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SOLUTION:
SOLUTION:
4. CHALLENGE The text shows the solution of the equation for n = 1, the innermost orbital radius of
2
the hydrogen atom. Note that with the exception of n , all factors in the equation are constants. The value of r1 is
−11
5.3×10 m, or 0.053 nm. Use this information to calculate the radii of the second, third, and fourth energy levels in
the hydrogen atom.
SOLUTION:
rn = n2k, where k = 5.3×10−11 m
(We are using k for the combination of all the constants in the equation.)
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Chapter 28 Practice Problems, Review, and Assessment
4. CHALLENGE The text shows the solution of the equation for n = 1, the innermost orbital radius of
2
the hydrogen atom. Note that with the exception of n , all factors in the equation are constants. The value of r1 is
−11
5.3×10 m, or 0.053 nm. Use this information to calculate the radii of the second, third, and fourth energy levels in
the hydrogen atom.
SOLUTION:
rn = n2k, where k = 5.3×10−11 m
(We are using k for the combination of all the constants in the equation.)
Figure 6
SOLUTION:
6. For a particular transition, the energy of a mercury atom drops from 8.82 eV to 6.67 eV.
Therefore Eexcited = Eground + ΔE
= -54.4 eV + 4.08 eV
= -50.3 eV
9. Rutherford’s Nuclear Model Summarize the structure of the atom according to Rutherford’s nuclear model.
SOLUTION:
In Rutherford’s nuclear model, all of an atom’s positive charge and virtually all of its mass are
concentrated in a tiny, centrally located nucleus around which negatively charged electrons orbit.
10. Absorption Spectrum The absorption spectrum for a sample of hydrogen gas is shown in Figure 12. Explain how
the absorption spectrum of a gas can be determined. Describe the reasons for the spectrum’s appearance.
9. Rutherford’s Nuclear Model Summarize the structure of the atom according to Rutherford’s nuclear model.
SOLUTION:
Chapter 28 Practicenuclear
In Rutherford’s Problems, Review,
model, all ofand Assessment
an atom’s positive charge and virtually all of its mass are
concentrated in a tiny, centrally located nucleus around which negatively charged electrons orbit.
10. Absorption Spectrum The absorption spectrum for a sample of hydrogen gas is shown in Figure 12. Explain how
the absorption spectrum of a gas can be determined. Describe the reasons for the spectrum’s appearance.
SOLUTION:
To obtain an absorption spectrum, white light is passed through a sample of gas and then a spectroscope.
Because the gas absorbs specific wavelengths, the normally continuous spectrum of white light contains
dark lines.
11. Spectra How do the emission spectra of incandescent solids and atomic gases differ? In what ways are they
similar?
SOLUTION:
Incandescent solids produce spectra consisting of a continuous band of colors, whereas gases produce
spectra made up of a set of discrete lines. All spectra are created by energy-level transitions in atoms.
12. Orbit Radius A helium ion behaves like a hydrogen atom. The radius of the ion’s lowest energy level is 0.0265 nm.
According to Bohr’s model, what is the radius of the second energy level?
SOLUTION:
2
The radius depends on n , so the second level would have a radius four times the first, or 0.106 nm.
13. Bohr Model Hydrogen has been detected transitioning from the 101st to the 100th energy levels. What is the
radiation’s wavelength? Where in the electromagnetic spectrum is this emission?
SOLUTION:
16. Quantum Model Explain why the Bohr model of the atom conflicts with the Heisenberg uncertainty principle,
whereas the quantum model does not.
SOLUTION:
The uncertainty principle does not allow a particle to have both a precisely known position and a
precisely known momentum at the same time. The Bohr orbits would require both these quantities.
17. Pumping Atoms Explain whether green light could be used to pump a red laser. Why could red light not be used to
pump a green laser?
SOLUTION:
Yes; green photons have enough energy to excite atoms into energy levels from which the atom can emit
red light. Red photons do not have enough energy to put the atoms in energy levels high enough to
enable them to emit green photons.
18. Lasers Explain how a laser makes use of stimulated emission to produce coherent light.
SOLUTION:
When a photon strikes an atom in the excited state, it stimulates the excited atom to emit a photon of the
same energy and in step with the incident photon. The incident photon remains unchanged and these two
photons in turn strike other excited atoms, producing more and more in-step, coherent light.
19. Laser Light What are four characteristics of laser light that make it useful?
SOLUTION:
concentrated, high power; directional; single wavelength; coherent light
20. Critical Thinking Suppose an electron cloud were reduced to almost the size of the nucleus. Use the Heisenberg
uncertainty principle to explain why this process would require adding a tremendous amount of energy.
SOLUTION:
The smaller the electron cloud, the more precisely we know the position of the electrons. If a particle’s
position is well known, its momentum must be uncertain. The uncertainty of the momentum can be large
only if momentum itself is large. Therefore, the kinetic energy of the electron also must be large, and it
takes lots of energy to do this.
