Revision Worksheet

XII Chemistry 17-18

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1. Define Doping.
2. The window panes of the old buildings are thick at the bottom. Why?
3. Name an element which can be added to silicon to give a :
(a) p – type semiconductor (b) n – type semiconductor.
4. State Henry’s Law and Raoult’s Law.
5. Define the term azeotrope? Give an example of it.
6. What would happen if Nickel spatula is used to stir a solution of CuSO4? E0Cu2+ / Cu = 0.34 V, E0
Ni 2+ / Ni = -0.25V?
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7. What is Frenkel’s and Schottky’s defects? Explain.

8. Explain the following terms: Unit cell, Coordination number, Ferromagnetism, Antiferromagnetism.
9. A compound formed by A & B crystallizes in the cubic structure where ‘A’ are at the corners of the cube
and B are at the face centre. What is the formula of the compound?

10. In crystalline solid, anions C are arranged in cubic close – packing, cations A occupy 50% of tetrahedral
voids & cations B occupy 50% of octahedral voids. What is the formula of solid?
11. (a) Excess of lithium makes LiCl crystal pink. Explain.
(b) What are F centres? How does a crystal changes due to presence of F centre?
12. 0.90g of a non – electrolyte was dissolved in 87.90g of benzene. This raised the boiling point of benzene
by 0.250C. If the molecular mass of non – electrolyte is 103.0 g/mol, calculate the molal elevation
constant for benzene?
13. A compound is formed by two elementsX and Y.Atoms of the element Y (as anion) make ccp and those
of element X (as cations) occupy all the octahedral voids. What is the formula of the compound.
14. When 20g of a non – volatile solid is added to 250 ml of water, the freezing point of water becomes
-0.90C. Calculate molecular mass of the solid if kf of water is 1.860Ckg/mol.
15. (a) Explain Hoffmann – Bromamide reaction.
(b) How can you distinguish between primary, secondary and tertiary amine?

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16. An element crystallizes in a structure having fcc unit cell with the edge length of 200 pm. Calculate its
density, if 200 g of this element contains 24 × 1023 atoms.
17. What is the cell potential for the cell at 250C Cr / Cr3+ 10.1 M //Fe2+ (0.01M) /Fe E0Cr+/Cr = -0.74V ;
E0 Fe2+/Fe = - 0.44V.

18. Calculate ∆ G0 for the reaction at 250C Zn (s) ∣ Zn2 + [0.0004M ∥ Cd2+ (0.2M) ∣ Cd (s). E0
Zn 2+/Zn = - 0.763V , E0Cd 2+/Cd = -0.403V , F=96500 C Mol-1 , R = 8.314 J/K.

19. (a) State Kohlrausch’s Law?

(c) At 298 K , the molar conductivities at infinite dilution of NH4Cl , NaOH and NaCl are 129.8 , 217.4
 and 108.9 scm2 mol-1 respectively .It molar conductivity of 0.01M NH4OH solution is 9.33 scm2 mol-
1
,calculate the degree of dissociation of NH4OH at this dilution?
20. (a) State Faraday’s Laws of electrolysis?
(b)How many g of chlorine can be produced by the electrolysis of molten NaCl with a current of
1 amp. for 15 min?
(d) How many electrons flow when a current of 5 amps is passed through a solution for 193 sec.
Given F = 96500 C. NA=6.002 × 1023 mol-1?
21. (a) The atomic radii increases considerably from N to P but very little increase is observed from As
to Bi. Why?
(b) Give reason for the following- the first ionization enthalpy of 15th group elements is higher than 16th
group elements?
(c) How does metallic character vary down the 15 group & why?
22. Give reasons:
(a) PCl5 exists but NCl5 does not.
(b) The stability of Hydrides follows the order- NH3 > PH3 > Ar5H3 > SbH3
(c) PH3 is a weaker base than NH3.
23. (a)Explain the chemistry behind brown ring test for detection of nitrate ions.
(b) Write two differences between white and red phosphorous.
(c) Give the structures of: (i) sulphurous acid and (ii) Peroxodisulphurous acid?
24. (a) Methylamine is a stronger base than aniline.
(b)Before nitration, aniline is converted to acetanilide.
(c) It is easier to brominate aniline as compared to benzene.
25. A compound (X) having formula C3H7 NO reacts with Br2 in the presence of NaOH to give another
compound (Y). Compound (Y) reacts with HNO2 to form ethanol and N2 gas . Identify (X) and (Y) .
Write the reaction involved.
26. Write a short note on:
(a) Carbylamine reaction
(b) Diazotization
(c) Gabrial phthalimide reaction
27. (a) Give a reaction to prove that : (i) Glucose has carbonyl group (ii) The six carbons in glucose are
arranged in a straight chain.
(b) What are anomers? Name the two anomers of glucose.
(c) What is nucleoside? What type of bonding occurs between two nucleotides?
28. (a) Explain why on addition of 1 mole of NaCl to 1 of water, the boiling point of water increases,
while addition of 1 mole of methyl alcohol to 1 of water, decreases the boiling point.
(b) What mass of ethylene glycol(molar mass= 62.0g mol-1) must be added to 5.50kg of water to lower
the freezing point of water from 0°C to -10°C? (kf for water =1.86K kg mol-1 )
29. How do you account for the following:
(a) Frenkel defect are not found in alkali metal halides.
(b) Schottky defect lowers the density of related solids.
(c) Impurity doped silicon is a semiconductor.

