately 550 mL (18.6 fl oz).
difficult to obtain. This has resulted in computer-aided numerical A thermowell with a T-type thermocouple (PP-T-20, Omega,
solutions of the problem, and, as outlined in an early review by Montre al, QC, Canada) was inserted along the centerline of the
Muehlbauer and Sunderland [11], the use of several mathematical
techniques such as the variational technique, the heat-balance in-
tegral technique, and the RiemanneMellin contour integral tech-
nique. More recently, model studies have focused on the
determination of the time required for freezing of materials. Pham
[12] has extended Planck's equation [13] to include sensible heat
effects during the freezing of food-based materials with simple
shapes. Other investigators such as Cleland et al. [14] and Hung [15]
used numerical methods, coupled with experimental data, to pre-
dict the freezing time of irregularly shaped bodies of food. While
these studies on the prediction of freezing time through the use of
either simple models or numerical techniques are useful for solid Fig. 1. Schedule 80 steel pipe with thread-o-lets, plugs, and installed thermowell.
142 A. McDonald et al. / Applied Thermal Engineering 73 (2014) 140e151
pipe through one of the thread-o-lets and was used to measure All the cooling and freezing tests were conducted in an 18.2 m3
the transient temperature of the water and ice during the cooling (640 ft3) cold room freezer (Foster Refrigerator USA, Kinderhook,
and freezing events. Thermal paste (8610 Non Silicone Heat NY, USA). Five tests in which the ambient air was held stagnant at
Transfer Compound, M.G. Chemicals, Burlington, ON, Canada) was temperatures of 5 C, 10 C, 15 C, 20 C, and 25 C were
applied to the thermocouple junction to reduce contact resistance conducted in a closed duct to reduce the effects of circulating air
between the thermocouple and the thermowell. The thermowell currents external to the pipe. Several tests were also conducted to
had an outer diameter of 12.7 mm (0.50 in) and extended inside simulate forced air cooling and freezing, over a temperature range
the pipe approximately 127 mm (5 in) (see Fig. 1). The other two of 25 to 5 C, in increments of 5 C. In order to control the flow of
orifices were plugged using 19 mm (0.75 in) NPT stainless steel air over the pipe, an experimental assembly was constructed of a
plugs and Teflon tape. The ambient temperature within the 254 mm 305 mm (10 in 12 in) galvanized sheet metal duct, a
freezer was measured using a T-type thermocouple. The temper- 0.25 kW (0.33 hp) direct-drive tube-axial fan (DDA-12-10033B,
ature inside the duct was recorded using a J-type rigid probe-style Leader Fan Industries, Toronto, ON, Canada), a galvanized sheet
thermocouple (TJ36-ICSS-14U-6-CC, Omega, Montre al, QC, Can- metal 305 mm (12 in) round to 254 mm 305 mm (10 in 12 in)
ada). Tap water was used as the process fluid. For all the tests, a rectangular reducer, and a 41 mm (1.625 in) slotted C-channel
10 vol.% air gap was introduced into the pipe to avoid excessive tubing (McMaster-Carr, Aurora, USA) (see Fig. 2a). The overall di-
increase of fluid pressure during the freezing process. The tran- mensions of the assembly were 2 m 0.66 m 0.48 m
sient temperature data was collected with a data acquisition (80 in 25.9 in 18.9 in) as shown in Fig. 2b. A triangular hole was
system (SCXI-1600, National Instruments, Austin, TX, USA) and a cut into the duct to allow access for the test pipe. The entire as-
measurement and automation explorer software for data pro- sembly was elevated at approximately 30 to ensure that the air gap
cessing (National Instruments, Austin, TX, USA) was used. The data in the pipe remained at one end of the pipe. A digital manometer
sampling interval was 1 Hz (1 sample per second). Once recorded, (475-1-FM, Dwyer Instruments, Michigan City, USA) was used to
the data was then exported into a Microsoft Excel file for further measure the air speed after exit from the fan and within the vicinity
analysis. of the pipe.