Chapter Assessment
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Section 1 Bohr's Model of the Atom: Mastering Concepts
21. BIG IDEA Describe how Rutherford determined that the positive charge in an atom is concentrated in a tiny region,
SOLUTION:
The smaller the electron cloud, the more precisely we know the position of the electrons. If a particle’s
position is well known, its momentum must be uncertain. The uncertainty of the momentum can be large
Chapter
only 28 Practice Problems,
if momentum Review,
itself is large. and Assessment
Therefore, the kinetic energy of the electron also must be large, and it
takes lots of energy to do this.
Chapter Assessment
Section 1 Bohr's Model of the Atom: Mastering Concepts
21. BIG IDEA Describe how Rutherford determined that the positive charge in an atom is concentrated in a tiny region,
rather than spread throughout the atom.
SOLUTION:
He directed a beam of α particles at a thin metal sheet and measured the number of particles deflected at
various angles. The small but significant number deflected at wide angles indicates a concentrated
nucleus.
22. How does the Bohr model explain why the absorption spectrum of hydrogen contains exactly the same wavelengths
as its emission spectrum?
SOLUTION:
Bohr said the energy of an emitted photon or an absorbed photon is equal to the change in energy of the
atom, which can have only specific values.
23. Review the planetary model of the atom. What are some of the problems with a planetary model of the atom?
SOLUTION:
As the electrons undergo centripetal acceleration, they would lose energy and spiral into the nucleus. In
addition, all atoms should radiate at all wavelengths, not discrete wavelengths.
24. Analyze and critique the Bohr model of the atom. What three assumptions did Bohr make in developing his model?
SOLUTION:
Bohr's model correctly predicted values for hydrogen's spectrum, but was unable to predict other
elements' spectra. Bohr's assumptions include quantized energy levels, atom emits or absorbs radiation
only when it changes states, and angular momentum is quantized.
25. Gas-Discharge Tubes Describe how line spectra from gas-discharge tubes are produced.
SOLUTION:
Energy is supplied to the gas, which causes the electrons to excite and move to higher energy levels.
The electrons then give off the difference in energy between energy levels as they drop back down to a
less excited state. The energy differences between levels corresponds to spectral lines.
26. How does the Bohr model account for the spectra emitted by atoms?
SOLUTION:
Photon wavelengths are determined by the difference in energies of allowed levels as electrons jump
inward to stationary states.
27. Explain why line spectra produced by hydrogen gas-discharge tubes are different from those produced by helium
gas-discharge tubes.
SOLUTION:
Each element has a different configuration of electrons and energy levels.
Chapter Assessment
Section 1 Bohr's Model of the Atom: Mastering Problems
28. A calcium atom drops from 4.68 eV above the ground state to 2.93 eV above the ground state. What is the
wavelength of the photon emitted? (Level 1)
SOLUTION:
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27. Explain why line spectra produced by hydrogen gas-discharge tubes are different from those produced by helium
gas-discharge tubes.
SOLUTION:
Chapter 28 Practice Problems, Review, and Assessment
Each element has a different configuration of electrons and energy levels.
Chapter Assessment
Section 1 Bohr's Model of the Atom: Mastering Problems
28. A calcium atom drops from 4.68 eV above the ground state to 2.93 eV above the ground state. What is the
wavelength of the photon emitted? (Level 1)
SOLUTION:
30. A calcium atom is in an excited state at the E7 energy level. How much energy is released when the atom drops
down to the E3 energy level? Refer to Figure 18.
SOLUTION:
2
31. A photon of orange light with a wavelength of 6.00×10 nm enters a calcium atom in the E8 excited state and ionizes
the atom. What kinetic energy will the electron have as it is ejected from the atom? Refer to Figure 18. (Level 1)
SOLUTION:
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30. A calcium atom is in an excited state at the E7 energy level. How much energy is released when the atom drops
down to the E3 energy level? Refer to Figure 18.
