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MEMBRANE BIOREACTOR
A Seminar Paper
By
May 2017
LETTER OF TRANSMITTAL
May 2017
Instructor
External Membrane Bioreactor” in partial fulfilment of the requirement for the Course Industrial
This study shows the membranebioreactorparameters and calculations needed for the design.
i
Table of Contents
Title Page
ii
B. Process Flow and Information ...........................................................................................13
1. Anoxic Tank..............................................................................................................15
1. Screening ....................................................................................................................17
2. Equalization Tank.......................................................................................................18
5. Sludge Wasting...........................................................................................................25
REFERENCES ....................................................................................................................................... 28
iii
CHAPTER1
INTRODUCTION
Nature has an amazing ability to cope with small amounts of water wastes and pollution,
but it would be overwhelmed if we treat the billions of gallons of wastewater and sewage
produced every day before releasing it back to the environment. (T.Subramani, Porkodi, &
Jayalakshmi, 2014)
the other uses of water. Much of the water used by homes, industries, and businesses must be
Wastewater is used water. It includes substances such as human waste, food scraps,
oils, soaps and chemicals. In homes, this includes water from sinks, showers, bathtubs, toilets,
washing machines and dishwashers. Businesses and industries also contribute their share of
Wastewater also includes storm runoff. Although some people assume that the rain that
runs down the street during a storm is fairly clean, it isn't. Harmful substances that wash off
roads, parking lots, and rooftops can harm our rivers and lakes.
Treating wastewater has the aim to produce an effluent that will do as little harm as
possible.
The objectives of the study is to design a wastewater treatment facility that discharges
an effluent complying with the standards stated in DENR Administrative Order (DAO) No. 35.
1
And to reuse the highly treated wastewater as water supply for the public market for human
recreation, i.e. washing meat, fish, fruits, and vegetables; flushing, and bathing.
B. Sources of wastewater
hospitals and other health centers, apartments and the like. They all produce high
volumes of wastewater.
b.) Non-Sewage
These include water from floods (stormwater), runoff (rain water running
through cracks in the ground and into gutters), water from swimming pools, water from
car garages and cleaning centers. They also include laundromats, beauty salons,
Wastewater is also generated from agricultural facilities. Water used for cleaning in
C. Public market
Public markets in the Philippines generate high in strength wastewater and in effect,
may pollute the nearby bodies of water destroying aquatic life and as well as the whole water
body. Wastewater from these establishments is generated from different sources and activities.
Sources of these are meat, fish, poultry, fruits and vegetables that are sold. Food stalls and
public restrooms are also present contributing to the wastewater. These sources are able to
2
generate wastewater containing high levels of organic material, suspended solids, fats, oils, and
grease that contains about two to three times the organic matter and solids typically found in
domestic wastewater.
The construction of a MBR treatment facility is very important and can be very useful
to the public market. The facility can contribute to the sustainable development and can treat
wastewater to the extent that it can be reused again as a water supply for commercial and
domestic purposes for the market area. The MBR facility can also reduce the level of organic
material, suspended solids and other particles that comprises the wastewater up to the point
that the effluent will be meeting the quality of effluent standards (Lazaro, Miura, & Perez,
2014).
primarily from household sewage. There are numerous processes that can be used to clean up
wastewaters depending on the type and extent of contamination. Wastewater can be treated
in wastewater treatment plants which include physical, chemical and biological treatment
processes to remove these contaminants and produce environmentally safe treated wastewater
One type of aerobic treatment system is the activated sludge process, based on the
to absorb the organic matter carried in the wastewater. Anaerobic wastewater treatment
processes (UASB, EGSB) are also widely applied in the treatment of industrial wastewaters
and biological sludge. Some wastewater may be highly treated and reused as reclaimed water.
Wastewater collection and treatment is typically subject to local, state and federal
3
Treating wastewater has the aim to produce an effluent that will do as little harm as
In the Philippines, Republic Act 9275, otherwise known as the Philippine Clean Water
Act of 2004, is the governing law on wastewater management. It states that it is the country's
policy to protect, preserve and revive the quality of our fresh, brackish and marine waters, for
The table below are the Significant Effluent Quality Parameters for Water Supply;
Sewerage, Waste Management and Remediation Activities based from (DAO, 2016).
Water collection, treatment and supply pH, Total Suspended Solids, Chloride,
(except those intended to prevent pollution) Fluoride,Iron
Treatment and disposal of hazardous waste Color, Temperature, pH, COD, Total
Suspended Solids, and other parameters
depending on the nature of their activities
Remediation activities and other waste Color, Temperature, pH, COD, Total
management services Suspended Solids, and other parameters
depending on the nature of remediation
activity
4
F. Tuguegarao Public Market
Don Domingo Tuguegarao Public Market, located along Balzain East, Tuguegarao
City. it is the second public market in the city after the old Pamilihang Bayan ngTuguegarao
which is now Mall of the Valley. However at present, it has no existing wastewater treatment
plant. Thus, the construction of a MBR treatment facility is very important and can be very
5
CHAPTER 2
limitations since its scale is predominantly large and more capital investment is needed. As
cited by Cele, 2014, it requires skill to operate which hinders its success in developing
more capital investment is required; rural areas also experience a disadvantage from this
Amongst the technologies that have been developed for wastewater treatment is
membrane bioreactors (MBRs). MBRs are increasingly being specified as a viable alternative
the use of activated sludge systems which, although effective, require a great deal of energy.
As a result, anaerobic technologies have been widely investigated for the treatment of
municipal wastewater.
A. Market Wastewater
As cited by Lazaro et al., 2014, wastewater from public markets is generated from
distinct sources and activities. These include: meat, poultry, fish preparation and sales, fruit
When combined into a common outfall, the resulting wastewater mixture typically
contains high levels of organic material, suspended solids, fats, oils and grease. It commonly
contains two to three times the organic matter and solids typically found in residential
6
To effectively manage high-strength wastewater, treatment infrastructure must be
designed and sized not only to address hydraulic loading in terms of volume (cubic meters per
day), but also organic loading, which is expressed in terms of kilograms of BOD (Biochemical
Oxygen Demand) per day, and solids loading, which is expressed in terms of Total Suspended
Solids (TSS).
Market wastewater containing high levels of organic material, suspended solids, fats, oils,
and grease can be treated using the activated sludge process. Like the conventional process,
Physical Treatment
Coarse screens, particularly, mechanical bar screens, are used for screening
large solids to lessen the labor costs and improve the flow conditions of the wastewater.
It will also serve as the preliminary treatment for the wastewater before entering the
Biological Treatment
Biological treatment process in an MBR begins after screening the wastewater. The
biological process takes place involving vigorous agitation, coming from air bubbles
generated from a blower system. This acts to scour and clean the surface of the membrane
to prevent buildup of a material and also to provide sufficient oxygen concentration for
C. Membrane Filtration
and wastewater treatment technologies such as physical filtration or biological and chemical
7
treatment. It is rapidly gaining acceptance throughout the world as the most effective and
pollutants across a membrane. Water permeates through the membrane into a separate channel
for recovery (Figure 2.C). Because of the cross-flow movement of wastewater and the waste
constituents, materials left behind di not accumulate at the membrane surface but are carried
out of the system for later recovery or disposal. The water passing through the membrane is
called permeate, while the water with the more-concentrated materials is called the concentrate.
pore size set during the manufacturing process. The requirement is that the membranes prevent
passage of particles the size of microorganisms, or about 1 micron (0.001 millimeters), so that
they remain in the system. This means that the MBR systems are good for removing solid
material, but the removal of dissolved wastewater components must be facilitated by using
D. Membrane Bioreactor
8
Membrane bioreactor (MBR) is the combination of a membrane process like
microfiltration or ultrafiltration with a suspended growth bioreactor, and is now widely used
for municipal and industrial wastewater treatment with plant sizes up to 80,000 population
treatment with membrane separation. This is more appropriately applied to processes in which
there is a coupling of these two elements, rather than the sequential application of membrane
wastewater (sewage) usually proceeds through a three stage process: sedimentation of gross
solids in the feed water followed by aerobic degradation of the organic matter and then a second
sedimentation process to remove the biomass. An MBR can displace the two physical
separation processes by filtering the biomass through a membrane. As a result the product water
quality is significantly higher than that generated by conventional treatment, obviating the need
Some advantages of MBRs over conventional processes include small footprint, easy
a.) Internal/submerged
9
The filtration element is installed in either the main bioreactor vessel or in a
separate tank. The membranes can be flat sheet or tubular or combination of both, and
can incorporate an online backwash system which reduces membrane surface fouling
by pumping membrane permeate back through the membrane. In systems where the
membranes are in a separate tank to the bioreactor, individual trains of membranes can
biomass must be continuously pumped back to the main reactor to limit MLSS
reduce fouling. Where the membranes are installed in the main reactor, membrane
modules are removed from the vessel and transferred to an offline cleaning tank.
b.) External/sidestream
The filtration elements are installed externally to the reactor, oftenin a plant
room. The biomass is either pumped directly through a number of membrane modules
in series and back to the bioreactor, or the biomass is pumped to a bank of modules,
from which a second pump circulates the biomass through the modules in series.
Cleaning and soaking of the membranes can be undertaken in place with use of an
Bioreactor 10
Effluent
influent
Treatedwater
Sidestream
Bioreactor membrane
Effluent
influent
Treated water
wastewater
Recirculation
Airsparging(Aeration)
CHAPTER 3
11
DESIGN
The design of wastewater treatment plants is usually based on the need to reduce
organic and suspended solids loads to limit pollution of the environment. Pathogen removal
has very rarely been considered an objective but, for reuse of effluents in agriculture, this must
now be of primary concern and processes should be selected and designed accordingly.
A. Wastewater Characteristics
very important in design, operation, and management of collection, treatment, and disposal of
characteristics which depend on the water usage in the community, the industrial and
Market wastewaters are known to be high in organic content. They are also high in
protein content from fish, poultry, and meat processing activities. These characteristics identify
market wastewater from domestic wastewater. Desirable treatment must be conducted in order
The ff. data on the characteristics of the market wastewater are obtained through tests
for the BOD5, COD, and TSS. The Average Design Flow is taken through estimation based on
existing data of different wastewater flow of several public markets in the Philippines. The
12
BOD5 1314 mg/L
Wastewater Temp. 20 0C
The MBR Facility is installed after the process of Activated Sludge Tank to perform
the separation volatile and semi-volatile organic compounds. The facility is a tool designed to
remove biological and chemical waste products from water, thereby permitting the treated
water to be used for other purposes. The proposed project will be placed at the Public Market.
Screening is applied to remove the large inorganic and organic particles to prevent
clogging of pipe lines and pumps. Since the wastewater contains high nitrogen content,Anoxic
Tank isapplied to denitrify wastewater where the electron donor is carbon from domestic
sewage and electron acceptor is nitrate. By denitrifying bacteria, nitrate will be converted to
nitrogen gas which able to escape from the tank. Sludge will conveys to Activated Sludge Tank
whichinvolves mixing air with the wastewater to provide the suitable condition for
microorganisms to digest organic matter and nutrients to sustain their life process. To sustain
the food to microorganism ratio, the treatment of domestic wastewater in the treatment facility
was also included. During this phase, flocculation will take place by the slime layer of the
bacteria, glycocalyx, and cause to bind them together with the wastewater. Biomass then
conveys to the external MBR to separate and remove pathogens particularly fecal coliform and
13
E. coli without applying disinfectant. Part of the biomass will return to the reactor. A high flow
recirculation pump used for External MBR facility to utilize the membrane.
Feed
MechanicalScreening
AnoxicTank
ActivatedSludgeTank
MBRFacility
Effluent
This section explains the required design parameter of the proposed project(Figure3.C).
Each treatment phase is briefly explained to complete the facility. This component covers the
idea of the designed MBR Facility from the start up to the ending conclusion.