3. Mathematical models Eq. (9) is valid for laminar free convective flow over cylinders
within an infinite fluid medium for uniform surface temperature or
3.1. Cooling time uniform heat flux. In this study, the tests were conducted in a
closed channel in which the cylinder occupied approximately 25%
Cooling of the liquid in a freezer with ambient temperature, T∞, of the height of the channel. It is possible that free convective
from an initial temperature (Ti) to its melting point, Tf, will occur motion occurred within the gap between the channel wall and the
before the initiation of freezing. The time required to cool the cylinder, increasing the heat transfer coefficient beyond the value
liquid from its initial temperature to the freezing point can be predicted by Eq. (9). It is also possible that with high values of
determined by considering a one-dimensional transient heat Rayleigh number, the free convection motion would be turbulent
conduction model in cylindrical co-ordinates for the cooling of the within the gap, further increasing the heat transfer coefficient.
stagnant fluid in the pipe. Assuming constant properties, the There are no correlation equations for the heat transfer coefficients
governing equation is for this specific case; however, verification of the Rayleigh number
would confirm the possible occurrence of free convective currents.
1 v vT 1 vT Ostrach [19] has shown that the critical Rayleigh number that is
r 2 ¼ ; 0 r Rinn : (1)
r vr vr aL vt required to induce free convective motion in enclosed spaces
bounded by rigid planes is 1708. Turbulence will first appear at a
The boundary and initial conditions are.
Rayleigh number that is approximately 5830. The length scale in
vTð0; tÞ the Rayleigh number is the gap distance between the planes. Under
¼ 0; (2) stagnant air conditions, the approximate radiation heat transfer
vr
coefficient is [20]
vTðRinn ; tÞ
kL ¼ U½TðRinn ; tÞ T∞ ; (3) 3 pipe s
4 T4
Tsur
vr ∞
ho;radiation z ; (10)
Tsur T∞
Tðr; 0Þ ¼ Ti T∞ : (4)
€ where the StefaneBoltzmann constant is s ¼ 5.67 108
Ozisik [17] has solved Eq. (1) with the boundary and initial
W m2 K4 and T is in Kelvin.
conditions of Eqs. (2)e(4) to give
Due to the difficulties in estimating the overall heat transfer
2uðTi T∞ Þ X∞
J0 ðbn rÞ coefficient for the stagnant air tests, the models developed in this
Tðr; tÞ ¼ T∞ þ exp aL b2n t ; study, coupled with the experimental results, will be used to esti-
Rinn 2
n¼1 bn þ u J0 ðbn Rinn Þ
2
mate values of the overall heat transfer coefficients. Mcquiston
et al. [21] has also suggested that the determination of overall heat
(5)
transfer coefficients over bare pipes exposed to free convection is
where u ¼ U/kL and the eigenvalues are complicated due to the lack of knowledge of the transient surface
temperature of the pipe upon which the heat transfer coefficients
bn J1 ðbn Rinn Þ ¼ uJ0 ðbn Rinn Þ: (6) will depend. Experimental data for the overall heat transfer co-
efficients for horizontal bare steel pipes that were presented by
The overall heat transfer coefficient (U) during this single-phase Mcquiston et al. [21] will also be used in this study.
heat transfer problem can be estimated by utilizing correlation Forced convection will dominate the heat transfer at the outer
equations that are available from the work of others. The pipe surface of the pipe during the forced air tests. Perkins and Leppert
material, insulation, and outside heat transfer coefficient (ho) [22] have shown that the average heat transfer coefficient over the
constituted the overall heat transfer coefficient at the outer surface pipe will be affected by flow in both the laminar boundary layer
of the pipe. In general region and in the separated region over the pipe, with significant
increases in the local heat transfer coefficient in the separated re-
1 00 1 1
¼R þ þ : (7) gion of flow. Provided that the Reynolds number is lower than the
U ho;convection ho;radiation critical value for laminar-to-turbulent transition for flow over cy-
lindrical bodies (2 105), the correlation equation for the average
The thermal resistance of the pipe material and any insulation is
given as heat transfer coefficient is [22]
! ! kair h i
Do;pipe Do;insul ho;convection ¼ 0:31Re0:50 0:67
Do þ 0:11ReDo Pr0:40 : (11)
ln Dinn;pipe ln Dinn;insul Do
00 00 00
R ¼ Rpipe þ Rinsul ¼ Do;pipe þ Do;insul : (8) Perkins and Leppert [22] accounted for the variation of dynamic
2kpipe 2kinsul
viscosity across the boundary layer by using a ratio of the dynamic
Free convection and radiation will occur at the outer surface viscosity at the cylinder wall to the bulk dynamic viscosity. The
of the pipe during the stagnant air tests. The orientation of the ratio was assumed to be unity for this study since the variation of
pipes in this study will be horizontal. The free convective heat dynamic viscosity of gases with temperature is small.
