p= 0.

6789
ITEM DATOS
# T(K) ΔG(J) K x Fx Fx^2
1 700 -32765.1 278.644 0.9670 -0.0008366 6.9991889E-07
2 750 -28231.75 92.535 0.9324 -0.0001229 1.5116081E-08
3 800 -23698.4 35.270 0.8631 0.57573207 0.3314674214
4 850 -19165.05 15.059 0.7986 -0.1453338 0.0211219014
5 900 -14631.7 7.067 0.6815 0.01930544 0.0003727
6 950 -10098.35 3.591 0.5570 0.00368947 1.3612193E-05
7 1000 -5565 1.953 0.4312 -0.0012866 1.655314E-06
8 1050 -1031.65 1.125 0.3184 0.00030399 9.2406975E-08
9 1100 3501.7 0.682 0.2286 0.00015453 2.3880537E-08

SO2 (g) + 0,5 O2(g) = SO3(g) ; 𝛥�=-96232+90,667T , J [718-2273K]

1-X 0.5(1-X) X

T(K) P(0.6789atm) P(1atm) P(2atm) P(5atm) P(7atm)

700 0.9670 0.99993631 0.99996816 0.99998726 0.9999909014
750 0.9324 0.9994226 0.99971127 0.9998845 0.9999175002
800 0.8631 0.90177826 0.9980137 0.99920516 0.9994322119
850 0.7986 0.80865218 0.85496598 0.89710944 0.9313519381
900 0.6815 0.71488025 0.76697373 0.81130945 0.8370999458
950 0.5570 0.59569399 0.65990495 0.73621594 0.7580142775
1000 0.4312 0.4716712 0.54341383 0.63236852 0.6637589479
1050 0.3184 0.3569679 0.42889341 0.52471615 0.5581428573
1100 0.2286 0.26147521 0.32607563 0.41975417 0.4548453141
 NUMERO DE MOLES PORCENTAJE MOLAR
moles totales #moles del S03 #moles del S02 #moles del 02 %SO3
1.0165 0.9670 0.0330 0.016516856 95.13%
1.0338 0.9324 0.0676 0.0338096915 90.19%
1.0685 0.8631 0.1369 0.0684578423 80.78%
1.1007 0.7986 0.2014 0.1007234836 72.55%
1.1593 0.6815 0.3185 0.1592749815 58.78%
1.2215 0.5570 0.4430 0.2215224942 45.60%
1.2844 0.4312 0.5688 0.2843806159 33.58%
1.3408 0.3184 0.6816 0.3407758285 23.75%
1.3857 0.2286 0.7714 0.3857230552 16.49%

2+90,667T , J [718-2273K] K=𝑋/((1−𝑋)√((1−𝑋))) 〖𝑋 ^3 (1−� 〗 ^2 P)+3𝑋^2 (�

(((3−𝑋)/2)/𝑃)^(1/2)

P(10atm)
0.999993631
0.9999422496 RESOLUCION MEDIANTE UNA HERRAMIENTA
0.9996025256 �^2+6�−7=0
0.9978208581 Ejm:
0.8566494037
0.7848897041
0.6910282801
0.594798872
0.4927241932

DIAGRAMA DE PRESION VS TEMP

P(0.6789atm) P(1atm) P(2atm

1.2000

1.0000

0.8000

0.6000

0.4000
0.6000

0.4000

0.2000

0.0000
700 750 800 850
 PORCENTAJE MOLAR PRESIONES PARCIALES
%SO2 %O2 PSO3 PSO2 PO2
3.25% 1.62% 0.6458 0.0221 0.0110
6.54% 3.27% 0.6123 0.0444 0.0222
12.81% 6.41% 0.5484 0.0870 0.0435
18.30% 9.15% 0.4925 0.1242 0.0621
27.48% 13.74% 0.3991 0.1866 0.0933
36.27% 18.13% 0.3095 0.2462 0.1231
44.28% 22.14% 0.2279 0.3006 0.1503
50.83% 25.42% 0.1612 0.3451 0.1726
55.67% 27.84% 0.1120 0.3780 0.1890

