EJEMPLO 15.

1 METODO BP PARA UNA COLUMNA DE DESTILACION

L1/U1 2
P 100 psia

PUNTO DE BURBUJA PARA LA ALIMENTACION

F3 100 kmol/h
T 118.799705 °F
P 100 psi

zi Pc A1 A2 A3 Ps
componente No pisa psia
Propano 13 0.3 617.4 5.353418 3371.084 414.488 234.536635
n-Butano 125 0.3 550.7 5.741624 4126.385 409.5179 69.5738829
n-Pentano 132 0.4 489.5 5.853654 4598.287 394.4148 21.9169973
1
K=y/x
y=KX
Composiciones en la alimentacion
C3 C4 C5
Propano n-butano n-pentano
Etapa zij zij zij
1 0 0 0
2 0 0 0
3 0.3 0.3 0.4
4 0 0 0
5 0 0 0

FLUJO DE CORRIENTES EN LA COLUMNA

Alimentaciones Vapor Laterales del vapor

No F No V No W
lbmol/h lbmol/h lbmol/h
1 0 1 0 1 0
2 0 2 150 2 0
3 100 3 150 3 0
4 0 4 150 4 0
5 0 5 150 5 0

Liquido Laterales del liquido

No L No U
lbmol/h lbmol/h
1 100 1 50
2 50 2 0
3 50 3 0
4 50 4 0
5 50 5 0
TEMPERATURA SUPUESTAS POR ETAPAS

No T
°F
1 80.9571327
2 116.678157
3 146.967742
4 173.066388
5 194.350235

COEFICIENTES DE DISTRIBUCION POR ETAPAS

Presion de vapor
C3 C4 C5 Coeficiente de distribucion
Propano n-butano n-pentano C3 C4
Etapa Ps Ps Ps Propano n-butano
Etapa psi psi psi Etapa Kij Kij
1 144.717431 38.0833194 10.7403577 1 1.44717431 0.38083319
2 228.689136 67.4171017 21.1168313 2 2.28689136 0.67417102
3 322.064027 103.310105 34.9332122 3 3.22064027 1.03310105
4 420.502718 144.01484 51.6278621 4 4.20502718 1.4401484
5 513.896901 184.852667 69.1988314 5 5.13896901 1.84852667

COEFICIENTE DE LA MATRIZ TRIDIAGONAL Y COMPOSICIONES PARA EL PROPANO

Coeficiente
No Aj No F-U
lbmol/hr lbmol/hr
1 1 -50
2 100 2 0
3 100 3 100
4 200 4 0
5 200 5 0

Coeficiente Propano n-Butano n-Pentano

No Bj Bj Bj
lbmol/hr lbmol/hr lbmol/hr
1 -150 -150 -150
2 -443.0337 -201.12565 -131.67525
3 -683.09604 -354.96516 -252.39982
4 -830.75408 -416.02226 -277.44179
5 -820.84535 -327.279 -153.79825

Coeficiente Propano n-Butano n-Pentano

No Cj Cj Cj
lbmol/hr lbmol/hr lbmol/hr
 1 343.033704 101.125653 31.6752469
2 483.096041 154.965157 52.3998183
3 630.754078 216.02226 77.4417931
4 770.845352 277.279 103.798247
5

Coeficiente Propano n-Butano n-Pentano

No Dj Dj Dj
lbmol/hr lbmol/hr lbmol/hr
1 0 0 0
2 0 0 0
3 -30 -30 -40
4 0 0 0
5 0 0 0

Coeficiente Propano n-Butano n-Pentano

No Pj Pj Pj
lbmol/hr lbmol/hr lbmol/hr
1 -2.2868914 -0.674171 -0.2111683
2 -2.2538292 -1.1589772 -0.4739559
3 -1.3780555 -0.9036039 -0.3777571
4 -1.3885528 -1.1783988 -0.5141317
5

Coeficiente Propano n-Butano n-Pentano

No Pj Pj Pj
lbmol/hr lbmol/hr lbmol/hr
1 0 0 0
2 0 0 0
3 0.06554324 0.1254876 0.19511793
4 0.0236131 0.10666112 0.19329096
5 0.00869512 0.23288649 0.75842158

