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By
Enrique Salazar
Samuel Stratton
Abed Aicha
Mohanad Alhamdan
Connor McBride
Roberto Obregon
College of Engineering
Lamar University
May 2017
Abstract
The primary objective of this project was to design a crude distillation unit that can
process 325,000 barrels of oil per day and to produce 50,000 bbl/day of Light Atmospheric
Naphtha. The current process is also capable of producing 1.3 million gallons/day of jet
fuel from kerosene, over 6.0 million gallons/day of gasoline, 3.4 million gallons/day of
diesel for the production of ultra-low sulfur diesel, about 8,000 tons/day of petroleum coke,
about 1,000 tons/day of sulfur, and 17.5 barrels per day of liquefied petroleum gases. A
crude blend of Ebok Heavy and Terengannu Light will be used with a 74/26 mixture. Based
on West Texas Intermediate Benchmark, the Ebok and Terengannu current prices are
around $38.14/bbl and $70.11/bbl, respectively. Revenues from sales for the current
process were estimated to be $23.78 million. The yearly raw material requirements will
have an expense of $15.05 million (63.3% of revenues). Total yearly expenses were
calculated to be $1.1 billion. Due to the scale of the design, this process involves the heavy
use of utilities which account for 27% of the total yearly expenses. Despite this, the process
presents a payback period of approximately 2 years of operation and the 12 th year a total
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TABLE OF CONTENTS
Introduction……………………………………………………………………………5-6
Crude Blending………………………………………………………………………..6-7
Desalter Design……………………………………………….8-9
Vacuum Distillation……………………………………….…12-14
Pinch Analysis……………………………………………..….20-22
MUMNE…………………………………………………........22-23
Operating Cost……………………………….……………….24-25
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Profitability Analysis……………………………………....…25-28
Permitting …………………………………………………….28-29
Reformer Area………………………………………………...29-31
Safety Concerns…………………………………………………………………….33-37
Works Cited……………………………………………………………………………...40
4
Introduction
to each other and to hydrogen atoms. The properties of the resulting molecules are
defined mainly by the arrangement of atoms, known as the form, and the number of
carbon atoms, referred to as the size or weight. The complexity of a hydrocarbons form
increases greatly as the size increases. Different end products such as gasoline, diesel,
and jet fuel, are composed of different weight portions, or fractions, of a hydrocarbon
mixture. Gasoline is composed of a mixture of hydrocarbons that are mostly between four
and twelve carbons in length. To separate the gasoline fraction from the others,
distillation units take advantage of boiling point differences between fractions. Our
process will maximize the production of gasoline to 6.0 million gallons per day of
gasoline by producing roughly 50,000 barrels per day of light naphtha, one of the main
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components of gasoline blending. To accomplish this task the front end of a whole
refinery has been designed, that is the Crude Unit and the Reformer area. The crude unit
will consist of a desalter, an atmospheric tower, and a vacuum section. The reformer area
design will include three reactions to transform light and heavy naphtha to higher-octane
rating molecules. A heat integration study has also been conducted to minimize the cost
of utilities and a heat exchanger network was designed to approximate the minimum
analysis was also conducted to understand the requirements and code regulations that are
in place for petroleum processing units. A complete safety analysis was conducted, with
Crude Blending
benefit. For this current design, multiple types of crudes were considered by their content
of estimated naphtha based on their D86 lab testing. It was found that Ebok Heavy and
Terengganu Light would provide the optimal naphtha cut for our target of 50,000 barrels
per day of light atmospheric naphtha. The crude Assays for both crudes were obtained
(Appendix A) and after conducting different blending calculations the optimum ratio of
6
Table 1.0 - Crude Blending characteristics
A crude blending composition of 70/30, and 63/35 was also considered, but such blends
did not yield in the optimum production our target. As shown in Figure 1.1 a ratio of
7
Figure 1.1 Crude Blending Composition
Raw crude comes in through the front end of a refinery and before entering the
atmospheric distillation tower, the crude must be cleaned. Due to the transportation, the
crudes contain a lot of salt from miles of pumping and tank settling. The crude must go
through a desalting system is to reduce the salt content of the treated oil to acceptable
8
Figure 1.2 - Single Stage Desalter General Process flow
The resulting blended crude does not have a high salt content based on literature,
and therefore only a single stage desalter was used to obtain a class 4 cost estimate. There
are various consultants that offer confidential technologies to use for a desalter design,
however, for this process the dual polarity electrostatic desalter can handle much higher