14
Figure 3.C: Proposed MBR Facility
1. Anoxic Tank
An anoxic tank is a tank after primary screening where raw untreated wastewater
enter and is being mixed for the equalization of sludge under the absence of oxygen. The
size of the tank can be determined by the daily flow rate of sewage into the tank. The
volume wastewater sample collected would be constant and its time would be variable. A
sample will be collected on an hourly interval for 24 hours for the accuracy of the
dimensions of the tank. This method is also applicable for solving the volume of an
Equalization Tank.
In order to determine of size of the activated sludge tank, the flow rate of sewage in
the public market must be identified. The Hydraulic Loading Rate (HLT) will then be
solved. HLT is expressed as rate of flow in cubic meters per second over the surface area
of the wet tank. This value is used to prevent the overflow of incoming wastewater in the
aeration tank.
15
The Food to Microorganism Ratio (F/M) depends on the country’s climate.
According to the stated standards, Philippines which lies under warm climate regions, the
range generally lies between 5 days in warmer climates to 10 days in temperate ones. In
this climate, nitrification is desired along with good BOD removal, and complete mixing
systems are employed. Mixed Liquor Suspended Solids (MLSS) assumed to have a value
of 2500 mg/l due to high level of MLSS clogging of membrane filter preventing the passage
of permeate leading to failure and degradation of the effectiveness in the system treatment
process. Furthermore, the volume of MLSS concentration will determine the HRT, or the
number of hours that wastewater stay in the aeration tank to perform a complete aeration
process.
D. Operational Parameters
Parameters of the wastewater during and after treatment should always be considered
in the design and operation as a guide in the design calculation and specifications of the
According to DAO 35, effluent standards of Class B water must not be greater than 30 mg/L
and 50 mg/L of BOD and Total Suspended Solids (TSS), respectively. These standards make
The table below is the Operational Parameters to be followed for the Design based from
Operational Parameters
16
MLVSS 3000 mg/L
Yield Coefficient (Y ) 0.5
Decay Constant (kd) 0.06 / day
BOD u 0.67
BOD 5
MLVSS 0.8
MLSS
Table 3.D: Operational Parameters
Assume:
BOD and TSS removal in screening are 15% and 25%, respectively.
BOD and TSS removal in Equalization Tank are 30% and 55%, respectively.
Oxygen transfer efficiency for air diffuser is 8% and safety factor of 2 is used to
S.G. of raw market wastewater is less than 2.65 and 4.5% of solid content
E. Design Calculations
1. Screening
Screening is first operation that the wastewater will be undergoing for treatment.
It is a physical unit operation that removes large particles, such as paper, plastics, rags,
that contributes to the clogging of pipes. It also helps in preventing damage to the
The calculation of BOD and TSS entering the equalization tank is taken from
the removal rate of the screen basket. With the aid of screens, about 15% and 25% of
17
BOD Loading:
TSS Loading:
BOD removal:
TSS Removal:
2. Equalization Tank
After passing through the wire mesh basket, the wastewater enters an
equalization tank. The equalization tank, from the term itself, equalizes the volume of
wastewater entering the activated sludge tank and as well as the proceeding treatment
processes. It prevents the passage of wastewater in the activated sludge tank in order
not to disrupt the wastewater being aerated and also not to agitate the settling particles
18
An effective size of the tank must be strategically computed. Having a daily
flow of 52.3 m3 per day and very small area for the tank, the volume of wastewater per
treatment cycle must be able to contain. The average hourly flow rate is computed for
12 hours of market operation per day. The treatment facility can accommodate two (2)
cycles of treatment per date having a Hydraulic Retention Time (HRT) of 12 hours.
HRT is the number of hours the wastewater is being retained or held in the equalization
tank.
Given:
m3
52.3
day m3
4.36
12 hrs. hr.
V Qt
V 4.36 m 3 / hr. 12 hrs.
V 52.32 m 3
Let the depth be 3m with a free board of 0.6 m , and the length and width to
19
V L WD
Length 3Width
52.32 m 3 3W W 3m
52.32 m 3
3W 2
3m
W = 2.4 m
L= 7.2 m
D = 3.6 m
Calculate for the remaining BOD and TSS from screening entering the
equalization tank.