30. Amino acids contain amino group and carboxyl group. These are monomers of proteins. Proteins occur
in every part of our body and form the fundamental basis of structure and function of life. They are also
required for growth and maintenance of body.
(a) What are essential amino acids? Why should these be part of our diet?
(b) What are the chief sources of proteins? Why should children take more proteins?
(c) Name a disease caused by the deficiency of amino acids?
(d) What values are possessed by children taking milk, pulses fruits regularly?
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31. (a)What happens when:

(i)Cl2 gas is passed through a hot conc solution of NaOH?
(ii) SO2 is passed through aqueous solution of Fe(III) salt?
(b) Answer the following:
(i) What is the basicity of H3PO3 and why?
(ii) Why F2 does not play a role of central atom in interhalogen compounds?
(iii) Why do noble gases have a very low B.P?

32. Complete and balance:

(a) (NH4)2SO4+ 2NaOH →
(b) 2FeCl3 (aq) +3NH4OH (aq) →
(c) AgCl(s) + 2NH3(aq) →
(d) NaNO3 + H2SO4 →
(e) 3NO2 (g) + H2O(l) →
33. Draw the structures of the following: (i) H2S2O8 (ii) HClO4 (iii) XeOF4 (iv) N2O5 (v) ClF3 (vi) S8
(a) How will you account for the following:
(i) Fluorine is a stronger oxidizing agent the chlorine.
(ii) Sulphur shows greater tendency of catenation than oxygen
34. (a) What is van’t Hoff factor? What possible values can it have if the solute molecules undergoes
dissociaction?

(b) An aqueous solution of contaning 12.48g of BaCl2 in 1.0kg of water boils at 373.0832K. Calculate
the degree od dissociation of BaCl2. ( given kb for H2O = 0.52 K m-1

35. (a) Convert: (i) Toluene to benzaldehyde (ii) Acetaldehyde to Acetamide

(b) A compound ‘A’ with formula C5H10O gives a positive 2, 4 –DNP test but a negative Tollen’s
test It can be oxidizing to carboxylic acid ‘B’ of molecular formula C3H6O2, when treated with alk.
KMnO4 under vigorous conditions. The salt of ‘B’ gives a hydrocarbon ‘C’ on Kolbes’ electrolytic
decarboxylation. Identify A, B, C & write chemical equations.

36. (a) Convert: (i) Toluene to m- nitrobenzoic acid (ii) Phenol to acetophenone

(b) Acompound A with molecular formula C5H12O on oxidation forms compound B with molecular
formula C5H10O. The compound B gives iodoform test but does not reduce ammoniacal silver nitrate.
The compound B on reduction with Zn – Hg/ HCl gives compound C with molecular formula C5H12.
Identify A, B, C & give the chemical reactions involved.
37. (a) Define Molar Conductivity of a solution and explain how molar conductivity changes with the
change in the concentration of a solution for a weak and a strong electrolyte.
(b) The resistance of a conductivity cell containing 0.001 m KCl solution at 298 K is 1500 Ω. What is
the cell constant if the conductivity of 0.001M KCl solution at 298 K is 0.146 × 10-3 S cm-1?
38. Illustrate the following name reactions:
(a) Cannizzaro’s Reaction
(b) Clemmensen Reduction
(c) Cross Aldol Condensation
(d) Hell-Volhard-Zelinsky Reaction
(e) Rosenmund Reaction
(f) Stephens Reaction
(g) Reimer Tiemann Reaction
 (h) Gattermann-Koch Aldehyde synthesis
(i) Aldol Condensation
(j) Wolff-Kishner Reduction
39. What is meant by the following? Give eg:
(a) Cyanohydrin
(b) Semicarbazone
(c) Hemiacetal
(d) Ketal
(e) 2,4-DNP derivative
(f) Aldol
(g) Oxime
(h) Imine
(i) Schiff’s base

40. Give a chemical test between:

(a)Acetaldehyde and benzaldehyde
(b) Propanone and Proponol
(c) Phenol and benzonic caid
(d) Benzaldehyde and acetophenone
(e) C6H5CH2NH2 and C6H5NH2
(f) Ethylamine and aniline
(g) methylamine and dimethylamine

Prepared By: Ms Anagha