flow rates than conventional use. The dual polarity electrostatic provides a more
complete dehydration. It is worth noting that the desalter was not simulated in aspen and
that the calculations used to size the desalter to obtain a volume and a cost were based on
Stokes’s law allows us to determine the settling rate based on different mass
transfer parameters of the crud and the water mixture. Figure 1.4 shows the calculated
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Figure 1.4 - Desalter Results
After the crude has been desalted through the single stage design that was
mentioned above, the crude goes through a series of heat exchanger networks called a
pre-heat train, the purpose of the pre-heat train is to use the energy from the atmospheric
tower to pre-heat the cold crude to minimize the total amount of utilities used for the
furnace. The heat exchanger network will be described more in detail later in this report.
The crude is then charged to a crude furnace and heated up to 650 oF to partially vaporize
the crude. Any other temperatures above 650 oF are typically avoided to reduce the
amount of cracking that can occur in the furnace and distillation unit. The vapor includes
all the components that comprise the products, while the liquid is the residue with a small
number of components in the range of gas oil. These components are removed from the
residue by steam stripping at the bottom of the column. Products are withdrawn from the
side of the column and side strippers are used to help controlling the composition of light
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components. In addition, to more effectively remove heat, liquid is extracted at various
points of the column and cooled down to be reinjected at a different position on the
column, the crude tower column setup, column calculated parameters, and product specs
are shown in Figure 1.5, Figure 1.6, and figure 1.7, respectively. The topped crude
leaving the atmospheric tower can still contain significant amount of valuable oils.
Different refineries can use these vacuum oils for the production of lubricating oils. Our
vacuum process will focus on the most common use of gas oil extraction for charge to
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Figure 1.6 - Atmospheric Column Design Specs.
The vacuum feed is also preheated to around 750 oF, which allows the separation
of the light vacuum gas oil (LVGO) and heavy vacuum gas oil (HVGO) from the vacuum
residuum stream. The temperature is also controlled just below where thermal
decomposition begins to occur. Steam is injected into the stripping zone to keep the
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temperature below 700 oF to again prevent further cracking of vacuum gas oil. It is also
that vacuum tower does not have a condenser or side strippers because there is no need to
control the spec of the vacuum products. The vacuum tower column setup, column
calculated parameters, and product specs are shown in Figure 1.8, Figure 1.9, and Figure
2.0, respectively.
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Figure 1.9 - Vacuum Distillation Design Specs
The purpose of the reforming complex is to transform the naphtha feeds from the
CDU into a gasoline blend that meets the requirements set by the EPA specific to the Gulf
Coast Region. These requirements are included in table 1.1. The properties of the naphtha
going into the complex are included in table 1.2. The light naphtha stream reaches 90% of
the target flow, which is 50,000 barrels per day. This stream has a low sulfur content and
can bypass the hydrotreating unit and still meet the gasoline specifications. The light
naphtha is then sent to an isomerization unit to increase its octane rating. the isomerization
unit will operate at around 400 F and 350 psia. The reactor has a platinum catalyst
supported by a gamma alumina base to help the process move more quickly. A hydrogen
to hydrocarbon ratio (H2/HC) of about 4 will be maintained in the reactor to reduce the
The heavy naphtha stream does not meet the required 85,000 barrels per day that is
needed to produce the set gasoline production of 6 million gallons per day. This deficit will
be made up by sending the atmospheric gas oil and vacuum gas oil streams, which add up
to 62,000 barrels per day from the CDU, to a hydrocracking unit to produce lighter
components, such as naphtha, kerosene and diesel. The heavy naphtha from the CDU and
from the hydrocracker are combined and sent to the hydrotreating unit to reduce the sulfur
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content below 10 ppm. A cobalt-molybdenum catalyst will be used for the hydrotreating
unit and the reactor will operate at a temperature of 550 F and a pressure of 500 psia. A
H2/HC ratio of 5 will be maintained in the reactor to prevent hydrocracking and to provide
the necessary hydrogen for the conversion of sulfur into hydrogen sulfide. The heavy
naphtha is then sent to the reformer unit. The Reformer increases the octane rating of the
naphtha to an amount that will allow for economical blending of the octane booster ethanol.
