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TITLE
Hydrogen and Oxygen
2. DATE OF EXPERIMENT
Wednesday, November 19th 2014
3. EXPERIMENT DONE
Wednesday, November 19th 2014
4. PURPOSE
a) Knowing Hydrogen Gas Production Method
b) Knowing the nature - Hydrogen Gas Properties
c) Identifying Gas Hydrogen and its compounds
d) Mengethaui Oxygen Gas Production Method in the Laboratory
e) Knowing the existence of Oxygen Gas In A Compound
5. BASIC THEORY
I. HYDROGEN
Hydrogen (Latin: hydrogenium, from Greek: hydor: water, genes:
forming) is a chemical element in the periodic table that has the symbol H and
atomic number 1. At standard temperature and pressure, hydrogen is a
colorless, odorless, non- metal, single-valent, and is a diatomic gas that is
highly flammable. With the atomic mass 1.00794 amu, hydrogen is the lightest
element in the world.
Hydrogen gas is highly flammable and will burn at concentrations as
low as 4% H2 in air. The enthalpy of combustion for hydrogen is -286 kJ /
mol. Hydrogen burning according to the chemical equation:
Physical
Phase gas
(0 °C, 101.325 kPa)
Density
0,08988 g/L
14,01 K
Melting point
(−259,14 °C, −434,45 °F)
20,28 K
Boiling point
(−252,87 °C, −423,17 °F)
Tripel point 13,8033 K, 7,042 kPa
The critical point 32,97 K, 1,293 MPa
Heat of fusion (H2) 0,117 kJ·mol−1
Heat of vaporization (H2) 0,904 kJ·mol−1
(25 °C) (H2)
Heat capacity
28,836 J·mol−1·K−1
The vapor pressure
P/Pa 1 10 100 1 k 10 k 100 k
T/K 15 20
Atomic properties
The crystal structure hexagonal
1, −1
The oxidation number
(oksida amfoter)
Electronegativity 2,20 (Scala Pauling)
The ionization energy 1st: 1312,0 kJ·mol−1
Atomic radius 25 pm
Atomic radius
53 pm
(calculation)
Covalent radii 37 pm
The radius of the
120 pm
Van Der Waals
Other Information
The thermal (300 K) 180,5
conductivity m W·m−1·K−1
Speed of sound (gas, 27 °C) 1310 m/s
Hydrogen is very reactive and reacts with every oxidizing element of
nature and nature is more electronegative than hydrogen such as halide groups.
Hydrogen can react spontaneously with chlorine and fluorine at room
temperature to form hydrogen halide. Hydrogen can also form compounds
with less electronegative elements such metals to form hydrides.
Hydrogen solubility in organic solvents is very small when compared
to its solubility in water. Hydrogen can be absorbed in a metal such as steel.
The absorption of hydrogen by the steel causes the steel is brittle, causing
damage in the manufacture of the equipment. With these properties, the
scientists can store hydrogen in metals platinum ga.
At normal temperatures are in the form of hydrogen diatomiknya but at
a very high temperature hydrogen dissociates into atomic-ataomnya. Atomic
hydrogen is very reactive and can react with metal oxides such as silver,
copper, of lead, bismuth, and mercury to produce the free metal.
Atomic hydrogen can also react with organic compounds to form such
complexes with C2H4 to form C2H6 and C4H10. At very high pressure
hydrogen can have properties such as metal.
COMPOUND
Although hydrogen is gaseous, we very rarely found in the earth's
atmosphere. Hydrogen gas is very light, if not combined with other elements,
will collide with other elements and terkeluarkan of the layers of the
atmosphere. On earth hydrogen commonly found as a compound (water) in
which the atoms are linked by oxygen atoms. The hydrogen atoms can also be
found in plants, petroleum, charcoal, and others. As an independent element,
its concentration in the atmosphere is very small (1 ppm by volume). As the
lightest gas, hydrogen combines with other elements "sometimes explosively"
to form a variety of compounds.
a. HYDRIDE
The term hydride is used to indicate that the oxidation number
of hydrogen which reacts with other elements is -1 and is denoted as
H-. Some examples of hydride compounds are LiH, NaH, LiAlH4,
BeH2 and others. Bond in hydride compounds can be covalently to the
very nature of ionic and can be a part of this hydride molecules,
oligomers, polymers, ionic solids, the absorption layers chemical, or
even be part of a metal. Hydride reacts as a Lewis base and act as
reducing agents and can also be reacted with hydrogen radicals and
protons. Various elements to form hydrides and now become an
important subject of research to find a metal that can store hydrogen to
generate electricity or batteries. Hydride also plays an important role in
the synthesis of organic compounds due to nature as a reductant.
b. HYDROCARBONS
In the field of organic hydrocarbon compounds are defined as
compounds consisting essentially of hydrogen and carbon, but this
sense is widespread due to some hydrocarbons also contain other
elements such as phosphorus, nitrogen, sulfur and even metal
(organometallic). Very broad class of hydrocarbons including alkanes,
alkenes, alkynes, alcohols, esters, carboxylic acids, aldehydes, ketones,
amides, aromatic compounds and macromolecules such berbabagai
wide class of protein, and carbohydrates.
Generally, hydrocarbons are the main source of energy on earth
but with consideration of the current condition of the earth's energy use
began little by little transferred to an environmental friendly energy
sources. Hydrocarbons are also a source or base material to create a
wide range of organic compounds that others such as the petrochemical
industry is the basis for the manufacture of other chemical compounds.
c. HYDROGEN HALIDE
Hydrogen halide is a chemical compound that is produced from
the reaction of hydrogen with the element of group 7 for example
halide ie HF, HCl, HBr, and HI. HAT compounds rarely found in
nature and are not stable. Compounds of hydrogen halide (HX) is
acidic due to their tendency to release H + in solution. Unless HF
hydrogen halide then the other is a strong acid. In solution fellow
halide molecules can form hydrogen bonds in which the bond is
causing some compounds having boiling points higher than expected.
Tendency to react with the hydrogen halide is disebakan they have a
big enough difference kelektronegatifitas. The following comparison
of the size of the atom and the dipole moments of some hydrogen
halide.
d. H2O
Water molecule has two hydrogen atoms and one oxygen atom
covalently bonded. Oxygen binds strongly hydrogen due to the high
electronegativity of oxygen to produce positive and negative poles of
the water molecules so that it is donating water molecule has a dipole
moment. Fellow of water molecules can form hydrogen bonds thus
increasing the boiling point of water. Water may be in the description
as a molecule that has a polarity that can terdeprotonasi by the
reaction:
ISOTOPES.
Isotopes are elements with the same atomic number, but different
mass. These differences occur because different numbers of neutrons.
Hydrogen has three isotopes in nature, namely 1H, 2H, and 3H.
• 2H, known by the name of Deuterium with essentially consists of one proton
and one neutron. Deuterium is not radioactive and harmless. This isotope is
used as a marker in the synthesis of organic compounds. Deuterium in the
form of 2H2O is often also used as a coolant in nuclear reactors and is also
used for the fusion reaction.
• 3H called Tritium containing two neutrons and one proton in its nucleus and
is radioactive and decays into helium-3 by emitting beta rays. Tritium is
widely used as tracers in the field as well as geochemical markers in chemistry
and biology experiments.
USEFULNESS
INDUSTRIAL SCALE
Oxygen or acid is a chemical element in the periodic table that has the
system epitome O and atomic number 8. It is kalkogen group elements and can
easily react with almost all other elements (mainly into oxide). At standard
temperature and pressure, two atoms of the element bind to form dioxygen, are
compounds with the formula O2 diatomic gas that is colorless, tasteless, and
odorless.
HISTORY
For several centuries, the experts sometimes realize that air is composed of
more than one component. The behavior of oxygen and nitrogen as components
of air led to the development of the phlogiston theory of combustion, which
captured the minds of chemists for a century. Oxygen has been made by several
experts, including Bayen and Borch, but they do not know how to collect it. They
also do not study its properties and does not recognize as a basic element oxygen.
Priestley is credited with its discovery, although Scheele also discovered it
independently. In the past, the atomic weight of oxygen is used as a standard of
comparison for other elements, until in 1961, when the IUPAC (International
Union of Pure and Applied Chemistry) using carbon 12 as the new standard of
comparison.
RESOURCE
Oxygen is the third most elements are found in abundance in the sun, and play
a role in the carbon-nitrogen cycle, the process is thought to be a source of energy
in the sun and stars. Oxygen under excited conditions give a bright red color and
the yellow-green on the Aurora Borealis.
STRUCTURE
ALLOTROPES
The color of liquid oxygen is blue like the sky blue color. This phenomenon is
not related; sky blue color is caused by the spread of Rayleigh. Oxygen is more
soluble in water than nitrogen. Air contains about one molecule of O2 for every
two molekul N2, compared with the atmospheric ratio of about 1: 4. The
solubility of oxygen in water depends on the temperature. At a temperature of 0 °
C, the concentration of oxygen in water is 14.6 mg • L-1, when at a temperature of
20 ° C the dissolved oxygen was 7.6 mg • L-1. At a temperature of 25 ° C and 1
atm air, fresh water containing 6.04 milliliters (mL) of oxygen per liter, when the
seawater contains about 4.95 mL per liter. At temperatures of 5 ° C, the solubility
increases to 9.0 mL (50% more than 25 ° C) per liter of pure water and 7.2 mL
(45% more) per liter for sea water.
ISOTOPE
6. DESIGN OF EXPERIMENT
a) Material & Tools
Hydrogen
No Tools and Materials Amount
1 Reaction tube side pipe 1
2 Measuring glass 2
3 Dish 1
4 Bunsen
5 Ca piece 1
6 Mg Powder
7 KI 0,05M
8 H2O2 4.5 % 1ml
9 Litmus paper
10 Wood 2
11 Zn powder 1
12 Glass cotton
13 Cotton
14 Pork
15 Aquades 1
16 KClO3
17 KMnO4
Oxygen
No Tools and Materials Amount
1 Reaction tube side pipe 1
2 Measuring glass 2
3 Plastic pipe 1
4 Plastic closed 1
5 Statif and clem 1
6 Bunsen 1
7 KClO4
8 KI 0.05 M
9 H2O2 4.5 %
10 Litmus paper 2
11 Wood 1
12 Kawi stone powder
b) Procedure of Experiment
Hydrogen experiment
1.
A few pieces of calcium
White powder
-Observed
White solution
2.
Small spoon of magnesium powder gray
-Entered into porcelain cup
containing distilled water
The powder does not dissolve
-Checked by PP
-Observed
Pink solution
3. 0,02 gram of zinc powder
-Heated
Formed gas bubbles
-Tested flame
Arise burst
-Added 4M solution of
hydrochloric acid sufficiently
The solution was gray, arise bubble
-Tested flame
Arise burst
5. A few drops of solution H2O2 4,5%
-Added 1mL KI
Yellow solution
-Observed
The solution changed purple
Oxygen experiment
1. Potassium Chlorate
-Heated
Greater flame
7. DATA
8. ANALYSIS
9. DISCUSSION
10. CONCLUSION
11. REFERENCES
Achmad, Hiskia. 2001. Kimia Unsur dan Radiokimia . Bandung : PT. Citra Aditya Bakti.
Amaria. dkk. 2014. Penuntun Praktikum Kimia Anorganik II Unsur-Unsur Golongan
Utama. Surabaya. Unesa Press.
Vogel (1985). Buku Teks Analisis Anorganik Kualitatif Makro dan Semimakro, Jakarta :
PT. Kalman Media Pusaka
.
ANSWER QUESTIONS
Hydrogen
1. Explain what is explosion gas and its function!
Gas bubbling was caused due to the reaction of H2 gas with the flame, which is
basically the H2 gas is indeed very reactive to the fire because it reacts with the O2.
And at the laboratory scale blast is used to identify the presence of H2 gas.
2. Write all reaction on the experiment above!
Experiment 1 : Ca(s) + 2H2O(l) Ca(OH)2(aq) + H2(g)
Experiment 2 : Mg(s) + 2H2O(l) Mg(OH)2(aq) + H2(g)
Experiment 3 : Zn(s) + 2H2O(l) Zn(OH)2(aq) + H2(g)
Experiment 4 : Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g)
Experiment 5 : 2KI(aq) + H2O2(aq) 2KOH(aq) + I2(aq) + H2(g)
3. Why hydrogen peroxide is used in dilute solution!
Hydrogen peroxide is a liquid that is practically colorless. Is highly explosive and
dangerous in tinggi.Biasanya concentration of hydrogen peroxide is used as an
aqueous solution, but the 90% solution in water use.
Oxygen
1. Calculate the volume of oxygen gas is obtained when available KCLO3 1 gram !
Mol KClO3: 1/122,5 = 0,008mol
2KClO3 + MnO2 2KCl + 3O2 + MnO2
M: 0,008 - - - -
R: 0,008 0,004 0,008 0,012 0,004
S: - 0,004 0,008 0,012 0,004
V O2 = 0,012 x 22,4
= 0,2688 L = 268,8 mL
2. Give the Lewis structure that indicates an O2 molecule with two unpaired valence
electrons!
3. Explain the events of experiments 1 and 2!
Experiment 1
In this experiment aims to find ways of making and identification of
oxygen gas. Potassium chlorate is grayed put the test tube to a height of
0.5 cm from the bottom of the tube and add three tablespoons of
manganese spatula then covered with a rubber stopper and a hose
connected to the measuring cup that has been filled with water and placed
upside down in the water. The test tube is heated, white smoke is visible
oxygen gas with a volume of more than 100 ml. heating process aims to
accelerate the reaction and manganese acts as a catalyst. For identification
of the tested gas flame with flame produced timber growing. It shows one
of the properties of oxygen gas that can enlarge the flame. The reaction
equation:
2KClO3(s) +2MnO2 (s)KCl(aq) + 4O2(g)+ 2KClO4(aq)
Experiment II
Subsequent experiments, a total of 0.05 g of permanganate put into a test
tube and add 5 drops of hydrogen peroxide 4.5%. Along with the mouth of
the tube was closed with a rubber stopper directly along the hose that is
connected to the measuring cup is placed upside down in the water. White
smoke formed an oxygen gas that drives the water in a measuring cup to
get out. But in this experiment the oxygen gas produced very little so that
the volume of gas that is obtained only 1 ml. same as the previous
experiment as a test identification of the gas flame with flame produced
timber growing. It shows one of the properties of oxygen gas that can
enlarge the flame. The reaction equation:
KMnO4(s) + 2H2O2 (aq) K+(aq) + Mn2-(aq) +3O2(aq) +3 H2O(l)