〖𝑋 ^3 (1−� 〗 ^2 P)+3𝑋^2 (�^2 𝑃−1)−3�^2 𝑃𝑋+�^2 𝑃=0

LUCION MEDIANTE UNA HERRAMIENTA LLAMADA SOLVER

�^2+6�−7=0

X 0.99982
f(x) -0.001
f(x)^2 2.174474837E-06

AGRAMA DE PRESION VS TEMPERATURA

P(0.6789atm) P(1atm) P(2atm) P(5atm) P(7atm) P(10atm)
850 900 950 1000 1050
PRESION TOTAL

0.6789
ALUMNO:CUADROS VERA VICTOR
0.6789
0.6789
0.6789
0.6789
0.6789
0.6789
0.6789
0.6789
1000 1050 1100
RA VICTOR
 p= 1
DATOS
# T(K) ΔG(J) K x Fx Fx^2 moles totales
1 700 -32765.1 278.644 0.9999 -1.9998089 3.99923569 1.0000
2 750 -28231.75 92.535 0.9994 -1.9982661 3.99306758 1.0003
3 800 -23698.4 35.270 0.9018 -0.5275182 0.27827543 1.0491
4 850 -19165.05 15.059 0.8087 0.1557152 0.02424722 1.0957
5 900 -14631.7 7.067 0.7149 -0.0102522 0.00010511 1.1426
6 950 -10098.35 3.591 0.5957 -0.0007344 5.3928E-07 1.2022
7 1000 -5565 1.953 0.4717 -9.179E-06 8.4253E-11 1.2642
8 1050 -1031.65 1.125 0.3570 -1.2092E-05 1.4621E-10 1.3215
9 1100 3501.7 0.682 0.2615 6.1191E-05 3.7443E-09 1.3693
 NUMERO DE MOLES PORCENTAJE MOLAR PRESIONES PARCIALES
#moles del S03 #moles del S02#moles del 02 %SO3 %SO2 %O2 PSO3 PSO2
0.9999 0.0001 3.1844449E-05 99.99% 0.01% 0.00% 0.9999 0.0001
0.9994 0.0006 0.0002887015 99.91% 0.06% 0.03% 0.9991 0.0006
0.9018 0.0982 0.0491108711 85.96% 9.36% 4.68% 0.8596 0.0936
0.8087 0.1913 0.0956739076 73.80% 17.46% 8.73% 0.7380 0.1746
0.7149 0.2851 0.1425598759 62.57% 24.95% 12.48% 0.6257 0.2495
0.5957 0.4043 0.2021530041 49.55% 33.63% 16.82% 0.4955 0.3363
0.4717 0.5283 0.2641644018 37.31% 41.79% 20.90% 0.3731 0.4179
0.3570 0.6430 0.3215160491 27.01% 48.66% 24.33% 0.2701 0.4866
0.2615 0.7385 0.3692623934 19.10% 53.94% 26.97% 0.1910 0.5394
ONES PARCIALES PRESION TOTAL
PO2
0.0000 1.0000
0.0003 1.0000
0.0468 1.0000
0.0873 1.0000
0.1248 1.0000
0.1682 1.0000
0.2090 1.0000
0.2433 1.0000
0.2697 1.0000
 p= 2
DATOS
# T(K) ΔG(J) K x Fx Fx^2 moles totales
1 700 -32765.1 278.644 0.99997 -1.9999045 3.9996178517 1.0000
2 750 -28231.75 92.535 0.9997 -1.9991334 3.9965343484 1.0001
3 800 -23698.4 35.270 0.9980 -1.9940216 3.9761221539 1.0010
4 850 -19165.05 15.059 0.8550 -0.1843666 0.0339910594 1.0725
5 900 -14631.7 7.067 0.7670 -0.049686 0.0024686996 1.1165
6 950 -10098.35 3.591 0.6599 -0.0042937 0.000018436 1.1700
7 1000 -5565 1.953 0.5434 0.00066374 4.40550252E-07 1.2283
8 1050 -1031.65 1.125 0.4289 -0.001077 0.00000116 1.2856
9 1100 3501.7 0.682 0.3261 0.00032887 1.08156283E-07 1.3370
 NUMERO DE MOLES PORCENTAJE MOLAR PRESIONES PARCIALES
#moles del S03
#moles del S02