Coeficiente Propano n-Butano n-Pentano

No xi,j xi,j xi,j SUM Fobj

1 0.59130488 0.36711351 0.04157842 0.99999681 1.0159E-11

2 0.25856273 0.54454063 0.19689705 1.00000042 1.7366E-13
3 0.11472153 0.46984587 0.41543323 1.00000063 4.0032E-13
4 0.03568673 0.38109429 0.58321955 1.00000057 3.1999E-13
5 0.00869512 0.23288649 0.75842158 1.00000319 1.0159E-11
2.1213E-11
Composiciones normalizadas en la fase liquida
Coeficiente Propano n-Butano n-Pentano
No xi,j xi,j xi,j SUM

1 0.59130677 0.36711468 0.04157855 1

2 0.25856263 0.5445404 0.19689697 1
3 0.11472146 0.46984557 0.41543297 1
4 0.03568671 0.38109407 0.58321922 1
5 0.00869509 0.23288575 0.75841916 1

Propano n-Butano n-Pentano

No yi,j yi,j yi,j SUM Fobj

1 0.85572397 0.13980946 0.00446569 0.99999911 7.95E-13 y=k*x

2 0.59130464 0.36711336 0.0415784 0.9999964 1.2989E-11
3 0.36947655 0.48539795 0.14512408 0.99999858 2.0089E-12
4 0.15006358 0.54883202 0.30110361 0.99999922 6.1547E-13
5 0.04468379 0.43049551 0.5248172 0.9999965 1.2219E-11
2.8628E-11 4.984E-11 MINIMIZAR
 K yi

2.34536635 0.70360991
0.69573883 0.20872165 Fobj
0.21916997 0.08766799
0.99999954 4.5696E-07
 C5
n-pentano
Kij
0.10740358
0.21116831
0.34933212
0.51627862
0.69198831

pag. 628
EJEMPLO 15.1 METODO BP PARA UNA COLUMNA DE DESTILACION
L1/U1 2
P 100 psia

PUNTO DE BURBUJA PARA LA ALIMENTACION

F3 100 kmol/h
T 118.7997048832 °F
P 100 psi

zi Pc A1
componente No pisa
Propano 13 0.3 617.4 5.353418
n-Butano 125 0.3 550.7 5.741624
n-Pentano 132 0.4 489.5 5.853654
1

Composiciones en la alimentacion
C3 C4 C5
Propano n-butano n-pentano
Etapa zij zij zij
1 0 0 0
2 0 0 0
3 0.3 0.3 0.4
4 0 0 0
5 0 0 0

FLUJO DE CORRIENTES EN LA COLUMNA

Alimentaciones Vapor
No F No V
lbmol/h lbmol/h
1 0 1 0
2 0 2 150
3 100 3 139.0718891616
4 0 4 135.7362298059
5 0 5 134.4290367013

Liquido
No L
lbmol/h
1 100
2 89.0718891679
3 185.7362298031
4 184.4290367157
5 50

TEMPERATURA SUPUESTAS POR ETAPAS

No T
 °F
1 81.0507327033
2 117.2535637131
3 147.0026554155
4 172.7808648754
5 193.954958775

COEFICIENTES DE DISTRIBUCION POR ETAPAS

Presion de vapor
C3 C4 C5
Propano n-butano n-pentano
Etapa Ps Ps Ps
Etapa psi psi psi
1 144.9035425955 38.1444998325 10.7608292609
2 230.2651186351 67.9970731196 21.3315700718
3 322.1842891773 103.3581745304 34.9523507882
4 419.3313613455 143.5155418544 51.4177011685
5 512.0517023316 184.0271533112 68.836701936

COEFICIENTE DE LA MATRIZ TRIDIAGONAL Y COMPOSICIONES PARA EL PROPANO

Coeficiente
No Aj No F-U
lbmol/hr lbmol/hr
1 1 -50
2 100 2 0
3 89.0718891616 3 100
4 185.7362298059 4 0
5 184.4290367013 5 0

Coeficiente Propano n-Butano n-Pentano

No Bj Bj Bj
lbmol/hr lbmol/hr lbmol/hr
1 -150 -150 -150
2 -434.4695671142 -191.067498841 -121.0692442694
3 -633.8040073468 -329.478395728 -234.3451243534
4 -753.6136169854 -379.2316224 -254.2214857202
5 -738.3461708568 -297.385929465 -142.5365153094

Coeficiente Propano n-Butano n-Pentano

No Cj Cj Cj
lbmol/hr lbmol/hr lbmol/hr
1 345.3976779526 101.9956096794 31.9973551077
2 448.0677775409 143.7421659224 48.6088945475
3 569.1845802841 194.8025856986 69.7924490189
4 688.3461708568 247.385929465 92.5365153094
5
Coeficiente Propano n-Butano n-Pentano
No Dj Dj Dj
lbmol/hr lbmol/hr lbmol/hr
1 0 0 0
2 0 0 0
3 -30 -30 -40
4 0 0 0
5 0 0 0

Coeficiente Propano n-Butano n-Pentano

No Pj Pj Pj
lbmol/hr lbmol/hr lbmol/hr
1 -2.3026511864 -0.6799707312 -0.2133157007
2 -2.1942116388 -1.1679667563 -0.487367436
3 -1.2984367224 -0.8640788151 -0.3655310625
4 -1.343253718 -1.1309542519 -0.4966293684
5

Coeficiente Propano n-Butano n-Pentano

No Pj Pj Pj
lbmol/hr lbmol/hr lbmol/hr
1 0 0 0
2 0 0 0
3 0.0684366777 0.1330699198 0.2094960516
4 0.0248048551 0.1129917055 0.2088294405
5 0.0093245643 0.2346593297 0.7560161205

Coeficiente Propano n-Butano n-Pentano

No xi,j xi,j xi,j SUM

1 0.5906754357 0.3653406703 0.0439838795 0.9999999855

2 0.2565197192 0.5372888178 0.2061914776 1.0000000146
3 0.1169074645 0.4600206426 0.4230719215 1.0000000286
4 0.0373301108 0.3783806721 0.5842892489 1.0000000319
5 0.0093245643 0.2346593297 0.7560161205 1.0000000145

Composiciones normalizadas en la fase liquida

Coeficiente Propano n-Butano n-Pentano
No xi,j xi,j xi,j SUM

1 0.5906754442 0.3653406756 0.0439838802 1

2 0.2565197154 0.53728881 0.2061914746 1
3 0.1169074611 0.4600206295 0.4230719094 1
4 0.0373301096 0.3783806601 0.5842892303 1
5 0.0093245642 0.2346593263 0.7560161095 1

Propano n-Butano n-Pentano

No yi,j yi,j yi,j SUM

1 0.8559096439 0.1393573734 0.0047330302 1.0000000476

 2 0.590675427 0.365340665 0.0439838789 0.9999999709
3 0.3766574726 0.4754689251 0.1478735779 0.9999999755
4 0.156536857 0.5430350546 0.3004280904 1.0000000019
5 0.0477465898 0.4318368782 0.5204165559 1.0000000238

ENTALPIAS DEL VAPOR Y LIQUIDO DE LAS ETAPAS, FLUJO DE VAPOR

Calculo de las entalpias del liquido y del vapor

a1 a2 a3
componente No 1 2 3
Propano 13 15.58683 2.504953E-02 1.404258E-05
n-Butano 125 20.79783 3.143287E-02 1.928511E-05
n-Pentano 132 25.64627 3.891760E-02 2.397294E-05

Propano n-Butano n-Pentano

No Hv0 Hv1 Hv2
btu/lbmol btu/lbmol btu/lbmol
1 1347.71378615 1791.85177 2210.10252
2 2005.68627432 2662.88999 3284.76483
3 2572.71573319 3412.02887 4209.13410
4 3083.29816758 4085.58763 5040.29313
5 3515.98362405 4655.74058 5743.86671

Entalpia molar de la fase vapor

Propano n-Butano n-Pentano Total
No Hv Hv Hv Hv
btu/lbmol btu/lbmol btu/lbmol btu/lbmol
1 1153.521227 249.707756 10.460482 1413.689465
2 1184.709597 972.861999 144.476698 2302.048294
3 969.032606 1622.313699 622.419719 3213.766024
4 482.649804 2218.617301 1514.245639 4215.512745
5 167.876228 2010.520476 2989.203329 5167.600033

Entalpia molar de vaporizacion

No 1.987 Btu/lbmol*R

Propano n-Butano n-Pentano

No � � �
btu/lbmol btu/lbmol btu/lbmol
1 7975.506506 9961.256098 11816.854978
2 7885.019646 9834.667640 11615.913390
3 7819.720248 9743.478568 11471.977200
4 7768.677088 9672.293288 11360.088563
5 7730.097241 9618.545045 11275.881700

Entalpia molar de la fase liquida

Propano n-Butano n-Pentano Total
No HL HL HL HL
 btu/lbmol btu/lbmol btu/lbmol btu/lbmol
1 -3914.874409 -2984.615697 -422.542249 -7322.032355
2 -1508.164923 -3853.315880 -1717.811807 -7079.292611
3 -613.413976 -2912.597476 -3072.704898 -6598.716350
4 -174.905709 -2113.901375 -3692.588410 -5981.395494
5 -39.294773 -1164.568353 -4182.292452 -5386.155578

TEMPERATURAS DE LAS CORRIENTES DE ALIMENTACION

No T
°F
1 0
2 0
3 118.799705
4 0
5 0

ENTALPIAS DE LA ALIMENTACION

Propano n-Butano n-Pentano

No Hv Hv Hv
btu/lbmol btu/lbmol btu/lbmol
1 0.000000 0.000000 0.000000
2 0.000000 0.000000 0.000000
3 2034.569710 2701.081142 3331.887304
4 0.000000 0.000000 0.000000
5 0.000000 0.000000 0.000000

Entalpia molar de vaporizacion

No 1.987 Btu/lbmol*R

Propano n-Butano n-Pentano

No � � �
btu/lbmol btu/lbmol btu/lbmol
1 8238.266554 10330.329063 12410.230752
2 8238.266554 10330.329063 12410.230752
3 7881.439356 9829.664308 11607.998290
4 8238.266554 10330.329063 12410.230752
5 8238.266554 10330.329063 12410.230752

Entalpia molar de la fase liquida

Propano n-Butano n-Pentano Total
No HF HF HF HF
btu/lbmol btu/lbmol btu/lbmol btu/lbmol
1 0.000000 0.000000 0.000000 0.000000
2 0.000000 0.000000 0.000000 0.000000
3 -1754.060894 -2138.574950 -3310.444394 -7203.080238
 4 0.000000 0.000000 0.000000 0.000000
5 0.000000 0.000000 0.000000 0.000000

Cantidad de calor en las etapas

No Q Parte 1
Btu/h F*HF-U*HL-W*HV
0 1443612.097352 366101.617767
2 0 0.000000
3 0 -720308.023766
4 0 0.000000
5 -1528510.724427 0.000000
-354206.405999

No �j �j �j

1
2 -9624.080649 10293.058635 -12136.987226
3 -10293.058635 10814.229095 36407.575738
4 -10814.229095 11148.995526 30866.042799
5

FLUJO DE LAS CORRIENTES EN FASE VAPOR

No Vn v fobj
lbmol/h lbmol/h
1 0 0 0
2 150 150 0
3 139.071889 139 0.000000
4 135.736230 136 0.000000
5 134.429037 134 0.000000
0.000000

FLUJO DE LAS CORRIENTES EN FASE LIQUIDA

No Vn v fobj
lbmol/h lbmol/h
1 100 100 0
2 89 89 0
3 186 186 0
4 184 184 0
5 50 50 0
0

Funcion objetivo global

fobj 1.01E-14
 A2 A3 Ps K yi
psia
3371.084 414.488 234.536635 2.34536635 0.70360991
4126.385 409.5179 69.5738829 0.69573883 0.20872165 Fobj
4598.287 394.4148 21.9169973 0.21916997 0.08766799
0.99999954 4.5696E-07
K=y/x
y=KX

Laterales del vapor

No W
lbmol/h
1 0
2 0
3 0
4 0
5 0

Laterales del liquido

No U
lbmol/h
1 50
2 0
3 0
4 0
5 0
Coeficiente de distribucion
C3 C4 C5
Propano n-butano n-pentano
Etapa Kij Kij Kij
1 1.449035426 0.381445 0.10760829
2 2.3026511864 0.67997073 0.2133157
3 3.2218428918 1.03358175 0.34952351
4 4.1933136135 1.43515542 0.51417701
5 5.1205170233 1.84027153 0.68836702

pag. 628
 Fobj

2.10549114E-16
2.13177691E-16
8.18487081E-16
1.01585542E-15
2.10549143E-16
2.46861843E-15

Fobj

2.26224102E-15 y=k*x
8.47445431E-16
5.99013214E-16
3.72574404E-18
5.67388707E-16
4.27981413E-15 6.7484326E-15 MINIMIZAR

a4 a5
4 5
-3.526261E-08 1.864467E-11
-4.588652E-08 2.380972E-11
-5.842615E-08 3.079918E-11
"Escriba aquí la ecuación."
 Parte 1
Fm-Wm-Um
-50.000000
0.000000
100.000000
0.000000
0.000000