SOLUTION:
Chapter 28 Practice Problems, Review, and Assessment
2
31. A photon of orange light with a wavelength of 6.00×10 nm enters a calcium atom in the E8 excited state and ionizes
the atom. What kinetic energy will the electron have as it is ejected from the atom? Refer to Figure 18. (Level 1)
SOLUTION:
32. A mercury atom is in an excited state at the E6 energy level. Refer to Figure 19. (Level 2)
SOLUTION:
a. E6 = 7.72 eV
10.44 eV − 7.72 eV = 2.72 eV
b. E2 = 4.66 eV
7.72 eV − 4.66 eV = 3.06 eV
E = hf
10.44 eV − 7.72 eV = 2.72 eV
b. E2 = 4.66 eV
Chapter 28 Practice Problems,
7.72 eV − 4.66 eV = 3.06 Review,
eV and Assessment
34. What energies are associated with a hydrogen atom’s energy levels of E2, E3, E4, E5, and E6? (Level 2)
SOLUTION:
35. Ranking Task Rank the following energy transitions of hydrogen atoms according to the energy of the released
photon, from least to greatest. Specifically indicate any ties. (Level 2)
A: from n = 5 to n = 3
B: from n = 5 to n = 4
C: from n = 4 to n = 2
D: from n = 3 to n = 2
E: from n = 2 to n = 1
SOLUTION:
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Chapter 28 Practice Problems, Review, and Assessment
35. Ranking Task Rank the following energy transitions of hydrogen atoms according to the energy of the released
photon, from least to greatest. Specifically indicate any ties. (Level 2)
A: from n = 5 to n = 3
B: from n = 5 to n = 4
C: from n = 4 to n = 2
D: from n = 3 to n = 2
E: from n = 2 to n = 1
SOLUTION:
36. Reverse Problem Write a physics problem with real-life objects for which the following equation would be part of
the solution: (Level 3)
SOLUTION:
A correct form of the answer is, “What is the energy of a photon emitted when a hydrogen atom
transitions from the n = 3 state to the ground state?”
b.
A correct
Chapter form ofProblems,
28 Practice the answer is, “What
Review, andisAssessment
the energy of a photon emitted when a hydrogen atom
transitions from the n = 3 state to the ground state?”
b.
c.
d.
Chapter Assessment
Section 2 The Quantum Model of the Atom: Mastering Concepts
−4
38. Lasers A laboratory laser has a power of only 0.8 mW (8×10 W). Why is it brighter than the light of a 100-W
lamp?
SOLUTION:
Light is concentrated into a narrow beam, rather than being spread over a wide area.
Chapter Assessment
Section 2 The Quantum Model of the Atom: Mastering Problems
40. DVD Players Lasers used in the DVD players such as the one shown in Figure 20 typically emit light at 640 nm.
What is the difference, measured in eV, between the two lasing energy levels? (Level 1)
SOLUTION:
41. The laser beam’s power equals the photon energy times the number of photons per second that are emitted.
(Level 2)
a. If you want a laser at 840 nm to have the same power as one at 427 nm, how many times more photons per
second are needed?
b. Find the number of photons per second in a 5.0-mW 840-nm laser.
SOLUTION:
a.
b.
41. The laser beam’s power equals the photon energy times the number of photons per second that are emitted.
(Level 2)
a. If you want a laser at 840 nm to have the same power as one at 427 nm, how many times more photons per
second are needed?
b. Find the number of photons per second in a 5.0-mW 840-nm laser.
SOLUTION:
a.
b.
a. Find the energy difference between the two states involved in the generation of each wavelength.
b. Identify the color of each wavelength.
SOLUTION:
a.
substituting the three values of λ gives 1.96 eV, 2.28 eV, and 1.08 eV.
b. red, green, and infrared respectively
44. If white light were emitted from Earth’s surface and observed by someone in space, would its spectrum appear to be
continuous? Explain.
SOLUTION:
No; as white light passed through Earth’s atmosphere, certain energies would be absorbed by the gases
composing the atmosphere. Its spectrum, therefore, would have black lines on it.
46. A certain atom has four energy levels, with E4 being the highest and E1 being the lowest. If the atom can make
transitions between any two levels, how many spectral lines can the atom emit? Which transition produces the
photon with the highest energy?
SOLUTION:
Six lines are possible. E4 → E1 has the highest energy photon.
47. A photon is emitted when an electron in an excited hydrogen atom drops through energy levels. What is the
maximum energy that the photon can have? If this same amount of energy were given to the atom in the ground
state, what would happen?
SOLUTION:
The maximum energy is 13.6 eV. This is also the ionization energy for hydrogen. The electron would
have enough energy to leave the nucleus.
48. Compare the quantum mechanical theory of the atom with the Bohr model.
SOLUTION:
The Bohr model has fixed orbital radii. The present model gives a probability of finding an electron at a
location. The Bohr model allows for calculation of only hydrogen atoms. The present model can be used
for all elements.
51. A beam of electrons strikes atomic hydrogen gas. What minimum electron energy is needed for the hydrogen atoms
to emit the red light produced when the atom goes from the n = 3 to the n = 2 state? (Level 3)
SOLUTION:
There must be enough energy to transition a stable hydrogen atom to the n = 3 state.