#moles del 02 %SO3 %SO2 %O2 PSO3 PSO2
1.0000 0.0000 1.5922E-05 100.00% 0.00% 0.00% 1.9999 0.0001
0.9997 0.0003 0.00014436 99.96% 0.03% 0.01% 1.9991 0.0006
0.9980 0.0020 0.00099315 99.70% 0.20% 0.10% 1.9940 0.0040
0.8550 0.1450 0.07251701 79.72% 13.52% 6.76% 1.5943 0.2705
0.7670 0.2330 0.11651314 68.69% 20.87% 10.44% 1.3739 0.4174
0.6599 0.3401 0.17004752 56.40% 29.07% 14.53% 1.1280 0.5813
0.5434 0.4566 0.22829308 44.24% 37.17% 18.59% 0.8848 0.7434
0.4289 0.5711 0.28555329 33.36% 44.42% 22.21% 0.6673 0.8885
0.3261 0.6739 0.33696218 24.39% 50.41% 25.20% 0.4878 1.0081
ONES PARCIALES PRESION TOTAL
PO2
0.0000 2.0000
0.0003 2.0000
0.0020 2.0000
0.1352 2.0000
0.2087 2.0000
0.2907 2.0000
0.3717 2.0000
0.4442 2.0000
0.5041 2.0000
 p= 5
DATOS
# T(K) ΔG(J) K x Fx Fx^2 moles totales
1 700 -32765.1 278.644 0.999987 -1.9999618 3.999847143 1.0000
2 750 -28231.75 92.535 0.999885 -1.9996534 3.9986138742 1.0001
3 800 -23698.4 35.270 0.999205 -1.9976123 3.9904551004 1.0004
4 850 -19165.05 15.059 0.897109 -0.4574319 0.2092439506 1.0514
5 900 -14631.7 7.067 0.811309 0.2369388 0.0561399965 1.0943
6 950 -10098.35 3.591 0.736216 -0.0432872 0.0018737783 1.1319
7 1000 -5565 1.953 0.632369 0.00075413 5.6871188E-07 1.1838
8 1050 -1031.65 1.125 0.524716 -0.0015635 2.4444959E-06 1.2376
9 1100 3501.7 0.682 0.419754 -0.0004401 1.9368429E-07 1.2901
 NUMERO DE MOLES PORCENTAJE MOLAR PRESIONES PARCIALES
#moles del S03
#moles del S02 #moles del 02 %SO3 %SO2 %O2 PSO3 PSO2
1.0000 0.0000 0.000006369 100.00% 0.00% 0.00% 4.9999 0.0001
0.9999 0.0001 5.7749254E-05 99.98% 0.01% 0.01% 4.9991 0.0006
0.9992 0.0008 0.0003974212 99.88% 0.08% 0.04% 4.9940 0.0040
0.8971 0.1029 0.0514452809 85.32% 9.79% 4.89% 4.2661 0.4893
0.8113 0.1887 0.0943452731 74.14% 17.24% 8.62% 3.7068 0.8621
0.7362 0.2638 0.1318920288 65.04% 23.30% 11.65% 3.2521 1.1652
0.6324 0.3676 0.1838157377 53.42% 31.05% 15.53% 2.6709 1.5527
0.5247 0.4753 0.2376419243 42.40% 38.40% 19.20% 2.1198 1.9201
0.4198 0.5802 0.2901229152 32.54% 44.98% 22.49% 1.6268 2.2488
ONES PARCIALES PRESION TOTAL
PO2
0.0000 5.0000
0.0003 5.0000
0.0020 5.0000
0.2446 5.0000
0.4311 5.0000
0.5826 5.0000
0.7764 5.0000
0.9601 5.0000
1.1244 5.0000
 p= 7
DATOS
# T(K) ΔG(J) K x Fx Fx^2 moles totales
1 700 -32765.1 278.644 0.99999 -1.9999727 3.99989082 1.0000
2 750 -28231.75 92.535 0.99992 -1.9997525 3.99900993 1.0000
3 800 -23698.4 35.270 0.99943 -1.998295 3.99318308 1.0003
4 850 -19165.05 15.059 0.93135 -1.2808702 1.64062844 1.0343
5 900 -14631.7 7.067 0.83710 -0.0044088 1.9438E-05 1.0815
6 950 -10098.35 3.591 0.75801 -0.0088348 7.8053E-05 1.1210
7 1000 -5565 1.953 0.66376 -0.0143465 0.00020582 1.1681
8 1050 -1031.65 1.125 0.55814 0.00418001 1.7472E-05 1.2209
9 1100 3501.7 0.682 0.45485 0.00077661 6.0313E-07 1.2726
 NUMERO DE MOLES PORCENTAJE MOLAR PRESIONES PARCIALES
#moles del S03
#moles del S02
#moles del 02 %SO3 %SO2 %O2 PSO3 PSO2
1.0000 0.0000 4.5493E-06 100.00% 0.00% 0.00% 6.9999 0.0001
0.9999 0.0001 4.125E-05 99.99% 0.01% 0.00% 6.9991 0.0006
0.9994 0.0006 0.00028389 99.91% 0.06% 0.03% 6.9940 0.0040
0.9314 0.0686 0.03432403 90.04% 6.64% 3.32% 6.3031 0.4646
0.8371 0.1629 0.08145003 77.41% 15.06% 7.53% 5.4184 1.0544
0.7580 0.2420 0.12099286 67.62% 21.59% 10.79% 4.7334 1.5111
0.6638 0.3362 0.16812053 56.82% 28.78% 14.39% 3.9776 2.0149
0.5581 0.4419 0.22092857 45.71% 36.19% 18.10% 3.2000 2.5333
0.4548 0.5452 0.27257734 35.74% 42.84% 21.42% 2.5019 2.9987
ONES PARCIALES PRESION TOTAL
PO2
0.0000 7.0000
0.0003 7.0000
0.0020 7.0000
0.2323 7.0000
0.5272 7.0000
0.7555 7.0000
1.0075 7.0000
1.2667 7.0000
1.4994 7.0000
 p= 10
DATOS
# T(K) ΔG(J) K x Fx Fx^2 moles totales
1 700 -32765.1 278.644 0.99999 -1.9999809 3.99992357 1.0000
2 750 -28231.75 92.535 0.99994 -1.9998267 3.99930696 1.0000
3 800 -23698.4 35.270 0.99960 -1.9988068 3.99522861 1.0002
4 850 -19165.05 15.059 0.99782 -1.9934391 3.97379952 1.0011
5 900 -14631.7 7.067 0.85665 -0.1017245 0.01034788 1.0717
6 950 -10098.35 3.591 0.78489 -0.08077 0.0065238 1.1076
7 1000 -5565 1.953 0.69103 0.02240922 0.00050217 1.1545
8 1050 -1031.65 1.125 0.59480 -0.0082526 6.8105E-05 1.2026
9 1100 3501.7 0.682 0.49272 -0.0017537 3.0755E-06 1.2536
 NUMERO DE MOLES PORCENTAJE MOLAR PRESIONES PARCIALES
#moles del S03
#moles del S02
#moles del 02 %SO3 %SO2 %O2 PSO3 PSO2
1.0000 0.0000 3.1845E-06 100.00% 0.00% 0.00% 9.9999 0.0001
0.9999 0.0001 2.8875E-05 99.99% 0.01% 0.00% 9.9991 0.0006
0.9996 0.0004 0.00019874 99.94% 0.04% 0.02% 9.9940 0.0040
0.9978 0.0022 0.00108957 99.67% 0.22% 0.11% 9.9673 0.0218
0.8566 0.1434 0.0716753 79.94% 13.38% 6.69% 7.9936 1.3376
0.7849 0.2151 0.10755515 70.87% 19.42% 9.71% 7.0867 1.9422
0.6910 0.3090 0.15448586 59.86% 26.76% 13.38% 5.9856 2.6763
0.5948 0.4052 0.20260056 49.46% 33.69% 16.85% 4.9459 3.3694
0.4927 0.5073 0.2536379 39.30% 40.46% 20.23% 3.9304 4.0464
ONES PARCIALES PRESION TOTAL
PO2
0.000032 10.000000
0.000289 10.000000
0.001987 10.000000
0.010884 10.000000
0.668815 10.000000
0.971104 10.000000
1.338136 10.000000
1.684687 10.000000
2.023215 10.000000