The reformer will operate at a temperature of 915 F and 300 psi. A platinum and tin catalyst
with a gamma alumina base will be used for the reactor. Since this reaction produces
hydrogen it will supply most of the other units needs for hydrogen, but a H2/HC ratio of
around 3 is still needed to prevent hydrocracking and coking. The plug flow diagrams of
Table 1.1 Gasoline Specifications set by the EPa for the Gulf Coast Region
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Table 1.2 Naphtha Feedstock Parameters
17
Figure 2.2 Continuous Catalytic Reformer Plug Flow Diagram
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Heat Exchanger Network and Utility Requirements
varying the quantity and capacities of the respective pumparounds while maintaining
adjusted to compensate for the pumparound heat capacities and adjust the product
specifications towards the required outputs. This is done to maximize the amount of high
temperature heating we get from the pumparounds and minimize the use of our heating
utility.
Our heating capacities, shown visually in “Stream T” of Figure #1. are described
in detail here. Stream 1 corresponding to the atmospheric distillation tower emits 301.3
MMBTU/hr of heat from 159.5°F to 102.0°F. Stream 2, 3 and 4 emit 100 MMBTU/hr,
484.0°F, and 594.5°F to 576.3°F; and correspond to stages 14-15, 19-20, and 24-25
respectively, within the atmospheric distillation tower. Stream 5 relating to the vacuum
distillation tower emits 91.8 MMBTU/hr, and operates from 463.7°F to 382.4°F. Finally,
streams 6 and 7 each emit 100 MMBTU/hr; operate between 518.2°F to 484.0°F, and
648.6°F to 605.4°F; and correspond to the stages of 3-4, and 10-11 respectively in the
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Pinch Analysis
The pinch analysis of the heat exchangers in our process utilized the 7 sources of
heat from both the vacuum and atmospheric tower’s respective pumparounds and
condensers and used them to heat the cold streams. Stream 1 and 5 are the condenser
heat duties of the atmospheric tower and vacuum tower respectively. Streams 2-4 are
associated with the atmospheric tower’s pumparounds from stages 14-15, 19-20, and 24-
25 respectively. Streams 6-7 are the vacuum tower’s pumparounds from stages 3-4, and
10-11 respectively. Finally stream 8 and 9 the cool streams, come from the crude feed
and the desalted crude. Using the heat duties of these streams and their inlet and exit
temperatures from their respective locations we determined the heat duties associated by
section and cumulative heat duties of the tower. This allowed us to determine the pinch
point as depicted in Table 1.3 and visibly expressed in Figure 2.4 and begin construction
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Table 1.3 Pinch Point Analysis (All temperatures are in °F)
21
Figure 2.4 Composite Curve of Crude Unit Heat Integration Network
MUMNE
condensers, were necessary for optimum utilization of heat in our process. One major
concern when constructing the matrix was that of superheated steam, to limit excessive
use of this utility we used our heating utility hps to first heat the crude as much as
possible before using our higher temperature streams from pumparounds to offset the cost
22
of creating and using superheated steam at these higher temperatures. Although our
streams going to the reformer require heating above appropriate temperatures for hps, the
viability of heating the crude outweighed that of heating the streams going to the
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Figure 2.5 Minimum Heat Exchanger Network Diagram (All heat Units are in MMBTU/hr)
For the crude distillation unit, there are two majors towers considered for the
separation. The towers include a distillation tower ran at atmospheric pressure, and a
tower run at vacuum pressure. The atmospheric tower also consists of three side strippers
and four pumparounds. The vacuum tower uses 2 pumparounds. Both towers are
preceded by a furnace for preheating the crude. Using the information from the MUMNE
analysis, 9 heat exchangers are necessary for proper heat integration. A desalter vessel
Using sizing and pricing from CAPCOST, with a CEPCI of 542, the atmospheric
distillation tower was priced at a Bare Module cost of $111 million. The vacuum tower
was also sized and priced via CAPCOST, with a Bare Module cost of $721 million.
Using sizing from hand calculations, the heat exchangers were priced using CAPCOST.
The overall Fixed Capital Investment for the equipment related to the flowsheet was
Operating Costs:
Operating costs of the equipment were considered in the economic analysis of the
expansion. For the equipment that was priced in CAPCOST, the annual operating cost
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was observed to be approximately $1.1 billion. The utilities cost was also measured
according to the energy analysis performed using data from the AspenPlus Simulation.
For the design, the annual Utility Cost was recorded at $297.8 million.
Profitability Analysis:
The crudes selected for the blend, Ebok Heavy and Terengganu Light, were
priced at $38.14/barrel and $70.11/barrel, respectively. Using the blend data from Table
1.0, the blend was priced in Table 1.4 at $46.45/barrel. This yielded a daily cost of $15
million.
Cost per day Barrels per day Barrel Cost Crude Crude
($/barrel) Fraction
25
The Products were priced using Gulf Coast data from EIA, and the product daily pricing
$23,783,755 Total:
A cash flow diagram was performed over a 14 year period, with a discounted rate
of 10%, and an assumed working capital of 20% of Fixed Capital Investment. The tax
rate was assumed at 40%, and the discount rate at 10%. An operating year was assumed
at 8160 hours, or 340 days, yielding a stream factor of 0.93. Table 1.6 shows the
Discounted Cash Flow Diagram. The cash flow analysis on Figure 2.6 shows that the
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Figure 2.6: Cash Flow Diagram.
Permitting
Permit No. 26638 lists the maximum allowable emissions rate for air contaminants
generated by the plant. It lists the lb/hr and TPY (tons per year) concentration as shown in
Table 1.7 These values are under the assumption that the plant will operate 365 days per
year (24 hours per day, 7 days per week, 52 weeks per year) for a total of 8760 hours per
year. Converting the listed lb/hr to TPY and vice versa paints a better picture as to how
much the plant can emit. Converting the listed lb/hr to TPY shows that if the plant were to
operate at the maximum allowable hourly emission rate, then it would exceed the
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maximum allowable yearly rate. Converting the listed TPY to lb/hr calculates a
recommended hourly emission to ensure that the plant stays within regulation. Following
this new lb/hr value is recommended, but it is possible to exceed it as long as the maximum
Reformer Area
The hydrotreater right before the furnace is responsible for removing impurities
from the feedstock, primarily sulfur and nitrogen. The hydrotreater uses catalysts from a
broad class of molybdenum sulfide catalysts. Nitrogen is also removed since it can alter
the metallic properties of the platinum and result in leaching of chloride when in water.
Sulfur can be removed from hydrocarbon streams by reaction with Hydrogen over the
sulfide.
29
The hydrogen sulfide is then removed from the gas stream by washing with an
amine solution. This creates sour water. It is then sent to a Claus process unit in another
part of the plant, where the hydrogen sulfide is converted to elemental sulfur.
For the reformer itself, there are 3 emission points regardless of the type of catalyst
regeneration is used (either semi-regenerative, cyclic, or continuous). They are the initial
depressurization and purge vent, the coke burn pressure control vent, and the final catalyst
purge vent.
The initial depressurization and purge cycle removes hydrocarbons from the
catalyst prior to the catalysts regeneration for the reformer. The vent gases from this initial
purge may have high levels of organic Hazardous Air Pollutants (HAP) such as benzene
and toluene.
The coke burn cycle is usually the largest emission source for the overall catalyst
regeneration cycle. The primary HAP’s are hydrochloric acid and chlorine. Caustic
injection or caustic scrubbing may be used in the flue gas recirculation line to remove HCl.
These removal techniques are implemented both protect the process equipment and to
The final purge and reduction cycle removes oxygen and any remaining
chlorination agent from the system and reduces the catalyst prior to returning reformer
catalyst to the reforming process or bringing the unit back online. The vent gases may have
low levels of the chlorinating agent and residual HCl or Cl2 remaining in the system. This
30
vent is typically vented to the atmosphere or the refinery’s fuel gas system depending on
the oxygen content of the vent gases or directly vented to a combustion device.
The TCEQ has placed NOx emissions specifications for process heaters for the
Beaumont-Port Arthur area that will be applicable to the furnace. It can be found under
Texas Administrative Code §117.105(3)(b)(2). This section of the codes lists specific NOx
emissions rate for various types of process heaters. The Texas Administrative Code lists
the NOx maximum emissions rate for a variety of process heaters depending on either the
In addition, the EPA also has its own set of regulations for catalytic reforming
units. Code §63.1566 and §63.1567, or MACT UUU, specify the regulations for catalytic
reforming units for organic and inorganic HAPs respectively. These codes reference
certain tables that are also a part of the code. The most often referenced tables are Table
15 to subpart UUU of Part 63 and Table 16 to Subpart UUU of Part 63 for §63.1566 and
Table 22 to subpart UUU of Part 63 Table 23 to subpart UUU of Part 63 and Table 25 to
Air emissions from atmospheric distillation include heater stack gas (CO, SOx,
NOx, hydrocarbons and particulates), vents and fugitive emissions (hydrocarbons). Air
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heater stack gas (CO, SOx, NOx, hydrocarbons and particulates), vents and fugitive
emissions (hydrocarbons).
pollution. The fractionator’s vacuum system is the main source of atmospheric emissions
from vacuum distillation operations. The gases removed from the vacuum still by the
vacuum system are passed through a barometric or surface condenser. Here, steam and
some of the vapors are condensed. Hydrocarbons which do not condense within such a
final water temperature obtained in the condenser; the lower the temperature within the
Wastewater from vacuum distillation operations comes from three major sources.
The first is water along with the noncondensables present within the crude that is drawn
from the vacuum column by the steam jets to the barometric or surface condensers. In the
condenser, water separates from the condensed hydrocarbons and can be discharged to
the wastewater system. The hydrocarbon liquid is usually sent to a slop (oily water) tank
or recycled to the crude oil desalter. The water phase is a major source of sulfides,
The second source of aqueous waste is the very stable oil emulsions formed
within steam ejectors or vacuum jets and barometric condensers used to create the
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barometric condensers are replaced with surface condensers. Steam stripping to separate
EPA code 40 CFR 419.42 lists the effluent limitations representing the degree of
effluent reduction attainable by the application of the best practicable control technology
currently available for any existing point source except as provided in 40 CFR 125.30
through 125.32 There are two values, one is the maximum limit for any 1 day and the
other is the average of daily values for 30 consecutive days. These values are presented in
metric (kilograms per 1000 m3 of feedstock) and English units (pounds per 1000 bbl of
feedstock). For example, the maximum daily average of sulfides present in the effluent is
0.118 pounds per 1000 bbl of feedstock and the thirty-day average of sulfides present in
Safety concerns
The most significant safety hazards occur during the operational phase of a
petroleum refining facility include chemical release, process safety, fires, and explosions.
Implementing good safety practices not only saves money, but it ensures the safety of
Chemical release is the most reported incident and is always occurring. Upon
conducting event tree analysis, chemical release could be either contained or disposed of
safely or it would lead to catastrophic fires or explosions. U.S. Chemical Safety Board
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(CSB) has reviewed and updated 125 incidents reported in 2012 in the United States.
Figure 2.7 depicts the classifications of these incidents by type of the event. It can be seen
that chemical release has the most number of occurrence of 77 incidents. Fires come next
with 37 incidents, which might be caused by chemical release. Other events like
overpressure, tank failure, hot work, and explosion have less chances of occurrence with
Since market demand changes over the time, flowrates of feed and products
change as well. It is essential to maintain that change within the designed operating
conditions ranges to ensure the safety of the process and equipment. Routine inspection
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for equipment is always scheduled and carried on along the year. Some equipment must
be checked weekly whereas others are checked monthly or on any other basis.
also important to have robust control system that works smart and fast enough to keep up
designing a process, to install safety equipment such as check valves, relief systems, etc.
Relief systems are the last line of defense that designed to prevent damaging the
equipment.
Fire and explosion are the principal hazards at refineries for many reasons. One
reason is that because of processing of products with low flash points. Another reason is
because heaters and exchangers can be sources of ignition. Some hydrocarbons ignite
when contact with oxygen in air and don’t need a source of ignition. Moreover, crude oil
contain sulfur which can cause crack in steel due to corrosion and leads to leakage.
Two major incidents, Tesoro Refinery explosion and Chevron Richmond Refinery
fire are considered while designing this project. These incidents found to be good study
cases specially that there are many sources of information on their causes and effects.
The Tesoro Refinery explosion is an example that directly relates to this situation. High
35
temperature hydrogen attack (HTHA) caused the nearly 40-year-old heat exchanger to
rupture and a large fire resulted. The pipe failure at Richmond, and the vessel failure at
Tesoro both could have been avoided with proper inspection, or with a material of
construction that is more resistant to sulfidation corrosion and HTHA, such as 316 stainless
steel. This steel is expensive however, and only having vessels which are most prone to the
conditions discussed above should be considered for construction with 316 stainless steel
naphtha isomerization unit, and a heavy naphtha reformer unit. The biggest risk to
personnel and equipment is the event of a chemical release. This complex is prone to
corrosion due to the presence of sulfur, especially before the hydrotreating unit’s reactor.
Corrosion if left unchecked can weaken piping and vessels to the point of failure. An
example of this type of corrosion, called sulfidation corrosion, can be seen at the Chevron
Richmond Refinery fire that occurred on August 6, 2012. This example involves the
formation of a vapor cloud consisting of light gas oil which resulted in a massive fire.
However, if the pipe had been filled with a more volatile component, such as naphtha, then
a vapor cloud explosion could have resulted. All the units in the NPC involve continuous
flows of hydrogen gas. The NPC has units that are operating at high temperatures and
pressures.
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Upon reviewing past incidents and applying engineering knowledge, it is highly
avoid the discussed incidents, always to inspect the equipment, pipes thoroughly. In
addition, choosing a material of construction for each process that suites its operating
history.
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APPENDIX A. CRUDE ASSAYS
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APPENDIX B. Aspen Process Flow Diagram
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Reference List
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Kaes, G. L. (2000). Refinery process modeling: a practical guide to steady state modeling of
petroleum processes (Using commercial simulators). Athens, GA: Athens Print. Co.
PART 80—REGULATION OF FUELS AND FUEL ADDITIVES. (n.d.). Retrieved May 01,
2017, from https://www.ecfr.gov/cgi-bin/text-
idx?SID=fecd1c93dc121c4b988dc16ae53a7d26&node=40%3A17.0.1.1.9&rgn=div5
Turton, R., Bailie, R. C., & Whiting, W. B. (2015). Analysis, synthesis, and design of chemical
processes. Upper Saddle River, NJ: Pearson Education International.
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