BOD Remaining:
TSS Remaining:
According to the Water and Wastewater Calculations Manual, 30% of BOD and
55% of the COD entering the equalization tank is retained. The other percentage of
these values passes through and enters the activated sludge tank. The sludge flow rate
(SFR) is also subtracted since it will also be retained in the equalization tank. The SFR
20
is the amount of sludge that has settled on the bottom of the equalization tank. The
sludge that settled below the tank is pumped out with the use of a sludge pump.
BOD Removal:
TSS Removal:
TSS Removed
SFR
S.G D water %solid content
15.10 kg/day
SFR
2.65 1000 kg/m 3 0.045
SFR 0.13 m 3 /day
The activated sludge tank is where the wastewater is converted into its reusable
form and decanted into a water tank for storage and reuse. The entire process of
Q in Q ave - SFR
Q in 52.3m 3 /day - 0.13m 3 /day
Q in 52.17 m 3 /day 50% will only proceed
Q in 26.09 m 3 /day
= (30 mg/L)(85%)
= 25.5 mg/L
22
BODu of Bio. Eff. Solids = (25.5mg/L)(1.45 mg O2/ mg cell)
= 36.98 mg/L
= 2 (24.8 mg/L)
= 49.6 mg/L
S = 5.22 mg/L
A minimum depth of 3 meters was set. But since the rate of flow is very
low, the value must be accepted. A free board of 0.6 m is also added and the
V L WD
Length 2Width
26.09 m 3 L W D
26.09 m 3 2W W 3
W = 2.1 m
L = 4.2 m
D = 3 m + 0.6 m
D = 3.6 m
23
L × W × d = 4.2 m × 2.1 m × 3.6m
V = 31.752 m
V
HRT
Q in
31.75m 3
HRT
52.3m 3 /day
HRT 0.6 day
HRT ≈𝟏𝟐𝐡𝐫𝐬
4.Oxygen Requirements
injected per day of aeration. Its theoretical requirements are taken from the BOD5 and
the concentration of microorganisms that should be present in the wastewater per day.
For the theoretical air requirements, the biomass yield observed and the sludge
Q S - S
BOD used in o
0.67
26.09m 3 /day 783.44mg/L - 5.22mg/L 1000 L 1kg
BOD used 3
6
0.67 1m 10 mg
BOD used 30.3kg/day
5. Sludge Wasting
of sludge that is removed per day in the tank. The tank must contain a sufficient amount
24
Sludge Wasting Flow Rate
c
V MLVSS
Q SW MLVSS Q O X E
5days
31.75m 3 3000mg/L
QSW 3000mg / L 26.09 m /day(50mg/ L 0.8
3
Q SW 6.0m 3 /day
The increase in mass of MLSS (Py) from the increase of MLVSS production
Px 7.81 kg/day
Py
0.80. 0.80.
Py 9.76 kg / day
PL= 𝟏.𝟎𝟎𝟒𝟓𝐤𝐠/𝐝𝐚𝐲
6. Membrane Design
Assuming the Design Flow is 20 L/hr-m2 and the Standard Filter Area is 25 m2.
L 1 m3 12 hr
Q P 20 25 m 2 5 cassetes
hr m 1000 L 1 cycle
2
= 30 m3/cycle
25
CONCLUSION
The study entitled “Wastewater Treatment in Public Market using External Membrane
complying with standards as stated in DAO 35. Different biological and physical treatments
applied to the wastewater resulted to an effluent passing the standards for bathing, cleaning and
etc.
sufficient for reuse. Since the expected effluent quality is water classification class C, the
treatment provided an effluent overly meeting the said requirement with the production of class
B water. As to this, the public market can therefore, use the treated water as a water supply for
human recreation.
The construction of the facility would be of great benefit for the market and in the
promotion of sustainable development, and a healthy and pollution free environment for
everybody.