52. The most precise spectroscopy experiments use “two-photon” techniques. Two photons with identical wavelengths
are directed at the target atoms from opposite directions. Each photon has half the energy needed to excite the
atoms from the ground state to the desired energy level. What laser wavelength is needed for a precise study of the
energy difference between n = 1 and n = 2 in hydrogen? (Level 3)
SOLUTION:
Chapter 28 Practice Problems, Review, and Assessment
52. The most precise spectroscopy experiments use “two-photon” techniques. Two photons with identical wavelengths
are directed at the target atoms from opposite directions. Each photon has half the energy needed to excite the
atoms from the ground state to the desired energy level. What laser wavelength is needed for a precise study of the
energy difference between n = 1 and n = 2 in hydrogen? (Level 3)
SOLUTION:
For each laser,
SOLUTION:
54. Interpret Scientific Illustrations After the emission of the visible photons described in the previous problem, the
mercury atom continues to emit photons until it reaches the ground state. From an inspection of Figure 22,
determine whether any of these photons would be visible. Explain.
54. Interpret Scientific Illustrations After the emission of the visible photons described in the previous problem, the
mercury atom continues to emit photons until it reaches the ground state. From an inspection of Figure 22,
determine whether any of these photons would be visible. Explain.
SOLUTION:
No. The three highest energy lines leave the atom in states at least 4.64 eV above the ground state. A
photon with this energy has a wavelength of 267 nm in the ultraviolet. The change from E4 to E2 involves
an energy change of only 0.79 eV, resulting in light with a wavelength of 1570 nm in the infrared.
55. Analyze and Conclude A positronium atom consists of an electron and a positron bound together. Although the
lifetime of this “atom” is very short—on the average, one-seventh of a microsecond—its energy levels can be
measured. The Bohr model can be used to calculate energies with the mass of the electron replaced by one-half its
mass. Describe how the orbital radii and the energy of each level would be affected. What would be the wavelength
of the E2 to E1 transition?
SOLUTION:
The radii would be twice as large because m appears in the denominator of the equation. The energies
would be half as large because m appears in the numerator. Therefore, the wavelengths would be twice
as large. Thus, the light emitted from E2 to E1 would be twice that for hydrogen: (2)(122 nm) = 244 nm.
56. Problem Posing Complete this problem so that it can be solved using the Bohr model of the hydrogen atom: “A
hydrogen atom is in its ground state…”
SOLUTION:
A possible form of the correct answer would be, “…when it absorbs a photon and goes to the third
excited state. What was the energy of the photon?”
58. Green laser pointers emit light with a wavelength of 532 nm. Research the type of laser used in this type of pointer,
and describe its operation. Indicate whether the laser is pulsed or continuous.
SOLUTION:
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It uses a pulsed Nd laser at 1064 nm. The IR is put into a “frequency doubling” crystal. Light with half
that wavelength, or 532 nm, results.
results of Rutherford’s experiments. The planetary model explains electrons and Rutherford’s results
but is unstable and would collapse in about 1 ns. Bohr’s model explains known spectra and fits
Rutherford’s nuclear model but has unexplained assumptions and fails the uncertainty principle. It is also
unable to describe atoms with more than one electron. The quantum model can explain all known facts
Chapter 28 Practice
but requires Problems,
computers Review,
to solve the and Assessment
equations.
58. Green laser pointers emit light with a wavelength of 532 nm. Research the type of laser used in this type of pointer,
and describe its operation. Indicate whether the laser is pulsed or continuous.
SOLUTION:
It uses a pulsed Nd laser at 1064 nm. The IR is put into a “frequency doubling” crystal. Light with half
that wavelength, or 532 nm, results.
SOLUTION:
EMF = BLv
= (5.0×10−5 T)(1.0 m)(4.0 m/s)
−4
= 2.0×10 V = 0.20 mV
−7
60. The force on a test charge of +3.00×10 C is 0.027 N. What is the electric field strength at the position of the test
charge?
SOLUTION:
61. A technician needs a 4-Ω resistor but only has 1-Ω resistors. Is there a way to combine what she has? Explain.
SOLUTION:
Yes. Put four 1Ω resistors in series.
RT = R1 + R2 + R3 + R4
8 4
62. The electrons in a beam move at 2.8×10 m/s in an electric field of 1.4×10 N/C. What value must the magnetic field
have if the electrons pass through the crossed fields undeflected?
SOLUTION:
8 4
62. The electrons in a beam move at 2.8×10 m/s in an electric field of 1.4×10 N/C. What value must the magnetic field
have if the electrons pass through the crossed fields undeflected?
SOLUTION:
63. Consider modifications needed for J.J. Thomson’s cathode-ray tube so that it could accelerate protons rather than
electrons. Then answer these questions:
a. To select particles of the same velocity, would the ratio E/B have to be changed? Explain.
b. For the deflection caused by the magnetic field alone to remain the same, would the B field have to be made
smaller or larger? Explain.
SOLUTION:
a.
b.
64. The stopping potential needed to reflect all the electrons ejected from a metal is 7.3 V. What is the electrons’
maximum kinetic energy in joules?
SOLUTION: