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  • Carbohidratos Estructura PDF

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    Patricia Narvaez
    50 просмотров6 страниц
    The document summarizes key aspects of carbohydrate chemistry: - Aldoses and ketoses differ based on whether the carbonyl group is an aldehyde or ketone. - Monosaccharides are classified based on the number of carbons (triose, tetrose, pentose, hexose) and end in -ose or -ulose. - Glyceraldehyde exists as two enantiomers that are mirror images and cause optical activity differences detectable by polarimetry. - Hexoses like glucose and galactose have multiple isomers differing in carbon chain structure.

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    Carbohidratos estructura.pdf

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    The document summarizes key aspects of carbohydrate chemistry: - Aldoses and ketoses differ based on whether the carbonyl group is an aldehyde or ketone. - Monosaccharides are classified based on the number of carbons (triose, tetrose, pentose, hexose) and end in -ose or -ulose. - Glyceraldehyde exists as two enantiomers that are mirror images and cause optical activity differences detectable by polarimetry. - Hexoses like glucose and galactose have multiple isomers differing in carbon chain structure.

    Авторское право:

    © All Rights Reserved
    Скачайте в формате PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    50 просмотров6 страниц

    Carbohidratos Estructura PDF

    Загружено:

    Patricia Narvaez
    The document summarizes key aspects of carbohydrate chemistry: - Aldoses and ketoses differ based on whether the carbonyl group is an aldehyde or ketone. - Monosaccharides are classified based on the number of carbons (triose, tetrose, pentose, hexose) and end in -ose or -ulose. - Glyceraldehyde exists as two enantiomers that are mirror images and cause optical activity differences detectable by polarimetry. - Hexoses like glucose and galactose have multiple isomers differing in carbon chain structure.

    Авторское право:

    © All Rights Reserved
    Скачайте в формате PDF, TXT или читайте онлайн в Scribd
    Отметить как неприемлемый контент
    из 6

    Aldoses

    Ketoses
    OH OH OH O
    Hydroxyl group
    O OH
    HO HO

    OH OH OH OH

    Ketone group
    Aldehyde group OH OH O

    HO OH
    O OH

    OH OH OH

    -ose -ulose
    OH

    HO O

    triose

    OH
    HO

    OH

    tetrose

    Metabolic intermediates
    OH

    O OH

    OH OH
    O O O
    pentose From ribose
    N O P P P
    O O O OH
    N
    OH OH H2N
    OH OH OH

    OH
    O N
    N HO

    HO

    OH OH
    Adenosine triphosphate (a ribonucleotide)
    glucose (a hexose)!

    Part of complex carbohydrates


    and nucleotides
    Glyceraldehyde enantiomers
    OH
    asymmetric carbon
    HO O
    Analyzer Polarizer
    (+)-glyceraldehyde
    Dextrorotatory
    Detector Polarimetry Light Source
    OH cell containing
    sugar solution
    HO O

    (-)-glyceraldehyde
    Levorotatory
    top
    H O H O
    C C
    1  
    H C OH H C OH
    2  
    HO C H HO C H
    3  
    HO C H HO C H
    4  
    bottom-most H H
    C OH HO C
    asymmetric carbon 5  
    H C OH H C OH
    6  
    H H

    bottom
    D-galactose L-galactose
    H O
    C

    H O C
    C

    H C OH + 3C
    C
    23 = 8
    C possible isomers
    H C OH
    H C OH
    H

    D-glyceraldehyde H C OH

    H O H O H H O
    C C C

    C OH C OH HO C

    HO C HO C HO C

    HO C C OH
    C OH

    H C OH H C OH
    H C OH

    H C OH H C OH
    H C OH

    H H
    H
    D-galactose D-glucose D-mannose

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