Aiits 1719 Jeem Ot Sol

1 AIITS-OT-PCM (Sol.
)-JEE(Main)/19
FIITJEE JEE(Main)-2019
ANSWERS, HINTS & SOLUTIONS

ALL INDIA INTEGRATED TEST SERIES
OPEN TEST
(Main)
Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS
1. C 31. B 61. B
2. C 32. C 62. C
3. B 33. A 63. D
4. C 34. B 64. D
5. D 35. B 65. A
6. C 36. D 66. D
7. D 37. B 67. C
8. B 38. D 68. D
9. D 39. A 69. C
10. D 40. D 70. D
11. D 41. A 71. A
12. B 42. C 72. C
13. D 43. C 73. B
14. A 44. B 74. B
15. A 45. D 75. C
16. C 46. B 76. D
17. D 47. B 77. A
18. B 48. A 78. B
19. B 49. B 79. C
20. A 50. C 80. A
21. D 51. C 81. B
22. D 52. A 82. A
23. B 53. B 83. B
24. D 54. D 84. B
25. B 55. B 85. A
26. A 56. A 86. D
27. B 57. B 87. A
28. C 58. B 88. B
29. A 59. A 89. C
30. B 60. B 90. B
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AIITS-OT-PCM (Sol.)-JEE(Main)/19 2
Physics PART – I
SECTION – A
1. C
Sol. Vertical component of initial velocities are same. Hence, identical vertical motions.
2. C
RT
Sol. v
M
3. B
Sol. k2  k3
3
k= k
2
4. C
Sol. When u0 has such a value that bob will just stop when string is horizontal. Then the
situation given in option (C) will arise.
5. D
Mg Mg
Sol. Kx = ; x=
3 3k
6. C

Sol. T  2
geff
7. D
Sol. T  Pa db Ec
T  (ML1 T 2 )a (ML3 )b (ML2 T 2 )c
Comparing power on LHS and RHS.
a + b + c = 0, –a – 3b + 2c = 0, –2a – 2c = 1
8. B
ft
Sol. v  vo 
m
  I
1 2f 2ft
fR = MR 2  ; R = ;  ; v = R
2 m mR
ft 2ft
vo   R
m mR
3ft mv o 2v
 vo ; t  ; v o
m 3f 3
3 AIITS-OT-PCM (Sol.)-JEE(Main)/19
9. D
m T 2m  1 T
Sol. f ; n
2  4 
10. D
1  5  1   3 
Sol. v cm 
2
2
1m / s
2
11. D
Sol. In SHM a = –2x and T = 2/
12. B
Rh
Sol. sin  90    
R
R
R-h
90-

13. D
x x
Sol. t1  and t 2 
v u
14. A
Sol. Translational velocity of A = Vo (towards right)
V
Rotational velocity of A = R = o (towards left)
2
15. A
GMm  GMm  GMm
Sol. W    =
2  4R   2  2R   8R
16. C
Sol. PV = nRT
17. D
2  x  H  h
Sol. V  2gx,r  2gx
g
r  4x   x  H  h 
Hh
rmax at x 
2
18. B
Sol. When stones are there inside the boat. the volume of water displaced is equal to the
weight of the boat + stones. When stones are unloaded into the water the volume of
water displaced is equal to the volume of stones unloaded plus (weight of boat) /
(density of water). This time the displaced volume of water is smaller than in the first
case. Therefore the water level falls.
19. B
Sol. Pressure node is formed at the both the ends and in
the middle.
20. A
2
1  3  mgh
Sol. W = –mgh + m  gh  = 

2  2   4
21. D
Sol. V  (10 3 )2  (10)2  20
22. D
g
Sol. T – mg = m
2
mg
N = 2 mg – T =
2
23. B
I
Sol. 100°C – Ir – r  Ir = 0°C
2
 Ir = 40°C ;  tF = 0° + Ir = 40°C
24. D
Sol. U = T(A)
2
 R 
U = T  1000  4    4 R2  = T × 4(9R2)
  10  
 
U = 36R2T
25. B
90
Sol. Total momentum =  (dm)v cos 
 90
M
dm =  Rd
R
M 2Mv
Total momentum =  R vRd cos   
26. A
gh
Sol. Pressure due to liquid =
2
Force = (Total Pressure) (Area of wall)
27. B
MR2 Y
L
Sol. For disc z-axis I = X
2
By parallel axis theorem
C
mR2
IX  X
4
mR2
IL =  m(C cos 45o )2
4
28. C
dx
Sol.  v  v 0  gt  ft 2
dt
1
 dx   vdt
0
29. A
V
1  v v 
Sol. t  t     v  s v1
2    

t
Area under v – t curve = S
30. B
Sol. Component of force or force must be act in direction of displacement to do positive work.
Chemistry PART – II
SECTION – A
31. B
Sol. XeF4 is planar because Xe is sp3d2 hybridised. Due to the presence of two lone pairs of
electrons, the shape is reduced to a square planar. CCl4 is tetrahedral because C is sp3
hybridised. The correct answer is (B)
32. C
Sol. SO32 get oxidized and its `n’ factor is 2.
The metal must have been reduced.
Applying the law of equivalence
50  0.1  (3 – n) = 25  0.1  2
n=2
33. A
Sol. It is a test for unsaturation. As benzene and naphthalene is also unsaturated, but they
are stabilized due to resonance, and thus does not give Bayer’s test.
34. B
Sol. Peroxide effect is observed when unsymmetrical alkene is treated with HBr only (and not
with HCl and Hl).
35. B
Sol. Absorption line in the spectra arise when energy is absorbed i.e., electron shifts from
lower to higher orbit, out of a and b, b will have the lowest frequency as this falls in the
Paschen series.
36. D
Sol. In (A) P O43 and S O42 both are isoelectronic and tetrahedral in shape. Same is in (B)
also. In (C) each C atom in C2H2 is sp hybridized same as C in CO2 hence, both are
linear. Only in (D) N2O is linear whereas NO2 is bent and therefore, the answer is (D)
37. B
2
Sol. Qp =
P  NH3

(3)2 9
 atm2 = 1.125 atm–2.
3 3
P  P  (1)(2) 8
N2 H2
Since value of Qp is larger than Kp (4.28  10–5 atm–2), it indicates net reaction will
proceed in backward direction.
38. D
Sol. pH  pKa  log

CH3COONa  5  log 0.110  5
CH3COOH 0.1
10
39. A
Sol. Let H+ ion concentration changes by x factor.
 pH = – log [H3O+]
 pH + pH = – log {x(H3O+]} = –log x – log [H3O+]
or pH = – log x = 0.3
 x = 0.5
40. D
PM MB MA 
Sol. i) Density of a gas     . Since  . at the same pressure A = B.
RT TB TA
But if pressure is different then A ≠ B.
ii) Pressure of the gases would be equal if their densities are equal other wise not.
3
iii) KE per mole = RT
2
 It will be different for the two gases
3RT T T
iv) Urms  , Since A  B ; Urms of A = Urms of B
M MA NB
41. A
Sol. PV = nRT
w RT RT
P 
M V M
PM eff

RT
M eff  (0.79  28)  (0.20  32)  (0.01  39.9)  28.9
28.9  1
   1.18 g / lit
0.0821 298
42. C
Sol. SiO 2  SiF4  H2 SiF6 
43. C
Sol. Si  OH4  2H4SiO4 
H O
 H6Si2O7 2
44. B
Sol. Anti elimination.
45. D
Sol. Ring expansion.
46. B
2
PNOPBr2
Sol. KP  2
PNOBr
47. B
Sol. G = -ive for spontaneous
48. A
Sol. Mg has full filled s-orbital.
49. B
Sol. O H
O=N=O , N , N
O O H H
H
50. C
 2p 2  2p2y
Sol. 1s2 ,  1s2 , 2s2 ,  2s2 , 2p2 ,  2py2  2p2z
z
51. C
Sol. Pequm = 1 atm
K1  pCO2  1atm
K 2  pNH3  pH2S = 0.5  0.5 = 2.5  10–2 atm2 = 0.25 atm2
2
2 2 1

K 3  pNH3   pCO2    
3 3
4 1 4
    0.148 atm3
9 3 27
 The order is K1 > K2 > K3
52. A
0.693 0.693 A 1.386
Sol. K1 =  K0  0 
t1/2 40 2t1/2 2  20
K 1 0.693 40
 
K0 40 1.386
0.693
=  0.5mol– litre
1.386
53. B
Sol. AgCl Ag+ + Cl–
In CaCl2
CaCl2 Ca+2 + 2Cl–
0.01 0.01 20.01
In NaCl
NaCl Na+ + Cl–
0.01 0.01 0.01
In AgNO3
AgNO3 Ag+ + Cl–
0.05 0.05 0.05
common ion effect is maximum in AgNO3
So, S1 > S3 > S2 > S4
54. D
Heat  Na2 CO3
Sol. SiCl4  H2O  Si(OH)4   SiO2 Heat
 Na2SiO3
A  B  C
55. B
Sol. The dimeric formula, Al2Cl6, is retained in non-polar solvent but is broken into
 Al H2O 6  Cl3 on dissolution in water on account of high heat of hydration.
56. A
Sol. Borax dissolves in water and gives an alkaline solution.


Na2B4 O7  7H2O 
 2NaOH 4H3BO3 Strong Weak
base acid
57. B
COOH Conc. H SO
2 4 KOH Cl2
 CO + CO2  CO 
Sol. –H2O CO2 is Poisonous gas
absorbed 
COOH COCl2
58. B
Sol. SiO2 is a compound of oxygen and silicon, the two most abundant elements of earth’s
crust and is used in building construction.
Si + 2CO (poisonous gas and a stable diatomic SiO2 + 2C molecule)
59. A
Sol. 2A 3B
t=0 a 0
t = t a – 2x 3x
3x a 2.3 a
given  1 i.e. x   t  –2
log = 11.0 min
a – 2x 5 4.6  10 a – 2x
60. B
nH2 1
Sol. Initially 
nH2S 2
8H2S  8H2 + S8
Initial moles : 2 1 –
moles at equil : 2–x 1+x –
nH2 1 x
At equilibrium :  2
nH2S 2  x
Hence x = 1
KP = 28/18 = 256
Mathematics PART – III
SECTION – A
61. B
Sol. Here x   ,  5    0,  
(1, 5)
We have x 2  5x  x  a  3
x 2  4x  a  3
From the graph 0  a  3  5
3  a  2
–5 –4 O
 Number of integral values of a
 2,  1,0,1,2
5
62. C
Sol. We can consider a like x and b like y
P  x, y  is a point which lies on 3x  4y  25
 x 2  y 2 is distance of any point from (0, 0)
 minimum value of x 2  y 2 is distance of 3x  4y  25 from (0, 0)
25
 x2  y2  5
9  16
 minimum x 2  y2  25
63. D
C1C2
Sol.  cos ec15o
1
1

sin15o
o
1 15
 1

sin 45o  30o  C1 C2
M
1

sin 45 cos 30  cos 45o sin30o
o o
1 2 2
 
1 3 1 1 3 1
  .
2 2 2 2
2 2  3 1

3 1
2 3 1  6  2  
 C1M  C1C2  C2M  6  2  1
64. D
Sol. For shortest normal chord t  2,  2 B
A

 A 2,2 2 
D  2,  2 2 
C  8,  4 2 
B  8,4 2 
D
 area of ABCD C
1
 
   8  2  4 2  8 2  3  12 2  36 2
2
65. A
Sol. Here SB  OB '  7  9  4 B’
 B '   0, 4  (0, 3)
x2 y2
 equation is  1 B E1
7 16
O S  7, 0  (4, 0)
66. D
Sol. PA .PB  PT2
T
2  8 2  PT 2
PT  4
B (10, 11)
P (2, 3) A (3, 4)
67. C
Sol. S  1,2 
S '   5,5 
2 2
SS '  2ae   5  1   5  2  5
5
ae 
2
2a  4 a  2
5 5
2e  e 
2 4
1 1
Now 2
 2
1
e  e '
1 1
 2 1
25 / 16 e '
1 16 9
2
 1 
e' 25 25
25 5
e' 2   e' 
9 3
68. D
Sol. We know that t n  5t n 1  8t n 2  0
t 6  5t 5  8t 4  0
t 6  8t 4
 1
5t5
69. C
x2 y2 x2 y2
Sol. Here   1and   1 are orthogonal then they will be confocal also.
a2 b2 A 2 B2
 ae  Ae '
a2e2  A 2e '2
a 2  b2  A 2  B 2
45 45 5 25
 5 
4  4 4
  4 25 1
 
4 4 45
4 5

 9
9  36  5
4  36
9
70. D
1
Sol.
4

4 sin3 10  4 sin3 50  4 sin3 70 
1
  3 sin10  sin30  3 sin 50  sin150  3 sin70  sin 210 
4
1 3
  3  sin10  sin 50  sin70   
4 2
1 3 1 3 3
  3  2 sin30 cos 20  sin70      3  cos 20  sin 70    
4 2 4 2 8
71. A
Sol. sin x  cos x  0 or

16 sin4 x  sin3 x cos x  sin2 x cos2 x  sin x cos3 x  cos 4 x  11 
 
16 1  2 sin2 x cos2 x  sin x cos x sin2 x  cos2 x  sin x cos x   11

16 1  2 sin2 x cos2 x  sin x cos x  sin2 x cos 2 x  11 
16 1  sin 2

x cos2 x  sin x cos x  11
16 sin2 x cos2 x  16 sin x cos x  5  0
 4 sin x cos x  5  4 sin x cos x  1  0
4 sin x cos x  5  0
sin x  cos x  0 and 4 sin x cos x  1
1
 sin 2x 
2
 5 9 13 17 21
x  , , , , ,
12 12 12 12 12 12
There are 6 solutions in 0, 2
72. C
Sol. 2,H1,H2 ,.....H20 ,3 are in H.P.
1 1 1 1 1
, , ,........, , are in A.P.
2 H1 H2 H20 3
Suppose common difference is d
1 1 1 1
 
2 H1 3 H20
Now 
1 1 1 1
 
2 H1 3 H20
1 1 1 1 1 1 1 1
    
2 H1 3 H20 3 2 H20 H1 21d  19d
    = 40
d d d d
73. B
n n
Sol. Given expression is equidistant be  x  3    x  2 
 Coefficient of x r  nCr xr .3nr  nCr x r .2nr  nCr 3nr  2nr xr  
74. B
Sol. For z  2i  2 2, centre (0, 2)
Y
radius is 2 2 P (z)
 z  2
APB  arg  
z  2
1
 ACB C
2 C
1  
   B A
2 2 4 (2, 0)
X
(–2, 0)
75. C
Sol. Say argz  
z  x  iy and z  r
1
 z  2  i 
2
 z cos   z sin  
2 2 xy
 x  2    y  1 
2
Distance of (x, y) from (2, 1) = Distance of (x, y) from line x – y = 0
 locus of z is a parabola
76. D
Sol. Select any 4 points we will get a quadrilateral and for each quadrilateral we will get one
point of intersection of diagonals.
77. A
Sol. Number of solutions of the given equation is same as the number of solutions of the
equation x1x 2 x3 x 4  30  2  3  5 (there x 4 is dummy variable) hence number of
solutions is 43  64
78. B
Sol. Number of ways getting one correct
 1 1 1 1 1 1
 7C1. 6  1         7C1  265
 1 2 3 4 5 6
Number of ways of getting two correct
 1 1 1 1 1
 7C2 5  1        7C2  44
 1 2 3 4 5
Number of ways of getting three correct
 1 1 1 1
 7C3 4  1       7C3  9
 1 2 3 4
Required number of ways  7 C1  265  7 C2  44  7C3  9
79. C
 25 r   r
 25 r   2  3
Sol. Tr 1  25 Cr  ab  x 
.c r . x  
25  r r
n  25,   0  r  15
2 3
 T16  25 C15 a10b10c15
Given 10a  10b  15c  1
Apply A.M.  G.M.
10a  10b  15c 35 10 10 15
 a b c
35
35
 1 
    a10b10 c15
 35 
80. A
2
Sol.  2a  b   3c  2a  b   2c 2  0
 2a  b  c  2a  b  2c   0
2a  b  c  0   2,  1
 1
2a  b  2c  0   1,  
 2
81. B
 1  1   1 1  1 
Sol. S  1  1       1   2   2   .....
 2  3   2 2  3 
S 1  1 1 
   1    2   ....
3 3  2  3 
2S 1 1
 1  2 2  .....
3 2  3 2 .3
2S 1 6 9
  S
3 1 5 5
1
6
82. A
Sol. Inverse of p   q  r     q  p  is ~ p   q  r   ~  q  p 
 ~ p ~  q  r     ~ q ~ p 
 ~ p   q ~ r     ~ q ~ p 
83. B
Sol. Let AP be the lamp post of height h at a point A on a P
circular path of radius r and centre C. h
Let B be the point on this path such that
PBA    AB  h cot  A
o
Since AB subtends an angle 45 at another point of the 
path it subtends an angle of 90 o at the centre C so that
BCA  90o
Also CA  CB  r B
C
 AB  2r
Also h cot   2r
 h  2 r tan 
84. B
Sol. Let us denote by P (n) the statement:
11n2  122n1 is divisible by 133.
For n  1, we find P (1) is true i.e. 113  123
 
 11  12  112  11  12  122   23 133  is divisible by 133.
 P (n) is true for n = 1.
Assume that the result is true for n  k .
i.e. P  k  is true  11k 2  122k 1 is divisible by 133.

 11k  2  122k 3  133q , were q is a positive integer …..(1)
Consider 11k 3  122k 3  11.11k  2  144.122k 1
 11.11k  2  11  133  122k 1
 
 11 11k  2  122k 1  133.122k 1
 11 133q  133.122k 1 [using (1)]

 133 11q  12 2k 1

k 3 2k  3
 11  12 is divisible by 133.
P  k  1 is true.
 By the principle of mathematical induction, the result is true for all n  N .
85. A
Sol. Since , ,  are roots of x 3  2x 2  3x  4  0
      2,    3,   4
2
 22  2 2   2 2          2       
 3 2  2  4  2   9  16  7
86. D
Sol. Given, a,a1,a 2 ,.....a 2n ,b are in A.P.
 a  b  a1  a 2n  a 2  a 2n 1  .......  an  an 1
Also given a,g1,g2 ,.......g2n ,b are in G.P.
ab  g1g2n  g2 g2n 1  gn gn 1
2ab
Further h 
ab
 The given expression
n a  b  a  b  2n
  2n  
ab  2ab  h
87. A
Sol. Let P be (h, k). If m be the slope of a normal, then m3  m  2  h   k  0 .
k
Now m1m2m3  k  m3  

k3  k 
So,     2  h  k  0
3   
k2 1
This   3   2  h   1  0
 
     2  h  k2  0
3 2
 locus is 3  2 2   2 x  y 2  0
   2 as the locus is y 2  4x
88. B
Sol. Both are rectangular hyperbolas.
89. C
n
Sol. 
Given 5  2 6  I f …..(1)
0  f 1
n

Let 5  2 6  F
0 F1
I  f  F in an integer,  f  F is integer
0  f F  2  f F 1
 1 f  F
n
From (1), we get I  5  2 6   f
1 1
 f  f
F 1 f
90. B
Sol. Consider the series
x2 x3
 log 1  x   x    .....
2 3
i
Put x  e 3
 
i i i2 i3
  e 3 e 3
  log  1  e 3   e 3    .....
  2 3
 
i i2 i3
  sin   3
e 3 e 3
  log  1  cos  i   e    .....
 3 3  2 3
 
i i2 i3
    e 3 e 3
  log  2 sin2  2i sin cos   e 3    .....
 6 6 6 2 3
 
i i2 i3
     e 3 e 3
  log  2i sin  cos  i sin    e 3    .....
 6 6 6  2 3
 
  i i2 i3
i
2
i
6
e 3 e 3
3
  loge  loge e    .....
2 3
 
i i2 i3
   e 3 e 3
   i  i   e 3    .....
 2 6 2 3
 
i i2 i3
  e 3 e 3
   i   e 3    .....
 3 2 3
 
i i2 i3
 e 3 e 3
 i  e3    .....
3 2 3
Compose imaginary part both sides.
2 3
sin sin
  3  3  ....
 sin 
3 3 2 3

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ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

Sol. pH  pKa  log

Mathematics PART – III

i.e. P  k  is true  11k 2  122k 1 is divisible by 133.

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