26
REFERENCES
Journal
DAO, D. A. (2016, March 30). Water Quality Guidelines and General Effluent
Lazaro, L. S., Miura, A. R., & Perez, I. C. (2014). Design of a Membrane BioReactor
Rakesh Kumar, R. N. (2006). Municipal Water and Waste Water Treatment. The
27
TERM PAPER PRESENTATION
In
(Written Report)
TOPIC: _________________________________________________________________________________________________
PRESENTER: ___________________________________________
Organization Little or no structure or organization; no Material are generally organized well, but Organizes written materials in a logical
subheadings or proper paragraph structure paragraphs combine sequence to enhance
&
Used multiple thoughts or sections and the reader's comprehension
Style subsections are not identified clearly
(paragraphs, subheading, etc.)
(2)
No grasp of information. Clearly Uncomfortable with content. Only basic Demonstration of full knowledge of the
Content
concepts are demonstrated and interpreted. subject with explanations and elaboration.
no knowledge of subject matter. No
&
questions are answered. No interpretation
Knowledge made.
(3)
29i
Application of No application of engineering and/or Serious deficiencies in proper selection and Critical selection and application of
scientific principles use of engineering principles. engineering principles ensuring
Engineering
reasonable results.
Principles
(4)
Design is done Incompletely without the Design is done, but procedures and Supports design procedure with
Documentation proper equations and equations are not documented or
(2) referenced documentation and references
without references
Outside Seeks no extra information other than Seeks information from a few sources - Seeks information on problems from
what is provided by instructor mainly from the textbook or the instructor multiple resources
Resources
(2)
Use of Supporting Graphs, tables or diagrams are used, but Uses graphs, tables, and diagrams, but only Uses graphs, tables, and diagrams to
no reference is made to them in a few instances are they applied to support points-to explain, interpret, and
Graphs, Tables, support, explain or interpret information assess information
etc (3)
Spelling & Several spelling and grammatical errors. Minor misspellings and/or grammatical Negligible misspellings and/or grammatical
errors. errors.
Grammar
(1)
Figure No figures or graphics are used at all Figures are present but are flawed-axes Figures are all in proper format
mislabeled, no data
Formatting
points, etc
(1)
30
Inadequate list of references or references Minor inadequacies in references. Reference section complete and
References
in text. Inconsistent or Consistent referencing system. comprehensive. Consistent and logical
(2) referencing system.
illogical referencing system.
TOTAL
Rater: ____________________________________
31
TERM PAPER PRESENTATION
In
(Oral Presentation)
TOPIC: _________________________________________________________________________________________________
PRESENTER: ___________________________________________
Talk is poorly organized, e.g. no clear Presents key elements of an oral presentation Plans and delivers an oral presentation
Delivery
introduction or summary of talk is adequately, but "tell them" not clearly applied effectively; applies
(2)
Presented the principle of "(tell them)" –well organized
Length and Presentation is inappropriately short or Presentation contains excessive or insufficient Presentation has enough detail appropriate
excessively long; omits key results during detail for time allowed or and technical content for the time constraint
Detail presentation and the audience
level of audience
(3)
Major difficulties with the mechanical aspects Has some minor difficulties with the Presents well mechanically. Makes eye contact
Mechanics of the presentation. No eye contact. Difficult mechanical aspects of the presentation. Eye Can be easily heard. Speaks comfortably with
to hear or understand speaking. Reads from contact is sporadic. Occasionally difficult to minimal prompts (notecards). Does not block
(4)
prepared hear or understand speaking. Overuses screen. No distracting nervous habits
prompts or does not use prompts enough
32
Script. Blocks the screen. Distracting nervous occasionally stumbles or loses place; appears
habits (um, ah, clicking to
Dialect Uses poor English Occasionally uses an inappropriate style of Uses proper American English
English-too conversational
(2)
Visual Aides Multiple slides are unclear or Visual aides have minor errors or are not Uses visual aids effectively
incomprehensible always clearly visible
(2)
Appearance Inappropriate attire, slovenly or too revealing Appearance is too casual for the Professional appearance
(3) circumstances
Listening Does not listen carefully to questions, does Sometimes misunderstands Listens carefully and responds to questions
not provide an appropriate appropriately; is able
and questions, does not respond appropriately to
answer, or is unable to answer questions the audience, or has some trouble answering to explain and interpret results for various
Response to about presentation material audiences and purposes
questions
Questions
(4)
TOTAL
Rater: ____________________________________
33