transfer coefficient for horizontal pipes is given by Churchill and In this study, the cooling and freezing experiments were con-
Chu [18] as ducted in a closed rectangular duct system (see Fig. 2). It has been
2 32 shown that when the diameter of a pipe occupies a portion of the
cross-sectional area of a ducted channel, blockage of the gas flow
k 6 7
1=6
6 0:387RaDo 7 will occur [23]. Blockage will affect the pressure and velocity dis-
ho;convection ¼ air 60:6 þ h i 7 ; RaDo 1012 : tributions around the cylindrical pipe, which will in turn affect the
Do 4 9=16 8=27 5
1þ 0:559
Pr location of the separation point on the cylindrical pipe and the
average heat transfer coefficient [22]. To that end, Robinson et al.
(9) [23] proposed an empirically determined blockage correction
144 A. McDonald et al. / Applied Thermal Engineering 73 (2014) 140e151
TL ðr; tÞ ¼ Tf ; 0 r < rin ðtÞ; (13) Eq. (20) was substituted into Eq. (14), and after separation gives
1 v vJ 1 vJ
1 v vTs 1 vTs r ¼ ; (21)
r 2 ¼ ; rin ðtÞ < r Rinn : (14) r vr vr as vt
r vr vr as vt
The boundary and initial conditions are 1 d df
r ¼ 0: (22)
r dr dr
Ts ðrin ; tÞ ¼ Tf ; (15) Substitution of Eq. (20) into the boundary and initial conditions
of Eqs. (15)e(17), followed by separation will produce homoge-
neous boundary conditions for J from Eqs. (15) and (16). Since f is
a function of r, only, Eq. (17) will remain non-homogeneous after
substitution of Eq. (20).
The solution for J(r,t) was assumed to be the product of two
functions, with < depending on r only, and t, on t only, so that
d2 <k 1 d<k
þ þ l2k <k ¼ 0; (24)
dr 2 r dr
dtk
þ as l2k tk ¼ 0: (25)
dt
Integration of Eqs. (24) and (25) gives
tk ðtÞ ¼ Ck exp as l2k t ; (27)
Fig. 3. Schematic of solidification in a circular pipe. where Ak, Bk, and Ck are integration constants.
A. McDonald et al. / Applied Thermal Engineering 73 (2014) 140e151 145
Application of the boundary condition at r ¼ rin (Eq. (15)) for l3, l4, l5, or l6 were such that the ½J0 ðlk rÞ ððJ0 ðlk rin ÞÞ=
J(rin,t) ¼ 0 to Eq. (26) gives ðY0 ðlk rin ÞÞÞY0 ðlk rÞ term was very large for either k ¼ 1, 2…, or 6,
compared to other values of k. It is important to note that any one of
J0 ðlk ri Þ the values could be used for a given solution since only one value of
Bk ¼ Ak : (28)
Y0 ðlk ri Þ k will produce a relatively large value of the ½J0 ðlk rÞ ððJ0 ðlk rin ÞÞ=
ðY0 ðlk rin ÞÞÞY0 ðlk rÞ term. So, one value of ak will apply. Therefore,
The boundary condition of Eq. (16) at r ¼ Rinn for
the integral of each term in Eq. (35) over the region rin(t) < r Rinn
ks ðvJðRinn ; tÞÞ=vr ¼ UJðRinn ; tÞ is applied to Eq. (26) in order to
of the solid was determined to give
find an expression for the eigenvalue, lk
ZRo ZRo
J ðl r Þ U Tf T∞ r J ðl r Þ
J1 ðlk Rinn Þ Y00 ðlk rii Þ Y1 ðlk Rinn Þ ln dr þ ak J0 ðlk rÞ 0 k in
k U r Y 0 ðlk rin Þ
lk ¼ : (29) U ln rRino Rkos ri in
ri (36)
J0 ðlk ri Þ ks
J0 ðlk Rinn Þ Y0 ðl ri Þ Y0 ðlk Rinn Þ
k
Y0 ðlk rÞ drz0:
One of the values of the separation constant is lk ¼ l0 ¼ 0.
Substitution of lk ¼ 0 into Eqs. (24) and (25) and application of the Eq. (36) will yield approximate values of ak. In addition, the
boundary conditions of Eqs. (15) and (16) to the solution of Eq. (24) expression was solved numerically since there are no closed form
showed that<0 ðrÞ ¼ 0 and J0 ðr; tÞ ¼ <0 ðrÞt0 ðtÞ ¼ 0. Therefore analytical solutions of the integrals of the Bessel functions of zero
X
∞ order, J0(lkr) and Y0(lkr).
J ðl r Þ
Jðr; tÞ ¼ ak J0 ðlk rÞ 0 k i Y0 ðlk rÞ exp as l2k t ; (30) Knowledge of the transient location of the solideliquid inter-
Y0 ðlk ri Þ face, rin(t), during the freezing event will enable estimation of the
k¼1
liquid freezing time within a pipe of inner radius, Rinn. Differenti-
where ak ¼ AkCk. ation of Eq. (34) at r ¼ rin and substitution into the solideliquid
The solution of the particular problem that is governed by Eq. interface energy equation of Eq. (19) produced
(22) is 2
U Tf T∞ X∞
fðrÞ ¼ E ln r þ F; (31) 6 J ðl r Þ
ks 6
4 þ ak lk 0 k in Y1 ðlk rin Þ J1 ðlk rin Þ
Y0 ðlk rin Þ
where E and F are constants of integration. rin U ln Rrinn
in
Rkinn
s k¼1
U Tf T∞
E¼ ; (32) (37)
U ln Rrinn
in
Rkinn
s
cðtÞ ¼ Rinn rin ðtÞ: (38)
U Tf T∞
F ¼ Tf ln rin : (33)
A MATLAB (MathWorks, Inc., Natick, MA, USA) code was used to
U ln Rrinn
in
Rkinn
s
solve the expressions for the first 6 values of lk (Eq. (29)). By dis-
cretizing the spatial domain, values of ak in Eq. (36) were calculated.
Finally, the temperature distribution in the solid phase is The values of time that corresponded to each rin value were
X ∞ calculated using Eq. (37). The differential equation in Eq. (37) was
U Tf T∞ r J ðl r Þ estimated by a first-order finite difference approximation. The
Ts ðr;tÞ Tf ¼ ln þ ak J0 ðlk rÞ 0 k in
r Y0 ðlk rin Þ infinite series summation in Eq. (37) was found to be insignificant,
U ln Rrinn
in
Rkinn
s in k¼1
with a dominant first term on the order of approximately 1070.
This simplified the expression to
Y0 ðlk rÞ exp as l2k t :
ks U Tf T∞ dr
(34) z in : (39)
rin ks dt
Eq. (24) is a SturmeLiuoville equation and the boundary con- rs Lrin U ln Rinn Rinn
ditions of Eqs. (15) and (16) are homogeneous, after transformation
in terms of J. Therefore, orthogonality can be applied to determine Eq. (39) gives a solution for the time corresponding to the
ak [17]. The initial condition of Eq. (17) was used to produce equally-spaced discretized ice thickness, c. A watereice system was
U Tf T∞ X ∞
r J ðl r Þ Table 1
ln þ ak J0 ðlk rÞ 0 k in Y0 ðlk rÞ ¼ 0: General properties of solid ice [5].
rin Y0 ðlk rin Þ
U ln rRino Rkso k¼1
Property Value
investigated in this study. General properties of solid ice that were Table 2
used in the model are shown in Table 1 [5]. Temperature and cooling rate data during cooling of water in 50.8 mm nominal
diameter (49.3 mm inner diameter) Schedule 80 steel pipes e stagnant air tests.
Table 3
Temperature and cooling rate data during cooling of water in 50.8 mm nominal
diameter (49.3 mm inner diameter) Schedule 80 steel pipes e forced air tests.
Table 4 In this study, and for a free-stream air velocity of 31 km/h, the
Overall heat transfer coefficients, U. Reynolds number was approximately 4.0 104, which is less than
Stagnant air Forced air the critical Reynolds number, indicating laminar flow. Small vari-
T∞ , C U, W m2 K1 T∞, C U, W m2 K1
ations in the Reynolds numbers occurred due to variations in the
film temperature. In industrial practice, ASHRAE have suggested
6.2 15.4 6.4 98.8
outdoor wind speeds of 24 km/h [24]. At this speed, the flow would
10.5 15.4 11.5 99.8
14.9 15.4 16.2 99.7 become turbulent if the pipe outer diameter, including the thick-
18.6 15.4 21.2 99.5 ness of any insulation, was approximately 390 mm (15.4 in) or
23.3 15.4 26.1 99.3 larger.
The cooling and freezing times, as determined from Eqs. (5) and
(34), respectively are shown in Fig. 5 for the stagnant tests at
suggested that the heat transfer coefficient be on the order of various ambient air temperatures. In all the tests in this study, a
101 W m2 K1 [17]. Mcquiston et al. [21] have also shown that for thermowell with a 12.7 mm outer diameter was inserted in the
50.8 mm diameter horizontal bare steel pipes, the combined effects center of the pipe. Therefore, the cooling time was determined at
of free convection and radiation would produce an overall heat the outer surface of the thermowell, where r ¼ 18.3 mm and the
transfer coefficient on the order of 13 W m2 K1. The predicted freezing time was determined as the time required for ice growth
value of the overall heat transfer coefficient in this study for the from the inner wall of the pipe to the outer surface of the ther-
stagnant air falls within the order-of-magnitude that was found by mowell. The cooling time of the water in the pipe was taken to be
other investigators [17,21]. the time required for the water temperature to decrease from the
Eqs. (7) and (12) were used to estimate the overall heat transfer initial temperature, Ti to the supercooled temperature, Tsuper. Fig. 5
coefficient for the forced air tests. Due to the forced convective shows that as the ambient air temperature increases, the cooling
nature of the tests, the contributions of radiation and the thermal and freezing times increase. Deviations between the experimen-
resistance of the metal pipe wall to the overall heat transfer coef- tally measured cooling times and those predicted by the model
ficient was small. As expected, the overall heat transfer coefficients could be as high as 25% (see Fig. 5a). This is most likely due to the
in the forced air tests were nearly an order-of-magnitude greater assumptions that were made during estimation of the heat transfer
than those of the stagnant air tests. Eqs. (11) and (12) will be valid coefficient. For free convection, coupled with radiation, as is the
for the case of laminar flow over the pipe, when the Reynolds case in this study, the heat transfer coefficient will depend on the
number is lower than the critical value for laminar-to-turbulent surface temperature of the pipe, which changes during the cooling
transition for flow over cylindrical bodies (2 105). The Reynolds process and will vary for different ambient air temperatures.
number will be based on the undisturbed, free-stream air velocity. However, it was assumed that the heat transfer coefficient was
Fig. 5. Plots of a) cooling time, b) freezing time, and c) total time versus temperature of stagnant ambient air for water in 50.8 mm nominal diameter Schedule 80 steel pipes.
148 A. McDonald et al. / Applied Thermal Engineering 73 (2014) 140e151
constant during each test. Further, Fig. 4 shows that during cooling The models for the estimation of the cooling and freezing times
of the liquid, the ambient air temperature is not constant, but were applied to the case where forced air was used to drive the
decreased to the desired set-point temperature. The model of Eq. cooling and freezing processes of the water in the pipe. Fig. 6 shows
(5) assumed a constant ambient temperature, which will produce that the cooling and freezing times are significantly reduced when
deviations in the model predictions and the experimental results forced air cooling is used, in lieu of free convection and radiation
for cooling time. During freezing of the water in the pipe, it is most with stagnant air (see Fig. 5). The deviations in the liquid cooling
likely that the surface temperature of the pipe was close to the time between the model predictions and the experimental results
melting point of water (0 C). Therefore, any variation in the heat can be as high as 50%, as shown in Fig. 6a. These deviations decrease
transfer coefficient would be due primarily to changes in as the ambient air temperature decreases. The deviations are also
temperature-dependent properties. In addition, the ambient tem- lower for the freezing times (see Fig. 6b), and are less than 8% when
perature, though it fluctuated slightly during the freezing period of the total of the cooling and freezing times are considered (see
the water, significant decreases were not observed (see Fig. 4). Fig. 6c). The large deviations observed for the prediction of the
Fig. 5b shows that the maximum deviation between the experi- liquid cooling times may be attributed to the non-constant ambient
mentally determined freezing time and the model prediction is no air temperatures at the beginning of the forced air tests.
more than 13% for any ambient temperature that was used in the
study. The total time required to cool and freeze the water in the 4.3. Cooling and freezing e practical scenarios
pipes is shown in Fig. 5c. There is good agreement between the
predictions of the models and the experiments for the total time, The cooling and freezing of liquids in pipes are of particular
with a maximum deviation of no more than 7%. importance in applications that involve heating, ventilating, and
The novelty of this study is such that a separation of variables air-conditioning (HVAC) or the transport of liquids outdoor in in-
method is used to provide estimates of the freezing time in a dustrial applications. When the fluids become quiescent in the
moving or free boundary problem. Other investigators have pipes that are exposed to cold ambient air conditions, the stagnant
developed alternate models to predict the freezing time of mate- fluids will cool and freeze more rapidly than if they were flowing
rials such as foodstuffs. Pham [12] has modified Planck's equation through the pipe. For the case of bare, uninsulated horizontal pipes,
[13] for predicting freezing times by incorporating the sensible heat Mcquiston et al. [21] have provided data on the overall heat transfer
effects into their model. To that end, Fig. 5b shows the predictions coefficients during free convection and radiation for pipes with
of freezing times from the model developed by Pham [12]. The outer diameters of 12.7 mm (0.5 in) to 127 mm (5 in), where the
figure shows that the model over-predicts the freezing times by temperature difference between the surrounding air and the pipe
approximately 25e45%, supporting the need for a new model to surface varies from DT ¼ 28 C (50 F) to DT ¼ 278 C (500 F). Fig. 7
refine the predictions of freezing time. presents a graphical summary of the maximum overall heat
Fig. 6. Plots of a) cooling time, b) freezing time, and c) total time versus temperature of forced ambient air for water in 50.8 mm nominal diameter Schedule 80 steel pipes.
A. McDonald et al. / Applied Thermal Engineering 73 (2014) 140e151 149
Table 5 ASHRAE [24], for a 25 mm thick insulation, the inner and outer
Typical values of the inner and outer diameters of standard tubing and pipe insu- diameters of the insulation are 61 mm and 114 mm, respectively.
lation (25 mm thick) [24].
The figure shows a similar trend to that observed in Fig. 8, in which
00
Do,pipe, mm Dinn,insul, mm Do,insul, mm Rinsul , m2 K W1 the insulation significantly increased the total time required for
12.7 13 60 1.3 cooling and freezing of water in the pipe.
15.9 16 73 1.6
22.2 23 73 1.2
28.6 29 73 1.0 5. Conclusions
34.9 35 89 1.2
41.3 42 89 1.0 This study focused on the estimation of the cooling and freezing
54.0 55 102 0.9 time of water in cylindrical pipes that were exposed to stagnant
66.7 68 114 0.8
79.4 80 127 0.8
and forced air at temperatures that ranged from 25 C to 5 C, in
114 115 168 0.9 increments of 5 C. A model that was based on the separation of
variables method was developed and used to estimate the freezing
time of water in both bare and insulated pipes. The model was
validated with experimental transient temperature data of water
Fig. 4 and the results presented in Tables 2 and 3 suggest that lower
during the cooling and freezing processes in a bare 50.8 mm
cooling rates will increase supercooling and the volume fraction of
nominal Schedule 80 steel pipe.
dendritic ice that is formed. It is expected that in insulated pipes,
The estimates of the cooling and freezing times of the water that
the amount of supercooling may be larger than that observed in
were obtained from the model were in good agreement with the
bare, uninsulated pipes.
experimental measurements. Larger deviations were observed in
In industrial practice, pipes will also be installed outdoors, and
the cooling times due to the assumption of constant ambient air
in most cases, they will be insulated. Exposure to winter winds at
temperature in the cooling phase in the model, while in the ex-
speeds on the order of 24 km/h [24] or greater are possible. Fig. 9
periments, the ambient temperature decreased from an initial
shows graphical results of the model prediction of the total cool-
value to the set-point temperature at the initial stage of that phase.
ing and freezing times of water in bare and insulated 50.8 mm
A further source of discrepancy in the forced air test was likely due
nominal Schedule 80 steel pipes exposed to cold air with a speed of
to uncertainties in the estimates of the heat transfer coefficient
24 km/h. The outer diameter of the steel pipe is 60.3 mm, and as per
external to pipe.
Future work and extensions of this study and model are
possible. In particular, the effects of internal pressurization on the
freezing time could be modeled analytically. This extension of the
model could be coupled with pressure vessel analysis to estimate
the burst pressures to predict failure in piping where freezing may
occur. Other liquid material systems could also be explored. Water
is a unique material in that its density decreases as it experiences a
phase change from liquid to solid. Materials such as oils and non-
Newtonian fluids may pose other unique issues as they cool,
freeze, and are pressurized in the cylindrical pipes.
Acknowledgements
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